Dodicor 2725 NF MSDS

Safety Data Sheet in accordance with Regulation (EC) No
1907/2006
DODICOR 2725 NF Page 1
Substance key: 000000212085 Revision Date: 16.11.2017

Version : 4 - 2 / EU Date of printing : 10.10.2019
1. Identification of the substance/preparation and of the company/undertaking
Trade name
DODICOR 2725 NF
Use of the substance/preparation.
Industry sector : Mineral Oil
Type of use : Corrosion inhibitor for the petroleum industry
Identification of the company
Clariant Produkte (Deutschland) GmbH
65926 Frankfurt am Main

Telephone no. : +49 69 305 18000
Information about the substance/preparation
Div. Functional Chemicals/PRODUCT SAFETY
+49 (0)6196 757 6228/ 6139/ 6227
e-mail: [email protected]
Emergency telephone number : 00800-5121 5121 (24 h)
2. Hazards identification
Causes burns.
Harmful by inhalation, in contact with skin and if swallowed.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
3. Composition/information on ingredients
Chemical characterization
Preparation of an Alkinol containing quaternary Ammonium compound with nonionic
surfactant
Hazardous ingredients
Prop-2-yn-1-ol
Concentration : 1-5%
CAS number : 107-19-7
EINECS number : 203-471-2
Hazard symbols T N
R phrases 10 23/24/25 34 51/53
Naphthenic acid imidazoline benzylquat
Concentration : 10 - 20 %
CAS number : 73049-47-5
Hazard symbols C
R phrases 34
1907/2006

Diethylene glycol
Hazard symbols Xn
R phrases 22
2-Butoxy ethanol
Hazard symbols Xn
R phrases 20/21/22 36/38
C11-Oxoalcohol,ethoxylated
CAS number : 127036-24-2
Hazard symbols Xi
R phrases 41
The text of the R-phrases is shown in section 16.
4. First aid measures

General information
Remove soiled or soaked clothing immediately
In case of accident or if you feel unwell, seek medical advice immediately.
After inhalation
When inhaled remove to fresh air and seek medical aid.
After contact with skin
In case of contact with skin wash off immediately with soap and water
After contact with eyes
In case of contact with eyes rinse thoroughly with water
After ingestion
When swallowed seek medical aid immediately and show the physician the packaging or the
label of the packaging.
5. Fire-fighting measures
Suitable extinguishing media
water spray jet
alcohol-resistant foam
carbon dioxide
dry powder
Special hazards from the substance itself, its combustion products or from its vapours
In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Nitrous gases (NOx)
Special protective equipment for firefighting
Use self-contained breathing apparatus
1907/2006

6. Accidental release measures

Personal precautions
Ensure adequate ventilation.
Use personal protective clothing.
Keep away sources of ignition.
Environmental precautions
Do not allow to enter drains or waterways
Methods for cleaning up/taking up
Take up mechanically. Dilute remainder with water and take up with absorbent material (eg
sawdust, sand, universal binder)
7. Handling and storage

Advice on safe handling
Open and handle container with care.
Ensure adequate ventilation.
Advice on protection against fire and explosion
Keep away from sources of ignition - refrain from smoking.
Further information on storage conditions
Keep container tightly closed
8. Exposure controls / personal protection

Occupational exposure controls
Exposure limit values
2-BUTOXYETHANOL
EU. Indicative Exposure and Directives relating to the protection of risks related to work
exposure to chemical, physical, and biological agents.
EU Exposure Limit Values Data
Revision : 07 2000
Time Weighted Average (TWA):
Values: 98 mg/m3 20 ppm
2-BUTOXYETHANOL
EU. Indicative Exposure and Directives relating to the protection of risks related to work
exposure to chemical, physical, and biological agents.
EU Exposure Limit Values Data
Revision : 07 2000
Skin designation:
Can be absorbed through the skin.
General protective measures

Avoid contact with eyes and skin
Do not inhale vapours
1907/2006

Hygiene measures
Observe the usual precautions when handling chemicals.
Respiratory protection : Use respiratory protection in case of insufficient exhaust
ventilation or prolonged exposure
Full mask, filter A
Full mask to standard DIN EN 136
Filter class 2
The use of filter apparatus presupposes that the environment
atmosphere contains at least 17% oxygen by volume, and
does not exceed the maximum gas concentration, usually
0.5% by volume. Relevant guidelines to be considered
include EN 136/141/143/371/372 as well as other national
regulations.
Observe applicable relevant national regulations,(e.g. TRGS
900 and BGR 190 in Germany).Take note of the
recommendedations regarding the duration for which
Respiratory Protective Equipment may be worn, according to
chapter 19 Abs. 5 GefStoffV in conjunction with the rules of
wearing such equipment.
Hand protection : For long-term exposure:
Butyl rubber gloves
Minimum breakthrough time / gloves : 480 min
Minimum thickness / gloves 0,7 mm
For short-term exposure (splash protection):

Nitrile rubber gloves.
Minimum breakthrough time / gloves : 30 min
Minimum thickness / gloves 0,4 mm
These types of protective gloves are offered by various

manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.
Eye protection : Depending on the risk, wear sufficient eye protection (safety
glasses with side protection or goggles, and if necessary, face
shield.)
Body protection : protective clothing
9. Physical and chemical properties

Form : Liquid
Colour : brownish yellow
Odour : slight, original odour
Pourpoint : approx. -20 °C
Method : DIN/ISO 3016
1907/2006

Starts to boil : > 100 °C

Method : DIN 51751
Flash point : approx. 92 °C
Method : EN 22719 (closed cup)
Ignition temperature : not tested.
Oxidizing properties : Not applicable
Self-ignition temperature : Not applicable
Flammability
Lower explosion limit : not tested.
Upper explosion limit : not tested.
Combustion number : Not applicable
Evaporation rate : Not applicable
Vapour pressure : approx. 1 mbar (20 °C)
Method : calculated
Density : approx. 1,01 g/cm3 (20 °C)

Method : DIN EN ISO 15212-1
Bulk density : Not applicable

Vapour density in relation to Not applicable
air :
Solubility in water : (20 °C)
soluble
Soluble in ... : fat
not tested.
pH value : approx. 4 (20 °C, 10 g/l)
Octanol/water partition not tested.
coefficient (log Pow) :
Viscosity (dynamic) : approx. 35 mPa.s (20 °C)
Method : DIN 53015
Viscosity (kinematic) : not tested.
10. Stability and reactivity

Thermal decomposition : 240 °C
Method : DTA
Hazardous reactions
Uncleaned empty vessels may contain product gases which can form explosive mixtures with
air.
1907/2006

11. Toxicological information

Acute oral toxicity : LD50 > 2.000 mg/kg (rat)
Method : OECD 401
Source : Analogy
Acute inhalation toxicity : not tested.
Acute dermal toxicity : not tested.
Irritant effect on skin : not tested.
Irritant effect on eyes : not tested.

Sensitization : not tested.
Mutagenicity : not tested.
Remarks
The product was classified on the basis of the calculation procedure of the Dangerous
Preparations Directive (1999/45/EC).
12. Ecological information

Biodegradability : > 80 %
Method : OECD 302 B
Source : Analogy
Fish toxicity : LC50 10 - 100 mg/l (96 h, golden orfe)

Source : Analogy
Bacteria toxicity : not tested.
Remarks
The product was classified on the basis of the calculation procedure of the Dangerous
Preparations Directive (1999/45/EC).
13. Disposal considerations

Product
In accordance with local authority regulations, take to special waste incineration plant
14. Transport information

1907/2006

ADR
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s.
Class: 8
Packing group: II
UN no. UN 3265
Primary risk: 8
Hazard no. : 80
Remarks Shipment permitted
Hazard inducer(s): NAPHTHENIC ACID IMIDAZOLINE BENZYL QUAT
Propargyl Alcohol
ADNR
Class: 8
Packing group: II
UN no. UN 3265
Primary risk: 8
Propargyl Alcohol
RID
Class: 8
Packing group: II
UN no. UN 3265
Primary risk: 8
Hazard no. : 80
Propargyl Alcohol
IATA
Class: 8
Packing group: II
UN/ID number: UN 3265
Primary risk: 8
Propargyl Alcohol
IMDG
Class: 8
Packing group: II
UN no. UN 3265
Primary risk: 8
Propargyl Alcohol
EmS : F-A S-B
1907/2006

15. Regulatory information

Labelling in accordance with EC-Directives
hazard warning labelling compulsory
Classification according to the calculation procedure of the Dangerous Preparations Directive
(1999/45/EC).
Hazard symbols
C Corrosive
Hazardous component(s) to be indicated on label
Prop-2-yn-1-ol
Naphthenic acid imidazoline benzylquat
Diethylene glycol
2-Butoxy ethanol
C11-Oxoalcohol,ethoxylated
R phrases
34 Causes burns.
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
28.2 After contact with skin, wash immediately with water and soap.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
61 Avoid release to the environment. Refer to special instructions/Safety data
sheets.
Chemical Safety Assessment
No Chemical Safety Assessment (CSA) is yet available for the substance, or for the
ingredients of the preparation, which constitute(s) this product.
16. Other information

Text of the R-phrases assigned to the ingredients/components mentioned in section
3:
10 Flammable.
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
22 Harmful if swallowed.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
34 Causes burns.
36/38 Irritating to eyes and skin.
41 Risk of serious damage to eyes.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Decimal notation: "Thousands" places are identified with a dot (example: 2.000 mg/kg
1907/2006

means "two thousand mg/kg"). Decimal places are identified with a comma (example: 1,35
g/cm3).
The data are based on the current state of our knowledge, and are intended to describe the
product with regard to the requirements of safety. The data should not be taken to imply
any guarantee of a particular or general specification. It is the responsibility of the user of
the product to ensure to his satisfaction that the product is suitable for the intended purpose
and method of use. We do not accept responsibility for any harm caused by the use of this
information. In all cases, our general conditions of sale apply.

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Safety Data Sheet in accordance with Regulation (EC) No

Substance key: 000000212085 Revision Date: 16.11.2017

1. Identification of the substance/preparation and of the company/undertaking

65926 Frankfurt am Main

Substance key: 000000212085 Revision Date: 16.11.2017

4. First aid measures

Substance key: 000000212085 Revision Date: 16.11.2017

6. Accidental release measures

7. Handling and storage

8. Exposure controls / personal protection

General protective measures

Substance key: 000000212085 Revision Date: 16.11.2017

For short-term exposure (splash protection):

These types of protective gloves are offered by various

9. Physical and chemical properties

Substance key: 000000212085 Revision Date: 16.11.2017

Starts to boil : > 100 °C

Density : approx. 1,01 g/cm3 (20 °C)

Bulk density : Not applicable

Viscosity (kinematic) : not tested.

10. Stability and reactivity

Substance key: 000000212085 Revision Date: 16.11.2017

11. Toxicological information

Acute inhalation toxicity : not tested.

Acute dermal toxicity : not tested.

Irritant effect on skin : not tested.

Irritant effect on eyes : not tested.

12. Ecological information

Fish toxicity : LC50 10 - 100 mg/l (96 h, golden orfe)

Bacteria toxicity : not tested.

13. Disposal considerations

14. Transport information

Substance key: 000000212085 Revision Date: 16.11.2017

Substance key: 000000212085 Revision Date: 16.11.2017

15. Regulatory information

16. Other information

Substance key: 000000212085 Revision Date: 16.11.2017

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