«) SOLUTIONS ASSIGNMENT Topic : HENRy’s LAW & ¢ Raoults LAWHenry's LAW Q41. State Henry’s law and mention two of its important applications. (Comptt. All India 2012) Q2. Explain why aquatic species are more comfortable in cold water rather than in warm water. a3 N, gas is bubbled through water at 293 K, how many millimoles of N,, gas would dissolve in 1 litre of water? Assume that N, exerts a partial pressure of 0.987 bar. Given that Henry's law constant for N, at 293 K is. 76.48 kbar. Q4. Why do gases nearly always tend to be less soluble in liquids as the temperature is raised?Qs- (i) Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two gases will have the higher value of Ky (Henry’s constant) and why? 6 . HLS. a toxic gas with rotten egg like smell, is used for the qualitative analysis. If the solubility of H,S in water at STP is 0.195 m, calculate Henry's law constant. A Henry's law constant for CO, in water is 1.67x10® Pa at 298 K. Calculate + the quantity of CO, in 500 mL of soda water when packed under 2.5 atm CO, pressure at 298 K.| pressure of ethane over a saturated * solution containing 6.56 x 107? g of ethane is 1 bar. If the solution were to contain 5.0 x 107 g of ethane, then what will be the partial pressure of the gas?Q\o 2.39 ‘The air is a mixture of a number of gases. The major components are oxygen and nitrogen with approximate proportion of 20% is to 79% by volume at 298 K. The water is in equilibrium with air at a pressure of 10 atm. At 298 K if the Henry's law constants for oxygen and nitrogen at 298 Kare 3.30 10” mm and 6.51 10” mm respectively, calculate the composition of these gases in water.Q\} Derive expression for Raoult’s law when the solute is — non-volatile. 2. Vapour pressure of chloroform (CHCL) and dichloromethane (CH,C1,) Example 2.5 Q at 298 K are 200 mm Hg and 415 mm Hg respectively. Calculate the vapour pressure of the solution prepared by mixing 25.5 g of CHCl, and 40 g of CH,Cl, at 298 K and, (i) mole fractions of each component in vapour phase SalitinwQgi3- 2.38 Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. Calculate the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of toluene. ql 2.8 The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K . Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg, Also find the composition of the vapour phase.under 760 mm Hg. 100 g of liquid A (molar mass 140 g mol”) was dissolved in 1000 g of liquid B (molar mass 180 g mol’). The vapour pressure of pure liquid B was found to be 500 torr. Calculate the vapour pressure of pure liquid A and its vapour pressure in the solution if the total vapour pressure of the solution is 475 Torr.devel 14 (see A) 08 013, a1F- a2r dvd 42 Gee B) 93, BIO