PN20210323687601

Material Safety Data Sheet

For
Ningbo Chiyang Electronic Co., Ltd.
No. 140 The 21th building Innovation 128 Park, No. 818 Qiming Rd, Ningbo, China

And for their product

Manganese Lithium Battery

Model/type reference ........................ : CY-LB01

Nominal Voltage ............................... : 9V

Rated Capacity ................................. : 2000mAh (18Wh)

Version number ................................ : V1.0

Revision date .................................... : N/A

Laboratory .......................................: Shenzhen NTEK Testing Technology Co., Ltd.

Address ...........................................: 1/F, Building C, Fenda Science Park, Sanwei Community, Xixiang

Street, Bao’an District, Shenzhen 518126 P. R. China

Compiled by (name+ signature) ..: Jemery Li

Approved by (+ signature) ...........: Mumu Huang

Shenzhen NTEK Testing Technology Co., Ltd.

Address: 1/F, Building C, Fenda Science Park, Sanwei Community, Xixiang Street, Bao’an District, Shenzhen 518126 P.R. China
Tel: +86(0)-755-3699 5529 http://www.ntek.org.cn
 PN20210323687601

Section 1- Chemical Product and Company Identification

Product Identification: Manganese Lithium Battery

Model No.: CY-LB01
Manufacturer’s / Supplier Name: Ningbo Chiyang Electronic Co., Ltd.
Address: No. 140 The 21th building Innovation 128 Park, No. 818 Qiming Rd, Ningbo, China
Telephone number of the supplier: +86-13282287117
Emergency Telephone No. (24h): +86-13282287117
Fax: None
E-mail address: [email protected]
Preparation Date: 2021-03-24
Effective date: 2021-01-01 ~ 2021-12-31
This MSDS was prepared by Shenzhen NTEK Testing Technology Co., Ltd.
Item Number: PN20210323687601
Referenced documents: ISO 11014:2009 Safety data sheet for chemical products

Section 2 – Hazards Identification

Preparation Not dangerous with normal use. Do not dismantle, open or shred the Manganese
hazards and
Lithium Battery ingredients contained within or their ingredients products could be
classification
harmful.
Apperance, Solid object with no odor, no color.
Color, and
Odor
Primary These chemicals are contained in a sealed enclosure. Risk of exposure occurs
Route(s) of
only if the cell is mechanically, thermally or electrically abused to the point of
Exposure
compromising the enclosure. If this occurs, exposure to the electrolyte solution
contained within can occur by Inhalation, Ingestion, Eye contact and Skin contact
Potential ACUTE (short term): see Section 8 for exposure controls In the event that this
Health
battery has been ruptured, the electrolyte solution contained within the battery
Effects:
would be corrosive and can cause burns.
Inhalation: Inhalation of materials from a sealed battery is not an expected route of
exposure. Vapors or mists from a ruptured battery may cause respiratory irritation.
Ingestion: Swallowing of materials from a sealed battery is not an expected route
of exposure. Swallowing the contents of an open battery can cause serious
chemical burns of mouth, esophagus, and gastrointestinal tract.
Skin: Contact between the battery and skin will not cause any harm. Skin contact
with contents of an open battery can cause severe irritation or burns to the skin.
Eye: Contact between the battery and the eye will not cause any harm. Eye contact
with contents of an open battery can cause severe irritation or burns to the eye.
CHRONIC (long term): see Section 11 for additional toxicological data

Page 2 of 10
 PN20210323687601

Medical Not applicable

Conditions
Aggravated by
Exposure
Reported as Not applicable
carcinogen

Section 3 – Composition/Information on Ingredients

Manganese Lithium Battery is a mixture.

Hazardous Ingredients Concentration or CAS Number

(Chemical Name) concentration ranges (%)
Lithium 4.45 7439-93-2

Manganese dioxide 68.77 1313-13-9

Carbon (C) 4.53 7440-44-0

Propylene carbonate 9.05 108-32-7

Dimethyl oxide 3.26 157621-61-9

DOL 7.94 N/A

LiCIO4 2.00 N/A

Labeling according to EC directives.

No symbol and risk phrase are required.
Note: CAS number is Chemical Abstract Service Registry Number.
N/A=Not applicable.

Section 4 – First-aid Measures

Inhalation If contents of an opened battery are inhaled, remove source of contamination or

move victim to fresh air. Obtain medical advice.
Skin contact If skin contact with contents of an open battery occurs, as quickly as possible
remove contaminated clothing, shoes and leather goods. Immediately flush with
lukewarm, gently flowing water for at least 30 minutes. If irritation or pain persists,
seek medical attention. Completely decontaminate clothing, shoes and leather
goods before reuse or discard.
Eye contact If eye contact with contents of an open battery occurs, immediately flush the
contaminated eye(s) with lukewarm, gently flowing water for at least 30 minutes
while holding the eyelids open. Neutral saline solution may be used as soon as it is

Page 3 of 10
 PN20210323687601

available. If necessary, continue flushing during transport to emergency care

facility. Take care not to rinse contaminated water into the unaffected eye or onto
face. Quickly transport victim to an emergency care facility.
Ingestion If ingestion of contents of an open battery occurs, never give anything by mouth if
victim is rapidly losing consciousness, or is unconscious or convulsing. Have victim
rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim
drink 60 to 240 mL (2-8 oz.) of water. If vomiting occurs naturally, have victim lean
forward to reduce risk of aspiration. Have victim rinse mouth with water again.
Quickly transport victim to an emergency care facility.

Section 5 – Fire-fighting Measures

Flammable In the event that this battery has been ruptured, the electrolyte solution contain
Properties within the battery would be flammable. Like any sealed container, battery cells may
rupture when exposed to excessive heat; this could result in the release of
flammable or corrosive materials.

Suitable
extinguishing Use extinguishing media suitable for the materials that are burning.
Media
Unsuitable
extinguishing Not available
Media
Explosion Sensitivity to Mechanical Impact: This may result in rupture in extreme cases
Data Sensitivity to Static Discharge: Not Applicable
Specific Fires involving Manganese Lithium Battery are controlled with water. When water is
Hazards used, however, hydrogen gas may evolve. In a confined space, hydrogen gas can
arising from form an explosive mixture. In this situation, smothering agents are recommended
the chemical to extinguish the fire
Protective
As for any fire, evacuate the area and fight the fire from a safe distance. Wear a
Equipment
pressure-demand, self-contained breathing apparatus and full protective gear.
and
Fight fire from a protected location or a safe distance. Use NIOSH/MSHA approved
precautions
full-face self-contained breathing apparatus (SCBA) with full protective gear.
for firefighters
NFPA Health: 0 Flammability: 0 Instability: 0

Section 6 – Accidental Release Measures

Personal Precautions, protective equipment, and Restrict access to area until completion of

Page 4 of 10
 PN20210323687601

emergency procedures clean-up. Do not touch the spilled material. Wear

adequate personal protective equipment as
indicated in Section 8.
Environmental Precautions Prevent material from contaminating soil and
from entering sewers or waterways.
Methods and materials for Containment Stop the leak if safe to do so. Contain the spilled
liquid with dry sand or earth. Clean up spills
immediately.
Methods and materials for cleaning up Absorb spilled material with an inert absorbent
(dry sand or earth). Scoop contaminated
absorbent into an acceptable waste container.
Collect all contaminated absorbent and dispose
of according to directions in Section 13. Scrub
the area with detergent and water; collect all
contaminated wash water for proper disposal.

Section 7 – Handling and Storage

Handling Don’t handle Manganese Lithium Battery with

metalwork. Do not open, dissemble, crush or
burn battery. Ensure good ventilation/
exhaustion at the workplace.
Prevent formation of dust.
Information about protection against explosions
and fires: Keep ignition sources away- Do not
smoke.
Storage If the Manganese Lithium Battery is subject to
storage for such a long term as more than 3
months, it is recommended to recharge the
Manganese Lithium Battery periodically.
3 months: -10°C~+40°C, 45 to 85%RH
And recommended at 0°C~+35°C for long period
storage.
The capacity recovery rate in the delivery state
(50% capacity of fully charged) after storage is
assumed to be 80% or more.
Do not store Manganese Lithium Battery
haphazardly in a box or drawer where they may
short-circuit each other or be short-circuited by
other metal objects.
Keep out of reach of children.
Do not expose Manganese Lithium Battery to
heat or fire. Avoid storage in direct sunlight.
Do not store together with oxidizing and acidic
materials.

Page 5 of 10
 PN20210323687601

Section 8 – Exposure Controls and Personal Protection

Engineering Controls Use local exhaust ventilation or other

engineering controls to control sources of dust,
mist, fumes and vapor.
Keep away from heat and open flame. Store in a
cool, dry place.
Personal Protective Equipment Respiratory Protection: Not necessary under
normal conditions.
Skin and body Protection: Not necessary
under normal conditions, Wear neoprene or
nitrile rubber gloves if handling an open or
leaking battery.
Hand protection: Wear neoprene or natural
rubber material gloves if handling an open or
leaking battery.
Eye Protection: Not necessary under normal
conditions, Wear safety glasses if handling an
open or leaking battery.
Other Protective Equipment Have a safety shower and eye wash fountain
readily available in the immediate work area.
Hygiene Measures Do not eat, drink, or smoke in work area.
Maintain good housekeeping.

Section 9 - Physical and Chemical Properties

Form: Solid
Physical
Color: Yellow
State
Odor: Odorless

Change in condition:

pH, with indication of the concentration Not applicable

Melting point/freezing point Not available.

Boiling Point, initial boiling point and Boiling
Not available.
range:
Flash Point Not available.

Upper/lower flammability or explosive limits Not available.

Vapor Pressure: Not applicable

Page 6 of 10
 PN20210323687601

Vapor Density: (Air = 1) Not applicable

Density/relative density Not available.

Solubility in Water: Insoluble

n-octanol/water partition coefficient Not available.

Auto-ignition temperature 130°C

Decomposition temperature Not available.

Odout threshold Not available.

Evaporation rate Not available.

Flammability (soil, gas) Not available.

Viscosity Not applicable

Section 10 - Stability and Reactivity

Stability The product is stable under normal conditions.

Conditions to Avoid (e.g. static discharge, shock Do not subject Manganese Lithium Battery to
mechanical shock.
or vibration)
Vibration encountered during transportation
does not cause leakage, fire or explosion.
Do not disassemble, crush, short or install with
incorrect polarity. Avoid mechanical or electrical
abuse.
Incompatible Materials Not Available

Hazardous Decomposition Products This material may release toxic fumes if burned
or exposed to fire
Possibility of Hazardous Reaction Not Available

Page 7 of 10
 PN20210323687601

Section 11 - Toxicological Information

Irritation Risk of irritation occurs only if the cell is

mechanically, thermally or electrically abused to
the point of compromising the enclosure. If this
occurs, irritation to the skin, eyes and respiratory
tract may occur.
Sensitization Not Available

Neurological Effects Not Available

Teratogenicity Not Available

Reproductive Toxicity Not Available

Mutagenicity (Genetic Effects) Not Available

Toxicologically Synergistic Materials Not Available

Section 12 - Ecological Information

General note: Water hazard class 1(Self-assessment): slightly

hazardous for water.
Do not allow undiluted product or large quantities
of it to reach ground water, water course or
sewage system.
Anticipated behavior of a chemical product in Not Available
environment/possible environmental
impace/ecotoxicity
Mobility in soil Not Available

Persistence and Degradability Not Available

Bioaccumulation potential Not Available

Other Adverse Effects Not Available

Page 8 of 10
 PN20210323687601

Section 13 – Disposal Considerations

Product disposal recommendation: Observe local, state and federal laws and regulations.
Packaging disposal recommendation: Be aware discarded batteries may cause fire, tape the battery
terminals to insulate them. Don’t disassembly the battery. Completely discharge containers (no tear
drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local,
state and federal laws and regulations.

Section 14 – Transport Information

The Manganese Lithium Battery (CY-LB01) had passed the UN 38.3 test and is classified as
non-dangerous goods and also complies with the UN Recommendations on the Transport of
Dangerous Goods; IATA Dangerous Goods regulations, and applicable U.S. DOT regulations for the
safe transport of Manganese Lithium Battery.
The Manganese Lithium Battery is transported according to the PACKING INSTRUCTION 966
Section Ⅱof IATA DGR 62nd edition (Proper shipping name and UN ID number: LITHIUM ION
BATTERIES PACKED WITH EQUIPMENT, UN No.: UN3481).
However, the Manganese Lithium Battery may also be transported according to the PACKING
INSTRUCTION 965 Section ⅠB of IATA DGR 62nd edition (Proper shipping name and UN ID
number: LITHIUM ION BATTERIES, UN No.: UN3480) or PACKING INSTRUCTION 967 Section Ⅱ
of IATA DGR 62nd edition (Proper shipping name and UN ID number: LITHIUM ION BATTERIES
CONTAINED IN EQUIPMENT, UN No.: UN3481).
More information concerning shipping, testing, marking and packaging can be obtained from
label master at http://www.labelmaster.com/.
Each package must be labeled with a Lithium Battery handling label.
Li-ion batteries can be treated as “Non-dangerous goods” under the United Nations
Recommendations on the Transport of Dangerous Goods, Special Provision 188, provided that
packaging is strong and prevent the products from short-circuit.
With regard to transport, the following regulations are cited and considered:
- The International Civil Aviation Organization (ICAO) Technical Instructions (2021-2022 edition).
- The International Air transport Association (IATA) Dangerous Goods Regulations (62nd edition).
- The International Maritime Dangerous Goods (IMDG) Code (Amdt. 39-18).
- The US Hazardous Materials Regulation (HMR) pursuant to a final rule issued by RSPA
- The Office of Hazardous Materials Safety within the US Department of Transportations’ (DOT)
Research and Special Programs Administration (RSPA)

Page 9 of 10
 PN20210323687601

Section 15 - Regulatory Information

OSHA hazard communication standard (29 CFR 1910.1200)

Hazardous ∨ Non-hazardous

Section 16 - Other Information

The information above is believed to be accurate and represents the best information currently
available to us. However, NTEK makes no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability resulting from its use.
Users should make their own investigations to determine the suitability of the information for their
particular purposes. Although reasonable precautions have been taken in the preparation of the data
contained herein, it is offered solely for your information, consideration and investigation. This
material safety data sheet provides guidelines for the safe handling and use of this product; it does
not and cannot advise on all possible situations, therefore, your specific use of this product should
be evaluated to determine if additional precautions are required.
The data/information contained herein has been reviewed and approved for general release on
the basis that this document contains no export controlled information.

****************** End of MSDS ******************

Page 10 of 10