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Answer Key (Isomerism)

The document contains examples and questions related to structural isomerism, conformational isomerism, geometrical isomerism, and optical isomerism. It includes diagrams of structural formulas and asks students to identify different types of isomers, determine number of isomers, and specify stereochemistry.

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14 views6 pages

Answer Key (Isomerism)

The document contains examples and questions related to structural isomerism, conformational isomerism, geometrical isomerism, and optical isomerism. It includes diagrams of structural formulas and asks students to identify different types of isomers, determine number of isomers, and specify stereochemistry.

Uploaded by

vatsalkalra1710
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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EXERCISE - 1 [A]

Structural Isomerism
Part - A

1. B 2. D 3. D 4. D 5. D 6. D 7. B

8. A 9. D 10. D 11. D 12. A 13. C 14. D

15. A 16. B 17. A 18. C 19. B, C 20. D 21. A

22. A, C, D 23. A 24. A, C, D 25. B 26. A, B 27. C 28. B

29. B 30. B 31. D 32. D

Part - B
-
1. (a) (b) (c) (d)
O
|
H

2. (a) Tautomers (b) Resonating pairs (c) Tautomers (d) Tautomers (e) Tautomers

O
O
3. (a) , , (b)
H
CH3
CH 3

CH3
|
(c) CH3  C  C  COOEt (d) CH2  C  C  CH2
| | |
OH OH OH

(e) CH2 = C = N – H (f) CH2  N  OH



O
(g) CH2  CH  CH  N  OH (h) CH3 – CH2 – C  N

O

4.

5. (a) 2; (b) 2; (c) 1; (d) 1; (e) 1 6. (a)2; (b) 2; (c) 2; (d) 2; (e) 2

7. (a) 1; (b)1; (c) 2; (d)1; (e) 2; (f) 1; (g) 1 8. (a) 2; (b) 2; (c) 2; (d) 1; (e) 2

9. (a) 3>1>2; (b) 4>2>1>3; (c) 4>1>3>2; (d) 1>3>4>2; (e) 3>2>4>1

10. 3>1>2
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EXERCISE - 1 [B]
Confonmational Isomerism
Part - A

1. C 2. B 3. B 4. A 5. C
6. D 7. B 8. C 9. C

Part - B

1. (i) (ii)

2. (i) (ii)

3. (i) trans (e, e) (ii) Cis (a, e) (iii) trans (e, e) (iv) trans (e, e)

4. (i) Conformers (ii) Conformers (iii) Positional isomers


(iv) geometrical isomers or diastereomers (v) Identical
5. Structural (Chain isomerism).

6. (C) both 7. False 8. IV > III > I > II

EXERCISE - 1 [C]
1. 5 2. 3 3. 4 4. 6 5. 4
6. 2 7. 8 8. 7 9. 5 10. 8
11. 8 12. 4 13. 4 14. 6 15. 4
16. 5 17. 4 18. 4 19. 0

EXERCISE - 2 [A]
Geometrical Isomerism
Part - A
1. B 2. D 3. B,C 4. B 5. D
6. A 7. B 8. C 9. A,C 10. D
11. B 12. D

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Part - B
1. b, c , e , f , g , i
2. (i) CH3 – CH = CH – CH3 (ii) CH3 – CH = CH – CH2 – CH3

(iii) CH3 – CH = CH – CH2 – CH2 – CH3 , CH3 – CH2 – CH = CH – CH2 – CH3

CH3
|
,
CH3  CH  CH  CH  CH3

(iv) CH3 – CH = CH – Cl
(v) CH3  C  C  H , Cl  CH2  C  C  H
| | | |
Cl Cl H Cl

3. (i) 4 (ii) 4 (iii) 4 (iv) 4 (v) 6 (vi) 10

4. (a) Z (b) Z (c) Z (d) Z

5. (i) (ii)

EXERCISE - 2 [B]
Optical Isomerism
Part - A
1. D 2. C 3. C 4. D 5. D 6. D
7. C 8. B 9. C 10. B 11. B 12. B
13. C 14. C 15. A 16. A 17. D 18. D
19. B

Part - B
1. a, b, c, e, g, h

2. (a) 2, (b) 1 ,

(c) 5,

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(d) 1, (e) 1, (d, and )

3. (a) 6, structural isomers = 4, stereoisomers of (c) = 3

H Cl H Cl
| | | |
HC CF (optically inactive) H  C  C  Cl (optically inactive)
| | | |
Cl F F F
(A) (B)

H H H Cl
| | | |
F  C  C  Cl (d, l, meso) F CCH (optically inactive)
| | | |
Cl F F Cl
(C) (D)

(b) 14, Structural isomers = 7, Stereoisomers = 14

F Br F F
| | | |
Cl  C  C  C  Br Cl  C  C  C  F Cl  C  C  C  I Br  C  C  C  Cl
| | | |
I I Br I

4. (a) (b) (c) (d)

5. (a) S (b) R (c) R, S (d) S, S

6. (i) Diastereomer (ii) Enantiomer (iii) Diastereomer

7. 8, yes 8. (i), (ii), (iii), (iv).


9. (i), (ii), (iii), (iv), (v), (vii) & (viii) are optically inactive species and (vi) is optically active.

10. Two, mirror images i.e. object and its mirror image.

11. These are not same compounds these are positional isomers.

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12. (i) P is sp3 hybridised and chiral.
(ii) N is chiral and inversion is not possible in ring structure. one C of cyclopropane ring is
also chiral.

13. (C)

14. 22 = 4 stereoisomers. All are optically active.

15. (7)
CH3
CH3 CH3 H3C CH3
*
*
CH3
1 1 3 1 1

16.

17. (a) or (b)

18. (i) 3 (ii) 3 (iii) 4(cyclic)

Cl Cl
Cl Cl Cl Cl

R Cl S Cl Cl Cl Cl Cl (iv) 6
Both are optically active Optically inactive (presence of plane of symmetry)
Both are diastereomers

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EXERCISE - 2 [C]
Only One Option Correct :
1. D 2. D 3. D 4. C 5. B
6. B 7. A 8. D 9. D 10. D
11. A 12. B 13. B 14. A 15. C
16. A 17. D 18. B 19. D 20. B
21. C 22. C 23. C 24. D 25. B
26. A 27. D 28. D 29. C 30. A
31. D 32. D 33. D 34. C 35. C
36. B 37. C 38. D 39. D 40. A
41. B 42. D 43. D 44. B 45. D
46. B 47. B 48. A 49. D 50. C
51. C 52. D 53. D 54. C 55. C
56. B 57. A
JEE Main : PYQ
1. A 2. D 3. D 4. B 5. B
6. C 7. A 8. C 9. C 10. B
11. A 12. B 13. A 14. A 15. D
16. A 17. D 18. B 19. C 20. A
21. C 22. B 23. C 24. D 25. C
26. C 27. D 28. 5 29. 6

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