Behaviour of Perfect Gas and Kinetic Theory of Gases

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(Physics)
Kinetic Theory of Gases
-By Vimal Kumar
University of
Delhi
CONCEPTS
Boyle’s Law:
At constant temperature the volume of a given mass of gas is inversely proportional to its
pressure.
Charle’s Law:
At constant pressure the volume of a given mass of gas is directly proportional to its
absolute temperature.
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Gay Loussac's Law:

At constant volume, the pressure of a given mass of gas is directly proportional to its
absolute temp.
Ideal Gas Equation:

for n mole of gas
Universal gas constant:
Ideal gas:
A gas which obeys gas law strictly is an ideal or perfect gas. The molecules of such a gas
are of point size and there is no force of attraction between them.
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Assumptions of Kinetic Theory of Gases
1. All gases consist of molecules which are rigid, elastic spheres identical in all respect
for a given gas.
2. The size of a molecule is negligible as compared with the average distance between
two molecules.
3. During the random motion, the molecules collide with one another and with the wall of
the vessel. The collisions are almost instantaneous.
4. The molecular density remains uniform throughout the gas.
5. The collisions are perfectly elastic in nature and there are no forces of attraction or
repulsion between them.
Pressure exerted by gas:
Where: n= no. of molecules per unit volume.

m=mass of each molecule.
=mean of square speed.

V = Volume
M = mass of gas
Average Kinetic energy of a gas:
If M is molecular mass and V is molecular volume and m is mass of each molecule. Then
1. Mean K.E per mole of a gas,
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2. Mean K.E per molecule of a gas,
3. K.E of 1gram of gas,
Avogadro Law:
The equal volume of all gases under similar condition of temp. and pressure contains an
equal number of molecules.
Delton’s law of partial pressure:

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Total pressure exerted by a mixture of nonreacting gases occupying a given volume is

equal to the sum of partial pressures which gas would exert if it alone occupied the same
volume at given temp.
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Degree of freedom:
f = 3N-k
where, f = no. of degree of freedom.
N = no. of atoms in a molecule. k = no. of independent relation between the
atoms.
1. Monoatomic gas – 2 degrees of freedom.
2. Diatomic gas – 5 degrees of freedom.
Law of equipartion of energy:
For any thermodynamical system in thermal equilibrium, the energy of the system is
equally divided amongst its various degree of freedom and energy associated with each
degree of freedom corresponding to each molecule is , where is the

Boltzmann’s constant and T is absolute temperature.
~ The law of equipartition of energy holds good for all degrees of freedom whether
translational, rotational or vibrational.
~ A monoatomic gas molecule has only translational kinetic energy
So, a monoatomic gas molecule has only three (translational) degrees of

freedom.
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~ In addition to translational kinetic energy, a diatomic molecule has two rotational

Kinetic energies
Here the line joining the two atoms has been taken as x-axis about which there is no
rotation. So, the degree of freedom of a diatomic molecule is 5, it does not vibrate.
At very high temperature, vibration is also activated due to which two extra degree of
freedom emerge from vibrational energy. Hence at very high temperature degree of
freedom of diatomic molecule is seven.
*(Each translational and rotational degree of freedom corresponds to one mole of
absorption of energy and has energy 1/2kBT).
Internal Energies & specific heats of monoatomic, diatomic& polyatomic

gases:
1. If ‘f’ is degree of freedom then for a gas of polyatomic molecules energy associated
with 1 mole of gas,
2. For a monoatomic gas f=3,
3. For a diatomic gas with no vibrational mode f=5, so

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4. For a diatomic gas with vibrational mode f=7, so
Mean free path:

It is the average distance covered by a molecule between two successive collisions. It is
given by,
Where, n is no. density and ‘d’ is diameter of the molecule.

Brownian Equation:
The zig-zag motion of gas molecules is Brownian motion which occurs due to random
collision of molecules.
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Kinetic Theory of gases
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-By Vimal Kumar

Gay Loussac's Law:

Ideal Gas Equation:

Universal gas constant:

Assumptions of Kinetic Theory of Gases

Pressure exerted by gas:

Where: n= no. of molecules per unit volume.

=mean of square speed.

2. Mean K.E per molecule of a gas,

3. K.E of 1gram of gas,

Delton’s law of partial pressure:

Total pressure exerted by a mixture of nonreacting gases occupying a given volume is

degree of freedom corresponding to each molecule is , where is the

~ A monoatomic gas molecule has only translational kinetic energy

So, a monoatomic gas molecule has only three (translational) degrees of

~ In addition to translational kinetic energy, a diatomic molecule has two rotational

Internal Energies & specific heats of monoatomic, diatomic& polyatomic

2. For a monoatomic gas f=3,

3. For a diatomic gas with no vibrational mode f=5, so

4. For a diatomic gas with vibrational mode f=7, so

Mean free path:

Where, n is no. density and ‘d’ is diameter of the molecule.

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