221-76021

Feb. 2013

Barrier Discharge Ionization Detector for GC-2010 Plus

BID-2010 Plus

Instruction Manual
Read the instruction manual thoroughly before you use the product.
Keep this instruction manual for future reference.
This page is intentionally left blank.
 Introduction
Read this Instruction Manual thoroughly before using the
product.
Thank you for purchasing this product.
This manual describes the installation, operation, usage cautions, and accessories and options for
this product. Read this manual thoroughly before using the product and operate the product in
accordance with the instructions in this manual.

 IMPORTANT
 If the user or usage location changes, ensure that this Instruction Manual is always kept
together with the product.
 If this manual or a product warning label is lost or damaged, immediately contact your
Shimadzu representative to request a replacement.
 To ensure safe operation, read all Safety Instructions before using the product.

 To ensure safe operation, contact your Shimadzu representative if product installation,

adjustment, re-installation (after the product is moved), or repair is required.

 Notice
 Information in this manual is subject to change without notice and does not represent a
commitment on the part of the vendor.
 Any errors or omissions which may have occurred in this manual despite the utmost care
taken in its production will be corrected as soon as possible, although not necessarily
immediately after detection.
 All rights are reserved, including those to reproduce this manual or parts thereof in any
form without permission in writing from Shimadzu Corporation.
 GCsolution® and CHROMATOPAC® are the registered trademarks of Shimadzu
Corporation in Japan.
 Shimadzu Corporation cannot be held liable for compensation for any damages that occur
through the use of this equipment or data output from this equipment or system.
 Shimadzu Corporation cannot be held liable for compensation for any damages that occur
as a result of this equipment or system being unable to take measurements due to any
type of problem.

© 2013 Shimadzu Corporation. All rights reserved.

Original version is approved in English.

BID-2010 Plus Instruction Manual i

Introduction

Indications Used in This Manual

Warnings, Cautions, and Notes are indicated using the following conventions:

Indication Meaning

Indicates a potentially hazardous situation which, if not avoided, could

result in serious injury or possibly death.

Indicates a potentially hazardous situation which, if not avoided, may

result in minor to moderate injury or equipment damage.
Emphasizes additional information that is provided to ensure the
proper use of this product.

The following symbols are used in this manual:

Indication Meaning

Indicates an action that must not be performed.

Indicates an action that must be performed.

Indicates information provided to improve product performance.

Indicates the location of related reference information.

ii BID-2010 Plus Instruction Manual

 Safety Instructions

Safety Instructions
The BID-2010 Plus is a detector for Shimadzu GC-2010 Plus Gas Chromatograph.
A gas chromatograph is an analysis system used to conduct qualitative and quantitative analysis.
To ensure safe product operation, read these important safety instructions carefully before use and
follow all WARNING and CAUTION instructions given in this section.

 Product Applications
! WARNING
Do not use this system for other than its intended purpose.

 Follow the procedures described in this Instruction Manual.

 Observe all warnings and precautions.
 Safety regulations and standards
For notifications on installation and safety controls, follow the necessary
procedures in compliance with the laws and regulations applicable in the country
where the product is used.

BID-2010 Plus Instruction Manual iii

Introduction

 Installation Site
! WARNING
 Be sure to use in a well ventilated location.
Use in a badly ventilated location may cause oxygen deficiency to occur due to the
gas used in the system.
 Connect this system to an appropriate voltage and frequency power supply.
Failure to do so may result in fire or electric shock. Furthermore, the system may
not operate to its full potential if the power voltage is unstable or there is
insufficient electrical power capacity.
 The system weighs 6.5 kg.
When installing the system, consider the combined weight of this system
and all other associated devices, and be sure to install the system in a flat,
stable location that can support the combined weight of the devices.
Failure to do so may result in the system overturning or falling from its installation
location.
 Install the necessary safety devices against overturning in case of an
earthquake, etc.
Failure to do so may result in the system overturning or falling from its installation
location.
 Be sure to ground the system.
Failure to do so may result in damage or short circuit. This is also important to
ensure stable operation of the system.
 Insert the power cord into an easy to reach power socket.
The power cord needs to be removed from the power socket in an emergency.
 Insert the power plug fully into the power socket.
If the power plug is not inserted fully into the power socket, fire may occur due to
heat generated by electric shocks or bad contacts.
 To prevent fires caused by the so-called tracking phenomenon, periodically
(at least once every 6 months) use a dry cloth to wipe away any dust
accumulated on the power plug.
 If the power cable becomes too hot to touch by hand, the electric current is
exceeding the rated current.
Stop using the system immediately, remove the plug from the power socket and
contact Shimadzu for repairs.
 If the power switches on and off when the power cable is moved, there is a
broken power wire inside the power cord.
Stop using the system immediately, remove the plug from the power socket and
contact Shimadzu for repairs.

*What is the tracking phenomenon?

When a plug is left inserted in a socket for an extended period of time, dust accumulates between
the plug and socket. If humidity is added to this dust, sparks can repeatedly be discharged between
the power plug pins.
This heat causes the insulated part of the power socket to overheat and deteriorate, which allows
electric current to flow between plug pins, causing fire.

iv BID-2010 Plus Instruction Manual

 Safety Instructions

! WARNING
 Do not fail to follow the instructions below for the power cable.
Failure to follow the instructions may result in fire caused by overheating, electric
shocks or other such accidents.
 Do not process the power cable.
 Do not forcibly bend or pull the power cable.
 Do not place heavy objects on the power cable.
 Do not fix the power cable in place with nails or staples.
 Do not place the power cable near heaters or devices that generate heat.
 Do not coil the power cable during use.
 Do not use an extension cable or power bar.
 Do not insert the plug diagonally into the socket.
 Do not insert the plug into the socket with wet hands.
 Do not use if the plug or cable covers are cracked or damaged.
 Plumb or coil the metallic gas pipes for the gas chromatograph so that they
are not near the plug socket, power cable or power plug.
If metallic pipes come into contact with the power supply, they may cause
explosion or burns due to generated heat.
 Do not use the power socket if it has become loose.
If the power plug may not be inserted fully into the power socket, fire may occur
due to heat generated by electric shocks or bad contact.

! CAUTION
 Do not place other devices or objects on top of this system, and do not place
this system on top of other devices or objects.
Doing so may result in the system overturning or falling from its installation
location.
 Do not install in a location where corrosive gas, organic solvents, halides,
gases that contain types of siloxane, oil mist, or large amount of dust or dirt
are present.
Doing so may prevent the system from operating fully, and may shorten the
service life of the system.
 Do not use in an environment where condensation may form on the system.
Doing so may prevent the system from operating correctly.
 Do not install in direct sunlight, directly in front of the air outlet of a heater or
air conditioner, or in a location that is subject to vibration.
Doing so may prevent the system from operating fully, and may shorten the
service life of the system.
 Do not use near devices that generate a strong magnetic field.
Doing so may cause damage or accidents due to malfunctions.
 Do not use pipes that may have oil inside for pipes that highly pressurized
gas will pass directly through.

BID-2010 Plus Instruction Manual v

Introduction

 Installation
To ensure safe operation, contact your Shimadzu representative if product installation, adjustment,
re-installation (after the product is moved), or repair is required.

! WARNING
This system must be fitted by a Shimadzu engineer or Shimadzu designated
service company.
Installation by any other unauthorized person may result in electric shock, accident
or damage.
Additionally, the warranty may be invalidated if the system is installed by someone
who is not a Shimadzu engineer or Shimadzu designated service company
engineer.
 To ensure safe operation, contact your Shimadzu representative if product
installation, adjustment, or re-installation (after the product is moved) is
required.
Installing, adjusting, or re-installing the product by yourself may cause an injury or
equipment failure, or affect stable operation of the product.

vi BID-2010 Plus Instruction Manual

 Safety Instructions

 Precautions for Work and Operation

! WARNING
 Follow the procedures described in this Instruction Manual.
Failure to do so may lead to fire, electric shock or accidents.
 Be sure to hold the plug section of the power plug when inserting into the
socket.
Holding the cable section when inserting or removing the power plug may cause
the insulation to break, causing heat, damage or accidents.
 Be sure that the input gas pressure does not exceed the maximum pressure
listed in the instruction manual.
If the gas pressure exceeds the usable range, the pressure control valve may
become damaged, causing gas to leak. This may cause oxygen deficiency or fire.
 If the same gas is used in this and other equipment, check the pressure
specifications for each equipment and adjust the supply pressure to ensure
that all conditions are fulfilled.

! CAUTION
 Do not connect other than the specified type of gas to this system.
Doing so may cause damage or accidents.

 If liquids such as water or organic solvents are spilled on the system, wipe
them up immediately.
Failure to do so may lead to damage, electric shock or fire.
 Observe all warnings and precautions.
 Always wear safety glasses during maintenance and/or inspection of the
syringes, glass inserts, columns and detectors.

BID-2010 Plus Instruction Manual vii

Introduction

 Precautions for Maintenance and Inspections

! CAUTION
 Before starting maintenance inspections, check to ensure that the
temperature of all parts of the system is below 50 °C.
Performing this work when the system is still hot may result in burns, or may cause
the screw threads and nuts to stick due to the heat.
 When replacing parts, be sure to use the parts listed in the instruction
manual.
Using other parts may cause damage or accidents.
 Always remove the power plug from the socket before inspection,
maintenance and replacing parts.
Failure to do so may result in accidents due to electric shocks or shorts.
 Check the electrical leakage breaker periodically.
The risk of electrical shock or fire increases if the electrical leakage breaker does
not operate correctly.
 When cleaning the exterior of this system, do not leave the system wet, and
do not use detergents that contain alcohol or thinner.
Doing so may prevent the system from operating fully, and may shorten the
service life of the system.
Use a soft cloth dampened with water or neutral detergent to wipe the system
clean, and then wipe dry using a dry cloth.

 Dangers of Repairing, Disassembly and Modification

! CAUTION
 Never disassemble or modify the system without our permission.
Doing so may result in accidents due to electric shocks or shorts. It may also result
in injury or damage to the system.

 Contact your Shimadzu representative for system repairs.

Failure to do so may result in fire, electric shock or injury.

viii BID-2010 Plus Instruction Manual

 Safety Instructions

 If an Abnormality is Detected
If the following type of abnormality occurs, immediately turn the gas chromatograph power switch
OFF and unplug the power cable. (If the power cable is tightened with screws to a power distribution
board, turn off the switch provided on the power distribution board.)
Next, contact the maintenance engineer in charge of the system installation area or your Shimadzu
representative.
 If foul odors or smoke are generated from the power plug or power cable.
 If the power plug becomes deformed due to overheating.
 If the base of the plug pins becomes blackened or burnt.
 If the plug pins become bent.
 If the plug becomes loose in the socket and comes out easily.
 If the power cable or plug becomes too hot to touch.
 If the system power switches ON/OFF when the power cable is touched or bent.
 If the power cable insulation becomes worn or cracked.

BID-2010 Plus Instruction Manual ix

Introduction

 Emergency Procedures
Follow these procedures in the event of an abnormality such as a burning smell or gas leak. Before
using the system again after an emergency, inspect the system. Contact your Shimadzu
representative if necessary.

Emergency Stoppage Procedures

1 Turn off the power switch (POWER) on the front of the GC-2010 Plus.
2 Turn off the power switches of all other devices.
3 Quickly close the main gas valves.
4 Remove the power cables of the "PURE HE ASSY"s attached to the main unit and rear of the
GC-2010 Plus.
(If the power cable is tightened with screws to a power distribution board, turn off the switch provided
on the power distribution board.)
5 Open the windows and doors of the room in which the system is installed to ventilate the room.

 Blackout Procedures
If a blackout or power outage occurs, follow the procedures below.
1 Quickly close the main gas valves.
2 Turn off the power switch (POWER) on the front of the GC-2010 Plus.
3 Turn off the power switches of all other devices.
4 Open the windows and doors of the room in which the system is installed to ventilate the room.
5 After the power supply returns, check the contents of the "Installation" and "Precautions for Work
and Operation", and start up the GC-2010 Plus as normal.

x BID-2010 Plus Instruction Manual

 Safety Instructions

Precautions for Handling and Storing High Pressure

Gas
The gas cylinders used with this system must conform to the "High Pressure Gas Safety Law". Be
sure that the "High Pressure Gas Safety Law" and "Security Regulations for General High-Pressure
Gas" are strictly observed. Additionally, be sure that regulations in the "Road Law", "Act on Port
Regulations", "Aviation Law" "Ship Safety Law" and "Fire Services Act" as well as MSDS (Material
Safety Data Sheet) published by the gas manufacturer are also strictly observed. In particular, gas
cylinders that have a capacity greater than 300 m3 require a permit under law.

 Precautions for Moving High Pressure Gas Cylinders

! CAUTION
 If a specialized cap is required for the high pressure gas cylinder, make sure
that it is fitted correctly.

Be sure to follow the instructions below for the gas cylinder.

 Do not drag gas cylinders.
 Do not knock gas cylinders over.
 Do not drop gas cylinders.
 Do not kick gas cylinders.
 Do not strike gas cylinders with other objects.
 Do not handle gas cylinders roughly but protect them from impact.

BID-2010 Plus Instruction Manual xi

Introduction

 Precautions for Storing High Pressure Gas Cylinders

! CAUTION
 Take the necessary precautions to ensure that gas cylinders do not fall over.
If the cylinder valve becomes damaged due to the cylinder falling over etc., high
pressure gas may escape with exceptional force causing the gas cylinder to take
off.
 Store empty gas cylinders and gas cylinders that still have remaining gas
separately.
 Do not store gas cylinders in the following types of location.
 Locations where the temperature exceeds 40 °C
 In direct sunlight
 Where there is fire within a 2 m radius of the cylinders
 Near electrical wiring or ground wiring
 In a corrosive atmosphere
 In a location that has continual vibrations
 Be sure to store gas cylinders away from naked flames or sparks, and do not
allow flames within 2 m of the cylinders. Furthermore, do not allow flames
within 5 m of related equipment when flammable gas is used.

xii BID-2010 Plus Instruction Manual

 Safety Instructions

 Precautions for Handling High Pressure Gas

! CAUTION
 High pressure gas should only be handled by persons who have adequate
experience and training.
 If any dust is adhered to the gas outlet valve, clean it thoroughly to remove
all of the dust using a gauze cloth etc.
 Always close the gas cylinder outlet valve when leaving the working area
after stopping or finishing work.
 Always wear gloves when installing and removing gas cylinders.
 When opening or closing a gas cylinder, always do so slowly by hand. Do
not hit with a tool such as a hammer etc. If you cannot operate it by hand,
contact the vendor.

 Be sure to adequately ventilate the room when using high pressure gas.

 Make sure that a fire extinguisher is close by in case of emergencies.

Particularly in the case of flammable gas, smoking and the use of fire are
prohibited within 5 m of the gas equipment.

BID-2010 Plus Instruction Manual xiii

Introduction

 Precautions for High Pressure Gas and Other Precautions

! CAUTION
 All acceptance and delivery of gas cylinders should be done by a
pre-determined manager.
 When accepting the high pressure gas cylinders, check the engraved marks,
cylinder color and gas name display to confirm the type of gas.
If the contents of the cylinder do not match your requirements, do not use the
cylinder and return it to the vendor.
 Check the joints, tubes, pipes and devices for leaks both before and after use.
When a bubble solution such as soapy water is used to inspect for gas leaks,
wash with fresh water and use a clean cloth to completely remove all of the soapy
water afterwards.

 Always use a designated degreased pressure regulator in the gas supply.

Do not connect the gas cylinder directly.
 Do not use pipes that may have oil inside for pipes that gas will pass directly
through.
 If the gas cylinder valve outlet freezes, use warm water to defrost it before
use.
 If there is a possibility that something other than the component gases has
entered the gas cylinder, contact the vendor with details such as the code
number of the gas cylinder.
 After use, return it immediately to the manufacturer or supplier.
Additional charges may apply to rental cylinders if the specified time period is
exceeded.
 Inspect the pressure gauge periodically to ensure that it is operating
correctly.
 Do not remote, delete or alter the paint, engraved marks or displays on the
gas cylinder.
Also, do not unnecessarily remove labels.
 Do not use the gas cylinder as part of an electrical circuit or for anything
other the intended purpose (such as a roller or mold etc.).

 Precautions for Discarding High Pressure Gas

! CAUTION
 When disposing of gas, gently open and close the cylinder outlet valve in a
well ventilated room, and vent the gas in small amounts to avoid any dangers.
After disposing of the gas, close the outlet valve of the gas cylinder and store the
gas cylinder in a place where it cannot fall over. Also be sure that the outlet valve
is not damaged during storage.
 Contact the gas manufacturer or vendor to dispose of the high pressure gas
cylinder.

xiv BID-2010 Plus Instruction Manual

 Warranty

Warranty
Shimadzu provides the following warranty for this product.
Please contact your Shimadzu representative for information about the period
1. Period:
of this warranty.
If a product/part failure occurs for reasons attributable to Shimadzu during the
2. Description:
warranty period, Shimadzu will repair or replace the product/part free of
charge. However, in the case of products which are usually available on the
market only for a short time, such as personal computers and their
peripherals/parts, Shimadzu may not be able to provide identical replacement
products.

3. Limitation 1. In no event will Shimadzu be liable for any lost revenue, profit or data, or
of Liability: for special, indirect, consequential, incidental or punitive damages,
however caused regardless of the theory of liability, arising out of or related
to the use of or inability to use the product, even if Shimadzu has been
advised of the possibility of such damage.

2. In no event will Shimadzu's liability to you, whether in contract, tort

(including negligence), or otherwise, exceed the amount you paid for the
product.

Failures caused by the following are excluded from the warranty, even if they
4. Exceptions:
occur during the warranty period.
1. Improper product handling
2. Repairs or modifications performed by parties other than Shimadzu or
Shimadzu designated companies
3. Product use in combination with hardware or software other than that
designated by Shimadzu
4. Computer viruses leading to device failures and damage to data and
software, including the product's basic software
5. Power failures, including power outages and sudden voltage drops, leading
to device failures and damage to data and software, including the product's
basic software
6. Turning OFF the product without following the proper shutdown procedure
leading to device failures and damage to data and software, including the
product's basic software
7. Reasons unrelated to the product itself
8. Product use in harsh environments, such as those subject to high
temperatures or humidity levels, corrosive gases, or strong vibrations
9. Fires, earthquakes, or any other act of nature, contamination by radioactive
or hazardous substances, or any other force majeure event, including wars,
riots, and crimes
10. Product movement or transportation after installation
11. When gas of a purity other than that specified is used.
* If there is a document such as a warranty provided with the product, or there is a separate contract agreed upon
that includes warranty conditions, the provisions of those documents shall apply.

BID-2010 Plus Instruction Manual xv

Introduction

After-Sales Service and Availability of

Replacement Parts
After-Sales If any problem occurs with this product, perform an inspection and take
appropriate corrective action as described in the troubleshooting
Service section of this manual.
If the problem persists, or the symptoms are not covered in the
troubleshooting section, contact your Shimadzu representative.

Replacement Replacement parts for this product will be available for a period of
seven (7) years after the product is discontinued. Thereafter, such
Parts Availability parts may cease to be available.
If Shimadzu receives notice of the discontinuation of units or parts, the
necessary quantity for the above period is immediately calculated and
secured. However, such units or parts may cease to be available within
seven years after the discontinuation of the product, depending on
individual manufacturer conditions and on changes in the quantity
required.

Maintenance, In order to maintain the instrument's performance and obtain accurate

measurement data, daily inspection and periodic inspection/calibration are
Inspections, and necessary.
For daily maintenance, inspection, and replacement parts, see “5. Maintenance
Adjustment and Inspection” and “7. Maintenance Parts” of this Instruction Manual.
Periodic inspection/calibration should be requested to your Shimadzu
representative.
Replacement cycles described for periodic replacement parts are rough
estimate.
Replacement may be required earlier than the described replacement cycles
depending on usage environment and frequency.

xvi BID-2010 Plus Instruction Manual

 Action for Environment (WEEE)

Action for Environment (WEEE)

To all users of Shimadzu equipment in the European Union:
Equipment marked with this symbol indicates that it was sold on or after 13th
August 2005, which means it should not be disposed of with general household
waste. Note that our equipment is for industrial/professional use only.

Contact Shimadzu service representative when the equipment has reached

the end of its life. They will advise you regarding the equipment take-back.

WEEE Mark

With your co-operation we are aiming to reduce contamination from waste electronic and electrical
equipment and preserve natural resource through re-use and recycling.
Do not hesitate to ask Shimadzu service representative, if you require further information.

BID-2010 Plus Instruction Manual xvii

Introduction

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xviii BID-2010 Plus Instruction Manual

 Contents
Introduction .........................................................................................i
Indications Used in This Manual ............................................................................... ii
Safety Instructions ................................................................................................... iii
Warranty ................................................................................................................. xv
After-Sales Service and Availability of Replacement Parts .................................... xvi
Action for Environment (WEEE).............................................................................xvii

1 Outline ......................................................................................1
1.1 Principle of the Barrier Discharge Ionization Detector (BID).............................1

2 Parts List ..................................................................................3

2.1 Parts List ..........................................................................................................3

3 Basic Operation........................................................................5
3.1 Introduction.......................................................................................................5
3.2 Gas Used .........................................................................................................7
3.3 Checking the Glass Insert and Injection Port Septum........................................8
3.4 Mounting the Column .......................................................................................9
3.5 Setting the Flow Rate ..................................................................................... 11
3.6 Setting the Flow Rate of Detector Gases .......................................................12
3.6.1 Detector Gases.....................................................................................................12
3.6.2 Sweep Gas ...........................................................................................................13
3.7 System Startup ...............................................................................................15
3.8 Setting the Column Oven/Injection Port Temperature ......................................16
3.8.1 Injection Port.........................................................................................................16
3.8.2 Column Oven........................................................................................................16
3.9 Setting the Detector Temperature...................................................................17
3.10 Lighting the Plasma........................................................................................18
3.11 Turning off the Plasma ...................................................................................20
3.12 Setting the Range/Attenuation........................................................................21
3.13 Checking the Baseline....................................................................................22
3.14 System Stopping ............................................................................................23

BID-2010 Plus Instruction Manual xix

Contents

4 Key Operation ........................................................................ 25

4.1 Configuring Detector Settings ........................................................................ 25
4.1.1 Display Screen......................................................................................................25
4.1.2 List of Settings ......................................................................................................26
4.1.3 PF Menu List.........................................................................................................28
4.2 Checking Installation Settings........................................................................ 29
4.2.1 Installation (Position) ............................................................................................30
4.2.2 Installation (Piping) ...............................................................................................31
4.2.3 Checking Line Configuration (Detector Settings) ..................................................32
4.3 Selecting a Detector ...................................................................................... 33
4.3.1 Setting the Detector Gas ......................................................................................34
4.4 Detector On/Off.............................................................................................. 35
4.5 Turning the Detector Light On and Off ........................................................... 35
4.6 Setting the Range .......................................................................................... 35
4.7 Zero Adjustment............................................................................................. 36

5 Maintenance and Inspection .................................................. 41

5.1 Maintenance and Inspection.......................................................................... 41

6 Troubleshooting ..................................................................... 43
6.1 Error Messages ............................................................................................. 48
6.1.1 Errors for Lighting the Detector.............................................................................49
6.1.2 APC Error .............................................................................................................50
6.1.3 Errors due to Incorrect Inputs ...............................................................................51

7 Maintenance Parts ................................................................. 53

7.1 Maintenance Parts List .................................................................................. 53

8 Specifications ......................................................................... 55
8.1 BID-2010 Plus Specifications......................................................................... 55

xx BID-2010 Plus Instruction Manual

 1 Outline
The BID-2010 Plus is a detector for the Shimadzu GC-2010 Plus Gas Chromatograph.
A gas chromatograph is an analysis system used to conduct qualitative and quantitative analysis.

1.1 Principle of the Barrier Discharge Ionization

Detector (BID)
The Barrier Discharge Ionization Detector is constructed of two main sections, the plasma
generation section and collector section. The plasma generation section contains three electrodes,
and generates non-equilibrium plasma from the electrical discharge of the dielectric barrier by
applying high voltage to the central electrode.
The metastable condition of the helium generated from the non-equilibrium plasma ionizes the
sample using the photon energy emitted when it returns to the ground state. These ions are
accumulated and amplified by the collector, and are output as a voltage value to the Chromatopak or
computer.
Gases other than neon which has a higher ionization potential than helium can be ionized because
the electrical excitation energy of the helium metastable condition is exceptionally high.
The inner wall of the plasma generation section suffers very little wear and remains stable over long
periods because the neutral gas temperature of the non-equilibrium plasma generated by the
dielectric barrier discharge is exceptionally low, and because the electrode is protected by the stable
dielectric substance (fused quartz).

Dielectric substance Plasma generation

(quartz tube) He section
Plasma

Sample

High voltage Ionization

electrode Potential (eV)
Collection
electrode

Column He

Sample Collector section

BID-2010 Plus Instruction Manual 1

1 Outline

This page is intentionally left blank.

2 BID-2010 Plus Instruction Manual

 2 Parts List
2.1 Parts List
This detector consists of the following contents.
BID-2010 Plus Parts List
100 V 200 V
Parts name Parts no. Notes
type type
Sold individually
APC-2010 Plus, BID 221-74880-41 1 1
S221-74880-81
Sold individually
BID ASSY, 100-120 221-76010-41 1
S221-76010-81
Sold individually
BID ASSY, 200-240 221-76010-48 1
S221-76010-88
POWER UNIT, BID S221-76011-41 1 1
BID-2010 Plus CONTROLLER S221-76012-41 1 1
Sold individually
INJ/DET COVER BID-2010 Plus 221-76013-41 1 1
S221-76013-81
Sold individually
PURE He ASSY 100 221-76050-41 1
S221-76050-81
Sold individually
PURE He ASSY 200 221-76050-48 1
S221-76050-88
Power installation
HV PWR PLATE 221-74946 1 1
plate
INSPECT. CERTIFICATE BID-2010 plus,
221-76016 1 1
BID-2010 Plus
BID2010 Plus CERTIFICATE 221-30991-49 1 1
INSTRUCTION MANUAL,
221-76021 1 1
BID2010 Plus E
DECLARATION OF CONFORMITY
228-30164 1 1
EXPLANATION
ACCESSORIES, BID-2010 Plus 221-76014-41 1 1
Sold individually
Details COLUMN GASKET, ALUMINUM 201-35183 1 1
S201-35183-84
PIPE ASSY MF-MM 3X0.3 S221-26170-03 1 1
PIPE ASSY MF-MM 3X0.6 S221-26171-06 1 1
GRAPHITE JIG, BID S221-41532-02 1 1
PIPE AIR IN, washing S221-72658-91 2 2
SCREW, SUS SEMS P3 M4x6 020-46546 3 3
SCREW, SUS SEMS P2 M4x6 020-46146 2 2
SCREW, SUS SEMS P2 M4x8 020-46147 3 3
TAPPING SCREW, SUS PAN
021-60313-01 2 2
HEAD 2M3x8
WASHER, SUS SPRING 2 M3 023-77030 2 2
WASHER, SUS SPRING 2 M4 023-77040 3 3
WASHER, SUS PLAIN M3 023-66130-01 2 2
WASHER, SUS PLAIN M4 023-66140-01 5 5
SPACER, BSU-305 037-38768-42 4 4
SPACER, BSU-440 037-38871-79 3 3
INSULATOR, BID 221-74988 1 1
BLIND PANEL BID AMP 221-76046 1 1

BID-2010 Plus Instruction Manual 3

2 Parts List

The parts with the part number starting with "S" are sold as maintenance parts or consumable
parts. Those with the part number not starting with "S" are not sold individually.

4 BID-2010 Plus Instruction Manual

 3 Basic Operation
3.1 Introduction
This section describes the basic operational procedures of BID-2010 Plus. For detailed operations of
the GC-2010 Plus, refer to the GC-2010 Plus instruction manual.
However, this manual contains an example of connecting the BID-2010 Plus to line 2 and outputting
the detector signal output to channel 2. Replace the line or output channel number to add to a
different line or output the detector signal output to a different channel.

! CAUTION
It is necessary to set each parameter before pressing the [Start GC].
Be sure to read the GC-2010 Plus instruction manual before starting the analyzer.

When using BID, use the BID exclusively for the detector on one analysis line.
Detector splitting is not supported as the BID uses a different flow measurement methods from
other detectors.

1. Switch the GC unit power on.

2. Press the [DET] key, press [Det Gas] in the PF menu, and check that the sweep gas is
flowing at around 5 to 10 mL/min in the displayed screen. Leave for more than 10 minutes
and then replace the gas. If for some reason the sweep gas supply has been stopped,
leave for longer than usual and wait until the gas in the piping has been completely
replaced.

The sweep gas is set by the Shimadzu engineer or specified service company field engineer
when the equipment is installed. To adjust the sweep gas flow rate, refer to "3.6 Setting the
Flow Rate of Detector Gases".

3. Insert the power plug of the "PURE HE ASSY" attached to the rear of the GC-2010 Plus
into a power socket.

! CAUTION
Before plugging in the power plug, allow helium to flow for more
than 10 minutes to ensure that the gas inside the system has been
completely replaced.
If the power plug is inserted when the gas purity inside the "PURE HE
ASSY" is still low before replacement is complete, the filter may become
saturated and require replacement.
Care is also required when replacing the gas in areas such as the piping
if the sweep gas supply has been stopped for some reason. Ensure that
the gas inside the system is completely replaced by measures such as
allowing the gas to flow for longer than usual before inserting the power
plug.
The "PURE HE ASSY" is a consumable item.

BID-2010 Plus Instruction Manual 5

3 Basic Operation

4. Press the [DET] key and check that the BID device controller is [Off] in the displayed
screen.

5. Press the [Start GC] key on the [SYSTEM] screen to start the controls.

6. Wait until the detector reaches the set temperature.

7. Open the [DET] screen, change the BID detector control to [On], and press the [Enter] key.

8. Press [Det Gas] in the PF menu, change the flow control in the displayed screen to [On]
and set the flow of the detector gas (DCG: DisCharge Gas) to 50 mL/min.

9. Press [Return] in the PF menu, and press the [PlasmaON] key in the detector screen PF
menu.
When the "Start lighting" message is displayed followed by the "Lighting on" message,
lighting is complete.

If lighting fails, refer to "The plasma is not lit" in "6 Troubleshooting".

10. When the baseline has stabilized, press the [Zero Adj] key in the [MONIT] screen to
perform zero point adjustment.

11. Start analysis.

6 BID-2010 Plus Instruction Manual

 3.2 Gas Used

3.2 Gas Used

The BID is a highly sensitive detector, and even minute impurities in the carrier gas can cause the
baseline to become unstable. Always use gases that exceed the following purity levels for the carrier
gas and detector gas.
This unit also includes expendable parts that remove impurities from the carrier gas and detector
gas.
It is recommended that these parts be replaced if the baseline becomes unstable.
Contact your Shimadzu representative for replacements. (Charges apply)
The "PURE HE ASSY" should be replaced approximately every 6 months if helium gas that exceeds
the indicated purity level (99.9999 %) is used at 100 mL/min and a high purity level is maintained in
the helium line by allowing sweep gas to flow at 5 to 10 mL/min when the system is stopped. (Please
note that this is a guide only and not a guarantee.) The life of the "PURE HE ASSY" is shortened
dramatically if air is allowed to enter by using gas with a low purity level, impurities or leaks in the
pipe, entry of air into the helium line when changing the gas cylinder, or stopping the sweep gas.
Parts name Parts no. Notes
PURE HE ASSY 100 221-76050-41 For 100 V
PURE HE ASSY 200 221-76050-48 For 200 V

 Carrier gas, detector gas (supply pressure 300 to 980 kPa)

Use 99.9999% or higher purity Helium cylinders.

BID-2010 Plus Instruction Manual 7

3 Basic Operation

3.3 Checking the Glass Insert and Injection Port Septum

The BID-2010 Plus can detect substances such as water and air with high sensitivity, meaning that
existing leaks or impurities in the injection port can cause a large amount of noise or wandering.
Change the septum and glass insert frequently.
For detailed procedures, refer to section "12. Injection Port" in the GC-2010 Plus Instruction Manual
(CD-ROM version).

! WARNING
High temperature
Risk of burns. Check that the temperature of each part is below 50 °C before
starting the work.

! CAUTION
Do not turn the screws when they are still hot.
Do not turn screws when they are still hot in order to prevent searing.

The type of glass insert differs depending on the type of injection port used and injection mode.
Check that;
 the selected type of insert matches the sample injection mode,
 the silica wall is set correctly, and
 the glass insert O-ring has not degraded.

Split Split-less

Replace the septum after approximately 100 injections. (Replace after approximately 50 injections
when a gas-tight syringe is used.)

Air entering the injection port when changing the septum or insert can cause the baseline to become
unstable. Wait around an hour after starting the system until the baseline stabilizes.

8 BID-2010 Plus Instruction Manual

 3.4 Mounting the Column

3.4 Mounting the Column

For detailed procedures, refer to section "4. Installing the Column" in the GC-2010 Plus Instruction
Manual (CD-ROM version).
Fix the graphite ferrule on the detector side at the position (74 mm) shown in the following figure.
Use the provided graphite fixing bracket for BID (P/N S221-41532-02) to fix in the position shown in
the figure.

 Changing the insertion length of the capillary columns affects the sensitivity and signal linearity.
 Use a thoroughly conditioned column to prevent BID contamination.
 If using a new graphite ferrule when replacing the column, heat it with a source such as a gas
burner before using it to attach the column.
 Change the graphite fixing position on the injection port side to 15 mm if performing split-less
analysis using a wide bore column with a 0.53 mm bore.

BID side

74 mm
Injection port side

34 mm

Graphite ferrule

Capillary column

Fixing position of graphite ferrule

BID-2010 Plus Instruction Manual 9

3 Basic Operation

 Conditioning the Column

The BID is highly sensitive with a low level of selectiveness, meaning that liquid phase steam flowing
from the column is also detected with high sensitivity. The column used for the BID therefore needs
to be sufficiently conditioned before connecting.
If there is a possibility that large amounts of a substance will flow from the column, attach the
column to the injection port side only (do not connect to the detector side), allow carrier gas to flow
through, and perform sufficient aging at a temperature that does not exceed the maximum usable
temperature of the column. Please take care, however, as performing more aging than necessary
can decrease the amount of liquid phase, which may affect separation.

Be sure to seal the detector if removing the column from the detector side when setting or supplying the
detector gas flow. If the BID is in a line, the column temperature can only be increased if the detector
temperature is higher than the column temperature, as the contamination prevention function stops the
column from reaching a higher temperature than the detector. If you want to increase the column
temperature without increasing the detector temperature, you will need to remove the detector from the
line.

10 BID-2010 Plus Instruction Manual

 3.5 Setting the Flow Rate

3.5 Setting the Flow Rate

Press the [FLOW] key and set the carrier gas conditions in the screen that appears.
Firstly, press the [Column] key and set the column information (bore, length, thickness) in the screen
that appears. Next, press the [Return] key, set each of the parameters and press the [Purge] key to
set the purge flow rate.

 The same analysis method as other detectors cannot be used because the flow rate
calculation method for this detector differs from that used with other detectors. (The same
line speed and flow rate are not obtained for the same pressure.)
If BID and a different detector are both connected to the same line, calculate the flow rate
according to BID.
 If the split ratio is low (total flow rate less than 10 mL/min), background noise from the
injection port may increase. Set the split ratio and total flow rate to larger settings.
 If a large amount of a high-concentration substance is detected and sufficient separation
cannot be done, decrease the amount injected by measures such as adjusting the split ratio,
or change the column temperature or flow conditions.
 For split-less analysis, fluctuations occur in the baseline soon after the set sampling time has
passed. This is because the background from the injection port fluctuates due to the split
ratio. It is not a malfunction.

For detailed procedures, refer to section "12. Injection Port" in the GC-2010 Plus Instruction
Manual (CD-ROM version).

BID-2010 Plus Instruction Manual 11

3 Basic Operation

3.6 Setting the Flow Rate of Detector Gases

3.6.1 Detector Gases

1. Press the [DET] key to display the Detector condition settings screen. If a different detector
is displayed when multiple detectors are connected, press [Next Det] in the PF menu to
display BID.

2. Press [Det Gas] in the PF menu to display the detector gas flow settings screen.

3. Set the flow rates for the gases.

Recommended detector gas flow settings are as follows.
Column Flow Detector Gas Flow (Recommended)
Less than 10 mL/min 50 mL/min
10 to 15 mL/min 70 mLmin
15 mL/min or greater 100 mL/min

4. Set the detector gas control to On.

Gas flow can be set between 0 and 100 mL/min.

However, the plasma becomes unstable if the gas flow is less than 20 mL/min, causing lighting
to be suspended and a message saying "DCG flow rate is not enough" to be displayed.
Using a flow higher than that recommended decreases sensitivity.
Using a flow lower than that recommended increases sensitivity but causes the following
phenomena:
 Dynamic range wanders and detection on the high-density side becomes difficult, causing
unclear peak.
 Solvents or substances with a high boiling point leave residue or stick to the inside of the
detector, causing operational instability such as baseline wandering and decreased
sensitivity.

12 BID-2010 Plus Instruction Manual

 3.6 Setting the Flow Rate of Detector Gases

3.6.2 Sweep Gas

Around 5 to 10 mL/min of sweep gas needs to flow through the system constantly even when the
system is off or the gas chromatograph is not powered, to keep the detector stabilized and reduce
stabilization time when the detector is started.
Follow the procedure below to change or adjust the sweep gas flow.

1. Turn the GC power on and turn the system OFF if it is ON.

2. Press the [DET] key and then press [Det Gas] in the PF menu to display the detector gas
flow rate settings, and switch the detector gas control OFF using PF menu [ON/OFF].

3. If the column is connected to BID, remove the column and stopper and seal the BID. The
BID can be stoppered and sealed by attaching a graphite ferrule for capillary column
connection that still contains the core using a split nut in the same way as a column.

4. Open the main valve of the helium gas cylinder.

5. While checking the flow rate on the detector gas flow rate setting screen, turn the PURE
HE ASSY adjustment knob on the back of the GC to adjust the flow rate. Adjust the flow
rate to one substantially lower (5 to 10 mL/min) than the discharge gas flow rate for
analysis (recommended value for capillary analysis 50 mL/min).

Adjustment knob

BID-2010 Plus Instruction Manual 13

3 Basic Operation

 An APC error will occur if the flow rate is set to a value higher than the discharge gas flow
rate that is controlled by APC.
 The sweep gas supply needs to be turned off when performing APC calibration.
Perform calibration after either turning off the main cylinder valve or turning off the sweep
gas by rotating the PURE HE ASSY adjustment knob when the column is detached.
 Around 5 to 10 mL/min of helium gas is consumed due to sweep gas flowing constantly even
when the system is off or the gas chromatograph is not powered, to protect the PURE HE
ASSY, keep the detector stabilized and reduce stabilization time when the detector is started.
Make sure to close the gas tap if you do not use the BID for a long time and want to turn off
the sweep gas supply.
Also, be sure to pull out the "PURE HE ASSY" power plug on the back of the GC at least one
hour before turning off the helium gas supply.

! CAUTION
When stopping the supply of sweep gas for any reason, always pull
out the "PURE HE ASSY" power plug on the back of the GC at least
one hour before stopping the gas supply.
If the power plug is removed and low purity gas enters the "PURE HE
ASSY" within one hour, the filter becomes saturated and requires
replacement.
The "PURE HE ASSY" is a consumable item.

14 BID-2010 Plus Instruction Manual

 3.7 System Startup

3.7 System Startup

Press the [SYSTEM] key when the GC is in the stopped state to display the GC start sequence
screen.
Set the start time to 10 minutes or longer.

! CAUTION
Before starting the BID, replace all of the air inside the cell with carrier gas
or detector gas.
To prevent damage to the BID cell, set the start time so that the air inside the BID
cell is completely replaced with carrier gas or detector gas before the temperature
is raised to the detection temperature.
Increasing the temperature of the column oven or injection port before replacing
the gas can damage the BID cell. Set the temperature to around room temperature
before startup.

Set each of the parameters for GC startup, and press [Start GC] in the PF menu to start GC and
start the heating control and gas control of the various sections.
BID control does not start unless the detector control is ON.
For detailed procedures, refer to section "7. Starting and Stopping the GC [SYSTEM]" in the
GC-2010 Plus Instruction Manual (CD-ROM version).

BID-2010 Plus Instruction Manual 15

3 Basic Operation

3.8 Setting the Column Oven/Injection Port Temperature

Set the column oven temperature and injection port temperature.
For detailed procedures, refer to section "11. Creating an Oven Temperature Program" and
"12. Injection Port" in the GC-2010 Plus Instruction Manual (CD-ROM version).

3.8.1 Injection Port

Press the [INJ] key to display the injection port screen, and set the temperature.

3.8.2 Column Oven

Press the [COL] key to display the column oven screen, and set the temperature.

16 BID-2010 Plus Instruction Manual

 3.9 Setting the Detector Temperature

3.9 Setting the Detector Temperature

To set the BID detector temperature, press the [DET] key to display the detector screen.

 Set the detector temperature to 150 °C or higher when using. Using at a temperature lower
than 150 °C can cause water vapor and air to build up, causing the baseline to become
unstable.
 Using at a detector temperature higher than 320 °C for extended periods of time can shorten
the life of the detector.
A temperature that is between 150 °C and 300 °C and does not exceed the maximum usable
temperature of the column is recommended. Setting a high detector temperature when
analyzing oxidized gases containing a large amount of oxygen can also shorten the life of the
detector. A detector temperature of approximately 160 °C is recommended in this case.
Decreasing the detector temperature is also recommended if not using the BID.
 If a polyimide capillary column is used for the outer covering, some types of polyimides can
cause noise or tailing if the detector temperature is higher than 300 °C, due to carbonization
of the polyimide on the surface of the column inserted in the detector.
In such cases, tailing can be removed by cutting the section inserted into the detector, but it
is recommended that the detector temperature be reduced.
It is not necessary to reduce the detector temperature below 300 °C when columns that
contain highly heat-resistant polyimids or SUS capillaries are used.

BID-2010 Plus Instruction Manual 17

3 Basic Operation

3.10 Lighting the Plasma

1. Select the detector.

Press the [DET] key to display the Detector settings screen.
If a different detector is displayed when multiple detectors are installed, press the toggle
key to switch the PF menu, and press [Next Det] to change the detector.

2. Check that the detector temperature is the same as the set value.
When lighting the BID, always check that the detector temperature is sufficiently high (over
150 °C).
If BID is lit when the detector temperature is below 150 °C, cyclical changes in the baseline,
reduced sensitivity or malfunction may occur.

! CAUTION
Do not light before the detector is at high temperature.
Doing so may result in cyclical changes in the baseline, reduced
sensitivity or malfunction.

3. Set the detector control to On.

If the detector control is [Off] in the top right area of the BID detector setting screen, use
the cursor keys (up/down) to move the position of the cursor to [Off], use the cursor keys
(left/right) to change the BID detector control to [On], and press the [Enter] key to confirm.

4. Press the [Det Gas] key in the PF menu, set the type of gas and flow rate, and turn the
detector gas control On.
Recommended detector gas flow settings are as follows.
Column Flow Detector Gas Flow (Recommended)
Less than 10 mL/min 50 mL/min
10 to 15 mL/min 70 mLmin
15 mL/min or greater 100 mL/min

Gas flow can be set between 0 and 100 mL/min.

However, the plasma becomes unstable if the gas flow is less than 20 mL/min, causing lighting
to be suspended and a message saying "DCG flow rate is not enough" to be displayed.
Using a flow higher than that recommended decreases sensitivity.
Using a flow lower than that recommended increases sensitivity but causes the following
phenomena:
 Dynamic range wanders and detection on the high-density side becomes difficult, causing
unclear peak.
 Solvents or substances with a high boiling point leave residue or stick to the inside of the
detector, causing operational instability such as baseline wandering and decreased
sensitivity.

5. Press [Return] in the PF menu to display the detector screen, and press [PlasmaON] in the
detector screen PF menu. The "Start lighting" message is displayed at the bottom left of
the screen, and the lighting operation starts.

18 BID-2010 Plus Instruction Manual

 3.10 Lighting the Plasma

6. When the lighting operation completes normally, the "Lighting on" message is displayed at
the bottom left of the screen, the BID icon lights in the MONIT screen, and the plasma item
in the DET screen changes to [On].

If lighting fails, the message "DET#1(-4) Plasma on failed" is displayed at the bottom left of the
screen, and the lighting operation ends. If the error message is displayed, see "6 Troubleshooting".
Press [Return] in the PD menu, and press the [PlasmaON] key in the detector screen PF menu.

7. If the BID is selected in a line and the BID detector control and detector gas control are on
when the gas chromatograph is started, the lighting operation starts automatically after the
detector reaches the set temperature.
This is unrelated to the automatic lighting setting in the gas chromatograph startup process.
Automatic lighting does not happen if the BID detector control and detector gas control are
changed to On after starting the system, even if the BID is set in a line.
Press [PlasmaON] in the PF menu on the BID screen.

BID-2010 Plus Instruction Manual 19

3 Basic Operation

3.11 Turning off the Plasma

Follow the steps below to turn the plasma off after it has been lit.
 Turn BID Control Off
 Turn Detector Gas Control Off.
 Remove BID from the LINE
 System Off

20 BID-2010 Plus Instruction Manual

 3.12 Setting the Range/Attenuation

3.12 Setting the Range/Attenuation

1. For analog signal output

The analog signal output can be set to wide or linear when a data processor is connected
to the analog signal output. (The signal range and analog signal type are set from the
[DET] key screen.)
Set the analog signal type to [Wide] when a wide-range compatible data processor (C-R7A,
C-R7Aplus, C-R8A) is connected. Set the analog signal type to [Linear] for all other data
processors.
The detector signal attenuation does not need to be changed when [Wide] is set. However,
if the attenuation of the data processor cannot be adjusted (e.g.: when an error peak
occurs because the input signal is exceeded), the detector signal attenuation needs to be
changed in the detector setting screen.
-0 -4
The attenuation can be set in 5 levels from ×1(2 ) to ×2 .
When the index number increases by 1, the output signal is halved. Be sure to perform
wide range calibration before use (refer to "2.7 Connecting external device cables" in the
GC-2010 Plus instruction manual (CD-ROM version)).
The linear settings range can be set in 5 steps, from ×1(10 0) to ×10-4 .
The output signal is a maximum at range x1, and is output at 1/10 for 10-1, 1/100 for 10-2,
1/1000 for 10-3, and 1/10000 for 10-4.
Use the small range (x1, x10-1) for sensitive analysis, and use the larger ranges (x10-2,
x10-3, x10-4) for all other cases.

2. For digital output

When a digital connection compatible data processor (GCsolution, LabSolutions) is
connected digitally, the range (attenuation) settings are not required (because digital
output is always output as x1).

BID-2010 Plus Instruction Manual 21

3 Basic Operation

3.13 Checking the Baseline

1. Set the chromatomonitor screen full scale for the GCsolution or LabSolutions (digital
signal) to 6.4 x 104 μV, and check that the baseline stabilizes without scaling out and
becomes horizontal. Set the attenuation to 3 (23) for Chromatopak (analog signal).

Stabilized baseline

2. If the baseline does not stabilize as shown in the figure below or scales out, refer to
"6 Troubleshooting".

Noise Wandering

(Positive) drift Other

(Negative) drift

Various Baseline Abnormalities

 Zero Adjustment
Press the GC [MONIT] key, press [Zero Adj] in the PF menu or use the [Zero Adjustment] function in
GCsolution or LabSolutions to set the signal output to 0 μV.
If the Chromatopak display does not return to 0 μV even when zero adjustment is performed on the
GC side, perform additional zero adjustment on the Chromatopak side. For details, refer to "4.7 Zero
Adjustment".

The zero adjustment function on GCsolution and LabSolutions is the same function as the GC unit, but
the Chromatopak zero adjustment function does not adjust the detector output signal. Always perform
zero adjustment on the GC unit.

22 BID-2010 Plus Instruction Manual

 3.14 System Stopping

3.14 System Stopping

1. Press the [System] key while the system is running, and select [Stop GC] in the PF menu
of the displayed screen.
The system stop operation is executed according to the stop time and flow off time set
beforehand.

 Do not remove the power plug of the "PURE HE ASSY" attached to the rear of the GC-2010 Plus
from the power socket. Sweep gas is supplied at a rate of approximately 10 mL/min in the GC
stopped state in order to protect the PURE HE ASSY parts and keep the equipment stabilized.
 To stop the sweep gas supply, follow the instructions in "3.6 Setting the Flow Rate of Detector
Gases" to turn the sweep gas OFF after removing the PURE HE ASSY power plug and waiting for
at least an hour.

! CAUTION
When stopping the supply of sweep gas for any reason, always pull out
the "PURE HE ASSY" power plug on the back of the GC at least one hour
before stopping the gas supply.
If the power plug is removed and low purity gas enters the "PURE HE ASSY"
within one hour, the filter becomes saturated and requires replacement.
The "PURE HE ASSY" is a consumable item.

What is the [Stop Time]?

This is the time period to stop temperature control for each part after the [Stop GC] button is pressed
(or after operation of each program has been completed).
Control of the carrier gas and make up continues after the set stop time has elapsed if the flow off
time is set, even if the temperature control has stopped.

BID-2010 Plus Instruction Manual 23

3 Basic Operation

What is the [Flow Off Time]?

This is the time that carrier gas control is continued for after temperature control is stopped.
There is a danger of the column degrading if the carrier gas supply is stopped when the column
oven temperature is still high. Set the flow off time to provide sufficient time for the column
temperature to reduce after the temperature control is stopped.
The recommended value is at least 30 min for BID.

Initial Value (Factory setting)

The flow off time is set to [Cont] and the carrier gas and make up gas do not stop. After the
temperature of each of the parts has sufficiently dropped (recommended temp.: 50 °C), turn off the
power switch on the bottom right of the GC unit to turn off the system.

For details on stopping the GC, refer to the GC-2010 Plus instruction manual (CD-ROM version).
To restart the equipment, follow the procedures in "3.7 System Startup".

 It is possible to keep the inside of the cells and detector gas flow path clean by constantly
supplying sweep gas to detector cells even when the BID is unused (for example, if the system is
off or the gas chromatograph is not powered). A continuous sweep gas supply of around 5 to 10
mL/min is needed to reduce the restarting time.
 Around 5 to 10 mL/min of helium gas is consumed due to sweep gas flowing constantly even
when the system is off or the gas chromatograph is not powered, to protect the PURE HE ASSY,
keep the detector stabilized and reduce stabilization time when the detector is started.
Make sure to close the gas tap if you do not use the BID for a long time and want to turn off the
sweep gas supply. Follow the steps and cautions in "3.6.2 Sweep Gas" when stopping the sweep
gas.

! CAUTION
When stopping the supply of sweep gas for any reason, always pull out the
"PURE HE ASSY" power plug on the back of the GC at least one hour before
stopping the gas supply.
If the power plug is removed and low purity gas enters the "PURE HE ASSY"
within one hour, the filter becomes saturated and requires replacement.
The "PURE HE ASSY" is a consumable item.

24 BID-2010 Plus Instruction Manual

 4 Key Operation
4.1 Configuring Detector Settings
4.1.1 Display Screen
Push the [DET] key to display the main screen shown below, where settings such as the detector
temperature, signal output port and detector gas flow rate can be configured.
Signal output settings are displayed for the selected detector line. (See “8.3 Specifying the Analytical
Flow Line Components" in the GC-2010 Plus Instruction Manual (CD-ROM Version))

Main DET key screen

BID-2010 Plus Instruction Manual 25

4 Key Operation

4.1.2 List of Settings

 Detector Control On/Off
Settings: On/Off; default setting: On
Select "On" to enable detection control.
Temperature control and gas control are enabled and a signal is output from detectors that are
selected in a line and have detector control enabled. The detector temperature and gas of all
selected detectors, including those for which detector control is disabled, are controlled and
increased to the set value.
Signal output is stopped if detector control is disabled during use and resumed if it is enabled again.

 Set the detector temperature to 150 °C or higher when using. Using at a temperature lower than
150 °C can cause the baseline to become unstable.
 Using at a detector temperature higher than 320 °C for extended periods of time can shorten the
life of the detector.
A temperature that is between 150 °C and 300 °C and does not exceed the maximum usable
temperature of the column is recommended. Setting a high detector temperature when analyzing
oxidized gases containing a large amount of oxygen can also shorten the life of the detector. A
detector temperature of approximately 160 °C is recommended in this case.
Decreasing the detector temperature is also recommended if not using the BID.
 If a polyimide capillary column is used for the outer covering, some types of polyimides can cause
tailing if the detector temperature is higher than 300 °C, due to carbonization of the polyimide on
the column surface inserted in the detector. Cutting the section inserted in the detector can stop
this tailing, but lowering the detector temperature is recommended. The temperature does not
need to be set below 300 °C if using a highly heat resistant polyimide column or SUS capillary.

 Temp (°C)
Setting range: 0.0 to 350.0 °C; default setting: 25.0 °C
Set the detector temperature. Usually set the temperature slightly (final temperature + around 20 °C)
higher than the column oven temperature (final temperature of progressive temperature increase) to
prevent substances with a high boiling point from sticking to the inside of the detector.
See "16.6.4 Setting the maximum temperature limits" under "16.6 GC Configuration" in the GC-2010
Plus Instruction Manual (CD-ROM Version) for information on setting the maximum temperature.

 Set the detector temperature to 150 °C or higher when using. Using at a temperature lower than
150 °C can cause the baseline to become unstable.
 Using at a detector temperature higher than 320 °C for extended periods of time can shorten the
life of the detector.
A temperature that is between 150 °C and 300 °C and does not exceed the maximum usable
temperature of the column is recommended. Setting a high detector temperature when analyzing
oxidized gases containing a large amount of oxygen can also shorten the life of the detector. A
detector temperature of approximately 160 °C is recommended in this case.
Decreasing the detector temperature is also recommended if not using the BID.
 If a polyimide capillary column is used for the outer covering, some types of polyimides can cause
tailing if the detector temperature is higher than 300 °C, due to carbonization of the polyimide on
the column surface inserted in the detector. Cutting the section inserted in the detector can stop
this tailing, but lowering the detector temperature is recommended. The temperature does not
need to be set below 300 °C if using a highly heat resistant polyimide column or SUS capillary.

26 BID-2010 Plus Instruction Manual

 4.1 Configuring Detector Settings

 Plasma
Settings: On/Off; default setting: Off (plasma is always lit automatically after starting the gas
chromatograph. This setting changes to "On" when the plasma is lit.)
This setting changes to "On" when the plasma is lit and "Off" when it is not.

 Filter Time Constant

Settings: 4 ms, 5 ms, 10 ms, 20 ms, 50 ms, 100 ms, 200 ms, 500 ms, 1 s, 2 s; default setting:
200 ms
The effect of signal processing for the detector signal. Increasing the set value decreases noise.
However, it also decreases peak height.
Set the filter time constant at the ideal value for the half width of peaks.
See "13.4 Filter Signal Time Constant" in the GC-2010 Plus Instruction Manual (CD-ROM Version)
for more details.

 Signal Output Port

Settings: Off, Ch1, Ch2, Ch3, Ch4; default setting: channel is allocated automatically.
The channel of the output signal from the gas chromatograph is set. There are digital and analog
signals, and a total of 4 channels. However, only Ch1 and Ch2 support analog output.

 Background sig save

Settings: Off, Buff1, Buff2; default setting: Off
Baseline wander results (data analyzed without injecting a specimen) can be background saved in
the wave memory of the gas chromatograph for 30 minutes.

 Background sig comp.

Settings: Off, Buff1, Buff2; default setting: Off
A saved background signal can be subtracted from analysis results.
This makes it possible to output a signal with a stable baseline if the baseline wanders greatly.

 Det sig subtraction

Settings: Off, DET#1, DET#2, DET#3, DET#4; default setting: Off
An output signal from another detector of the same type can be subtracted in real time from the
output signal of the detector.
This cannot be used for the BID as only one unit can be loaded in the gas chromatograph.

See "13.5 Setting the Output Signals" in the GC-2010 Plus Instruction Manual (CD-ROM Version)
for details on detector signal output, background saving, background compensation and detector
signal subtraction.

BID-2010 Plus Instruction Manual 27

4 Key Operation

 Signal Range
Settings: x1, x10-1, x10-2, x10-3, x10-4; default setting: x10-1
Analog signals are output as x10-X if the analog signal type is Linear.
Change the setting if the maximum signal input value of the data processor is exceeded and "E"
(Error) is displayed as the peak mark, for example from x1 to x10-1 or from x10-2 to x10-3.
Digital signals are always output as x1, regardless of the setting.

 Signal Attenuation
Settings: x1, x2-1, x2-2, x2-3, x2-4; default setting: x2-1
Analog signals are output as 2-X if the analog signal type is Wide.
Change the setting if the maximum signal input value of the data processor is exceeded and "E"
(Error) is displayed as the peak mark, for example from x1 to x2-1 or from x2-2 to x2-3.
Digital signals are always output as x1, regardless of the setting.

 Analog Signal Type

Settings: Linear, Wide; default setting: Linear
Configure this setting when making an analog connection with the chromatopack.

Wide
Use this setting when connecting to the C-R8A, C-R7A or C-R7A plus using the standard accessory
wide range signal cable.
The signal from the gas chromatograph is raised to the one-half power when output and squared
when displayed after being input into the chromatopack.
Perform a calibration with the detector signal output set to off when connecting to the C-R8A, C-R7A
or C-R7A plus for the first time or when changing the chromatopack. See "2.7 Connecting external
device cables" in the GC-2010 Plus Instruction Manual (CD-ROM Version) for information on
calibration.

Linear
Configure this setting when connecting to chromatopacks other than the C-R8A, C-R7A or C-R7A
plus.
An optional cable (Signal Cable, Linear; part no. S221-47251-42) is required for linear signal
connections to the C-R8A, C-R7A or C-R7A plus.
Wide range calibration does not need to be performed for linear connections.

4.1.3 PF Menu List

PF Menu Description
PlasmaON Starts lighting the plasma. If the BID is selected in a line and the BID detector control and
detector gas control are on when the gas chromatograph is started, the lighting operation
starts automatically after the detector reaches the set temperature.
Det Gas This is displayed if an advanced pressure controller (APC) is installed. Set the gas flow
supplied to the detector. This is not displayed if no advanced pressure controller is
installed.
Next Det Switches to the settings screens of other installed detectors. This can also be done by
pressing the [DET] key from the detector screen. This is not displayed if no other
detectors are installed.

28 BID-2010 Plus Instruction Manual

 4.2 Checking Installation Settings

4.2 Checking Installation Settings

Press the [FUNC] key and select "7. Service/Maintenance" on the displayed screen to display the
[Service/Maintenance] screen.

BID-2010 Plus Instruction Manual 29

4 Key Operation

4.2.1 Installation (Position)

1. Press the [1] number key in the "Service/Maintenance" screen or use the up and down
cursor keys to move the cursor to "1. GC Installation" and press the [ENTER] key.

2. Check that the BID is recognized and is being displayed.

If it is not displayed, the control component may not be correctly installed or there may be
a malfunction.

3. Check that the installation position of the unit is correctly set.

The installation position of the BID is 2.

4. Change the installation position by using the up and down cursor keys to move the cursor
to the applicable field, entering a numerical value and pressing [ENTER].
Installation positions are as follows.
(0 = not installed; 9 = installed in a position not shown in the diagram.)

View from above

30 BID-2010 Plus Instruction Manual

 4.2 Checking Installation Settings

4.2.2 Installation (Piping)

1. Press the [2] number key in the "Service/Maintenance" screen or use the up and down
cursor keys to move the cursor to "Installation (Piping)" and press the [ENTER] key.

2. Check that the control component is recognized and is being displayed.

The control component is automatically recognized and displayed if it is correctly installed.
If it is not displayed, the control component may not be correctly installed or there may be
a malfunction.

3. Check the slot number.

Select the slot number of the advanced pressure controller connected to the detector.
The DET APC No. and recognition are automatically displayed if a slot is set.
"APC (BID)" is used for the BID.

4. Check the heater port.

Select the heater port of the detector that the flow controller set in the slot is connected to.

See "16.7 Service and Maintenance" in the GC-2010 Plus Instruction Manual (CD-ROM
Version) for more details.

BID-2010 Plus Instruction Manual 31

4 Key Operation

4.2.3 Checking Line Configuration (Detector Settings)

Press the [SET] key to display the SET key screen.
Press [LineConfg] in the PF menu to display the Line Configuration screen.

Check that the BID is set in the appropriate line in the Detector field.
Change the line configuration by using the up and down cursor keys to move the cursor to the BID
line, using the left and right cursor keys to select a line number and pressing the [ENTER] key.

See "8. Setting the Analytical Parameters and File Management" in the GC-2010 Plus Instruction Manual
(CD-ROM Version)
for more details.

When using BID, set BID only in its analysis line.

Putting the BID in the same analysis line as other detectors causes values such as retention time and
area value to be displayed incorrectly. This is because, unlike other detectors, pressure is applied inside
the BID, meaning that values such as flow and split ratio are calculated by a different method from other
detectors. This also means that advanced flow technologies such as backflushing, detector splitting,
detector switching and MDGC-2010 are not supported.

32 BID-2010 Plus Instruction Manual

 4.3 Selecting a Detector

4.3 Selecting a Detector

The following key operations and screen displays are used when selecting a detector.
Press the [DET] key to display the Detector settings screen. If multiple detectors are installed, the
settings screen of the currently selected detector is displayed.
The PF menu display can be changed by pressing the toggle key and different detectors can be
selected by pressing [Next Det] (PF1).
"No detector" is displayed if the [DET] key is pressed when no detector is selected in the line.

BID-2010 Plus Instruction Manual 33

4 Key Operation

4.3.1 Setting the Detector Gas

1. Press the [DET] key to display the Detector settings screen.

2. Press [Det Gas] in the PF menu to display the detector gas settings screen.

3. Set the detector gas flow between 20 and 100 mL/min (around 5 to 30 kPa).
Recommended detector gas flow settings are as follows.
Column Flow Detector Gas Flow (Recommended)
Less than 10 mL/min 50 mL/min
10 to 15 mL/min 70 mL/min
15 mL/min or greater 100 mL/min

Gas flow can be set between 0 and 100 mL/min.

However, the plasma becomes unstable if the gas flow is less than 20 mL/min, causing lighting
to be suspended and a message saying "DCG flow rate is not enough" to be displayed.
Using a flow higher than that recommended decreases sensitivity.
Using a flow lower than that recommended increases sensitivity but causes the following
phenomena:
 Dynamic range wanders and detection on the high-density side becomes difficult, causing
poor peak shapes.
 Solvents or substances with a high boiling point leave residue or stick to the inside of the
detector, causing operational instability such as baseline wandering and decreased
sensitivity.
PF Key Description
Return Returns to the Detector settings screen.
Program Displays the detector gas flow program screen.
On/Off Turns detector gas flow control on and off.

34 BID-2010 Plus Instruction Manual

 4.4 Detector On/Off

 It is possible to keep the inside of the cells and detector gas flow path clean by constantly
supplying sweep gas to detector cells even when the BID is unused (for example, if the system is
off or the gas chromatograph is not powered). A continuous sweep gas supply of around 5 to 10
mL/min is needed to reduce the restarting time.
 Around 5 to 10 mL/min of helium gas is consumed due to sweep gas flowing constantly even when
the system is off or the gas chromatograph is not powered, to protect the PURE HE ASSY, keep
the detector stabilized and reduce stabilization time when the detector is started.
Make sure to close the gas tap if you do not use the BID for a long time and want to turn off the
sweep gas supply. Follow the steps and cautions in "3.6.2 Sweep Gas" when stopping the sweep
gas.

4.4 Detector On/Off

If BID control is [Off], use the cursor keys (up/down) to move to the [Off] position at the top right of
the screen, use the cursor keys (left/right) to change the BID detector control to [On] and press the
[ENTER] key.

4.5 Turning the Detector Light On and Off

See "3.10 Lighting the Plasma" for details on turning on the plasma light of the detector.
See "3.11 Turning off the Plasma" for details on turning off the plasma light of the detector.

4.6 Setting the Range

Change the range (attenuation) if making an analog signal connection.
This does not need to be set if using GCsolution or LabSolutions.
See "3.12 Setting the Range/Attenuation" for details on changing this.

BID-2010 Plus Instruction Manual 35

4 Key Operation

4.7 Zero Adjustment

Adjust the zero point of the output signal.

1. Select the detector you want to set the zero point of in the Monitor Main screen.
Press the [MONIT] key to display the main screen. If the BID is not displayed in the screen,
press [Chng Line] and select the line where the BID is installed.
See "9. Monitoring the GC" in the GC-2010 Plus Instruction Manual (CD-ROM version) for
details on the Monitor screen. (Press the toggle key if [Chng Line] is not displayed in the
PF menu.)

2. Perform one of the following key operations.

36 BID-2010 Plus Instruction Manual

 4.7 Zero Adjustment

 Key Operation 1: Automatic Zero Adjustment

Press [Zero Adj] in the PF Menu. The signal output becomes 0 μV and the baseline automatically
moves to the zero point.
When using the chromatopack, the baseline may not be displayed in the full scale range on the
chromatopack depending on the detection range or the attenuation of the chromatopack. Adjust the
zero point using the zero adjustment function of the chromatopack in this case.
See "4.7 Zero Adjustment" for details.

While zero adjustment in GCsolution and LabSolutions is the same function as with the gas
chromatograph, performing zero adjustment on the chromatopack does not adjust the output signal of the
detector.
Make sure to perform zero adjustment on the gas chromatograph itself.

Zero adjustment

Z key of
chromatopack

Zero point of
chromatopack

Analysis can be performed

when the baseline is stable.

<Example> If using the chromatopack

If performing this key operation does not change the signal level, this may be because the plasma
light is not lit or the output signal is not in the normal range. See "6 Troubleshooting" for details on
how to solve this problem.

BID-2010 Plus Instruction Manual 37

4 Key Operation

 Key Operation 2: Manual Zero Adjustment

The signal level can be changed manually by pressing [Up] and [Down] in the PF menu.

<Example> If using the chromatopack

[Down]

Z key of
[Up] chromatopack

Zero point of
chromatopack

Went into negative numbers Zero adjustment Analysis can be

because [Down] was of chromatopack performed when the
pressed too many times. baseline is stable.

If performing this key operation does not change the signal level, this may be because the plasma
light is not lit or the output signal is not in the normal range. See "6 Troubleshooting" for details on
how to solve this problem.

38 BID-2010 Plus Instruction Manual

 4.7 Zero Adjustment

 Key Operation 3: Removing Zero Adjustment

Press [ZeroFree] in the PF menu to restore the baseline to its level before zero adjustment was
performed.

BID-2010 Plus Instruction Manual 39

4 Key Operation

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40 BID-2010 Plus Instruction Manual

 5 Maintenance and Inspection
5.1 Maintenance and Inspection
You do not need to replace any parts in the BID, but the following operations need to be performed
to maintain the injection port or other detectors.

Refer to section "18. Maintenance and Inspection" in the GC-2010 Plus Instruction Manual (CD-ROM
version) for details.

Make sure to stop the system as instructed in "3.14 System Stopping" before performing
maintenance and inspections to ensure safety and maintain the performance of the equipment.

! WARNING
High temperature
There is a risk of fire. Check that the various sections have cooled sufficiently
before performing maintenance and inspections.
Your hand may come into contact with hot parts of the BID when removing the
INJ/DET upper cover of the gas chromatograph.
Make sure to wait until the detector has cooled sufficiently before performing
maintenance and inspections.

BID-2010 Plus Instruction Manual 41

5 Maintenance and Inspection

This page is intentionally left blank.

42 BID-2010 Plus Instruction Manual

 6 Troubleshooting
This section describes countermeasures to common problems that may occur with the BID.
Refer to "19. Troubleshooting" in the GC-2010 Plus Instruction Manual (CD-ROM version) if a
problem with the gas chromatograph occurs.
Contact your Shimadzu representative if the measures described here do not solve the problem or if
a malfunction not described here occurs.

 The plasma is not lit.

Cause Countermeasures
The column is not connected. Connect the column.
The helium gas is not being supplied or the Supply helium gas and set a suitable flow.
flow is not suitable. Refer to "3.6 Setting the Flow Rate of Detector Gases".
The insertion length of the column is not Make sure that 74 mm of column is inserted in the BID
suitable. detector. If the insertion length is different, use the graphite
fixing bracket to adjust it.
The end of the SUS column is bent. Straighten the column toward the end from the graphite ferrule.
The temperature of the detector is too low. Set the temperature of the detector higher. (recommended:
150 to 300 °C)
The temperature of the detector is too high. Set the temperature of the detector lower. (recommended: 150
to 300 °C)
There is water in the detector. Water impedes the lighting of the plasma light. Increase the
detector temperature to 350 °C, leave for approximately 12
hours and perform the lighting operation again.
The purity of the helium has decreased due Wait for the gas in the pipe to be replaced and the purity of the
to air entering when the gas cylinder was supplied gas to improve. If there is no improvement after
changed. leaving for approximately 12 hours, this means that the filter of
the "PURE HE ASSY" may be saturated and requires
replacement. Contact your Shimadzu representative for
replacement.
The pipe between the BID and the APC is The pipe needs to be replaced. Contact your Shimadzu
blocked. representative for replacements.
There is an abnormality in the plasma light Contact your Shimadzu representative for replacements.
detection or in the BID control unit.
A malfunction has occurred in the plasma Contact your Shimadzu representative for replacements.
generation circuit.
The APC is malfunctioning. Contact your Shimadzu representative for replacements.

 There is an abnormality in the baseline. There is a large amount of noise.

Cause Countermeasures
The insertion length of the column is not Make sure that 74 mm of column is inserted in the BID
suitable. detector. If the insertion length is different, use the graphite
fixing bracket to adjust it.
The end of the SUS column is bent. Straighten the column toward the end from the graphite ferrule.
The electrical connector is not correctly Contact your Shimadzu representative for replacements.
connected.

BID-2010 Plus Instruction Manual 43

6 Troubleshooting

There are large amounts of impurities in the  Purge the air from the flow path. Perform the clean up
carrier gas or detector gas. process described in section "7. Starting and Stopping the
GC [SYSTEM]" of the GC-2010 Plus instruction manual
(CD-ROM version).
 Replace the gas cylinder with one containing higher purity
gas. The recommended purity is 99.9999% or higher. If there
is no improvement after replacing the gas cylinder and
leaving for approximately 12 hours, this means that the filter
of the "PURE HE ASSY" may be saturated and requires
replacement. Contact your Shimadzu representative for
replacements.
The gas is leaking. Contact your Shimadzu representative for replacements.
The APC is malfunctioning. Contact your Shimadzu representative for replacements.

 There is an abnormality in the baseline. The baseline is drifting or wandering.

Cause Countermeasures
The insertion length of the column is not Make sure that 74 mm of column is inserted in the BID
suitable. detector. If the insertion length is different, use the graphite
fixing bracket to adjust it.
The end of the SUS column is bent. Straighten the column toward the end from the graphite ferrule.
There are large amounts of impurities in the  Purge the air from the flow path. Perform the clean up
carrier gas or detector gas. process described in section "7. Starting and Stopping the
GC [SYSTEM]" of the GC-2010 Plus instruction manual
(CD-ROM version).
 Replace the gas cylinder with one containing higher purity
gas. The recommended purity is 99.9999% or higher. If there
is no improvement after replacing the gas cylinder and
leaving for approximately 12 hours, this means that the filter
of the "PURE HE ASSY" may be saturated and requires
replacement. Contact your Shimadzu representative for
replacements.
The injection port (glass insert) or column is Clean or replace the glass insert.
dirty. Refer to section "12. Injection Port" in the GC-2010 Plus
Instruction Manual (CD-ROM version).
Condition the column.
The temperature of the various sections is Check the temperature of the various sections. Contact your
not stable. Shimadzu representative if this does not stabilize after a long
period of time.
The flow is not stable. Check the pressure and flow of the APC. Contact your
Shimadzu representative if this does not stabilize after a long
period of time.
Dirt or water is flowing out from inner parts Raise the detector temperature and leave for approximately 12
such as the O-ring, etc. hours to stabilize operation. Contact your Shimadzu
representative if operation does not stabilize even after a long
period of time has elapsed.
The pipe between the BID and the APC is The pipe needs to be replaced. Contact your Shimadzu
blocked. representative for replacements.
The gas is leaking. Contact your Shimadzu representative for replacements.
The APC is malfunctioning. Contact your Shimadzu representative for replacements.

44 BID-2010 Plus Instruction Manual

 6 Troubleshooting

 Peak is not detected

Cause Countermeasures
Plasma goes out. Perform the lighting procedure again.
There are large amounts of impurities in the  Purge the air from the flow path. Perform the clean up
carrier gas or detector gas. process described in section "7. Starting and Stopping the
GC [SYSTEM]" of the GC-2010 Plus instruction manual
(CD-ROM version).
 Replace the gas cylinder with one containing higher purity
gas. The recommended purity is 99.9999% or higher. If there
is no improvement after replacing the gas cylinder and
leaving for approximately 12 hours, this means that the filter
of the "PURE HE ASSY" may be saturated and requires
replacement. Contact your Shimadzu representative for
replacements.
The plasma position is inadequate. Check that the detection gas flow rate is correct, and perform
the lighting operation again.
Detector control is not ON. Set the detector control to ON.

 Cannot perform zero adjustment

Cause Countermeasures
Air remains inside the detector. Let detector gas flow through and wait at least an hour.
Detector gas is not on. Let suitable detector gas flow through and wait at least an
hour.

 The retention times for all peaks change to the same direction
Cause Countermeasures
The APC offset is fluctuating. Perform APC calibration.
The sweep gas supply needs to be stopped during calibration.
For instructions on how to stop the sweep gas, refer to the
cautions in "3.6.2 Sweep Gas".
For instructions on how to perform APC calibration, refer to
"3.6 AFC and APC Offset Calibration" in the GC-2010 Plus
Instruction Manual (CD-ROM Version).
Trap ASSY failure. Replace the trap ASSY and then perform APC calibration.
Contact your Shimadzu representative for replacement of the
trap ASSY.
The APC is malfunctioning. Contact your Shimadzu representative for replacements.

BID-2010 Plus Instruction Manual 45

6 Troubleshooting

 Low detection sensitivity

Cause Countermeasures
The insertion length of the column is not Make sure that 74 mm of column is inserted in the BID
suitable. detector. If the insertion length is different, use the graphite
fixing bracket to adjust it.
The end of the SUS column is bent. Straighten the column toward the end from the graphite ferrule.
The split ratio is too large (for split analysis). Reduce the split ratio.
Insufficient sample injection, or the sample Increase the amount of sample injection. Or increase the
concentration is too low. sample concentration.

1. Over-increasing the injection amount may cause

contamination of the injection port.
2. Excessively high concentrations can contaminate the
detector.
The range and attenuation values are Change the range and attenuation values.
unsuitable.
The capillary column is not mounted Mount the capillary column correctly.
correctly. Refer to "3.4 Mounting the Column"
An unsuitable column is being used, and the Consider factors such as the polarity and replace with a
peak is tailing. suitable column.
Sample components are attached to the Reconsider the analysis conditions such as inert processing
injection section, column and detector. for the insert, cutting the detector insert section, changing the
temperature of the injection section or detector, or changing
the column.
There are large amounts of impurities in the  Purge the air from the flow path. Perform the clean up
carrier gas or make up gas. process described in section "7. Starting and Stopping the
GC [SYSTEM]" of the GC-2010 Plus instruction manual
(CD-ROM version).
 Replace the gas cylinder with one containing higher purity
gas. The recommended purity is 99.9999% or higher. If there
is no improvement after replacing the gas cylinder and
leaving for approximately 12 hours, this means that the filter
of the "PURE HE ASSY" may be saturated and requires
replacement. Contact your Shimadzu representative for
replacements.
The carrier gas is leaking. Contact your Shimadzu representative for replacements.
APC flow rate is unsuitable. Check that the APC flow rate is set to 40 mL/min, VENT1 flow
rate is set to about 30 mL/min, and VENT2 flow rate is set to
about 10 mL/min.
If the flow rate is substantially wrong, a resistance pipe may be
blocked or the APC may be damaged. Contact your Shimadzu
representative for replacements.

 There is an abnormality in the peak shape.

Cause Countermeasures
The plasma is temporarily shielded and the Reduce the size of the sample injection, increase the split ratio
sample is not ionized because the amount when split analysis is performed, or reduce the sample
of sample injection is too large, or the concentration.
sample concentration is too high.
The tip of the capillary column is carbonized Disconnect the column, cut into a suitable shape and reduce
and some of the sample is attached. the detector temperature below 300 °C.

46 BID-2010 Plus Instruction Manual

 6 Troubleshooting

 Other Problems
For any of the phenomena below, refer to section "19.1 Troubleshooting" in the GC-2010 Plus
instruction manual (CD-ROM version).
 APC does not match the setting values.
 Cannot stop a gas leak.
 Temperature of each part does not increase.
 Cannot set the column inlet pressure or total flow rate, or the actual state is clearly different from
the setting values.
 A ghost peak is detected.
 There is an abnormality in the peak shape.
 Poor reproducibility of the retention time.
 Poor reproducibility of the peak area value.
 High background level.

BID-2010 Plus Instruction Manual 47

6 Troubleshooting

6.1 Error Messages

The GC-2010 Plus has a self diagnostic function. When a malfunction is detected, the following error
messages are displayed and an alarm sounds. The displayed error details are registered in the error
log.
A error cancellation confirmation screen is displayed when a "Confirmation screen" error occurs. In
this case, select one of the following.

Cancel error Returns to the state before the error occurred, and system control continues.
If the error has been solved, the error message is no longer displayed.
If the error has not been solved, the error message continues to be displayed.
Determine the cause of the error, take the necessary measures and cancel the
error.
Hold error Select this to maintain the current state in order to determine the cause of the error
and take the necessary measures.

The "Code" in the table below is a fixed error number. If you need to contact your Shimadzu
representative, notify them of this number. The code number is also recorded in the error log.

The following message is displayed if a ROM malfunction occurs and the GC-2010 Plus cannot
start.
There are no codes for these errors.

Rom Error Please call a service person.

Rom Error(Fatal) Please call a service person.

The system cannot be used when these messages are displayed.

Turn the system power OFF, and contact your Shimadzu representative.

48 BID-2010 Plus Instruction Manual

 6.1 Error Messages

6.1.1 Errors for Lighting the Detector

Confirmation
Code Message Remarks
Screen
4129 to 4132 DET#n Discharge failed Yes
This is displayed when the output from the plasma generation circuit shorts. The error is not
cleared until the system is rebooted. If the error above is still displayed after turning the power
back on, a cable may be damaged. Turn the system power OFF, and contact your Shimadzu
representative.

Confirmation
Code Message Remarks
Screen
4208 to 4211 DET#n Plasma on failed No
This is displayed when the BID plasma does not light. Check the detector temperature and
detector gas flow rate, and perform the light operation again.

Confirmation
Code Message Remarks
Screen
4212 DCG APC are not ready No
This is displayed when the detector gas (DCG) APC is not ready when lighting the plasma.
Check that the gas supply pressure is stable and that there are no leaks. If there are no problems
with the gas supply, there may be a hardware malfunction. Turn the system power OFF, and
contact your Shimadzu representative.

Confirmation
Code Message Remarks
Screen
4213 DCG flow rate is not enough No
This is displayed when the DCG flow rate is below 20 mL/min when or after lighting is started.
The plasma is forcibly turned off. Check the DCG flow rate setting value and gas supply pressure,
and check that there are no leaks. If there are no problems with the gas supply, there may be a
hardware malfunction. Turn the system power off and contact your Shimadzu representative.

BID-2010 Plus Instruction Manual 49

6 Troubleshooting

6.1.2 APC Error

Confirmation
Code Message Remarks
Screen
2144 to 2147 DetAPCn DCG leaks Yes
This is displayed when the pressure does not increase to the set value. Check that the gas is
being supplied and that there are no leaks from the connectors.

Confirmation
Code Message Remarks
Screen
2148 to 2151 DetAPCn DCG valve leaks Yes
The sweep gas flow rate is not stable. If there are no problems with the gas supply, follow the
procedure below to make the necessary adjustments. If the issue is not resolved after making the
adjustments, the valve inside the APC may be malfunctioning.
Turn the system power OFF, and contact your Shimadzu representative.
(1) Refer to "3.6 Setting the Flow Rate of Detector Gases" to turn the sweep gas flow rate OFF,
and check that the flow rate monitor value is 0 mL/min.
(2) If the flow rate monitor value is not 0 mL/min, perform APC calibration. For details on how to
perform APC calibration, refer to "3.6 AFC and APC Offset Calibration" in the GC-2010 Plus
Instruction Manual (CD-ROM Version).
(3) Adjust the sweep gas flow rate to approximately 5 to 10 mL/min. (Refer to "3.6.2 Sweep
Gas")

Confirmation
Code Message Remarks
Screen
2152 to 2155 DetAPCn DCG is out of control Yes
Check that a stable supply of gas is flowing at the required pressure.
If there are no problems with the gas supply, the sweep gas may be flowing at a greater rate than
the set rate. Check that the sweep gas flow rate is approximately 5 to 10 mL/min. If there are no
problems with the sweep gas flow rate, there may be a problem with the APC control system.
Contact your Shimadzu representative.

50 BID-2010 Plus Instruction Manual

 6.1 Error Messages

6.1.3 Errors due to Incorrect Inputs

Confirmation
Code Message Remarks
Screen
5079 to 5082 DCGn calc. prss out of range No
The pressure calculated from the set flow rate value exceeds the setting range. Change the
detector gas flow rate setting value.

Confirmation
Code Message Remarks
Screen
5006 to 5008 CARn calc. prss out of range No
5070 to 5072
The carrier gas pressure calculated from the set line speed, flow rate, split ratio, column
temperature, column settings or APC flow rate value for BID exceeds the setting range. Change
the various setting values.

Confirmation
Code Message Remarks
Screen
5009 to 5011 CARn calc. flow out of range No
The carrier gas overall flow rate calculated from the set pressure, split ratio, column temperature,
column settings or APC flow rate value for BID exceeds the setting range. Change the various
setting values.

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6 Troubleshooting

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52 BID-2010 Plus Instruction Manual

 7 Maintenance Parts
7.1 Maintenance Parts List
Part Number Name Notes
S221-76010-81 BID ASSY,100-120 Detector section 100 V
S221-76010-88 BID ASSY,200-240 Detector section 200 V
S221-74950 CAP. ADAPTOR BID Capillary adapter
S221-74937-41 COLLECT CABLE ASSY Cable assy for collector
S221-74979-41 BIAS CABLE ASSY Cable assy for bias
S221-74963-41 LED CABLE ASSY LED Cable ASSY
S221-76011-41 POWER UNIT, BID High voltage power ASSY
S221-76039-41 CPU CABLE ASSY CPU - High voltage power cable ASSY
S221-76044-41 CABLE, DET-POWER Cable ASSY for DET-POWER
S221-76012-41 BID-2010 Plus CONTROLLER
S221-74880-81 APC-2010 Plus, BID Aging is completed
S221-76050-81 PURE HE ASSY 100
S221-76050-88 PURE HE ASSY 200
S221-76091-81 HELIUM PURIFIER, 100V Includes 100 V connection parts
S221-76091-88 HELIUM PURIFIER, 200V Includes 200 V connection parts
S221-76093-43 PRESSURE CONTROLLER, Aging is completed
2K 8KIN CL
S221-76013-41 INJ/DET COVER BID2010 Plus INJ/DET section cover for BID
S221-26170-03 PIPE ASSY MF-MF 3X0.3 Length 300 mm O.D. = 3 mm
S221-26171-06 PIPE ASSY MF-MM 3X0.6 Length 600 mm O.D. = 3 mm
S221-76094-41 RESTRICTOR ASSY, BID
S221-41532-02 GRAPHITE JIG, BID

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7 Maintenance Parts

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54 BID-2010 Plus Instruction Manual

 8 Specifications
8.1 BID-2010 Plus Specifications
Item Specification Value
Detection Method Low frequency dielectric barrier discharge ionization method
Range 5 steps (for analog or linear output): ×1 / ×10-1 / ×10-2 / ×10-3 / ×10-4
Attenuation 5 steps (for analog or wide output): ×1 / ×2-1 / ×2-2 / ×2-3 / ×2-4
Dynamic range 105
Minimum detectable quantity 1 pgC/s (dodecane, discharge gas flow 50 mL/min)
Maximum usage 350 °C
temperature

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8 Specifications

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