CP 2 - Investigating PH

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Edexcel Chemistry GCSE

CP 2: Investigate the change in pH on


adding powdered calcium hydroxide or
calcium oxide to a fixed volume of dilute
hydrochloric acid
Notes

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Investigating pH (neutralisation)

Aim
Investigate the change in pH on adding powdered calcium hydroxide or calcium oxide to a fixed
volume of dilute hydrochloric acid.

Equipment list

● 25 cm​3 measuring cylinder or volumetric pipette and pipette filler
● Beaker
● Glass rod
● Universal indicator or pH probe
● Spatula

Chemicals required
● Hydrochloric acid
● Powdered calcium hydroxide or calcium oxide

Method
1. Using the measuring cylinder or volumetric pipette, add 25 cm​3​ of dilute hydrochloric acid to
a beaker.
2. Add a few drops of universal indicator. Compare the initial colour of the solution to a pH
colour chart and record the pH. Alternatively, a pH probe can be used.
3. Add calcium hydroxide or calcium oxide (one level spatula at a time) to the beaker, stirring
and recording the pH between additions.
4. Stop adding calcium hydroxide/calcium oxide when the pH remains constant.

Key points
● The equations for the reactions, depending on which base is used, are:
CaO + 2HCl → CaCl​2​ +H​2​O
Ca(OH)​2​ + 2HCl → CaCl​2​ + 2H​2​O
● A volumetric pipette offers greater accuracy than a measuring cylinder when measuring the
volume of hydrochloric acid.
● Stirring the solution before taking a pH reading ensures the reaction is complete and that
the pH is consistent throughout the mixture.
● Using a pH probe instead of universal indicator offers greater accuracy.

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Diagram

Hans Kirkendoll ​ ​CC0 1.0

Safety Precautions
● Safety glasses must be worn.
● Hydrochloric acid is corrosive in high concentrations. Wash hands immediately after any
contact with the skin.
● Calcium hydroxide may cause skin and eye irritation so wear gloves and safety goggles.
Wash hands immediately after any contact with the skin.
● Clear up any spillages or broken glassware immediately.

Analysis of results
The starting pH and final pH can be recorded to investigate the effect of adding calcium
hydroxide/calcium oxide to hydrochloric acid.

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