(@bohring - Bot) Adv Paper 1 (07.05.2024)

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(MOCK TEST)

JEE (Advanced)
(07.05.2024)

PAPER – 1

Time Allotted: 3 Hours Maximum Marks: 186

General Instructions:

 The test consists of total 54 questions.

 Each subject (PCM) has 18 questions.

 This question paper contains Three Sections.

 Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.

 Each Section is further divided into Two Parts: Part-A & Part-B.

1. Part–A (01 – 04) contains 4 multiple choice questions which out of 4 options have only one
correct answer. Each question carries +3 marks for correct answer and –1 mark for wrong
answer.

Part-A (05 – 12) contains 8 multiple choice questions which have one or more than one
correct answer. Each question carries +4 marks for all correct answer.
Full Marks : +4 If only (all) the four option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.

2. Part-B (01 – 06) contains 6 Numerical answer type questions with answer
XXXXX.XX and each question carries +3 marks for correct answer. There is no negative marking.

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Physics SECTION – I

PART – A
(One Options Correct Type)
This part contains 04 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.

1. At t = 0, an object is projected from ground with an initial velocity of 100 m/s directed at angle 37
above the horizontal. At t = 4 sec it explodes in air into two parts with the mass ratio 1 : 2. Take
the point of projection as origin and horizontal and vertical directions as x and y axes respectively.
The motion of object is confined to the xy plane. At t = 10 sec, the coordinates of the lighter part
is (400m, 60m). Find the coordinates of the heavier part at this moment. (i.e. t = 10 sec) (Given g
4
= 10 m/s2, cos37  )
5
(A) (500 m, 140 m)
(B) (500 m, 140 m)
(C) (500 m, 120 m)
(D) (1000 m, 120 m)

2. A pipe P open at one end but closed at the other end is filled with hydrogen gas at temperature
127C. An another pipe Q open at both ends and having length equal to twice the length of pipe
P is filled with a mixture of 1 mole of Hydrogen and 1 mole of Helium gases at temperature
147C. The pipe P is vibrating in its first overtone and pipe Q is vibrating in its second overtone.
f
The ratio of their frequencies of vibration P is
fQ
3
(A)
5
4
(B)
3
2
(C)
3
1
(D)
3

3. A particle of mass m is attached to one end of a light inextensible


string which passes through a hole in a frictionless table top. At the m
other end of the string is attached a block of mass M. Initially the
particle is moving in a circle of radius r with angular velocity . If the
hanging block is pulled slightly downwards and then released, it will
undergo small oscillation. Find the frequency of the oscillation.
M
1 3m2
(A)
 M
2 3m2
(B)
 M
1 3m 2
(C)
2 M

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3 3m 2
(D)
2 M

4. A stone is projected in air directed at an angle  above the horizontal.


u
The maximum angle of projection  with the horizontal so that the
stone always moves away from the thrower during its motion in air, is
(neglect air resistance)
 v
O
 1
(A) sin1  
3
2
(B) sin1  
3
 8
sin1 
 3 
(C)
 
 5
sin1 
 3 
(D)
 

(One or More than one correct type)


This part contains 08 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.

5. Two elastic balls of masses m1 and m2 are placed on top of each other (with a m1
small gap between them) and then dropped onto the ground. Then
m2

m2
(A) The upper ball ultimately receives the largest possible fraction of total energy if 3
m1
m1
(B) The upper ball will reach a maximum height of 4h if 3
m2
(C) If m2 >> m1 the maximum height attained by ball m1 after collision will be 9h.
(D) If m2 >> m1, the maximum height attained by the ball 2h.

6. Two insects each of mass m are at opposite ends of a diameter of a turntable of radius R.
2
Moment of inertia of the turntable about its central vertical fixed axis is I  mR2 . The turntable is
3
rotating freely with angular speed  and both the insects start crawling slowly towards each other
on the turntable. Then
(A) The insect have to apply maximum horizontal force on the turntable when they are at a
R
distance from the centre of the turntable.
2
(B) The insects have to apply maximum horizontal force on the turntable when they are at a
R
distance from the centre of the turntable.
3
(C) The angular speed of the turntable when the insects exert maximum force on the
turntable equal 3.
(D) The maximum force exerted by an insect on the turn table during the motion is equal to
3m2R.

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7. Consider a frictionless tunnel is made in Earth along a diameter. A uniform string of mass per unit
length  and length R/3 (where R is the radius of the earth) is suspended in the tunnel with its
upper end at the surface of the earth. (Given acceleration due to gravity at the surface of the
earth = g)
5gR
(A) The minimum force required to hold the string in the tunnel is
18
(B) If the string is released in the tunnel from rest the speed of the string when its lower end
2gR
touches the centre of the earth is
3
(C) If the string is released in the tunnel from rest the speed of the string when its lower end
gR
touches the centre of the earth is
3
(D) The minimum work required to pull the chain completely to the surface of the earth is
2gR 2
81

8. A particle of mass m and charge q moving in gravity y


free space with velocity v0 parallel to x-axis enters a E0

region of uniform electric field E  E0 ˆj at point C. At C
v0
the moment particle collides elastically with a smooth d/2
surface at D the electric field E is switched off and a

magnetic field B  B kˆ is switched on. If the particle
0
O D x
hits the surface directly at point O after rebounding d
from point D, then which of the following option(s) is/are
correct.
mv 02
(A) E0 
qd
mv 02
(B) E0 
2qd
2mv 0
(C) B0 
qd
mv 0
(D) B0 
qd

9. In the circuit shown in the figure initially the switch ‘S’ was open R C
and capacitor uncharged. Now the switch ‘S’ is closed at time t =
0, then which of the following statement(s) is/are correct. (Given
L R L
C )
2R2

S

3
(A) The minimum current passing through the cell is .
4R
(B) The current passing through the cell will be minimum at time t = RCn2.

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(C) The charge on the capacitor when current passing through the cell is minimum, is q =
3C
4
(D) When the current in the circuit is minimum, the ratio of potential difference across the
2
inductor and the capacitor equals .
3

10. In the given AC circuit as shown in the figure. 200 F 100 

1H 50 

~
200 V, 50 rad/s

(A) The rms current through the ac mains is 10 A


(B) Total power dissipated in the circuit is 600 W
(C) The rms potential difference across the inductor is 100 V

(D) The phase difference between the currents passing in the capacitor and inductor is
2

11. In a Young’s double slit apparatus a parallel beam screen y


of light of wavelength  = 0.3 mm with respect to air
is incident on the slits at angle 30 with x-axis as S1
shown in the figure. Distance of slits S1 and S2 from
point O are equal. The medium to the left and right 30
side of the plane of the slits have refractive indices O x
S2
5 25
and respectively. Distance between the slits 30 S2
3 18
S1 and S2 equals 1.5 mm. Distance between the 1m
plane of the slits and the screen is 1m. Then
(A) The y-coordinate of the point on the screen where the phase difference between
interfering waves is zero equals 0.75 m.
(B) The y-coordinate of the point on the screen where the phase difference between
interfering wave is zero equals 0.36 m.
(C) If the intensity due to each light wave at point O is I0 then the resultant intensity at point O
equal 3I0.
(D) The y-coordinate of the nearest minima from the origin O is approximately y = 48 mm.

12. A thin uniform rod of length  and mass 2m suspended vertically is free A

to rotate about a smooth horizontal axis which passes through its upper
end A. A point mass m moving horizontally with velocity v0 hits the
lower end B of the rod and sticks to it. After collision the rod just
reaches the horizontal position. Which of the following statement(s)
is/are correct?
v0
m B

(A) The value of v0 is 4g


9g
(B) The angular acceleration of the rod when it reaches the horizontal position is
8

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(C) The magnitude of vertical component reaction force by the hinge on the rod in horizontal
3mg
position is
5
(D) The magnitude of acceleration of centre of mass of the system (rod + point mass) when
4g
the rod is in horizontal position is .
5

PART – C
(Numerical Answer Type)
This part contains 06 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. XXXXX.XX).

1. A soap bubble of radius R1 is slowly given a charge q. Because of mutual repulsion of the surface
charges, the radius increases slightly to R2. The air pressure inside the bubble drops, because of
v 
the expansion, to p  1  , where p is the atmospheric pressure, v1 is the initial volume and v2 is
 v2 
the final volume. If q = 4n2 0PR2 (R32  R13 ) . Find the value of n. (neglect the surface tension).

2. A convex lens has a focal length 15 cm in air. The O


refractive index of lens is 1.5. The lens is placed
inside the water at a depth 11 cm below the water 48 cm
surface. A point object is placed in air on the
principal axis of the lens at a height 48 cm above
the water surface as shown in the figure. The 11 cm
distance (in m) of final image of the object from the
water surface, is

125
3. A non-uniform string of length L  m and mass m has a non-uniform linear density given by 
64
= 0x where x is distance from lower end of the string and 0 is a constant. Find the time required
(in sec) for a transverse pulse generated at lower end of the string to travel to the other end of the
string.

4. Consider a cylindrical body that can move without friction along a


straight wire parallel to its axis of symmetry as shown in the figure.
Particles moving horizontally at speed v 0  (3  2 2 ) m/s collide
the body uniformly from both left and right. Collisions with the left
end of the body are elastic while those with the right end are
completely inelastic though the particles do not stick to the cylinder
after the collision. The speed (in m/s) of the cylinder after a long
time will be (Assume that temperature of body remains constant)

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5. The radiation emitted when an electron jumps from the third excited state to second excited state
in doubly ionized Li ion (z = 3) falls on a metal surface to produce photoelectron, when the
photoelectron with maximum kinetic energy is made to move perpendicular to a magnetic field of
9.1
2  104 T, its traces out a circular path of radius cm. The work function of the metal (in eV)
1.6
is (Given mass of electron = 9.11  1031 kg)

6. A plane light wave of intensity I = 2kW/m2 falls on a plane mirror. The intensity of reflected light is
60% of intensity of the incident light. The angle of incidence is 30. If the pressure exerted by the
light on the mirror is n  10 6 N/m2, find the value of n.

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Chemistry SECTION – II

PART – A
(One Options Correct Type)
This part contains 04 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.

1. The purple colour produced in test of S2- ion with sodium nitro prusside reagent is due to
(A) Na2[Fe(CN)5NO]
(B) Na4[Fe(CN)5(NOS)]
(C) Na4[Fe(CN)6]
(D) Na2[Fe(CN)5(NOS)]

2. According to Freudlisch’s adsorption isotherm, the graph between log x/m and logP is given
below, where x/m is extent of adsorption and P is the pressure

logx/m  = 45o

0.4

logP
The extent of adsorption at pressure 2 atm is (Given log2 = 0.3 and log5 = 0.7)
(A) 8
(B) 2
(C) 5
(D) 9

3. A compound NpSq has cubic close packing (ccp) arrangement of S. N is present at alternative
tetrahedral voids. If all the atoms along one body diagonal are removed. The empirical formula of
the compound is:
(A) N5S14
(B) N4S5
(C) NS2
(D) NS

4. The number of angular nodes and radial nodes in 4dz2 are respectively
(A) 0, 2
(B) 1, 1
(C) 2, 1
(D) 2, 0

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(One or More than one correct type)


This part contains 08 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.

5. An ideal gas in thermally insulated container, at internal pressure P1, volume V1 and absolute
temperature T1 expands irreversibly against zero external pressure so that the pressure of gas
becomes P2, volume V2 and temperature T2. Which of the following statement(s) is/are correct?
(A) S surrounding  0
(B) V2 Pext = 0

Ssystem  nRn Pext = 0

V1 P1V1T1 P2V2T2

(C) H  0
(D) P1V1  P2 V2

6. For a first order reaction X  g   2Y  g  Z  g  , initially only 3 moles of X(g) was taken in 10 L
rigid closed container at 300 K. After 10 seconds the reaction was stopped forcefully and a
pinhole was made in the container at the same temperature. The molar ratio of X(g) and Y(g)
gases coming out is 1 : 2. The correct option(s) is/are:
(Given molar masses of X, Y and Z are 16, 4 and 8 g/mole respectively n2  0.7 and n3  1.1 ,
R = 0.08 atm L-1 K-1 mol-1)
(A) The total pressure inside the container when reaction was just stopped is 12 atm.
(B) The rate constant of reaction is 4 × 10-2 sec-1.
(C) Moles of Z just after reaction was stopped forcefully is 1.0.
(D) The rate of formation of Y after 10 second is 0.4 mol L-1 sec-1.

7. Fusion of chromite ore (FeCr2O4) with Na2CO3 in the presence of O2 gives X which on
acidification with conc. H2SO4 gives Y. Both X and Y contain chromium ion. Correct statement(s)
is/are:
(A) Both X and Y are colourful compound and colour of these compounds is due to ligand to
metal charge transfer.
(B) Both X and Y are paramagnetic in nature.
(C) Acidified solution of Y can convert Sn2+ ion into Sn4+ ion.
O
(D) Both X and Y have Cr Cr bond..

8. In an evacuated vessel of capacity 49.2 L, 4 moles of Ar(g) and 5 moles of PCl5(g) were
introduced and the temperature is maintained at 240 K (assume that at this temperature
decomposition of PCl5 takes place). At equilibrium, the total pressure of the mixture was found to
be 4.8 atm. (Given R = 0.082 atm L mol-1 K-1). Correct statement(s) is/are
(A) The degree of dissociation of PCl5(g) into PCl3(g) and Cl2(g) is 0.6.
(B) 

KP for the reaction PCl5  g 
 PCl3  g   Cl2  g  is 2.7 atm.
(C) At equilibrium total moles of gases are 12.
(D) On removing Ar(g) from the equilibrium mixture at constant pressure and temperature,
the extent of dissociation of PCl5 will increase.

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9. Which of the following is/are stronger acid than COOH  benzoic acid

(A) OH

NO2

(B) COOH
OH

(C) OH
O 2N NO2

NO2

(D) COOH

CH3

10. Which of the following statement(s) is/are true?


(A) Sucrose on reaction with Fehling solution gives red precipitate.
(B) -D-(-) fructofuranose and -(L)-(+) fructofuranose are diasteomers.
(C) Glucose on reaction with nitric acid gives glucaric acid.
(D) In Lactose reducing half is -D-glucose and non reducing half is -D-Galactose.

11. Choose the correct option(s) for the following reaction sequence
 i CH3  CH CH2 /H3PO4 ,
 2
ii O 

 iii H /H O
 P 
Ac 2 O/H
 Q  CH3 COOH
2 Major 
 iv  NaOH
 v  CO2 4  7 atm
 vi HCl
(A) Compound ‘Q’ has antipyretic action.
(B) Compound ‘P’ gives test with neutral ferric chloride.

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OH O O
C O C CH3

(C) Compound ‘Q’ is

(D) Compound ‘P’ can also be prepared by reaction of salicyaldehyde with Fehling solution
followed by acidification.

12. The correct statement (s) for the following addition reactions is/are
(i)
i B2H6 / THF

 ii H2 O2 ,OH ,
 P
isomeric products 
H
(ii)
i HgOAc   THF H O
 2
 ii NaBH ,OH ,
2
 Q
4
isomeric products
H
(A) Only one product is formed in (ii) reaction.
(B) Addition of water proceeds through syn-addition in both the reactions.
(C) Hydroboration in (i) reaction is controlled by steric factor.
(D) The product ‘Q’ is oxidized by CrO3 while product ‘P’ is not oxididised by CrO3.

PART – B
(Numerical Answer Type)
This part contains 06 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. XXXXX.XX).

1. The total numbers of stereoisomers obtained if NH3 is replaced by bidentate en ligand in complex

Co  CN2 NH3 2 Cl2  (en = NH2CH2CH2NH2)

2. Calculate the value of [x – y] for XeOF4 where x = total number of lone pair in XeOF4, y = total
number of d - p bonds in XeOF4.

3. Among S3O9, P4O10, SO2, SOF3, SNF4, N2O4, Al2O3 the total number of molecules containing
d - p bond is

4. The solubility of AgCN(s) in 1 L of 0.4 M NH3 is Y × 10-1 mol/L. The value of Y is…..
(Given that the value of KSP AgCN = 5 × 10-10 and Kf of [Ag(NH3)2]+ is 5 × 1010

5. Melamine formaldehyde is a condensation polymer of melamine and formaldehyde. The number


of nitrogen atoms in one molecule of melamine is X. X is…..

6. Total number of products (including both structural and stereoisomers) formed by


monochlorination of the following compound is…….
CH3
Cl2 /h

monochlorination

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Mathematics SECTION – III

PART – A
(One Options Correct Type)
This part contains 04 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.

1. Let x1  7 2  7 8 , x 2  7 3  7 7 and x3  7 4  7 6 , then


(A) x1 > x 2 > x 3
(B) x1 < x 2 < x 3
(C) x1 + x3 < 2x2
(D) x1 + x3 > 2x2

2. In a triangle ABC with sides a, b and c a semicircle touching the sides AC and BC is inscribed
whose diameter lies on AB, then the radius of the semicircle is
a
(A)
2
2abc A B C
(B) sin sin sin

s ab  2 2 2
2
(C)
ab
2abc A B C
(D) cos cos cos

s ab  2 2 2

 
e  Jx
 
 x2
3. If e dx  a , then dx where J > 0 is
0 0
x
(A) 2a J
a
(B)
J
(C) a J
2a
(D)
J

4. Let A and B are two non singular matrices such that B  I, A5 = I and AB2 = BA, then the least
value of n for which Bn = I is
(A) 63
(B) 64
(C) 31
(D) 32

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(One or More than one correct type)


This part contains 08 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.

2 5 1
5. Considering the equation   where x, y  N the number of solutions of the equation is
x y 6
(A) 6 if both x and y are multiple of 4
(B) 6 if both x and y are the type 4n + 2, n  0
(C) 0 if x is multiple of 4 where y is of the form 4n + 2, n  0
(D) 0 if x is of the type 4n + 2, n  0 and y is the multiple of 4

9x 9  60
6. If  5x 13
 3x 10
 5x
dx = n 5xp  3x q  5xr  c where p, q, r  I, then p + q + r is

(A) –3
(B) –5
(C) 3
(D) 15

1 1 k
7. Upon t – y plane the path defined by the equation    0 is
x 2m
y 2m
 x  y n
1
(A) A parabola when m  , k = 1, n = 0
4
1
(B) A hyperbola when m  , k = 1, n = 0
2
1
(C) A pair of lines of m  , n = k = 1
2
1
(D) A pair of lines if m  , n = 1, k = 1
2

8. Which of the following statements are true?


(A) n2 – n + 41 is a prime number for every n  N

1  2n
(B) 
n 1
n!
 ln 2 n is rational

 1 1 1 
(C) ln     .....   can be simplified to an integer
 1  3 1  2  3  5 1  2  3  4  5  7 
(D) The coefficient of x5 in (1 – t)–6 is 10C6

100 100 100 100 100 x


9. If C6  4 C7  6 C8  4 C9  C10 has the value equal to C y , then the value of
(x + y) can be
(A) 114
(B) 115
(C) 198
(D) 199

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14

10. Let a and b are unit vectors such that a  b  1 . Let      a  b   a   a   a   b , then
3
(A)  
4
(B)  is perpendicular to b

(C)  is parallel to a
  
(D)  is parallel to a  b

 sin x ,   x  0
11. Let f  x    g(x) = f(|x|) + |f(x)|  x  [–, ], then
cos x , 0  x  
(A) g(x) = 0 has three real roots
(B) g(x) = 0 has infinitely many real roots
(C) lim g  x  does not exist
x 0
(D) g(x) is a periodic with period 

12. The function of f(x) = max{(1 – x), (1 + x), 2}, x  (–, ) is


(A) continuous at all points
(B) differentiable at all points
(C) differentiable at all points except at x = 1 and x = –1
(D) continuous at all points except at x = 1 and x = –1

PART – B
(Numerical Answer Type)
This part contains 06 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. XXXXX.XX).

 1     1  
n
1. The least value of a for which the expression 4 cosec x     2a  sgn  lim     has at
 1  sin x    n  2   
 
least one solution in  0, 
 2

2x
2. Total number of critical points in the domain of f  x   are equal to
x2

3. The equation of tangent to the curve y = 4 + sin2 x at x =  is y = k, then the value of k is

4. Let z1, z2 and z3 be three non zero complex numbers such that z1 + z2 + z3 = z1z2 + z2z3 + z3z1 =
z z
0, then 1 22 is equal to
z3

5. Suppose x, x2 – 24 and x + x2 are consecutive terms of A.P., then the sum of all possible values
of common differences of sequence is

6. A person flips 4 fair coins and discards those which turn up tails. He again flip the remaining coins
m
and then discards those which turn up tails. If P  (m and n are coprimes) denotes the
n
probability that he discards at least three coins, then the value of (m + n) is

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FIITJEE MOCK TEST

PHYSICS, CHEMISTRY & MATHEMATICS


(07.05.2024)

ANSWER KEY (Paper-1)


MOCK TEST (JEE ADVANCED)

Q. Q. Q.
PHYSICS CHEMISTRY MATHEMATICS
No. No. No.
1. D 1. B 1. B

2. B 2. C 2. C

3. C 3. B 3. D

4. C 4. C 4. C

5. AC 5. ABC 5. AB

6. BCD 6. ABC 6. ABCD

7. AB 7. AC 7. ABCD

8. AC 8. AC 8. BC

9. ACD 9. BC 9. AC

10. ABD 10. CD 10. ABD

11. ACD 11. ABD 11. BC

12. CD 12. AC 12. AC

1. 8 1. 4 1. 4.50

2. 3.11 2. 14 2. 2

3. 1.25 3. 5 3. 4

4. 1 4. 1.81 4. 1

5. 3.95 5. 6 5. 50

6. 8 6. 8 6. 445

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(MOCK TEST)

JEE (Advanced)
(07.05.2024)

PAPER – 1

ANSWERS, HINTS & SOLUTIONS


Physics SECTION – I

PART – A

1. D
Sol. At t = 10 sec
4
xcm  100   10  800 m
5
3
ycm  100   10  5  100  100 m
5
m1x1  m2 x 2
xcm 
m1  m2
m  400  2mx 2
800 
3m
 x2 = 1000 m
m y  m2 y 2
ycm  1 1
m1  m2
m  60  2my 2
100 
3m
 y2 = 120 m

2. B
3v P 3v
Sol. fP  , fQ  mix
4 P 2 Q

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fP  v H2 THz Mmix 7 2 400 3 2
 Q Hz       
fQ 2 P v mix  mix Tmix MH2 5 3 420 2 3

3. C
Sol. In equilibrium
Mg = m2r
When the weight is displaced by a small distance x downwards and released.
From conservation of angular momentum
mr2 = m(r  x)2
Mg  T m2r  m 2 (r  x)
Acceleration of the weight a = 
M M
m 2 r2 4  m  r 3 
=  r  4
(r  x)  2r 1  3
M  (r  x)  M  (r  x) 
m2r   x   m2r  3x 
3
= 1   1    
M   r  M  r 

 x
3
3x 
 1    1  
from binomial approximation  r r 
since x  r 
 
3m2 x
a= 
M
1 3m 2
 frequency f =
2 M

4. C
Sol. x = u cos t
1 2
y = u sin  t  gt
2
vx = u cos , vy = u sin   gt
The stone is at the greatest distance from the point of projection O. when its velocity is
perpendicular to the position vector.
The condition for this is
y v    1 
 x v  ucos  ˆi  (usin   gt)jˆ , r  ucos tiˆ   u sin t  gt 2  ˆj
x vy  2 
3usin  2u2
 t2  t 2 0
g g
If this is not happen, discriminate D < 0
2
 3u sin   2u2
    4
 g  g2
8
 sin  
9
8
sin max 
3

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5. A, C
Sol. The upper ball will ultimately receives the largest possible fraction of total energy if after collision
between the two balls m2 comes to rest.
(m2  m1 ) 2gh  2m1 2gh
  0  m2 = 3m1
m1  m2
If m2 >> m1
v1 = u1 + 2u2 = 2gh + 2 2gh  3 2gh
v12
hmax   9h
2g

6. B, C, D
Sol. From conservation of angular momentum
(2mx 2  I)  (2mR2  I)
(2mR2  I)
  =
2mx 2  I
Force exerted by insect on the turntable
(2mR2  I)2 2
F  m2 x  m x
(2mx 2  I)2
dF
For F to maximum =0
dx
2
mR2
I 3 R
 x  
6m 6m 3
 2 2 2 
 2mR  mR 
   3    3
 R2 2 2 
 2m  mR 
 9 3 
R
Fmax  m 2 x  m  92   3m2R
3

7. A, B
Sol. (A) Required force F = weight of the chain F
R
gx 5gR

2R/3
 (dx)
R

18 dx R/3
(B) Initial potential energy of the chain
R
GM  x2  x
Ui  
2R/3
dx  3  2
2R  R


 x2 
gR 2 31gR2

 dx  3  2   
 2R
R  81
Final potential energy of the chain
R/3
gR2  x2  40gR2
Uf  
0
dx
2R
 3  2
 R
  
 81

1 2gR
mv 2  Ui  Uf  v 
2 3

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gR 2
Ui  31
81
 2 R
 gR  3  2
Uf  
GMm
     gR
R R 3
4gR 2
W = U =
81

8. A, C
y vy
d
2
Sol. d  v0 2  v md
0
qE0 / m qE0
mv 02 r
E0   r
qd 
When the particle strike at D O D v0
qE d qE0 d
vy  2 0 
m 2 m
mv 2m qE0 d
d = 2r sin  = 2 sin  
qB qB m
mE0 m mv 02 2mv 0
 B2 = 2  
qd qd qd qd

9. A, C, D
Sol. Current passing through the cell at any time t
I

R
 
1  e Rt /2  e  t /RC
R

R

  
1  e  t /2   e  t/  (where  = RC)
R
dI dI2
I will minimum when  0 and 2  0
dt dt
dI   t / 2   t / 
 e  e
dt 2R R
d2I  
 e t / 2  2 e t / 
dt 2 4R2 R
  t /2   t / 
 e  e 0
2R R
 e t/2   2  t = 2n2 = 2RCn2
 1   1 3
I  1    
R 2  R 4 4R
Charge on capacitor at this time

 
1  3C
q  C 1  e  t/   C  1   
 4  4

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10. A, B, D
2
 1 
Sol. z1  R 2  XC2  (100)2   4 
 100 2 
 50  2  10 
z 2  R2  XL2  (50)2   50  1  50 2 
2

XC 100  200
tan 1    1  , I1   2A
R 100 4 100 2
X 50  200
tan 2   L   2   , I2  2 2A
R 50 4 50 2
rms current through ac mains = I12  I22 = 10A
rms potential difference across the inductor = I2XL= 2 2  50  100 2 V
phase difference between the currents passing through the capacitor and inductor =
   
   
4  4 2

11. A, C, D
Sol. If the angular position of the point on the screen where phase difference is zero equals , then
5 25
dsin30  dsin   0
3 18
3 3
 sin    tan  
5 4
y 3
   y = 0.75 m
1 4
If phase difference at point O
2 2 5 1 25 
 (dsin30)  
  1.5  10 3  
 3  10 4 3 2 3
25 
Intensity at O, I  4I0 cos2  3I0
6
Path difference at O
 25 25
x   
2 3 6
The path difference at the nearest minima below O
9
x 
2
25 9 25 
 dsin    
18 2 6 3
18 6
 sin   
75d 125
Since, sin  << 1
y
sin   tan  
D
y 6
  m  y = 48 m
1 125

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12. C, D
Sol. From conservation of angular momentum
 2  3v
mv 0    m 2  2m      0
 3  5
 
From conservation of mechanical energy
2
1 5  3v  
 m 2  0   mg  2mg
2 3  5   2
20g
 v0 
3
At horizontal position
 = I
 5m 2
mg  2mg  
2 3
6g

5
When the rod is at horizontal position horizontal component of hinge force F x = 3m acm
4g
3mg  Fy  3m
5
3mg
Fy 
5

PART – B

1. 00008.00
Sol. Let the new pressure inside the bubble after expansion be P
4
P R13
R3
P  3  P 13
4 3 R2
R2
3
2
P  P 
20
R13 q2
P P
R32

322 0R32
 q  322 0PR2 R32  R13 
n=8

2. 00003.11
Sol. For image formed by the refraction at water surface
4
1
4/3 1 3
 
v1 48 
 v1 = 64 cm
For the lens
u2 = (64 + 11) =  75 cm
focal length of the lens in water fw can be found by
fw (  1) 1.5  1
 
fair     1.5 
  1   1

 w   4 / 3 

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 fw = 4fair = 60 cm
For image formed by the lens
1 1 1
 
v 2 7.5 60
v2 = 300 cm
distance of final image for water surface = 300 cm + 11 cm = 3.11 m

3. 00001.25
Sol. Tension in the string at a distance x from the lower end
x
0 x 2

T  (0 xdx)g 
0
2
g

T xg
Speed of wave at this point v = 
 2
125
L 8
dx gx 2 dx 8L

dt

2
 t
g 
0
x

g
=
10
64  1.25 sec

4. 00001.00
Sol. Let the speed of the cylinder after a long time be v.
The particle moving from left reach the body with a relative speed v0  v and rebound with same
relative speed. In a short time interval t the particle coming from a distance (v0  v)t reach the
cylinder and each imparts an impulse proportional to 2(v0  v) to the body. Thus the force from
the left is proportional to 2(v0  v)2. Similarity particle in elastically colliding with the right at a
negative speed (v + v0) produce a force proportional to (v0 + v)2. The condition for constant speed
of the body is 2(v 0  v)2  (v 0  v)2
2 1  2  1
 v v0   (3  2 2 )  1m/s
2 1  2  1 
 

5. 00003.95
 1 1 
Sol. Energy of the emitted photon = 13.6  32  2  2  eV  5.95 eV
3 4 
2mK
Since, r 
qB
Maximum kinetic energy of the photoelectrons
 9.1 
 104  (1.6)2  10 38  4  10 8
r 2 q2B2  1.6 
K max   J = 2eV
2m 2  9.1 1031
h =  + kmax
  = h  kmax = 5.95  2 = 3.95 eV

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6. 00008.00
Sol. I = rate of flow of energy through unit area = nh, where n is the no. A cos 30
of photons following through unit area per sec. Rate of flow of
nh nh I
momentum (momentum flux) through unit area =   .
 C C 30
Consider a cylindrical beam of parallel rays whose section the
mirror is A.
I
Rate of flow of momentum through this beam = A cos 
C
 IA cos  
Normal component of the momentum flux =   cos 
 C 
 IA cos2  
Momentum flux of the reflected photon = 0.6  
 C
 
IA cos2 
Force = Rate of change of momentum = (1.6)
C
3
1.6  2  103 
F (1.6)Icos2  4  8  10 6 N/m2
Pressure =  
A C 3  108

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Chemistry SECTION – II

PART – A

1. B
Sol. Na2 S  Na2 Fe  CN5 NO    Na 4 Fe  CN 5 NOS  
Purple colour

2. C
x 1
Sol. log  logk  logP
m n
x
log  0.4  log2
m
x
log  0.4  0.3
m
x
log  0.7
m
x
5
m

3. B
Sol. N3 S 1 1
6  6
2 8

N3 S 3
3
4
N4S5

4. C
Sol. Angular nodes in 4dz2 = 2
Radial nodes in 4dz2 = 1

5. A, B, C
T2 V
Sol. Pext = 0 q=0 Ssys  nCv n  nRn 2
T1 V1
W = - Pext V U =0 T1 = T 2
W=0 H  0
V2
T1 = T 2 S surrounding  0 S sys  nRn
V1

6. A, B, C
Sol. X  g   2Y  g Z  g X = 2 mole
 3 Y = 2 mole
3 x 2x x
Z = 1 mole
r1 P1 M2 Total moles = 5

r2 P2 M1 PV = nRT
5  0.08  300
1 3x 4 P
 10
2 2x 16
= 12 atm
1 3x 1
 
2 2x 2

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3 – x = 2x dY  2  0 
x=1 r   0.2 mol L1 sec 1
dt 10
1 3 1
K n  1.1  0.7
10 2 10
0.4
  4  10 2 / sec
10

7. A, C
Sol. FeCr2 O4  Na2CO3  O2 
 Na 2CrO 4  Fe 2O3  CO 2
' X'

Na2 CrO 4  H  Na2Cr2O7  H2 O


'Y'
O
Cr O O O
O O Cr Cr
O O O
'X' O O
'Y'

8. A, C
Sol. PCl5  g  
 PCl3  g Cl2  g

 PV = nRT
5 4.8  49.2
5 x x x n
mT  4  5  x  x  x 0.082  240
9 + x = 12
=9+x
x = 12 – 9
x=3
3
   0.6
5
3 3
 4.8   4.8
KP  12 12
2
 4.8
12
3 4.8  3
 
12 2
= 1.8 atm

9. B, C

10. C, D
Sol. Sucrose is non-reducing sugar.
-D-(-) fructofuranose and -(L)-(+) fructofuranose are enantiomers.

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11. A, B, D
Sol. CH3 CH3
H3C C H H3C C O OH OH

CH3  CH CH2 /H3PO 4


 
O2
 

H

NaOH

OAc OH ONa

COOH COOH
  2 i CO
Ac 2 O/H
  
ii HCl 

Aspirin

12. A, C

PART – B

1. 00004.00
Co  CN2  en  Cl2 

Sol.
CN
CN NH2
Cl CN Co
CN NH2 Cl NH2
Co Co Cl NH2
Cl
CN NH2 Cl NH2
Cl CN optically active hence mirror image

2. 00014.00
Sol. O
F F
Xe
x = 15 x - y = 14
F F y=1

3. 00005.00
Sol. O
O F
O O O P F
O
S S P O O S F N S
O O O F
S F
O O O O O F F
S P O
O P O
O O
O

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4. 00001.81
Sol. Range 1.81 – 1.82


AgCN  s  
 Ag  aq   CN  aq 
 

ss s
y



  Ag  NH3 2 
Ag  2NH3  

ss 0.4  2s s
y 0.4  2s  2y sy
s
5  1013 
 0.4  2s 
2
y
3
5  10  s y
s2
25 
 0.4  2s 
2

s
5
0.4  2s
2 – 10s = s
11s = 2
2
s  1.81 10 1
11

5. 00006.00
Sol. NH2

N N

H2N N NH2

6. 00008.00
Sol. CH2 Cl CH3 CH3 CH3
Cl
Cl Cl
and its mirror image and its mirror image
CH3 CH3

Cl Cl

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Mathematics SECTION – III

PART – A

1. B
d2 y dy
Sol. Let y  x1/7  2
 0 for x > 0 and  0 for x > 0  y is increasing and convex graph
dx dx

F D
I
B
E H
C
G
A

A  2, 21/7  , B  8, 81/7  , E  4, 41/7  , F  6, 61/7  , C  3, 31/7  , D  7, 71/7 


 41/7  61/7   31/7  21/7   21/7  81/7 
GI  5,  , H  5,  , G  5, 
 2   2   2 
 I(5, 2x3), H(5, 2x2), G(5, 2x1)  x1 < x2 < x3

2. C
Sol. Area (ABC) = Area (APC) + Area (BPC)
C

b a
r r
A B
P
1 1 2
 =  br   a  r   r 
2 2 ab

3. D
1
Sol. Put x = J t  dx = J dt
2 t
   
e Jt e  Jt 2a e Jx 2a
 2  
 x2
e dx  a  J dt  a  dt   dx 
t t J x J
0 0 0 0

4. C
Sol. Given A5 = I = BA5 = B  (BA)A4 = B  AB2A4 = B
 ABAB2A3 = B  AAB2B2A3 = B  A2B4AA2 = B  A2B3(BA)A2 = B
 A2B3AB2A2 = B  A2AB8A2 = B  A3AB16A = B = A4AB32 = B
IB32 = B  B31 = I

5. A, B
Sol. In all cases both are even. Let x = 2p, y = 2q
2 5 1
   6q + 15p – pq = 0  (p – 6)(q – 15) = 90
2p 2q 6
 (p – 6)(q – 15) = 2  32  5

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(A) When both p and q are even, then (p – 6) is even and (q – 15) is odd so number of
solutions
=132=6
(B) p and q both are odd  6 solutions
(C) p even and q odd  (p – 6)(q – 15) is multiple of 4 which is not true
(D) p odd and q even, then also (p – 6)(q – 15) is multiple of 4 which is not true

6. A, B, C, D
9x 9  60  9x 4  60x 13 
Sol.  5x 13
 3x10  5x
dx =  5  3x 3
 5x 12
dx

dt
Put 5 + 3x–3 – 5x–12 = t  (–9x–4 + 60x–13)dx = dt =  t
 ln t

7. A, B, C, D
Sol. (A) x  y = 1  x  y  2 xy  1  4xy = (1 – (x + y))2
 4xy = 1 + (x + y)2 – 2(x + y)  (x – y)2 – 2(x + y) + 1 = 0 is a parabola
1 1
(B)   1  xy – t – y = 0 is a hyperbola
x y
1 1 1
(C)    t2 + 3xy + y2 = 0 is a pair of lines
x y xy
1
(D) x+y=  (x + y)2 = 0 pair of lines
xy

8. B, C
Sol. For n = 41, n2 – n + 41 is not a prime
 ln 2 ln2 2 ln3 2  ln 4 ln2 4
(B)     .....     .....
 1! 2! 3!  1! 2!
=  eln 2  1   eln 4  1  1  3  4 = a rational number  B is correct
2n  1  1 1 1 1 1 1 1
(C) Tn    =     ..... 
 2n  1 !  2n !  2n  1 ! 2! 3! 4! 5!
1 1 1 1 1 1  1
= 1       .....   , ln    1 = integer  C is correct
1! 2! 3! 4! 5! e e

9. A, C
Sol. If we have 4 girls and 100 boys and we want to select 10 students from total of 104 students then
the ways will be 4 C1  100 C9  4 C2  100 C8  4 C3100 C7  4 C4100 C6  4 C0100 C10
= 4 100 C9  6 100 C8  4 100 C7  100 C6  100 C10 = 104
C10  104
C94
x + y = 104 + 10 = 114 or x + y = 104 + 94 = 198

10. A, B, D
1
Sol. a  b  1  2  2a  b  1  cos     = 120
2
a  b  a  a  a b  a  b a  b  1 a
2
 1 
a  b   a  a   b  a   a  b  a
 2 
 a  b   a   a   a   b  a   a = b  a  a   a  a  b  1 a  b
2

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1  1
    a  b b  ab
2  2

11. B, C

Sol. For 0  x  , f(|x|) + |f(x)| = cos |x| + |cos x|, then g(x) = 0 for x
2
 Infinitely roots

12. A, C
Sol. From graph it is clear that f(x) is continuous every where but not differentiable at x = 1 and x = –1

y=1–x y y=x+1

(–1, 2) (1, 2)

PART – B
1. 00004.50
4 1 4 1
Sol.   2a . Let f  x   
sin x 1  sin x sin x 1  sin x
2 4 1
f   x   0  sin x  least f(x) =  9
3 2 2
1
3 3
sin 2a  9  a  4.5

2. 00002.00
 4 1
 3  , x2
Sol. f x   x
  x2  f(x) is not differentiable at x = 2 also f(x) = 0  x = 4
 1  4
, x2
 x 2 x3

3. 00004.00
Sol. Given in the figure

y=4

O x=

4. 00001.00
Sol. z1 + z2 = –z3  |z1 + z2| = z3
z1z2 + z2z3 + z3z1 = 0  |z3(z1 + z2)| = |z1z2|  |z3|2 = |z1||z2|

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5. 00050.00
Sol. x, x2 – 24, x + x2 are in A.P.  2x2 – 48 = 2x + x2  x = 8 or –6
Possible sequences are 8, 40, 72  d1 = 32
–6, 12, 30  d2 = 18, sum = 50

6. 00445.00
1 3
Sol. Let C1, C2, C3, C4 be coins P(S) = 1 – coin is not discarded = (1 – P(HH) = 1  
4 4
Hence, S can take the value 0, 1, 2, 3, 4, P(S = 3 or 4) = P(S = 3) + P(S = 4)
189 m
   m + n = 445
256 n

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