Dr.

Nervana Ehab, PhD

E / 2 = 22%
F / 1 = 16%
 Cambridge IGCSE™
*6941276161*

CHEMISTRY0620/63
Paper 6 Alternative to Practical May/June 2023

 1 hour

You must answer on the question paper.

No additional materials are needed.

INSTRUCTIONS
● Answer all questions.
● Use a black or dark blue pen. You may use an HB pencil for any diagrams or graphs.
● Write your name, centre number and candidate number in the boxes at the top of the page.
● Write your answer to each question in the space provided.
● Do not use an erasable pen or correction fluid.
● Do not write on any bar codes.
● You may use a calculator.
● You should show all your working and use appropriate units.

INFORMATION
● The total mark for this paper is 40.
● The number of marks for each question or part question is shown in brackets [ ].
● Notes for use in qualitative analysis are provided in the question paper.

This document has 16 pages. Any blank pages are indicated.

IB23 06_0620_63/3RP
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1 This question is about separating mixtures.

(a) T
 he apparatus in Fig. 1.1 can be used to separate a mixture of liquids with different boiling
points.

Fig. 1.1

(i) Name the separation technique that uses the apparatus shown in Fig. 1.1.

........................................................................................................................................ [1]

(ii) Name the items of apparatus labelled A and B.

A ..........................................................................................................................................

B ..........................................................................................................................................
[2]

(iii) Draw an arrow on Fig. 1.1 to show where the apparatus should be heated. [1]

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(b) Fig. 1.2 shows the apparatus that can be used to separate insoluble calcium carbonate from
aqueous sodium chloride.

Fig. 1.2

(i) State the term used for the solid removed from a liquid using the apparatus shown in
Fig. 1.2.

........................................................................................................................................ [1]

(ii) The calcium carbonate obtained using the apparatus in Fig. 1.2 is contaminated with
aqueous sodium chloride.

Describe how the aqueous sodium chloride can be removed.

..............................................................................................................................................

........................................................................................................................................ [1]

(iii) Name the method of separation that can be used to obtain solid sodium chloride from an
aqueous solution of sodium chloride.

........................................................................................................................................ [1]

 [Total: 7]

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2 
A student investigates the temperature change when solid citric acid reacts with solid
sodium carbonate.

The student does six experiments.

(a) Experiment 1

●  lace 5.0 g of solid sodium carbonate in a 100 cm3 beaker.

P
● Use a thermometer to stir the solid sodium carbonate for 30 seconds. Measure the
temperature of the solid sodium carbonate.

Experiment 2

● Add 1.0 g of solid citric acid to the solid sodium carbonate in the beaker from Experiment 1.
●  se the thermometer to stir the mixture for 30 seconds. Measure the temperature of the
U
mixture.
● Rinse the beaker and thermometer with water.

Experiment 3

●  lace 5.0 g of solid sodium carbonate in the 100 cm3 beaker.

P
● Add 2.0 g of solid citric acid to the solid sodium carbonate in the beaker.
● Use the thermometer to stir the mixture for 30 seconds. Measure the temperature of the
mixture.
● Rinse the beaker and thermometer with water.

Experiment 4

● Repeat Experiment 3, using 4.0 g of solid citric acid instead of 2.0 g.

Experiment 5

● Repeat Experiment 4, using 5.0 g of solid citric acid instead of 4.0 g.

Experiment 6

● Repeat Experiment 5, using 6.0 g of solid citric acid instead of 5.0 g.

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Use the information in the description of the experiments and the thermometer diagrams to
complete Table 2.1.

Table 2.1

mass of mass thermometer

temperature after
experiment solid sodium of solid diagram after
30 seconds / °C
carbonate / g citric acid / g 30 seconds

30

1 5.0 0.0 25

20

20

2 5.0 1.0 15

10

10

3 5

10

4 5

5 –5

–10

6 –5

–10

[4]

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(b) Complete a suitable scale on the y-axis and plot the results from Experiments 1 to 6 on Fig. 2.1.

Draw a line of best fit through your points.

temperature
/ C

mass of
0 citric acid
0 1 2 3 4 5 6 /g

Fig. 2.1
[4]

(c) State whether the reaction between solid sodium carbonate and solid citric acid is exothermic
or endothermic.
Explain your answer.

.....................................................................................................................................................

............................................................................................................................................... [1]

(d) Deduce which experiment had the greatest temperature change compared to the temperature
in Experiment 1.

............................................................................................................................................... [1]

(e) 
From your graph, deduce the temperature, after stirring for 30 seconds, that is obtained when
3.5 g of solid citric acid is added to 5.0 g of solid sodium carbonate.

Show clearly on the grid how you worked out your answer.

 temperature = .............................. °C [2]

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(f) S
 uggest why the solid sodium carbonate and solid citric acid are stirred before the temperature
is measured.

.....................................................................................................................................................

............................................................................................................................................... [2]

(g) E
 xplain why using a polystyrene cup in place of the glass beaker would increase the accuracy
of the results.

.....................................................................................................................................................

............................................................................................................................................... [2]

 [Total: 16]

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Question 3 starts on the next page.

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3 A student tests two solids: solid G and solid H.

Tests on solid G


Table 3.1 shows the student’s observations for solid G.

Solid G contains three ions.

Table 3.1

tests observations
test 1

Do a flame test on solid G. lilac coloured flame

test 2

Heat half of solid G in a boiling tube. solid G became a solution, condensation

Hold anhydrous cobalt(II) chloride paper above formed at the top of the boiling tube;
the boiling tube. cobalt(II) chloride paper turned pink

test 3

Dissolve the remaining solid G in water to form

solution G. Divide solution G into three portions.

To the first portion of solution G, add aqueous white precipitate which dissolves in excess
sodium hydroxide dropwise and then in excess.

test 4

To the second portion of solution G, add a pale purple solution

few drops of acidified aqueous potassium
manganate(VII).

test 5

To the third portion of solution G, add 1 cm3 white precipitate

of dilute nitric acid followed by a few drops of
aqueous barium nitrate.

(a) State what conclusion can be made about solid G from the observations in test 2.

............................................................................................................................................... [1]

(b) State what conclusion can be made about solid G from the observations in test 4.

............................................................................................................................................... [1]

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(c) The observations in test 3 show that one of two possible cations could be in solid G.

Identify these two possible cations.

.....................................................................................................................................................

............................................................................................................................................... [2]

(d) Identify two ions, other than those you gave in (c), which must be in solid G.

.....................................................................................................................................................

............................................................................................................................................... [2]

Tests on solid H

Solid H is copper(II) carbonate.

(e) About 10 cm3 of dilute hydrochloric acid is added to solid H.

Any gas given off is tested.

observations ...............................................................................................................................

.....................................................................................................................................................

............................................................................................................................................... [2]

The solution formed in (e) is solution I.

Solution I is divided into two portions.

(f) To the first portion of solution I, add aqueous sodium hydroxide dropwise and then in excess.

observations when added dropwise ...........................................................................................

observations in excess ...............................................................................................................

[2]

(g) To the second portion of solution I, add 1 cm3 of dilute nitric acid followed by a few drops of
aqueous silver nitrate.

observations ...............................................................................................................................

............................................................................................................................................... [1]

 [Total: 11]

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4 Oxalic acid is a white solid which is soluble in both water and ethanol to form colourless solutions.

Plan an experiment to determine if oxalic acid is more soluble in water or in ethanol, at room
temperature.
Your answer should include how your results tell you if oxalic acid is more soluble in water or in
ethanol, at room temperature.

You are provided with oxalic acid, water, ethanol and common laboratory apparatus.

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...................................................................................................................................................... [6]

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Notes for use in qualitative analysis

Tests for anions

anion test test result

carbonate, CO32– add dilute acid, then test for carbon effervescence, carbon dioxide
dioxide gas produced
chloride, Cl – acidify with dilute nitric acid, then white ppt.
[in solution] add aqueous silver nitrate
bromide, Br – acidify with dilute nitric acid, then cream ppt.
[in solution] add aqueous silver nitrate
iodide, I– acidify with dilute nitric acid, then yellow ppt.
[in solution] add aqueous silver nitrate
nitrate, NO3– add aqueous sodium hydroxide, ammonia produced
[in solution] then aluminium foil; warm carefully
sulfate, SO42– acidify with dilute nitric acid, then white ppt.
[in solution] add aqueous barium nitrate
sulfite, SO32– add a small volume of acidified the acidified aqueous potassium
aqueous potassium manganate(VII) manganate(VII) changes colour
from purple to colourless

Tests for aqueous cations

cation effect of aqueous sodium hydroxide effect of aqueous ammonia

aluminium, Al 3+ white ppt., soluble in excess, giving white ppt., insoluble in excess
a colourless solution
ammonium, NH4+ ammonia produced on warming –
calcium, Ca2+ white ppt., insoluble in excess no ppt. or very slight white ppt.
chromium(III), Cr3+ green ppt., soluble in excess green ppt., insoluble in excess
copper(II), Cu2+ light blue ppt., insoluble in excess light blue ppt., soluble in excess,
giving a dark blue solution
iron(II), Fe2+ green ppt., insoluble in excess, green ppt., insoluble in excess,
ppt. turns brown near surface on ppt. turns brown near surface on
standing standing
iron(III), Fe3+ red-brown ppt., insoluble in excess red-brown ppt., insoluble in excess
zinc, Zn2+ white ppt., soluble in excess, giving white ppt., soluble in excess, giving
a colourless solution a colourless solution

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Tests for gases

gas test and test result

ammonia, NH3 turns damp red litmus paper blue
carbon dioxide, CO2 turns limewater milky
chlorine, Cl 2 bleaches damp litmus paper
hydrogen, H2 ‘pops’ with a lighted splint
oxygen, O2 relights a glowing splint
sulfur dioxide, SO2 turns acidified aqueous potassium manganate(VII) from purple to colourless

Flame tests for metal ions

metal ion flame colour

lithium, Li+ red
sodium, Na+ yellow
potassium, K+ lilac
calcium, Ca2+ orange-red
barium, Ba2+ light green
copper(II), Cu2+ blue-green

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