SAFETY DATA SHEET

2-Ethylhexanol
10050
Version / Revision 4.01 Revision Date 03-Feb-2022
Supersedes Version 4.00*** Issuing date 03-Feb-2022
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SECTION 1: Identification of the substance / mixture and of the company /

undertaking
1.1. Product identifier
Identification of the
substance/preparation 2-Ethylhexanol
CAS-No 104-76-7
EC No. 203-234-3
Registration number (REACh) 01-2119487289-20

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Formulation
coatings
cleaning agent
Dilution of a concentrate
Oil field drilling and production operations
Functional Fluids
Intermediate
Uses advised against None

1.3. Details of the supplier of the safety data sheet

Company/Undertaking OQ Chemicals GmbH
Identification Rheinpromenade 4A
D-40789 Monheim
Germany

Product Information Product Stewardship

FAX: +49 (0)208 693 2053
email: [email protected]

1.4. Emergency telephone number

Emergency telephone number +65 3158 1198 (available 24/7)
000800 100 7479 (for domestic shipments only)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
This substance is classified based on Directive 1272/2008/EC and its amendments (CLP Regulation)

Acute inhalation toxicity Category 4, H332

Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2, H319
Target Organ Systemic Toxicant - Single exposure Category 3, H335

Additional information
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For full text of Hazard- and EU Hazard-statements see SECTION 16.

2.2. Label elements

Labelling according to Regulation 1272/2008/EC and its amendments (CLP Regulation).

Hazard pictograms

Signal word Warning

Hazard statements H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary statements P261: Avoid breathing gas/mist/vapours.

P280: Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTRE/doctor if you feel unwell.

2.3. Other hazards

Vapour/air-mixtures are explosive at intense warming
Components of the product may be absorbed into the body by inhalation, ingestion and through the skin

PBT and vPvB assessment This substance is not considered to be persistent, bioaccumulating nor toxic
(PBT), nor very persistent nor very bioaccumulating (vPvB)

SECTION 3: Composition / information on ingredients

3.1. Substances

Component CAS-No REACh-No 1272/2008/EC Concentration (%)

2-Ethylhexan-1-ol 104-76-7 01-2119487289-20 Acute Tox. 4; H332 > 99,5
Skin Irrit. 2; H315
Eye Irrit. 2; H319
STOT SE 3; H335
For full text of Hazard- and EU Hazard-statements see SECTION 16.

SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation
Keep at rest. Aerate with fresh air. When symptoms persist or in all cases of doubt seek medical advice.

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Eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses.
Immediate medical attention is required.

Skin
Wash off immediately with soap and plenty of water. When symptoms persist or in all cases of doubt seek medical
advice.

Ingestion
Call a physician immediately. Do not induce vomiting without medical advice.

4.2. Most important symptoms and effects, both acute and delayed
Main symptoms
cough, headache, weakness, dizziness, gastrointestinal discomfort, nausea, unconsciousness, shortness of
breath.

Special hazard
Lung irritation.

4.3. Indication of any immediate medical attention and special treatment needed
General advice
Remove contaminated, soaked clothing immediately and dispose of safely. First aider needs to protect himself.

Treat symptomatically. If ingested, irrigate the stomach using activated charcoal.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media
foam, dry chemical, carbon dioxide (CO2), water spray

Unsuitable Extinguishing Media

Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture

Under conditions giving incomplete combustion, hazardous gases produced may consist of:
carbon monoxide (CO)
carbon dioxide (CO2)
Combustion gases of organic materials must in principle be graded as inhalation poisons
Vapours are heavier than air and may spread along floors
Vapour/air-mixtures are explosive at intense warming

5.3. Advice for firefighters

Special protective equipment for firefighters
Fire fighter protection should include a self-contained breathing apparatus (NIOSH-approved or EN 133) and full
fire-fighting turn out gear.

Precautions for firefighting

Cool containers / tanks with water spray. Dike and collect water used to fight fire. Keep people away from and
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upwind of fire.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel: For personal protective equipment see section 8. Avoid contact with skin and
eyes. Avoid breathing vapors or mists. Keep people away from and upwind of spill/leak. Ensure adequate
ventilation, especially in confined areas. Keep away from heat and sources of ignition.
For emergency responders: Personal protection see section 8.

6.2. Environmental precautions

Prevent further leakage or spillage. Do not discharge product into the aquatic environment without pretreatment
(biological treatment plant).

6.3. Methods and material for containment and cleaning up

Methods for containment
Stop the flow of material, if possible without risk. Dike spilled material, where this is possible.

Methods for cleaning up

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. If liquid has been spilt in
large quantities clean up promptly by scoop or vacuum. Dispose of in accordance with local regulations. Take
necessary action to avoid static electricity discharge (which might cause ignition of organic vapours).

6.4. Reference to other sections

For personal protective equipment see section 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
Provide sufficient air exchange and/or exhaust in work rooms.

Hygiene measures
When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash hands before
breaks and immediately after handling the product.

Advice on the protection of the environment

See Section 8: Environmental exposure controls.

Incompatible products
strong oxidizing agents

7.2. Conditions for safe storage, including any incompatibilities

Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking. Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapours). In case of fire, emergency cooling with water spray should be
available. Ground and bond containers when transferring material. Vapour/air-mixtures are explosive at intense
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warming.

Technical measures/Storage conditions

Keep containers tightly closed in a cool, well-ventilated place. Handle and open container with care. Keep at
temperatures between 0 and 49 °C (32 and 120 °F).

Suitable material
stainless steel

Unsuitable material
None known

Temperature class
T3

7.3. Specific end use(s)

Formulation
coatings
cleaning agent
Dilution of a concentrate
Oil field drilling and production operations
Functional Fluids
Intermediate

SECTION 8: Exposure controls / personal protection

8.1. Control parameters
Exposure limits India

No exposure limits established.

8.2. Exposure controls

Appropriate Engineering controls
General or dilution ventilation is frequently insufficient as the sole means of controlling employee exposure. Local
ventilation is usually preferred. Explosion-proof equipment (for example fans, switches, and grounded ducts)
should be used in mechanical ventilation systems.

Personal protective equipment

General industrial hygiene practice

Avoid contact with skin, eyes and clothing. Do not breathe vapours or spray mist. Ensure that eyewash stations
and safety showers are close to the workstation location.

Hygiene measures
When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash hands before
breaks and immediately after handling the product.

Respiratory protection
Respirator with A filter. Full mask with above mentioned filter according to producers using requirements or
self-contained breathing apparatus. Equipment should conform to EN 136 or EN 140 and EN 143.

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Hand protection
Wear protective gloves. Recommendations are listed below. Other protective material may be used, depending on
the situation, if adequate degradation and permeation data is available. If other chemicals are used in conjunction
with this chemical, material selection should be based on protection for all chemicals present.

Suitable material nitrile rubber

Evaluation according to EN 374: level 6
Glove thickness approx 0,55 mm
Break through time > 480 min

Suitable material polyvinylchloride

Evaluation Information derived from practical experience
Glove thickness approx 0,8 mm

Eye protection
Tightly fitting safety goggles. In addition to goggles, wear a face shield if there is a reasonable chance for splash
to the face.
Equipment should conform to EN 166

Skin and body protection

Impervious clothing. Wear face-shield and protective suit for abnormal processing problems.

Environmental exposure controls

If possible use in closed systems. If leakage can not be prevented, the substance needs to be suck off at the
emersion point, if possible without danger. Observe the exposure limits, clean exhaust air if needed. If recycling is
not practicable, dispose of in compliance with local regulations. Inform the responsible authorities in case of
leakage into the atmosphere, or of entry into waterways, soil or drains.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance liquid @ 20 °C (68 °F)
Colour colourless
Odour slight
Odour threshold 0,08 ppm
pH 5,8 (0,9 g/l in water @ 20 °C (68 °F)) OECD 105***
Melting point/range -89 °C (Pour point)
Boiling point/range 184 °C @ 1013 hPa
Flash point 77 °C @ 1013 hPa***
Method ISO 2719
Evaporation rate No data available
Flammability (solid, gas) Does not apply, the substance is a liquid
Lower explosion limit 0,79 Vol %
Upper explosion limit 12,7 Vol %

Vapour pressure
Values [hPa] Values [kPa] Values [atm] @ °C @ °F Method
0,93 0,093 0,00091 20 68 OECD 104
3,8 0,38 0,003750 50 122 OECD 104
Vapour density 4,5 (Air = 1) @ 20 °C (68 °F)

Relative density
Values @ °C @ °F Method
0,832 20 68 DIN 51757
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Solubility 0,9 g/l @ 20 °C, in water, OECD 105

log Pow 2,9 (measured) OECD 117
Autoignition temperature 280 °C @ 1017 hPa***
Method DIN 51794
Decomposition temperature No data available
Viscosity 9,845 mPa*s @ 20 °C
Method DIN 51562, dynamic***
Oxidizing properties Does not apply, substance is not oxidising. There are no chemical groups
associated with oxidizing properties***
Explosive properties Does not apply, substance is not explosive. There are no chemical groups
associated with explosive properties

9.2. Other information

Molecular weight 130,23
Molecular formula C8 H18 O
log Koc 2,12 calculated***
Dissociation constant pKa 15,75 @ 25 °C (77 °F) (calculated)
Refractive index 1,431 @ 20 °C
Surface tension 47 mN/m (0,81 g/l @ 20°C (68°F)), OECD 115

SECTION 10: Stability and Reactivity

10.1. Reactivity
The reactivity of the product corresponds to the typical reactivity shown by the substance group as described in
any text book on organic chemistry.

10.2. Chemical stability

Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

Hazardous polymerisation does not occur.

10.4. Conditions to avoid

Avoid contact with heat, sparks, open flame and static discharge. Avoid any source of ignition.

10.5. Incompatible materials

strong oxidizing agents.

10.6. Hazardous decomposition products

No decomposition if stored and applied as directed.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Likely routes of exposure Ingestion, Inhalation, Eye contact, Skin contact

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Acute toxicity
2-Ethylhexan-1-ol (104-76-7)
Routes of Exposure Endpoint Values Species Method
Oral LD50 ~2047 mg/kg rat, male OECD 401
Dermal LD0 > 3000 mg/kg rat, male/female OECD 402
Inhalative LC50 > 0,89 - < 5,3 mg/l rat, male/female OECD 403
(4h)

2-Ethylhexan-1-ol, CAS: 104-76-7

Assessment
The available data lead to the classification given in section 2

Irritation and corrosion

2-Ethylhexan-1-ol (104-76-7)
Target Organ Effects Species Result Method
Skin rabbit severe irritation OECD 404 4h
Eyes rabbit irritating OECD 405
Respiratory tract human irritating

2-Ethylhexan-1-ol, CAS: 104-76-7

Assessment
The available data lead to the classification given in section 2

Sensitization
2-Ethylhexan-1-ol (104-76-7)
Target Organ Effects Species Evaluation Method
Skin Human experience not sensitizing Maximisation Test

2-Ethylhexan-1-ol, CAS: 104-76-7

Assessment
Based on available data, the classification criteria are not met for:
Skin sensitization
For respiratory sensitization, no data are available

Subacute, subchronic and prolonged toxicity

2-Ethylhexan-1-ol (104-76-7)
Type Dose Species Method
Subchronic toxicity NOEL: 125 mg/kg/d rat, male/female OECD 408 Oral
(90d)
Subchronic toxicity NOAEL: 250 rat, male/female OECD 408 Oral
mg/kg/d (90d)
Subchronic toxicity NOEL: 125 mg/kg/d mouse, male/female OECD 408 Oral
(90d)
Subchronic toxicity NOAEL: 250 mouse, male/female OECD 408 Oral
mg/kg/d (90d)
Subchronic toxicity NOAEC: 120 ppm rat, male/female OECD 413 Inhalation
(90 d)

2-Ethylhexan-1-ol, CAS: 104-76-7

Assessment
Based on available data, the classification criteria are not met for:
STOT RE

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Carcinogenicity, Mutagenicity, Reproductive toxicity

2-Ethylhexan-1-ol (104-76-7)
Type Dose Species Evaluation Method
Mutagenicity Salmonella negative OECD 471 In vitro study
typhimurium (Ames)
Mutagenicity Escherichia coli negative OECD 472 In vitro study
Mutagenicity CHO (Chinese negative OECD 473 In vitro study
Hamster Ovary) (Chromosomal
cells Aberration)
Mutagenicity mouse negative OECD 476 In vitro study
lymphoma cells (Mammalian
Gene Mutation)
Carcinogenicity NOAEL 500 rat, male/female negative OECD 451, Oral
mg/kg/d
Carcinogenicity NOAEL 750 mouse negative*** OECD 451, Oral
mg/kg/d male/female***
Mutagenicity CHO (Chinese negative OECD 476 In vitro study
Hamster Ovary) (Mammalian
cells Gene Mutation)
Mutagenicity mouse*** negative OECD 474*** in vivo
Reproductive toxicity NOAEL 10000 rat, parental*** OECD 416 Fertility read
mg/kg/d Oral*** across
Reproductive toxicity NOAEL 3000 rat, parental*** OECD 416 Maternal toxicity
mg/kg/d Oral*** read across
Reproductive toxicity NOAEL 3000 rat*** OECD 416 Developmental
mg/kg/d Oral*** toxicity read
across
Developmental Toxicity NOAEL 191 mouse*** negative OECD 414, Maternal toxicity,
mg/kg/d*** Oral*** Developmental
toxicity,
Teratogenicity***
Developmental NOAEC: 850 rat*** OECD 414, Maternal toxicity,
Toxicity*** mg/m³*** Inhalative*** Developmental
toxicity,
Teratogenicity***
Developmental NOAEL 840 rat*** OECD 414, Maternal
Toxicity*** mg/kg/d*** Dermal*** toxicity***
Developmental NOAEL 2520 rat*** OECD 414, Developmental
Toxicity*** mg/kg/d*** Dermal*** toxicity,
Teratogenicity***

2-Ethylhexan-1-ol, CAS: 104-76-7

CMR Classification
The available data on CMR properties are summarized in the table above. They do not indicate a classification
into categories 1A or 1B
Evaluation
Based on available data, the classification criteria are not met for:
Mutagenicity
Developmental toxicity
Reproductive toxicity
Carcinogenicity***

2-Ethylhexan-1-ol, CAS: 104-76-7

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Main symptoms
cough, headache, weakness, dizziness, gastrointestinal discomfort, nausea, unconsciousness, shortness of
breath.
Target Organ Systemic Toxicant - Single exposure
respiratory system
The available data lead to the classification given in section 2
Target Organ Systemic Toxicant - Repeated exposure
Based on available data, the classification criteria are not met for:
STOT RE
Aspiration toxicity
no data available
Other adverse effects
Components of the product may be absorbed into the body by inhalation, ingestion and through the skin.
Note
Handle in accordance with good industrial hygiene and safety practice. Further details on substance data can be
found in the registration dossier under the following link:
http://echa.europa.eu/information-on-chemicals/registered-substances.

SECTION 12: Ecological information

12.1. Toxicity

Acute aquatic toxicity

2-Ethylhexan-1-ol (104-76-7)
Species Exposure time Dose Method
Leuciscus idus (Golden orfe) 96h LC50: 17,1 mg/l 84/449/EEC C.1
Pimephales promelas (fathead 96h LC50: 28,2 mg/l OECD 203
minnow)
Daphnia magna (Water flea) 48h EC50: 39 mg/l 84/449/EEC C.2
Desmodesmus subspicatus 72h EC50: 11,5 mg/l 88/302/EEC C.3
(Biomass)
Desmodesmus subspicatus 72h EC50: 16,6 mg/l (Growth 88/302/EEC C.3
rate)
Activated sludge (domestic) 24h NOEC: > 300 mg/l ETAD Fermentation tube
method

Long term toxicity

2-Ethylhexan-1-ol (104-76-7)
Type Species Dose Method
Aquatic toxicity Scenedesmus EC10: 3,2 mg/l (72 88/302/EEC C.3
subspicatus h) Biomass***
Aquatic toxicity*** Scenedesmus EC10: 5,3 mg/l (72 88/302/EEC C.3***
subspicatus*** h) Growth rate***

12.2. Persistence and degradability

2-Ethylhexan-1-ol, CAS: 104-76-7
Biodegradation
100 % (14 d), activated sludge, non-adapted, aerobic, OECD 301 C,
97 % (7 d), activated sludge, industrial, non-adapted, aerobic, OECD 302 B (Zahn-Wellens Test).***

Abiotic Degradation
2-Ethylhexan-1-ol (104-76-7)
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Type Result Method

Hydrolysis No data available
Photolysis Rate constant: 1,13 x 10^(-11) measured***
cm^3/(molecule x s) Atmospheric
lifetime: 24,6 h***

12.3. Bioaccumulative potential

2-Ethylhexan-1-ol (104-76-7)
Type Result Method
log Pow 2,9 @ 25 °C (77 °F)*** measured, OECD 117
BCF 38 calculated

12.4. Mobility in soil

2-Ethylhexan-1-ol (104-76-7)
Type Result Method
Adsorption/Desorption Koc: 131,1 @ 20 °C calculated
Surface tension 47 mN/m (0,81 g/l @ 20°C (68°F)) OECD 115
Distribution to environmental no data available***
compartments***

12.5. Results of PBT and vPvB assessment

2-Ethylhexan-1-ol, CAS: 104-76-7
PBT and vPvB assessment
This substance is not considered to be persistent, bioaccumulating nor toxic (PBT), nor very persistent nor very
bioaccumulating (vPvB)

12.6. Other adverse effects

2-Ethylhexan-1-ol, CAS: 104-76-7
No data available

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product Information
Disposal required in compliance with all waste management related state and local regulations. The choice of the
appropriate method of disposal depends on the product composition by the time of disposal as well as the local
statutes and possibilities for disposal.
Hazardous waste according to European Waste Catalogue (EWC)

Uncleaned empty packaging

Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for
reuse.

SECTION 14: Transport information

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Section 14.1 - 14.6

ICAO-TI / IATA-DGR Not restricted

IMDG Not restricted

14.7. Transport in bulk according to Annex

II of MARPOL and the IBC Code
Product name Octanol
Ship type 2
Pollution category Y

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance
or mixture
Regulation 1272/2008, Annex VI
not listed***

International Inventories

2-Ethylhexan-1-ol, CAS: 104-76-7

AICS (AU)
DSL (CA)
IECSC (CN)
EC-No. 2032343 (EU)
ENCS (2)-217 (JP)
ISHL (2)-217 (JP)
KECI KE-13766 (KR)
INSQ (MX)
PICCS (PH)
TSCA (US)
NZIoC (NZ)
TCSI (TW)

National regulatory information India

Hazardous Chemicals, Schedule 2: Threshold Quantities at an Isolated Storage
not listed

Hazardous Chemicals, Schedule 3: Threshold Quantities in an Industrial Installation

not listed

For details and further information please refer to the original regulation.

SECTION 16: Other information

Full text of H-Statements referred to under sections 2 and 3

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H315: Causes skin irritation.

H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.

Abbreviations
A table of terms and abbreviations can be found under the following link:
http://echa.europa.eu/documents/10162/13632/information_requirements_r20_en.pdf

Training advice
For effective first-aid, special training / education is needed.

Sources of key data used to compile the datasheet

Information contained in this safety data sheet is based on OQ owned data and public sources deemed valid or
acceptable. The absence of data elements required by OSHA, ANSI or Annex II, Regulation 1907/2006/EC
indicates, that no data meeting these requirements is available.

Further information for the safety data sheet

Changes against the previous version are marked by ***. Observe national and local legal requirements. For more
information, other material safety data sheets or technical data sheets please consult the OQ homepage
(www.chemicals.oq.com).
Disclaimer
For industrial use only. The information contained herein is accurate to the best of our knowledge. We do not
suggest or guarantee that any hazards listed herein are the only ones which exist. OQ makes no warranty of any
kind, express or implied, concerning the safe use of this material in your process or in combination with other
substances. User has the sole responsibility to determine the suitability of the materials for any use and the
manner of use contemplated. User must meet all applicable safety and health standards.

End of Safety Data Sheet

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