Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Antifrogen N
Version number: GHS 1.0 Date of compilation: 2019-12-03

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name Antifrogen N
Registration number (REACH) not relevant (mixture)
Article number A0288225
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses General use
1.3 Details of the supplier of the safety data sheet
Chemos GmbH & Co. KG
Sonnenring 7
84032 Altdorf
Germany

Telephone: +49 871-966346-0

Telefax: +49 871-966346-13
e-mail: [email protected]
Website: http://www.chemos.de/
e-mail (competent person) [email protected]
1.4 Emergency telephone number
Emergency information service +49 89 1 92 40

Poison centre

Country Name Postal code/ Telephone Telefax

city

United Kingdom National Poison Information Centre SE14 5ER Lon- +44 171 635 91 91
Medical Toxicology Unit don

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

Section Hazard class Category Hazard class and cat- Hazard state-
egory ment

3.1O acute toxicity (oral) 4 Acute Tox. 4 H302

3.9 specific target organ toxicity - repeated exposure 2 STOT RE 2 H373

For full text of abbreviations: see SECTION 16.

The most important adverse physicochemical, human health and environmental effects
Delayed or immediate effects can be expected after short or long-term exposure.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)
- Signal word warning

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Antifrogen N
Version number: GHS 1.0 Date of compilation: 2019-12-03

- Pictograms
GHS07, GHS08

- Hazard statements
H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure.

- Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P314 Get medical advice/attention if you feel unwell.
P330 Rinse mouth.
P501 Dispose of contents/container to industrial combustion plant.

- Hazardous ingredients for labelling Ethane-1,2-diol

2.3 Other hazards
Results of PBT and vPvB assessment
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

SECTION 3: Composition/information on ingredients

3.1 Substances
Not relevant (mixture)

3.2 Mixtures
Description of the mixture

Name of substance Identifier Wt% Classification acc. to GHS Pictograms

Ethane-1,2-diol CAS No 90 Acute Tox. 4 / H302

107-21-1 STOT RE 2 / H373

EC No
203-473-3

For full text of abbreviations: see SECTION 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General notes
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and
covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medic-
al advice. In case of unconsciousness place person in the recovery position. Never give anything by mouth.

Following inhalation
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. Provide fresh air.

Following skin contact

Wash with plenty of soap and water.

Following eye contact

Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at
least 10 minutes, holding the eyelids apart.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Antifrogen N
Version number: GHS 1.0 Date of compilation: 2019-12-03

Following ingestion
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms and effects are not known to date.

4.3 Indication of any immediate medical attention and special treatment needed
none

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media
Water spray, BC-powder, Carbon dioxide (CO2)

Unsuitable extinguishing media

Water jet

5.2 Special hazards arising from the substance or mixture

Hazardous combustion products
Carbon monoxide (CO), Carbon dioxide (CO2)

5.3 Advice for firefighters

In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surroundings. Do
not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separately. Fight
fire with normal precautions from a reasonable distance.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel
Remove persons to safety.

For emergency responders

Wear breathing apparatus if exposed to vapours/dust/spray/gases.

6.2 Environmental precautions

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

6.3 Methods and material for containment and cleaning up

Advice on how to contain a spill
Covering of drains

Advice on how to clean up a spill

Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal
binder

Appropriate containment techniques

Use of adsorbent materials.

Other information relating to spills and releases

Place in appropriate containers for disposal. Ventilate affected area.

6.4 Reference to other sections

Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials:
see section 10. Disposal considerations: see section 13.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Antifrogen N
Version number: GHS 1.0 Date of compilation: 2019-12-03

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Recommendations
- Measures to prevent fire as well as aerosol and dust generation
Use local and general ventilation. Use only in well-ventilated areas.

Advice on general occupational hygiene

Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective
equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals
in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)
See section 16 for a general overview.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limit values (Workplace Exposure Limits)

Coun- Name of agent CAS No Identi- TWA TWA STEL STEL Ceiling-C Ceiling-C Nota- Source
try fier [ppm] [mg/m³] [ppm] [mg/m³] [ppm] [mg/m³] tion

EU ethylene glycol 107-21-1 IOELV 20 52 40 104 2000/

39/EC
GB ethane-1,2-diol 107-21-1 WEL 10 particle EH40/
2005

GB ethane-1,2-diol 107-21-1 WEL 20 52 40 104 vap EH40/

2005
Notation
Ceiling-C ceiling value is a limit value above which exposure should not occur
particle as airborne particles
STEL short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute peri-
od (unless otherwise specified)
TWA time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours
time-weighted average (unless otherwise specified)
vap as vapours

Relevant DNELs of components of the mixture

Name of substance CAS No Endpoint Threshold Protection goal, Used in Exposure time
level route of exposure

Ethane-1,2-diol 107-21-1 DNEL 35 mg/m³ human, inhalatory worker (industry) chronic - local ef-
fects
Ethane-1,2-diol 107-21-1 DNEL 106 mg/kg human, dermal worker (industry) chronic - systemic
bw/day effects

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Antifrogen N
Version number: GHS 1.0 Date of compilation: 2019-12-03

Relevant PNECs of components of the mixture

Name of substance CAS No Endpoint Threshold Organism Environmental Exposure time

level compartment

Ethane-1,2-diol 107-21-1 PNEC 10 mg/l aquatic organisms freshwater short-term (single

instance)
Ethane-1,2-diol 107-21-1 PNEC 1 mg/l aquatic organisms marine water short-term (single
instance)

Ethane-1,2-diol 107-21-1 PNEC 199.5 mg/l aquatic organisms sewage treatment short-term (single
plant (STP) instance)
Ethane-1,2-diol 107-21-1 PNEC 37 mg/kg aquatic organisms freshwater sedi- short-term (single
ment instance)

Ethane-1,2-diol 107-21-1 PNEC 3.7 mg/kg aquatic organisms marine sediment short-term (single
instance)
Ethane-1,2-diol 107-21-1 PNEC 1.53 mg/kg terrestrial organisms soil short-term (single
instance)

8.2 Exposure controls

Appropriate engineering controls
General ventilation.

Individual protection measures (personal protective equipment)

Eye/face protection
Wear eye/face protection.

Skin protection
- Hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tight-
ness/impermeability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air
them well. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves men-
tioned above together with the supplier of these gloves.

- Other protection measures

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended.
Wash hands thoroughly after handling.

Respiratory protection
In case of inadequate ventilation wear respiratory protection.

Environmental exposure controls

Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

Physical state liquid

Colour light yellow - clear

Odour characteristic

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Antifrogen N
Version number: GHS 1.0 Date of compilation: 2019-12-03

Other safety parameters

pH (value) 7.5 – 8.5 (water: 0.3 g/ml, 20 °C)

Melting point/freezing point -70 °C

Initial boiling point and boiling range 170 °C at 1,013 mbar

Flash point 120 °C

Evaporation rate not determined

Flammability (solid, gas) not relevant, (fluid)

Explosive limits not determined

Vapour pressure 100 Pa at 51.1 °C

Density 1.14 g/cm³ at 20 °C

Vapour density this information is not available

Solubility(ies) not determined

Partition coefficient

- n-octanol/water (log KOW) this information is not available

Auto-ignition temperature 410 °C

Viscosity

- Kinematic viscosity 28 mm²/s at 20 °C

- Dynamic viscosity 31.92 cP at 20 °C

Explosive properties none

Oxidising properties none

9.2 Other information

Surface tension 49 mN/m

Refractive index 1.436 (20 °C)

Solvent content 90 %

Solid content 0%

Temperature class (EU, acc. to ATEX) T2 (maximum permissible surface temperature on the equip-
ment: 300°C)

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Antifrogen N
Version number: GHS 1.0 Date of compilation: 2019-12-03

SECTION 10: Stability and reactivity

10.1 Reactivity
Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".

10.2 Chemical stability

See below "Conditions to avoid".

10.3 Possibility of hazardous reactions

No known hazardous reactions.

10.4 Conditions to avoid

There are no specific conditions known which have to be avoided.

10.5 Incompatible materials

Oxidisers

10.6 Hazardous decomposition products

Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are
not known. Hazardous combustion products: see section 5.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Test data are not available for the complete mixture.

Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).

Classification according to GHS (1272/2008/EC, CLP)

Acute toxicity
Harmful if swallowed.
GHS of the United Nations, annex 4: May be harmful in contact with skin.

- Acute toxicity estimate (ATE)

Oral 555.6 mg/kg

Acute toxicity estimate (ATE) of components of the mixture

Name of substance CAS No Exposure route ATE

Ethane-1,2-diol 107-21-1 oral 500 mg/kg

Skin corrosion/irritation
Shall not be classified as corrosive/irritant to skin.

Serious eye damage/eye irritation

Shall not be classified as seriously damaging to the eye or eye irritant.

Respiratory or skin sensitisation

Shall not be classified as a respiratory or skin sensitiser.

Germ cell mutagenicity

Shall not be classified as germ cell mutagenic.

Carcinogenicity
Shall not be classified as carcinogenic.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Antifrogen N
Version number: GHS 1.0 Date of compilation: 2019-12-03

Reproductive toxicity
Shall not be classified as a reproductive toxicant.

Specific target organ toxicity - single exposure

Shall not be classified as a specific target organ toxicant (single exposure).

Specific target organ toxicity - repeated exposure

May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

SECTION 12: Ecological information

12.1 Toxicity
Shall not be classified as hazardous to the aquatic environment.

12.2 Persistence and degradability

Data are not available.

12.3 Bioaccumulative potential

Data are not available.

12.4 Mobility in soil

Data are not available.

12.5 Results of PBT and vPvB assessment

Data are not available.

12.6 Other adverse effects

Data are not available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.

Waste treatment of containers/packagings

Completely emptied packages can be recycled. Handle contaminated packages in the same way as the substance itself.

Remarks
Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be
handled separately by the local or national waste management facilities.

SECTION 14: Transport information

14.1 UN number not subject to transport regulations

14.2 UN proper shipping name not relevant
14.3 Transport hazard class(es) none
14.4 Packing group not assigned to a packing group
14.5 Environmental hazards non-environmentally hazardous acc. to the dan-
gerous goods regulations

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Antifrogen N
Version number: GHS 1.0 Date of compilation: 2019-12-03

14.6 Special precautions for user

There is no additional information.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
The cargo is not intended to be carried in bulk.

Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN)
Not subject to ADR, RID and ADN.

International Maritime Dangerous Goods Code (IMDG)

Not subject to IMDG.

International Civil Aviation Organization (ICAO-IATA/DGR)

Not subject to ICAO-IATA.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
Deco-Paint Directive (2004/42/EC)

VOC content 90 %

Directive on industrial emissions (VOCs, 2010/75/EU)

VOC content 90 %

15.2 Chemical Safety Assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Abbreviations and acronyms

Abbr. Descriptions of used abbreviations

2000/39/EC Commission Directive establishing a first list of indicative occupational exposure limit values in imple-
mentation of Council Directive 98/24/EC
Acute Tox. Acute toxicity

ADN Accord européen relatif au transport international des marchandises dangereuses par voies de naviga-
tion intérieures (European Agreement concerning the International Carriage of Dangerous Goods by In-
land Waterways)
ADR Accord européen relatif au transport international des marchandises dangereuses par route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)

ATE Acute Toxicity Estimate

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

Ceiling-C Ceiling value

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

DGR Dangerous Goods Regulations (see IATA/DGR)

DNEL Derived No-Effect Level

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Antifrogen N
Version number: GHS 1.0 Date of compilation: 2019-12-03

Abbr. Descriptions of used abbreviations

EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identi-
fier of substances commercially available within the EU (European Union)
EH40/2005 EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-li-
cence/)

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-
tions
IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)
ICAO International Civil Aviation Organization

IMDG International Maritime Dangerous Goods Code

index No The Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation
(EC) No 1272/2008

IOELV Indicative occupational exposure limit value

MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant")

NLP No-Longer Polymer

PBT Persistent, Bioaccumulative and Toxic

PNEC Predicted No-Effect Concentration

ppm Parts per million

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-
tions concerning the International carriage of Dangerous goods by Rail)

STEL Short-term exposure limit

STOT RE Specific target organ toxicity - repeated exposure

TWA Time-weighted average

VOC Volatile Organic Compounds

vPvB Very Persistent and very Bioaccumulative

WEL Workplace exposure limit

Key literature references and sources for data

Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures. Regulation (EC)
No. 1907/2006 (REACH), amended by 2015/830/EU.
Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN). International Maritime Dangerous
Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).

Classification procedure
Physical and chemical properties: The classification is based on tested mixture.
Health hazards, Environmental hazards: The method for classification of the mixture is based on ingredients of the mix-
ture (additivity formula).

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Antifrogen N
Version number: GHS 1.0 Date of compilation: 2019-12-03

List of relevant phrases (code and full text as stated in chapter 2 and 3)

Code Text

H302 Harmful if swallowed.

H373 May cause damage to organs through prolonged or repeated exposure.

Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended
for this product.

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