Scribd Logo
Upload

Welcome to Scribd!

  • 4 views

    Lab Report Experiment 3

    Uploaded by

    Amiratul Fazirah
    The document describes an experiment to prepare and standardize an HCl solution. The procedure involves preparing a diluted HCl solution from concentrated HCl and titrating it against a sodium carbonate standard. Calculations are shown to determine the exact molarity of the prepared HCl solution. Key steps and results are summarized in tables. The conclusion states that the accurate concentration of the prepared HCl solution is 0.068 M.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Lab Report Experiment 3

    Uploaded by

    Amiratul Fazirah
    4 views4 pages
    The document describes an experiment to prepare and standardize an HCl solution. The procedure involves preparing a diluted HCl solution from concentrated HCl and titrating it against a sodium carbonate standard. Calculations are shown to determine the exact molarity of the prepared HCl solution. Key steps and results are summarized in tables. The conclusion states that the accurate concentration of the prepared HCl solution is 0.068 M.

    Original Description:

    EXP 3 REPORT

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    The document describes an experiment to prepare and standardize an HCl solution. The procedure involves preparing a diluted HCl solution from concentrated HCl and titrating it against a sodium carbonate standard. Calculations are shown to determine the exact molarity of the prepared HCl solution. Key steps and results are summarized in tables. The conclusion states that the accurate concentration of the prepared HCl solution is 0.068 M.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    4 views4 pages

    Lab Report Experiment 3

    Uploaded by

    Amiratul Fazirah
    The document describes an experiment to prepare and standardize an HCl solution. The procedure involves preparing a diluted HCl solution from concentrated HCl and titrating it against a sodium carbonate standard. Calculations are shown to determine the exact molarity of the prepared HCl solution. Key steps and results are summarized in tables. The conclusion states that the accurate concentration of the prepared HCl solution is 0.068 M.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 4

    FAKULTI SAINS GUNAAN

    UNIVERISITI TEKNOLOGI MARA


    CAWANGAN SABAH

    ANALYTICAL CHEMISTRY
    REPORT SHEET
    Experiment No EXPERIMENT 3

    Title PREPARATION AND STANDARDIZATION OF HCL


    SOLUTION WITH PRIMARY STANDARD NA2CO3
    SOLUTION

    Name AMIRATUL FAZIRAH BINTI AMIU

    Student ID 2020874606

    Course CHM256

    Group G4

    Date of Experiment 10TH MAY 2022

    Date of Submission

    Lecturer’s Name MADAM DIANA BINTI INDIM @ HINDIN

    EXPERIMENT 3

    PREPARATION AND STANDARDIZATION OF HCl


    SOLUTION WITH PRIMARY STANDARD Na₂CO₃ SOLUTION
    ANALYTICAL CHEMISTRY

    1.State the objective of this experiment.


    To prepare an acid solution from a concentrated HCl and to determine the accurate concentration of
    the HCl solution by standardization with standard solution.

    2.Describe the procedure (in brief).


    A. Preparation of HCl solution
    2.10 mL of HCl was measured by using a 10-mL measuring cylinder and transferred into a 250 mL
    volumetric flask which already contained some distilled water. The measuring cylinder is rinsed with
    distilled water and transferred into the volumetric flask. The volumetric flask was filled with more
    water until it reached the calibration mark and sealed with a stopper and turned it upside down a few
    times.

    B. Standardization of HCl solution


    The burette was filled with the prepared diluted HCl, and the initial burette reading was recorded.
    25.0 mL of the standard Na2CO3 was pipetted into a 250 mL conical flask. 3 drops of methyl orange
    were added to the conical flask as indicator. The Na2CO3 in the conical flask was titrated with the HCl
    from the burette slowly while shaking the flask until the indicator colour changed from yellow to red.
    The reading at the end point of the titration was recorded. The experiment was repeated 3 times and
    all the readings were recorded in a table.

    RESULTS / DATA

    TABLE 1:
    Molecular weight of HCL 36.5 g/ml
    Density @ specific gravity 1.19 g/ml
    Percent concentration (w/w) % 37% w/w

    TABLE 2:
    ANALYTICAL CHEMISTRY
    Titration Rough 1 2 3
    Final burette reading 38.00 mL 35.50 mL 38.70 mL 34.50 mL
    Initial burette reading 0.00 mL 0.00 mL 0 mL 0 mL
    Volume of HCl used 38.00 mL 35.50 mL 38.70 mL 34.50 mL

    38 mL+35.5 mL +38.7 mL+34.5 mL


    Average volume of HCl:
    4
    146.7 mL
    = 4
    = 36.7 mL
    Molarity of Na2CO3 (from Exp.2): 0.05 M

    QUESTIONS
    a) Based on the information in Table 1, calculate the molarity of the concentrated HCl
    solution.
    Molarity of the concentrated HCl
    37 1 mol 1.19 g 1000 mL
    = × × ×
    100 36.5 g 1 mL 1L
    mol
    = 12. 063
    L
    = 12. 063 M of concentrated HCl

    b) What volume of the concentrated HCl is needed to prepare 250 mL 0.1 M HCl solution?
    Using the dilution formula,
    M1V1 = M2V2; M1 = 12.062 M, V1 =?, M2 = 0.1 M, V2 = 250 mL
    12.063 (V1) = (0.1) (250)
    25
    V1 = mL
    12.063
    = 2.0725 mL
    ≈ 2.1 mL of HCl

    c) Write a balanced equation for the reaction between HCl and Na2CO3.

    Na2CO3 + 2HCl → 2NaCl + H2O + CO2


    ANALYTICAL CHEMISTRY
    d) Using the data above and the stoichiometric ratio from the equation, calculate the exact
    molarity of the HCl solution.
    Ma =? , Va = 36.7 mL , Mb = 0.05 M , Vb = 25.0 mL
    Using the stoichiometric equation:
    MaVa = a
    MbVb b

    Ma (36.7) 2
    =
    (0.05)(25) 1

    36.7 Ma = 2
    1.25 1
    36.7Ma = 2.5
    2.5
    Ma =
    36.7
    = 0.068 M

    CONCLUSION
    To prepare a standard HCl solution, we need to find the molarity first by dividing the molar mass
    from density of HCl and using the dilution equation to find the volume which is needed. From the
    titration experiment that was conducted before, the accurate concentration of HCl is calculated to be
    0.068 M.

    You might also like