Dowsil 7091
Dowsil 7091
Dowsil 7091
Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
Print Date: 04/26/2023
DOW SILICONES CORPORATION encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.
1. IDENTIFICATION
Product name: DOWSIL™ 7091 Adhesive Sealant Black
COMPANY IDENTIFICATION
DOW SILICONES CORPORATION
2200 WEST SALZBURG ROAD
MIDLAND MI 48686-0994
UNITED STATES
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Reproductive toxicity - Category 2
Label elements
Hazard pictograms
Hazards
Suspected of damaging fertility or the unborn child.
Precautionary statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Use only outdoors or in a well-ventilated area.
Wear protective gloves, protective clothing, eye protection and/or face protection.
Response
IF exposed or concerned: Get medical advice/ attention.
Storage
Store locked up.
Disposal
Dispose of contents and/or container to an approved waste disposal plant.
Other hazards
No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
Inhalation: Move person to fresh air and keep comfortable for breathing; consult a physician.
Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media: Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical.
Water spray.
Unusual Fire and Explosion Hazards: Exposure to combustion products may be a hazard to
health..
Fire Fighting Procedures: Use water spray to cool unopened containers.. Evacuate area..
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.. Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations..
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Remove undamaged containers from fire area if it is safe to do so.
Special protective equipment for firefighters: In the event of fire, wear self-contained
breathing apparatus.. Use personal protective equipment..
Environmental precautions: Discharge into the environment must be avoided. Prevent further
leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local
authorities should be advised if significant spillages cannot be contained.
Methods and materials for containment and cleaning up: Wipe up or scrape up and contain for
salvage or disposal. Local or national regulations may apply to releases and disposal of this material,
as well as those materials and items employed in the cleanup of releases. You will need to determine
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
which regulations are applicable. For large spills, provide dyking or other appropriate containment to
keep material from spreading. If dyked material can be pumped, store recovered material in
appropriate container.
See sections: 7, 8, 11, 12 and 13.
Conditions for safe storage: Keep in properly labelled containers. Store locked up. Store in
accordance with the particular national regulations.
Do not store with the following product types: Strong oxidizing agents.
Unsuitable materials for containers: None known.
The following substance(s), which have Occupational Exposure Limit(s) (OEL), may be formed during
handling or processing:, Isopropanol
Exposure controls
Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain
airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure
limit requirements or guidelines, general ventilation should be sufficient for most operations. Local
exhaust ventilation may be necessary for some operations.
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
Appearance
Physical state paste
Color black
Odor slight
Odor Threshold No data available
pH Not applicable
Melting point/range No data available
Freezing point No data available
Boiling point (760 mmHg) Not applicable
Flash point closed cup >100 °C ( 212 °F)
Evaporation Rate (Butyl Acetate Not applicable
= 1)
Flammability (solid, gas) Not classified as a flammability hazard
Lower explosion limit No data available
Upper explosion limit No data available
Vapor Pressure Not applicable
Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) 1.39
Water solubility No data available
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
Toxicological information appears in this section when such data are available.
Acute toxicity (represents short term exposures with immediate effects - no chronic/delayed
effects known unless otherwise noted)
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
Diisopropoxydi(ethoxyacetoacetyl)titanate
LD50, Rat, male, 23,020 mg/kg OECD 401 or equivalent
Octamethyl Cyclotetrasiloxane
LD50, Rat, male, > 4,800 mg/kg No deaths occurred at this concentration.
Diisopropoxydi(ethoxyacetoacetyl)titanate
For similar material(s): LD50, Rabbit, 12,870 mg/kg
Octamethyl Cyclotetrasiloxane
LD50, Rat, male and female, > 2,400 mg/kg No deaths occurred at this concentration.
Brief exposure (minutes) is not likely to cause adverse effects. Vapor from heated material
may cause respiratory irritation. Excessive exposure may cause: Central nervous system
effects.
Diisopropoxydi(ethoxyacetoacetyl)titanate
For similar material(s): LC50, Rat, male and female, 4 Hour, vapour, > 198.65 mg/l
No deaths occurred at this concentration.
Octamethyl Cyclotetrasiloxane
LC50, Rat, male and female, 4 Hour, dust/mist, 36 mg/l OECD Test Guideline 403
Skin corrosion/irritation
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
Diisopropoxydi(ethoxyacetoacetyl)titanate
For similar material(s):
Brief contact is essentially nonirritating to skin.
Octamethyl Cyclotetrasiloxane
Brief contact is essentially nonirritating to skin.
Diisopropoxydi(ethoxyacetoacetyl)titanate
For similar material(s):
May cause moderate eye irritation.
May cause slight corneal injury.
Octamethyl Cyclotetrasiloxane
Essentially nonirritating to eyes.
Sensitization
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
Diisopropoxydi(ethoxyacetoacetyl)titanate
For similar material(s):
Did not demonstrate the potential for contact allergy in mice.
Octamethyl Cyclotetrasiloxane
Did not cause allergic skin reactions when tested in guinea pigs.
Diisopropoxydi(ethoxyacetoacetyl)titanate
May cause drowsiness or dizziness.
Route of Exposure: Inhalation
Target Organs: Central nervous system
Octamethyl Cyclotetrasiloxane
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Aspiration Hazard
Diisopropoxydi(ethoxyacetoacetyl)titanate
Based on physical properties, not likely to be an aspiration hazard.
Octamethyl Cyclotetrasiloxane
May be harmful if swallowed and enters airways.
Chronic toxicity (represents longer term exposures with repeated dose resulting in
chronic/delayed effects - no immediate effects known unless otherwise noted)
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
Diisopropoxydi(ethoxyacetoacetyl)titanate
For similar material(s):
Based on available data, repeated exposures are not anticipated to cause significant
adverse effects.
Octamethyl Cyclotetrasiloxane
In animals, effects have been reported on the following organs:
Kidney.
Liver.
Respiratory tract.
Female reproductive organs.
Carcinogenicity
Diisopropoxydi(ethoxyacetoacetyl)titanate
No relevant data found.
Octamethyl Cyclotetrasiloxane
Results from a 2 year repeated vapour inhalation exposure study to rats of
octamethylcyclotetrasiloxane (D4) indicate effects (benign uterine adenomas) in the uterus
of female animals. This finding occurred at the highest exposure dose (700 ppm) only.
Studies to date have not demonstrated if these effects occur through pathways that are
relevant to humans. Repeated exposure in rats to D4 resulted in protoporphyrin
accumulation in the liver. Without knowledge of the specific mechanism leading to the
protoporphyrin accumulation the relevance of this finding to humans is unknown.
Teratogenicity
Diisopropoxydi(ethoxyacetoacetyl)titanate
For similar material(s): Did not cause birth defects or other effects in the fetus even at doses
which caused toxic effects in the mother.
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
Octamethyl Cyclotetrasiloxane
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
Diisopropoxydi(ethoxyacetoacetyl)titanate
No relevant data found.
Octamethyl Cyclotetrasiloxane
In laboratory animal studies, effects on reproduction have been seen only at doses that
produced significant toxicity to the parent animals. In animal studies, has been shown to
interfere with fertility.
Mutagenicity
Diisopropoxydi(ethoxyacetoacetyl)titanate
In vitro genetic toxicity studies were negative.
Octamethyl Cyclotetrasiloxane
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
Ecotoxicological information appears in this section when such data are available.
Toxicity
Diisopropoxydi(ethoxyacetoacetyl)titanate
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Rasbora heteromorpha (Harlequin fish), static test, 96 Hour, 4,200 mg/l
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
Octamethyl Cyclotetrasiloxane
Acute toxicity to fish
Based on testing of comparable products: The estimated maximum aqueous concentration of
Octamethyl Cyclotetrasiloxane (D4) from migration to water from the product as supplied is
below the D4 established no-effect threshold (< 0.0079 mg/L) for aquatic organisms.
Diisopropoxydi(ethoxyacetoacetyl)titanate
Biodegradability: For similar material(s): Material is readily biodegradable. Passes OECD
test(s) for ready biodegradability.
10-day Window: Pass
Biodegradation: 66 %
Exposure time: 28 d
Method: OECD Test Guideline 301D
Octamethyl Cyclotetrasiloxane
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability.
10-day Window: Not applicable
Biodegradation: 3.7 %
Exposure time: 28 d
Method: OECD Test Guideline 310
Bioaccumulative potential
Diisopropoxydi(ethoxyacetoacetyl)titanate
Bioaccumulation: For similar material(s): Bioconcentration potential is low (BCF < 100 or
Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 0.05
Bioconcentration factor (BCF): 3 Fish Estimated.
Octamethyl Cyclotetrasiloxane
Bioaccumulation: Bioconcentration potential is high (BCF > 3000 or Log Pow between 5 and
7).
Partition coefficient: n-octanol/water(log Pow): 6.49 Measured
Bioconcentration factor (BCF): 12,400 Pimephales promelas (fathead minnow) Measured
Mobility in soil
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
Diisopropoxydi(ethoxyacetoacetyl)titanate
For similar material(s):
Partition coefficient (Koc): 1.53 Estimated.
Octamethyl Cyclotetrasiloxane
Partition coefficient (Koc): 16596 OECD Test Guideline 106
Treatment and disposal methods of used packaging: Empty containers should be recycled or
otherwise disposed of by an approved waste management facility. Waste characterizations and
compliance with applicable laws are the responsibility of the waste generator. Do not re-use
containers for any purpose.
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Components CASRN
Calcium carbonate treated with stearic acid Not available
Polydimethylsiloxane hydroxy-terminated 70131-67-8
Calcium carbonate (synthetic) treated with synthetic fatty acid Not available
Siloxanes and silicones, dimethyl 63148-62-9
Calcium carbonate (natural) treated with natural fatty acid Not available
Carbon black 1333-86-4
California Prop. 65
WARNING: This product can expose you to chemicals including Methanol, which is/are known to the
State of California to cause birth defects or other reproductive harm. For more information go to
www.P65Warnings.ca.gov.
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
Revision
Identification Number: 4130744 / A713 / Issue Date: 04/25/2023 / Version: 8.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
ACGIH BEI ACGIH - Biological Exposure Indices (BEI)
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
STEL Short-term exposure limit
TWA 8-hour, time-weighted average
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)
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Product name: DOWSIL™ 7091 Adhesive Sealant Black Issue Date: 04/25/2023
DOW SILICONES CORPORATION urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US
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