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Pearson Edexcel International Advanced Level

Time 1 hour 20 minutes
Paper
reference WCH16/01
Chemistry
 

International Advanced Level

UNIT 6: Practical Skills in Chemistry II

You must have: Total Marks

Scientific calculator, ruler

Instructions
• Use black ink or black ball-point pen.
• centrethe
Fill in boxes at the top of this page with your name,
number and candidate number.
• Answer all questions.
• Answer the questions in the spaces provided
– there may be more space than you need.

Information
• The total mark for this paper is 50.
• The marks for each question are shown in brackets
– use this as a guide as to how much time to spend on each question.
• You will be assessed on your ability to organise and present information, ideas,
descriptions and arguments clearly and logically, including your use of grammar,
punctuation and spelling.
• A Periodic Table is printed on the back cover of this paper.

Advice
• Read each question carefully before you start to answer it.
• Show all your working in calculations and include units where appropriate.
• Check your answers if you have time at the end.
Turn over

*P68794A0116*
P68794A
©2022 Pearson Education Ltd.

L:1/1/1/1/
 Answer ALL the questions.
Write your answers in the spaces provided.
1 Compound X is a green crystalline solid that contains two cations, one anion and
water of crystallisation. Tests were carried out on X.
(a) State what can be deduced about X from its colour.
(1)

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(b) About 2 cm3 of aqueous sodium hydroxide was added to a few crystals of X in a
test tube and the mixture warmed gently. A pungent gas was evolved that turned
damp red litmus paper blue.
Identify, by name or formula, the cation that is indicated by this test.
(1)

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(c) A spatula measure of X was dissolved in about 20 cm3 of distilled water to form a
green solution Y. Portions of Y were tested.
Complete the table.

Test Observation Inference

(i) 1 cm3 of aqueous As well as the sulfate ion, (3)

barium chloride was two of the anions that
added to 5 cm3 of Y .................................................................... might give the same
observation are
....................................................................

.................................................................... ............................................................... . . . . .

............................................................... . . . .

(ii) 5 cm3 of dilute Sulfate ion is present (1)

hydrochloric acid was
added to the reaction
mixture in (c) (i) ....................................................................

....................................................................

2
*P68794A0216* 
 Test Observation Inference

(iii) A few drops of A green precipitate A cation responsible (1)

sodium hydroxide formed that remained for the green colour
solution were added to unchanged on standing could be
5 cm3 of a fresh sample
of Y ............................................................... . . . . .

............................................................... . . . . .

(iv) Sodium hydroxide The green precipitate The formula of the (1)
solution was added to dissolved to form a ion responsible for the
the mixture from (c) (iii), green solution green colour of this
a little at a time, until solution is
there was no further
change
............................................................... . . . . .

(v) Hydrogen peroxide The green solution The ion responsible for (1)
solution was added to turned yellow the yellow colour of the
the green solution from solution is
(c) (iv) and the mixture
was warmed
............................................................... . . . . .

(vi) Dilute sulfuric acid was The yellow solution The ion responsible for (1)
added to the yellow turned orange the orange colour of the
solution from (c) (v) solution is

............................................................... . . . . .

(d) State what can be deduced from the observation in (c) (iii) that the green
precipitate does not change on standing. Justify your answer.
(2)

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(e) Give a possible formula of X. Water of crystallisation is not required.

(1)

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(Total for Question 1 = 13 marks)

3
 *P68794A0316* Turn over
2 Compound P is a white crystalline solid. The percentage composition by mass of P is
carbon 60.87 %, hydrogen 4.35 % and oxygen 34.78 %.
The mass spectrum of P has a molecular ion peak at m / z = 138.
(a) Determine the molecular formula of P using all these data.
You must show your working.
(4)

4
*P68794A0416* 
 (b) Samples of P are subjected to a series of tests.
• When a spatula measure of P is added to a solution of
sodium hydrogencarbonate, vigorous effervescence occurs.
• When a spatula measure of P is added to a cold dilute solution
of acidified potassium manganate(VII), the colour of the solution
does not change.
• When a spatula measure of P is added to a dilute solution of bromine water,
the solution turns colourless and a white precipitate forms.
• When a small sample of P is ignited, it burns with a very smoky flame.
(i) State what can be deduced about P from all of these tests.
Justify your answers.
(4)

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5
 *P68794A0516* Turn over
 (ii) Describe how you would ignite the sample of solid P to show that it burned
with a smoky flame.
You may include a labelled diagram in your answer.
(3)

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6
*P68794A0616* 
 (c) Use the information from (a) and (b) to draw three possible structures of
compound P.
(2)

7
 *P68794A0716* Turn over
 (d) The infrared spectrum of P is shown. One of the peaks has been circled.

100
Transmittance / %

50

0
4000 3000 2000 1500 1000 500
Wavenumber / cm–1

8
*P68794A0816* 
 Infrared data for some organic functional groups

Group Wavenumber range / cm–1

C H stretching vibrations

Alkane 2962 – 2853

Alkene 3095 – 3010

Alkyne 3300

Arene 3030

C H bending vibrations

Alkane 1485 – 1365

Arene (5 adjacent hydrogen atoms) 750 and 700

Arene (4 adjacent hydrogen atoms) 750

Arene (3 adjacent hydrogen atoms) 780

Arene (2 adjacent hydrogen atoms) 830

Arene (1 isolated hydrogen atom) 880

Explain how the circled peak in the IR spectrum and the table of infrared data
may be used to deduce the structure of P.
(2)

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(Total for Question 2 = 15 marks)

9
 *P68794A0916* Turn over
3 Iron(II) ethanedioate is an orange solid which is only slightly soluble in water but
dissolves in dilute acid on heating. The formula of the compound is FeC2O4 • x H2O,
where x is the number of moles of water of crystallisation.
(a) The number of moles of water of crystallisation in FeC2O4 • x H2O may be
determined by titration. The procedure is
Step 1 Accurately weigh approximately 2 g of iron(II) ethanedioate into a
250 cm3 beaker.
Step 2 Add about 100 cm3 of dilute sulfuric acid to the beaker and heat the
mixture until the solid dissolves completely.
Step 3 Use the solution prepared in Step 2 to prepare 250.0 cm3 of
iron(II) ethanedioate solution.
Step 4 Fill a burette with a standard solution of potassium manganate(VII).
Step 5 Transfer a 25.0 cm3 portion of the iron(II) ethanedioate solution to a
conical flask and heat it to about 60 °C.
Titrate the hot solution with the potassium manganate(VII) solution.
Step 6 Repeat Step 5 until concordant results are obtained.
The half-equations for the reactions in the titration are

Fe2+ ® Fe3+ + e−
C2O42− ® 2CO2 + 2e−
MnO4− + 8H+ + 5e− ® Mn2+ + 4H2O
(i) Describe the procedure used in Step 3.
(3)

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10
*P68794A01016* 
 (ii) State the colour of the solution at the end-point of the titration.
(1)

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(iii) In an experiment, 2.02 g of iron(II) ethanedioate was used to prepare the

solution and potassium manganate(VII) solution of concentration
0.0195 mol dm−3 was used in the titration.
The mean titre was 34.25 cm3.
Calculate the value of x in FeC2O4 • x H2O, giving your answer to an
appropriate number of significant figures.
(5)

11
 *P68794A01116* Turn over
 (b) Another experiment followed the progress over time of the reaction of
ethanedioate ions with manganate(VII) ions in acid.
The results are shown.

3.50
A

3.00

2.50
[MnO4– (aq)] / 10–4 mol dm–3

B
2.00

1.50

1.00

0.50

0
0 20 40 60 80 100 120 140 160
Time / s

12
*P68794A01216* 
 (i) Describe in outline a continuous monitoring method for obtaining results
such as these. Practical details are not required but any essential apparatus
should be named and the means of obtaining concentrations from the
measurement should be stated.
(3)

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................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(ii) Determine the rate of reaction at point A and at point B. You must show your
working on the graph and include units with your answers.
(2)
Rate at point A

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Rate at point B

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(iii) Explain why the values obtained in (b) (ii) are different from the results of
typical rate experiments.
(2)

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(Total for Question 3 = 16 marks)

13
 *P68794A01316* Turn over
4 The identity and purity of an organic compound may be checked by measuring its
melting temperature. Students were asked to determine the melting temperature of
samples of a solid organic compound using the apparatus shown.

Thiele tube thermometer capillary tube Bunsen burner

beaker containing a solid sample on a

rubber band
clear mineral oil watch glass

14
*P68794A01416* 
 (a) Give the steps of the procedure to determine the melting temperature of the
solid organic compound, using the apparatus shown.
You may include a diagram in your answer. You do not need to show how the
apparatus is clamped in position.
(5)

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(b) State how the melting temperature of an impure sample of an organic compound
would differ from that of the pure compound.
(1)

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(Total for Question 4 = 6 marks)

TOTAL FOR PAPER = 50 MARKS

15
 *P68794A01516*
16
*P68794A01616* 