ABB Protection Solutions
ABB Protection Solutions
A P P L I C AT I O N G U I D E
On Earth, hydrogen exists combined with oxygen in Fuel for Heat for Feedstock for
water or with carbon, constituting hydrocarbons Transport Industry Chemicals
Carbon Capture
Hydrogen Storage
Hydrogen production
Hydrogen Consumption
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ABB participates throughout
the hydrogen ecosystem
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ABB Portfolio for the Hydrogen Ecosystem
HRS
ABB Power Drivers Batteries/SC
Hydrogen
Quality &
Refueling
Rectifiers
Station On board
Unit Operation & Control Motor H₂ Storage Full Cell Drives Motor
Transmission Grid
ABB Ports
and Marine ABB Ability Platform - integrated Functional, technological and operational ecosystem
ABB Offering
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ABB IS PRESENT THROUGHOUT THE HYDROGEN ECO -
SYSTEM, WITH SOLUTIONS FOR HYDROGEN PRODUC-
TION, HYDROGEN STOR AGE, AND HYDROGEN DIS-
TRIBUTION AND CONSUMPTION. IN THIS DOCUMENT,
WE WILL FOCUS ON HYDROGEN PRODUCTION.
Main concerns and problems One kilogram of hydrogen contains 3.1 times the en-
ergy of one kg of gasoline and 2.6 times the energy
related with H₂ of 1 kg of natural gas.
What’s an Electrolyzer?
An electrolyzer is a device that produces hydrogen
Water 9 kg 1 kg
through a chemical process, namely electrolysis,
which separates the hydrogen and oxygen mole-
Electrolysis
cules in water using electricity.
Total H+ H+
SOEC process:
U
87% Direct 39% Alkaline 100% Alkaline
renewables 58% PEM
13% Grid 3% Solid-Oxide
H² Electrolyte O₂
solid oxide
H₂O
6000 Alkaline 50 Alkaline
Cathode Anode 7000 PEM 100 PEM
steam electrode air electrode 300 Grid 10 Grid
Op. Op.
temp. press. Cathode Anode
Type [°C] [Bar] Gas Gas Cost
Alkaline H₂ O₂
(AEL) 15 – 220 <30 H₂O H₂O Lowest
Acidic O₂
(PEM) 40 – 80 <30 H₂ H₂O High
Solid H₂ Not
Oxide 500 – 1,000 <10 H₂O O₂ commercial
Levelized Cost of Hydrogen Currently, electricity costs account for more than
60% of the Levelized Cost of Hydrogen (LCOH) share
(LCOH) in Alkaline Electrolyzer (AEL) systems and more than
40% in Proton Exchange Membrane (PEM) systems.
The 3 major factors affecting LCOH are:
—
Electrolyzer System
Electrolyze System CAPEX
CAPEX Forecast
Forecast
1400
1200
1000
800
600
400
200
2020 2021 2022 2023 2024 2025 2026 2027 2028 2029 2030
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Layout for an alkaline electrolyzer plant
High pressure
Feed water supply Vented oxygen Gas/water separator Deoxo Buffer tank compressor
O₂ H₂
Electrolyzer
Dryer
High pressure
buffer tank
High voltage
supply
Water/KOH
Electrolyte Tank
Lye
Filter
Transformer Rectifier
Hydrogen
—
Oxygen
NOTE: THIS CONFIGUR ATION IS FOR A GENERIC
Water SYSTEM AND MIGHT NOT BE REPRESENTA-
TIVE OF ALL EXISTING MANUFACTURERS.
Water/KOH
BASED ON IRENA ANALYSIS.
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Layout for a PEM electrolyzer plant
Condensate
Low High
pressure pressure Deoxo Hydrogen
side side
Dryer
Gas
Gas Gas
O₂ H₂ reservoir
separator separator
Circulation Electrolyzer
pump
Transformer Rectifier
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NOTE: THIS CONFIGUR ATION IS FOR A GENERIC
Hydrogen
SYSTEM AND MIGHT NOT BE REPRESENTA-
Oxygen
TIVE OF ALL EXISTING MANUFACTURERS.
Water BASED ON IRENA ANALYSIS.
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Layout for a SOEC electrolyzer plant
Heater
Gas/Water Pre-heater Pre-heater
H₂ Separator Steam Air
O₂ Vented out
Feed liquid
water supply
Evaporator
Stack
Transformer Rectifier
—
Hydrogen NOTE: THIS CONFIGUR ATION IS FOR A GENERIC
SYSTEM AND MIGHT NOT BE REPRESENTA-
Oxygen
TIVE OF ALL EXISTING MANUFACTURERS.
Water BASED ON IRENA ANALYSIS.
Different solutions – different Typically, the DC energy consumption for 1 Nm³ of
H₂ is around 4 – 6 kWh. Therefore, a 4,000 Nm³/h
production scales: plant is capable of producing 360 kg of H₂ per hour
while consuming 20 MWh.
Commercially, PEM electrolyzers are available with
hydrogen production capacities ranging from 0.27
Here are some examples of commercial
to 1.05 Nm³/h – suitable for replacing pressurized
configurations:
hydrogen cylinders – to 10, 30, and even up to
30 Nm³/h.
• Alkaline Electrolyzer (AEL):
• 15 Nm³/h with 1 stack, energy consumption of
Medium-sized units fall within the range of 100 to
5.4 kWh/Nm³, and a power rating of 80 kW.
800 Nm³, and large-scale plants with PEM electrolyz-
• 100 Nm³/h with 6 stacks, energy consumption of
ers can generate up to 5,000 Nm³/h. Alkaline elec-
5 kWh/Nm³, and a power rating of 500 kW.
trolyzers, on the other hand, can range from 50 to
• Proton Exchange Membrane (PEM):
19,400 Nm³/h.
• 300 Nm³/h with 1 stack, energy consumption of
5 kWh/Nm³, and a power rating of 1.5 MW.
But what is Nm³? A normal cubic meter (Nm³) refers
• 5,000 Nm³/h with 10 stacks, energy consumption
to the amount of gas that fits into the volume of one
of 5 kWh/Nm³, and a power rating of 25 MW.
cubic meter at a temperature of 0 °C and one atmo-
spheric pressure (1 bar). Keep in mind: 1 kg of H₂ is
equal to 11.12 Nm³.
To mitigate the effects of the converters’ reactive For splitting liquid water, a voltage of 1.48 volts is
power, filter circuits are incorporated into the sys- required. This is the voltage at which an electrolysis
tem. Additionally, the power grid needs to be stable cell operating at 25 °C can function without produc-
enough to endure the reactive power, potentially ne- ing excess heat. However, commercial cells operate
cessitating the installation of compensation sys- above this voltage and generate excess heat; in fact,
tems such as Static Synchronous Compensators the actual cell voltage is typically around 1.8 V.
(STATCOMs).
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Power supply for a system with several electrolysis stacks;
adapted from Energiepark Mainz
High voltage
transformer
(110/30 kV)
30 kV
Circuit breaker
Balance of plant
power supply
transformer
Power Supply Units
0.4 kV (30/0.4 kV + rectifier)
~400 VDC
-10.000 ADC
Electrolysis stacks
O₂
Hydrogen
Production H₂
Equipment
Stack Gas/Liquid Separation Skid Hydrogen Purification Skid
Auxiliary
Units
Alkaline Solution
Compressor Air Unit Cooling Water Unit Deionized Water Unit Nitrogen Purge Unit Preparation/Recovery Unit
The number of cells in today’s Proton Exchange Given that 290 cm² × 1.5 A/cm² = 435 A and
Membrane (PEM) stacks ranges between 30 – 220, 60 cells × 1.8 V/cell = 108 V, the resulting power
each with an active area of up to 1,500 cm². Most would be 435 A × 108 V = 46.9 kW.
PEM electrolysis stacks feature a rectangu-
lar-shaped cell design and operate at temperatures In AEL stacks, the current density is much lower, in
of 55 to 70 °C with current densities roughly varying the range of 0.2 to 0.8 A/cm² and 1.8 V per cell, and
between 1.4 – 2.5 A/cm². the active area is in the range of 10,000 to
30,000 cm².
Therefore, depending on the stack configuration,
PEM stacks could require from 50 V to 400 V and up Here an exemplary performance for a single AEL cell:
to 3,800 A. For instance, a commercial PEM electro-
lyzer, with an active area of 290 cm² and a stack
composed of 60 cells, provides 10 Nm³/h at 46 kWe.
2.50
2.00
Unit Cell Voltage (V)
1.50
1.00
1.50
0.00
Compressor Transformers
— Scrubbers
Example of 2,425 Nm³/h block
made with 5 × 485 Nm³/h AEL electrolyzers
In total, there are 416 AEL stacks, each one compris- This redundancy ensures that if one section encoun-
ing 258 cells. The cells are connected in series elec- ters a problem, the other can continue to produce
trically and the fluids run in parallel. hydrogen. Hence, instead of 423 or 422 stacks, it is
more efficient to consider 420 ÷ 2 = 210 or 416 ÷ 2 =
In this case, the cell voltage is 1.75 V, the current 208 stacks per section.
density is 0.175 A/cm², and the active cell area is
29,077 cm². Therefore, the stack voltage is Moreover, the plant is segmented into power blocks,
258 × 1.75 = 452 V, and the stack current is each consisting of a transformer, a rectifier, and a
29,077 × 0.175 = 5,088 A, which gives a stack power certain number of stacks in parallel. This arrange-
of 5,088 × 452 = 2.3 MW. ment reduces the capital expenditure (CAPEX). The
design includes either 26 or 30 power blocks, each
The goal is to develop a plant of 1 GW, or close to with 16 or 14 stacks, respectively.
that value, with an optimized layout. Given a security
factor of 20% (considering voltage variations due to With this configuration, we have 2 × 13 groups of
the grid and the min-max voltage of cells during 16 stacks, totaling 416 stacks, or 2 × 15 groups of
lifespan), the High Voltage (HV) Transformer could 14 stacks, totaling 420 stacks. A group of 16 stacks
be 230 kV. requires a transformer and rectifier capable of sup-
plying 452 V and 16 × 5,088 A = 81,408 A, while a
So, 230 ÷ 1.2 = 191.6 kV, and 191.6 kV ÷ 452 V = 423, group of 14 stacks necessitates a transformer and
which represents the maximum number of stacks. rectifier capable of supplying 452 V and
Hence, 2.3 MW × 423 stacks = 973 MW, providing the 14 × 5,088 A = 71,232 A.
total power output of the plant.
This solution could optimize the plant’s operation
Additionally, the plant includes various auxiliary more effectively, compared to having a transformer
voltages. For reasons of security, resiliency, and rectifier for each stack.
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Major stack specifications summary:
Alkaline Electrolyzer PEM Electrolyzer
Parameter Current KPI Future KPI Future KPI Future KPI
Plant size (MW, DC basis) 957 960 960 960
Stack size (MW) 2.3 10 2.5 10
# of stacks 416 96 384 96
Cell voltage (V) 1.75 1.75 1.75 1.75
Current density (A/cm²) 0.175 0.75 1.50 2.50
# of cells 258 258 258 258
Stack voltage (VDC) 452 452 452 452
Stack Current (A) 5,088 22,124 5,531 22,124
Cell active area (cm²) 29,077 29,499 3,687 8,850
Actual cell area (cm²) 34,208 34,704 4,852 11,644
Operating Pressure (barg) 0.02 0.06 30 30
Stack production volume (GW/year) 1 1 1 1
Purity (%) 99.99 99.99 99.99 99.99
Oxygen limit <5 ppm <5 ppm <5 ppm <5 ppm
Moisture content −65 °C dew point −65 °C dew point −65 °C dew point −65 °C dew point
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Current Alkaline: 1 GW Alkaline (2.3 MW stack), 2 sets of BOP, simplified layout
Vents to atmosphere
Valve Valve Valve
Gas/Liquid Outside facility
Rectifier Separator
Transformer O₂ Vent
Power x28
Transformer Valve
66 KV AC
230 KV AC /
66 KV AC Valve Water filtration
16 stacks
Valve Filter Transport
Group 1
Rectifier
Dry cooling/ Tap water
452 VDC cooling tower Circulation
pump
Lye tank Water
16 stacks treatment
Group 2
H₂ buffer
Gas/Liquid Lye tank
Rectifier Valve Separator Circulation scrubber Valve Valve H₂ Vent
452 VDC pump Compressor
H₂
230 kV 3 phase
Valve
Deoxo Valve
Valve
16 stacks
Group 25
Dryer
Rectifier
H₂ Storage &
452 VDC Transport
16 stacks
Rectifier
24 VDC
110 VAC
380 VAC
Auxiliary
Power
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Current Alkaline: 1 GW Plant Layout
KOH KOH
Gas / liquid separation Gas / liquid separation Scrubber Scrubber DE-oxo TSA Driver TSA Driver
Compressor DI Water
Indoor
AEL stacks
Rectifiers
Transformers
Indoor
System Control &
Offices
LV protections In a 100 MW electrolyzer plant, the power consump-
tion for different systems is as follows:
Protection for low voltage components is primarily
needed in the rectifier (on both the AC and DC • Circulation pumps consume 98 kW of power,
sides), the compressor, the cooling system, the • The process cooling system consumes 892 kW
heaters, and the water purification system. It’s also of power,
necessary for all motor starters required for the sys- • The gas purification system consumes 207 kW
tem’s pumps. of power,
• The compression system consumes 2,600 kW of
Typical voltage levels within the plant include power (considering four four-stage reciprocating
24 VDC, 110 VAC, 240 VAC, and 380 VAC. Depending compressors, each using 650 kW).
on the plant design and stack configuration, the rec-
tifier might be designed for 400 VDC or even for
voltages in the thousands.
Utility 1
Emax 2
Tmax XT
Molded
Case Circuit
Breaker
Tmax s800
AF
Contractors
OS switch
EQmatic Tmax fuse unit Tmax XT2
Ekim M Touch LRIU
Emax 2
Air Circuit
Breaker
Pump or
Pump compressor Pump
Manual
Operated
Switch Fuses
Measuring & monitoring Moreover, it’s vital to relay other key measurements
to the control system, such as water consumption,
Measuring voltage and current is crucial, particularly energy use, and the status of various devices,
for monitoring the degradation of the stack and/or among others.
individual cells.
M4M
Network ABB Ability™ ABB Ability™ 3rd Party System
Analyzer Energy Manager Edge Industrial
ABB Ability™ Gateway
Asset Manager
ABB EQmatic
Energy
Analyzer
>160A: M4M Energy meter <160A: CMS current sensors compa- EQmatic(1)
analyzer with stan- tible with any MCB (ABB or 3rd party)
dard CTs compati-
ble with any load
S200
Miniature
Circuit
Breaker
3rd Party Devices
Insite Bus - Plug & play flat cable (max 96 channels between sensors and I/O channels
ABB Ability™
Asset
Manager