1 s2.0 S1290072908002998 Main
1 s2.0 S1290072908002998 Main
1 s2.0 S1290072908002998 Main
www.elsevier.com/locate/ijts
a r t i c l e i n f o a b s t r a c t
Article history: Traditional dehumidifiers and regenerators of liquid desiccant systems often use packed columns sup-
Received 9 November 2007 porting adiabatic heat and mass transfer between air and liquid desiccant. As new-style equipment,
Received in revised form 18 December 2008 internally-cooled dehumidifiers can improve dehumidification performance due to restraining tempera-
Accepted 18 December 2008
ture increase of the desiccant. Similar to internally-cooled dehumidifiers, an idea of internally heating
Available online 15 January 2009
is imitated to put forward internally-heated regenerators. The uniform mathematical model for an inter-
Keywords: nally cooled dehumidifier and internally heated regenerator was presented and validated by comparison
Liquid desiccant of computation results with experimental data in this study. The case study focused on the parameters
Internally heated regenerator distribution comparisons of the internally cooled/heated dehumidifier/regenerator with adiabatic ones
Internally cooled dehumidifier and demonstrated coupled heat and mass transfer behavior. The results show that the internally-heated
Optimal design regenerator can produce higher regeneration efficiency than the adiabatic one to produce better energy
efficiency and eliminate the dehumidification possibility which would happen in adiabatic regenerators.
The internally-cooled dehumidifier can also provide better dehumidification performance comparing with
the adiabatic one; however its benefit would be not as good as the internally-heated regenerator. In ad-
dition, effect of the width of the air channel on internally cooled/heated dehumidifier/regenerator was
discussed and the results can help the optimal design of this kind of dehumidifiers and regenerators.
© 2008 Elsevier Masson SAS. All rights reserved.
1290-0729/$ – see front matter © 2008 Elsevier Masson SAS. All rights reserved.
doi:10.1016/j.ijthermalsci.2008.12.017
Y. Yin et al. / International Journal of Thermal Sciences 48 (2009) 1664–1671 1665
Nomenclature
thin plastic plates, and one side of each thin plastic plate was mass transfer driving force–vapor partial pressure difference be-
for the desiccant solution/air passage; the other side is for wa- tween liquid desiccant and air reduces; as a result, dehumidifica-
ter/air passage. So the indirect evaporation process in the water/air tion performance would decay with the progress of the process in
passage provided cooling to the dehumidification process. The ex- dehumidifiers. Similarly in regeneration processes of desiccant so-
perimental results indicated the effects of inlet parameters of air lution, temperature of liquid desiccant goes down in adiabatic re-
and solution on the PHE effectiveness. Considering the fact that generators because it is necessary for desiccant solution to provide
there were different velocities and properties in air layer and des- latent heat of vaporization to transfer water in the desiccant so-
iccant falling film in the cross-section normal to the flow, some lution to air. Hence, the regeneration performance would become
investigators [19–22] considered the coupled heat and mass trans- weaker and weaker with the process going in regenerators. In or-
fer as two-dimensional cases using Navier–Stokes equations, but der to keep more driving force in dehumidifiers and regenerators,
for solution of the equations, very complex computations have to heated or cooled sources are proposed to import to the regener-
be taken besides assumptions about boundary conditions, so sim- ation and dehumidification processes. Here plate heat exchanger
plified models need developing and validating to probe into the is used for the internally cooled/heated dehumidifier/regenerator.
heat and mass transfer behavior between air and desiccant in de- Fig. 1(a) shows the schematic of internally cooled/heated dehu-
humidifiers and regenerators. midifier/regenerator. Air and desiccant enter the plate exchanger
Similar to internally-cooled dehumidifiers, an idea of internally from the top, and desiccant solution (LiCl–H2 O) is sprayed to the
heating is imitated to put forward internally-heated regenerators.
walls by distributing device and flow down along walls to the bot-
Till now, little work has been conducted on internally-heated re-
tom by its gravity; there air and desiccant solution contact directly
generation processes. In addition, simultaneous heat and mass
to conduct the heat and mass transfer. Fig. 1(b) shows the fluid
transfer between liquid desiccant and air is very complex, and
flow configuration in a unit. In each unit there are two channels in
it need further analysis on the coupled heat and mass trans-
the dehumidifier/regenerator with 1 m height; one (channel II) is
fer processes of internally cooled/heated dehumidifier/regenerator.
for the liquid desiccant and air with the width of 12 mm, and the
This paper will put forward the idea of internal heating source
other (channel I) is for coolant or heating fluid with the width of
based on internally cooling, and investigate simultaneous heat and
2.5 mm. When dehumidification process is necessary, the coolant
mass transfer behavior of an internally-cooled dehumidifier and
enters into channel I. While in regeneration processes, the heating
internally-heated regenerator using a mathematical model vali-
dated by experimental data. fluid enters into the channel I.
Along the height of the dehumidifier and regenerator, finite
2. Methodology segments are divided to generate control volumes for describing
the heat and mass transfer processes, and the control volume is
2.1. Mathematical model shown in Fig. 1(c). To demonstrate the simultaneous heat and mass
transfer for the processes, following assumptions are made in the
In adiabatic dehumidifiers, temperature of liquid desiccant and derivation of the steady-state governing equations for the dehu-
air would rise because of the release of vaporization heat, and midifier and regenerator:
1666 Y. Yin et al. / International Journal of Thermal Sciences 48 (2009) 1664–1671
Substitute Eqs. (1) and (3) into (4) to yield: Eqs. (1) and (2) are the governing equations of heat and mass
transfer processes of air, which is used to solve the temperature
dha = β h C · ( T s − T a ) + h w (1 − β)( T w − T a ) and humidity ratio of air in control volumes. Eq. (10) can infer the
2W dz temperature change of solution in control volumes. Temperature
+ β h D · (ω T s ,sat − ωa ) · (q v + Cp v · T a ) (5)
Ga change of cooling or heating fluid is determined by Eq. (11). Af-
ter calculating air parameters, flow rate and concentration change
The Lewis number and NTU are defined as:
of desiccant solution are computed by Eqs. (12) and (13). During
hC above computation, the Lewis number is usually assumed as con-
Le = (6)
h D · Cpa stant, however the NTU number is greatly depended on the mass
hD · W · Hβ transfer coefficient between air and desiccant solution. Therefore,
NTU = (7) experimental data is necessary to determine the mass transfer co-
G a /2
efficient between air and desiccant solution and to validate the
Substitute Eqs. (6) and (7) into (5) to yield: model.
Y. Yin et al. / International Journal of Thermal Sciences 48 (2009) 1664–1671 1667
In dehumidification:
E=M−S (20)
UE = 2
UM + U 2S (21)
Table 2
Comparison of the computation results with experimental data for regeneration.
G a,in T a,in ωa,in T w ,in G s,in T s,in X s,in Le ωa,out T a,out T s,out
(m3 /s) (◦ C) (g/kg) (◦ C) (kg/s) (◦ C) (%) Exp. Comp. Exp. Comp. Exp. Comp.
1 0.062 26.5 11.4 70.5 0 .1 70.0 37.5 0.3 24.5 24.8 37.1 37.3 66.3 65.4
2 0.067 26.5 11.5 70.5 0 .1 70.8 38.0 0.35 23.9 23.9 38.9 38.8 64.8 65.2
3 0.076 26.0 11.7 70.5 0 .1 71.0 38.0 0.35 24.0 23.7 39.8 39.5 64.9 64.1
4 0.051 21.0 6.3 65.0 0.12 64.5 32.2 0.39 20.8 21.1 29.4 29.4 58.6 59.1
5 0.050 21.7 6.3 74.0 0.12 74.3 33.6 0.45 28.0 28.4 34.1 34.4 67.7 67.8
6 0.050 22.4 6.3 78.0 0.12 77.1 34.8 0.5 27.3 28.2 35.3 35.6 73.1 71.4
7 0.050 22.9 6.7 76.0 0.12 74.0 36.2 0.5 25.5 25.3 36.8 36.8 70.3 69.3
8 0.050 23.1 6.6 76.0 0.12 74.5 37.3 0.5 24.3 23.7 37.1 37.0 69.9 69.9
9 0.050 25.1 7.2 78.0 0.12 75.1 38.3 0.5 23.5 22.4 37.7 37.2 70.3 70.3
10 0.050 26.6 7.2 78.0 0.12 73.0 39.2 0.5 21.4 21.6 38.4 38.7 69.9 70
ratio in the internally-heated regenerator is much more than that Fig. 4 shows the comparison of parameters of the solution and
in the adiabatic one shown in Fig. 3(d). Combining Eq. (20), it is air in the adiabatic and internally cooled dehumidifiers. Fig. 4(a)
concluded that the regeneration efficiency of the internally-heated displays that temperature distribution of the desiccant and water
regenerator is higher than that of the adiabatic one. in both dehumidifiers. In the adiabatic dehumidifier, the desiccant
1670 Y. Yin et al. / International Journal of Thermal Sciences 48 (2009) 1664–1671
Fig. 6. Effect of the channel II width on the dehumidification with different air flow
temperature increases from 26.0 to 30.6 ◦ C gradually because of rates.
the release of vapor latent heat during dehumidification process,
which would make mass transfer between air and desiccant de-
cay, however internally-cooled dehumidifier can remove the latent
heat by internally coolant to keep lower temperature of desiccant,
which manage to give less outlet humidity ratio of the air, just as
shown in Fig. 4(b) humidity ratio of the dehumidified air is less
1 g/kg than that in the adiabatic one, anyway the difference is not
as obvious as that in the regenerators.
Fig. 4(c) depicts the comparison of temperature distributions of
air in both dehumidifiers. In this case, the figure shows that the air
temperature decreases at the beginning and then increases in both
dehumidifiers, which is because the temperature of the air is lower
than the desiccant at the beginning, and then with the progress of
the dehumidification, the latent heat release dominates the process
so that the air temperature increases. From the figure, it can be
seen that the outlet temperature of the air in the internally-cooled
dehumidifier is higher than that in the adiabatic one, although
the difference between them is very small, only 0.3 ◦ C, the rea- Fig. 7. Effect of the channel II width on the regeneration with different air flow
son for which is that in the internally-cooled dehumidifier more rates.
mass transfer causes more latent heat release from the dehumid-
ification, and as a result the air would gain more heat to be with mance goes down with increase of the channel width, which is
higher outlet temperature. The outlet temperature difference be- the result from that smaller width of the channel II can pro-
tween both dehumidifiers greatly depends on the Lewis number vide higher air velocity and mass transfer coefficient. However,
and operation conditions. During our experiments, the same fact too small width of the channel would bring another problem,
happened under some operation conditions, which was that the which is too high pressure resistance in the channel and more en-
outlet air temperature in the internally cooled dehumidifier was ergy consumption of pumps. Fig. 7 shows the effects of the air
slightly higher than that in the adiabatic one. In above computa- channel width on the regeneration with three different air flow
tion for the dehumidification, the Lewis number was assumed as rates (0.006, 0.012 and 0.018 kg/s) under the operation conditions
1.5. In order to check the behavior of effect of Lewis number on shown in Table 3. The results show that higher air flow rate can
the process, Fig. 5 demonstrates outlet temperature and humidity produce better regeneration performance, for better regeneration
ratio of the air at different Lewis numbers in both dehumidifiers. performance it is recommended that the width of the air channel
The results indicate that the Lewis number has little influence on should be less than 1.5 cm, however pressure resistance problem
outlet humidity ratio of the air, and however has a little influence should also be considered here as in the optimal design of the
on outlet temperature of air since the outlet temperature of air dehumidifier. Hence, the designs of the internally cooled/heated
changes less than 1 ◦ C with the obvious change of Lewis number. dehumidifier/regenerator need to consider roundly the dimension
The results also show that the outlet temperature of the air in the size, thermal performance and air pressure resistance.
internally-cooled dehumidifier is slightly higher than that of the
adiabatic one. 4. Conclusions
Usually the internally cooled/heated dehumidifier/regeneration
expected is with suitable dimensions and good thermal perfor- The idea of internal heat/sink source was put forward in order
mance. The width of the heat and mass transfer channel is an to keep high temperature of desiccant solution in the regenera-
important parameter for optimal design of this kind of dehumid- tor and lower temperature of the desiccant solution in the de-
ifier. Fig. 6 indicates the effects of the width of channel between humidifier for better mass transfer performance compared with
air and desiccant with three different air flow rates (0.0076, 0.0151 traditional packing, and a unitized model for the internally-cooled
and 0.0227 kg/s) under the typical operation conditions shown dehumidifier and internally-heated regenerator was presented. By
in Table 3. In this case, for better dehumidification performance utilizing experimental data, the correlations of mass transfer co-
it is recommended that the width of the channel should be less efficient between air and desiccant were developed for the dehu-
than 2 cm. The results show that the dehumidification perfor- midification and regeneration, which indicated the effect of tem-
Y. Yin et al. / International Journal of Thermal Sciences 48 (2009) 1664–1671 1671
perature and flow rate of desiccant on mass transfer coefficients. [5] P. Gandhidasan, Prediction of pressure drop in a packed bed dehumidifier oper-
In addition, model validation was carried out by comparing the ating with liquid desiccant, Applied Thermal Engineering 22 (2002) 1117–1127.
[6] D.I. Stevens, J.E. Braun, S.A. Klein, An effectiveness model of liquid desiccant
computation results with experimental data. It was found that the
system heat/mass exchangers, Solar Energy 42 (1989) 449–550.
errors were within 5% and showed acceptable accuracy. Whereas [7] V. Martin, D.Y. Goswami, Effectiveness of heat and mass transfer processes in
further study is still necessary to develop more comprehensive a packed bed liquid desiccant dehumidifier/regenerator, HVAC&R Research 6
mass transfer coefficient correlations under wider range experi- (2000) 21–39.
mental conditions and deal more accurately with the model as- [8] T.W. Chung, H. Wu, Comparison between spray towers with and without fin
coil for air dehumidification using triethylene glycol solutions and development
sumptions, such as actual Lewis number, definite description of
of the mass transfer correlations, Ind. Eng. Chem. Res. 39 (2000) 2076–2084.
wetness. Anyhow, the present study highlights the importance of [9] X.H. Liu, Y. Zhang, K.Y. Qu, Y. Jiang, Experimental study on mass transfer per-
actual Lewis number and wetness, which should be paid more at- formances of cross-flow dehumidifier using liquid desiccant, Energy Conversion
tention in future study. and Management 47 (2006) 2682–2692.
A case of the internally cooled/heated dehumidifier/regenerator [10] Yonggao Yin, Xiaosong Zhang, Zhenqian Chen, Experimental study on dehu-
midifier and regenerator of liquid desiccant cooling air conditioning system,
using the plate exchanger with the parallel flow was studied nu- Building and Environment 42 (2007) 2505–2511.
merically to discuss the heat and mass transfer behavior between [11] Yonggao Yin, Xiaosong Zhang, A new method for evaluating coupled heat and
air and desiccant. The results show that the internally-heated re- mass transfer coefficients between air and liquid desiccant, International Jour-
generator can avoid the dehumidification possibility which would nal of Heat and Mass Transfer 51 (2008) 3287–3297.
[12] Chengqin Ren, Yi Jiang, Yinping Zhang, Simplified analysis of coupled heat and
happen in adiabatic one, and in addition it could offer higher re-
mass transfer processes in packed bed liquid desiccant–air contact system, So-
generation efficiency than the adiabatic one to produce better en- lar Energy 80 (2006) 1221–1231.
ergy efficiency. The internally-cooled dehumidifier can also provide [13] A.Y. Khan, Cooling and dehumidification analysis of an internally cooled liquid
better dehumidification performance comparing with the adiabatic desiccant absorber, Applied Thermal Energy 18 (1998) 265–281.
one; however its benefit would be not as good as the internally- [14] A.Y. Khan, J.L. Martinez, Modeling and parametric analysis of heat and mass
transfer performance of a hybrid liquid desiccant absorber, Energy Conversion
heated regenerator. Effect of the air channel width on the dehu-
and Management 39 (1998) 1095–1112.
midifier and regenerator was discussed and reasonable width is [15] H.W. Coleman, F. Stern, Uncertainties in CFD validation, Journal of Fluids Engi-
recommended to optimize the design of this kind of dehumidifier neering 119 (1997) 795–803.
and regenerator. [16] J.R. Taylor, An Introduction to Error Analysis—The Study of Uncertainties in
Physical Measurements, University Science Books, California, 1982.
[17] S. Jain, P.L. Dhar, S.C. Kaushik, Experimental studies on the dehumidifier and
Acknowledgements
regenerator of a liquid desiccant cooling system, Applied Thermal Engineer-
ing 20 (2002) 253–267.
The authors would like to thank the supports by National Natu- [18] W.Y. Saman, S. Alizadeh, An experimental study of a cross-flow type plate heat
ral Science Foundation of China (No. 50676018), China Scholarship exchanger for dehumidification/cooling, Solar Energy 73 (2002) 59–71.
Council and Foundation for Excellent Doctoral Dissertation of the [19] G. Grossman, Simultaneous heat and mass transfer in film absorption under
laminar flow, International Journal of Heat and Mass Transfer 26 (1983) 357–
Southeast University in China. In addition, the constructive com-
371.
ments of the reviewers and editor are appreciated greatly. [20] A. Ali, K. Vafai, A.R.A. Khale, Analysis of heat and mass transfer between air
and falling film in a cross flow configuration, International Journal of Heat and
References Mass Transfer 47 (2004) 743–755.
[21] M. Park, J.R. Howell, G.C. Vliet, J. Peterson, Numerical and experimental results
[1] K. Gommed, G. Grossman, Experimental investigation of a LiCl–water open ab- for coupled heat and mass transfer between a desiccant film and air in cross-
sorption system for cooling and dehumidification, Trans. of ASME, Journal of flow, International Journal of Heat and Mass Transfer 37 (1994) 395–402.
Solar Energy Engineering 126 (2004) 710–715. [22] Y.J. Dai, H.F. Zhang, Numerical simulation and theoretical analysis of heat and
[2] Y.J. Dai, R.Z. Wang, H.F. Zhang, et al., Use of liquid desiccant cooling to improve mass transfer in a cross flow liquid desiccant air dehumidifier packed with
the performance of vapor compression air conditioning, Applied Thermal En- honeycomb paper, Energy Conversion and Management 45 (2004) 1343–1356.
ergy 21 (2001) 1185–1202. [23] M.R. Conde, Properties of aqueous solutions of lithium and calcium chlorides:
[3] L.Z. Zhang, J.L. Niu, A pre-cooling Munters environmental control desiccant formulations for use in air conditioning equipment design, International Jour-
cooling cycle in combination with chilled-ceiling panels, Energy 28 (2003) nal of Thermal Science 43 (2004) 367–382.
275–292. [24] Yonggao Yin, Xiaosong Zhang, Gen Wang, Lei Luo, Experimental study on a new
[4] H.M. Factor, G. Grossman, A packed bed dehumidifier/regenerator for solar air- internally cooled/heated dehumidifier/regenerator of liquid desiccant systems,
conditioning with liquid desiccants, Solar Energy 24 (1980) 541–550. International Journal of Refrigeration 31 (2008) 857–866.