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Chemical Structure

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TOPIC 1: CHEMICAL STRUCTURES

1.1 EXPLAIN WHAT IS MEANT BY CHEMICAL STRUCTURE


Think about building something with Legos or other blocks. When you put them together, the way they
fit, connect, and stack is like the structure of a chemical compound. In chemistry, the "blocks" are
atoms—the smallest building blocks of all matter.

Atoms can remain single; or atoms come together to form molecules (combinations of two or more
atoms); or atoms also lose or gain electrons to form ions. Therefore, the particles that are building
blocks can be atoms, molecules or ions.

The chemical structure tells you how these particles are connected and arranged. It's not just which
particles are there, but also how they're linked (which particle connect to which) and their shape in
space.

Definition of chemical structure:

Chemical structure is a description of packing and arrangement of particles (atoms or molecules or


ions.

For example, let's say you have a simple molecule like water (H2O). This molecule has two hydrogen
atoms (H) and one oxygen atom (O). The way these atoms are arranged: the oxygen in the center with
the two hydrogens at an angle—is its chemical structure. This shape is what gives water its unique
properties, like the ability to dissolve many substances and to stick to other water molecules.

Chemical structure can get more complex when dealing with larger structures, like sodium chloride,
diamond, or metals where the arrangement can include chains, branches, or rings in 3 dimensions. But
the basic idea is the same: the structure describes how the particles are packed together, which
determines how the substance behaves and what it can do.

1.2 & 1.3 DESCRIBE HOW ATOMS, IONS AND MOLECULES ARRANGE TO FORM
STRUCTURES AND THEIR RESPECTIVE PROPERTIES.
Atoms, ions, and molecules can arrange themselves in various ways to form different types of
structures. Each type has unique physical properties based on how the building blocks are connected
(structure) and interact with each other (bonding).

Let's break it down into the four categories: Structures can be classified as: Giant ionic crystalline solids;
Giant covalent/molecular solids; Simple covalent structures which can be solids, liquids and gases;
Giant metallic structure-solid.
1. Giant Ionic Crystalline Solids:
 These structures are made of positively charged ions (cations) and negatively charged
ions (anions) that are held together by strong ionic bonds, which are the attraction
between oppositely charged ions. This type of structure usually forms a regular,
repeating pattern known as a crystal lattice.

 Physical Properties: These structures tend to have


 high melting and boiling points,
 are usually hard and brittle,
 and often soluble or dissolve in water.
 They also conduct electricity when melted or dissolved in water because the
ions can move freely.

 Example: Sodium chloride (table salt, NaCl) is a common example. In NaCl, sodium (Na⁺)
and chloride (Cl⁻) ions are arranged in a repeating cubic structure.
2. Giant Covalent Structures: also called Giant Molecular (made of molecules
eg silicon dioxide in sand) or Giant Atomic (made of atoms eg. carbon in
diamond and graphite)
These are composed of a large number of atoms or molecules that are interconnected
by covalent bonds (where atoms share electrons) in a repeating pattern or network.
These structures are typically quite strong due to the covalent bonds.

 Example 1: Diamond is a well-known example of a giant atomic solid. It's made of


carbon atoms where each carbon atom is bonded to four other carbon atoms in a three-
dimensional network.

 Physical Properties of diamond:

 High melting and boiling points,


 Hardest natural substance on
earth,
 Do not conduct electricity as
they do not have free-moving ions or
electrons.
 Transparent and sparkling

 Example 2: Graphite another giant atomic solid made of carbon atoms. Each carbon
atom is linked with 3 other carbon atoms by single covalent bond resulting in the
hexagonal ring that is arranged in a layer. The layers are separated by weak Van der
Waals forces, which allow the layers to slide over each other, this gives it a lubricating
feeling. In general, graphite is used in pencil points, batteries as an electrode.
 Physical properties of graphite
 High melting and boiling point
 Soft, flaky and brittle
 Good lubricant since layers can slide over each other making graphite slippery
 Conducts electricity since there are free electrons (each carbon has one free
electron not used in bonding)
 Black opaque and shiny

Diamond and graphite are allotropes of carbon. Allotropes are elements in the same physical state
having different structures.

 Example 3: Sand, which is a giant molecular solid. It is composed of silicon dioxide (SiO2)
molecules arranged in a 3-dimensional network.

3. Simple Covalent Structures (Solids, Liquids, Gases):


 These structures consist of small molecules held together by covalent bonds. The forces
holding these molecules together (intermolecular forces) are much weaker than
covalent or ionic bonds, allowing for more variation in state (solid, liquid, gas).
 Physical Properties of simple covalent structures: The properties can vary greatly
depending on the type and strength of intermolecular forces. Generally, these
structures

 Have low melting and boiling points compared to giant structures


 can be solids, liquids and gases
 are poor conductors of heat and electricity
 soluble in organic solvents but not in water

 Examples of simple covalent structures:

 Solid: Iodine (I₂) is a solid at room temperature with a simple covalent structure.

 Liquid: Water (H₂O) is a liquid at room temperature.

 Gas: Carbon dioxide (CO₂) is a gas at room temperature.

4. Giant Metallic Structures:


 In these structures, atoms are arranged in a lattice where valence electrons are free to
move throughout the structure, creating a "sea of electrons." This electron mobility is
what gives metals their unique properties.
 Physical Properties of Metals are

 Shiny, malleable (hammered into shape) and ductile(drawn into a


wire),
 Good conductors of heat and electricity,
 Have high melting and boiling points.
 Solids except for mercury

 Example: Iron is a common metallic structure, with a repeating lattice of iron atoms and
a sea of electrons that allows for electrical and thermal conductivity.

Each of these types of structures represents a different way in which atoms, ions, or molecules can be
arranged, leading to unique properties and applications in everyday life.

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