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Chapter 2 Heat

Heat flows spontaneously from an object at higher temperature to one at lower


temperature.
An eighteenth-century model of heat pictured heat flow as movement of a fluid
substance called caloric.
More often used than the calorie is the kilocalorie (kcal), which is 1000 calories. Thus,
1 kcal is the heat needed to raise 1 kg of water by 1 C 0. Often a kilocalorie is called
Calorie (with capital), and it is the unit that the energy value of food is specified
The idea that heat is related to energy was pursued by a number of scientist in the 1800s:

o James Prescott Joule – Joules experiment The falling weight causes the paddle
wheel to turn. The friction between the water and the paddle wheel causes the
temperature of the water to rise slightly. Joule determined that a given
amount of work done was always equivalent to a particular amount of heat
input. Quantitatively, 4.186 J of work was found to be equivalent to 1 calorie
(cal) of heat. This is known as the mechanical of heat: 4.186 J = 1cal and 4.186
kJ = 1kcal
As a result of these and other experiments, scientist interpret heat not as a
substance, and not exactly as a form of energy, rather, heat refers to a transfer of
energy. When heat flows from a hot object to a cooler one, it is energy that is being
transferred from one object to another because of a difference in temperature.

o SI units of Heat (as any form of energy) is Joule


o 1 cal raises 1 g of water by 1 Co, or 1 kcal raises 1kg of water by Co
o Heat – an energy transfer from one place or object to another at a lower temperature
o The sum total of all the energy of all the molecules in an object is called
internal energy.
Distinguishing Temperature, Heat, and Internal Energy
-
Temperature is a measure of the average kinetic energy of individual molecules
-
Internal energy refers to the total energy of all the molecules in the object
-
Heat, refers to a transfer of energy from one object to another
because of a difference in temperature
Specific Heat

o If heat flows into an object, the object’s temperature rises.


o The quantity of heat required to raise the temperature of one gram of a
substance by one Co.
o The Scottish scientist Joseph Black, in the 18th century, noticed that equal
masses of different substances needed different amounts of heat to raise them
through the same temperature interval, and, from this observation, he founded
the concept of specific heat.
o The amount of heat Q required to change the temperature of a given material
is proportional to the mass of the material present and to the temperature
change.
o Q = mc dT
Where c is a quantity characteristics of the material called its
specific heat c= Q/ mdT
o specific heat is in units of J/kg.Co SI unit = kcal/kg .Co
o Specific heat of gas depends very much on how the process of changing its
temperature is carried out. Most commonly, we deal with the specific heat of
gases kept at constant pressure or constant volume.

The exchange of energy, is the basis for a technique known as calorimetry, which is
quantitative measurement of heat exchange. Instrument used is called calorimeter
Important: the calorimeter must be well insulated so that almost no heat is
exchanged with the surroundings

o One important use of calorimeter is in determination of specific heats of


substances. In the technique “method of mixtures”, a sample of a substance
is heated to a high
temperature, which is accurately measured, and then quickly placed in the cool
water of the calorimeter. The heat lost by the sample will be gained by the water and
the calorimeter cup. By measuring the final temperature of the mixture, the
specific heat can be calculated.

Latent Heat
When a material changes phase from solid to liquid, or liquid to gas, a certain amount
of energy is involved in this changes of phase.

o The heat required to change 1.0 kg of a substance from the solid to the liquid
state is called the heat of fusion it is denoted by L F. The heat of fusion of
water is 79.7kcal/kg, in proper SI units 333kJ/kg (=3.33 x105J/kg)
o The heat required to change a substance from the liquid to the vapor phase is
called the heat of vaporization LV. For water it is 539kcal/kg or 2260 kJ/kg
o The heats of vaporization and fusion also refer to the amount of heat released
by a substance when it changes from a gas to a liquid, vice versa. Thus steam
releases 2260 kJ/kg when it changes to water, and water releases 333 kJ/kg
when it becomes ice.
o The heat involved in a change of phase depends not only on the latent heat but
also on the total mass of the substance: Q =mL
Don Mariano Marcos Memorial State University
South La Union Campus
College of Education

Activity: PHASE CHANGE AND LATENT HEAT (Conceptual Problem)


Directions: Answer the following questions below. Your answer must be encoded and
submitted until 5pm today.

Questions:

1. Refer to the illustration of


Phase Diagram for Water,
explain how solid turn into
liquid. What condition/s must
be met for water to undergo
phase change?

- The phase diagram shows the


different phases of water based on
varying pressure and temperature
levels. Based from the diagram, as
temperature rises, as heat energy
is absorb by the ice to above its
melting point which is 0°C at 1
atm, it will start to melt into a
liquid state until all of it turns into
liquid state. The condition that it
undergo is that it has to be
exposed at a rising temperature
and in a constant pressure of one
atmosphere.

2. Is phase change related to Latent heat? Explain why or why not

- Yes, because latent heat involves heat energy that is required for a substance to undergo
phase change. During a phase change, a solid, liquid or gas, they absorbs or releases energy as
heat and this energy results in either breaking or forming of intermolecular bonds between
the molecules of the substance, that causes it to transform in a new state of matter having
different physical properties.

3. How is learning phase change and latent heat beneficial to us?

-Phase change and latent heat is beneficial to us in a way where it helps in understanding the
behavior of matter and how it will change when energy is added or removed. It is helpful in
our everyday activities such as cooking. It allows people to correctly measure the amount of
energy needed for boiling water or melting frozen food, and cooking the food where it will
not get burn or overcooked.

THERMODYNAMICS
SY 2023-2024

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