1.

Few electrons have following quantum numbers,

(i) n = 4, l = 1 (ii) n = 4, l =0

(iii) n = 3, l = 2 (iv) n = 3, l – 1

Arrange them in the order of increasing enrgy from lowest to highest.

(a) (iv) < (ii)<(iii) <(i) (b) (ii)<(iv)<(i)<(iii)

(c) (i)< (iii)< (ii)< (iv) (d) (iii)<(i)< (iv)<(ii)

2. Though the five d – orbitals are degenerate, the first four d – orbitals are similar to each other in shape whereas the ffth d –
orbital is different from others. What is the name of the fifth orbital?

(b) (c) (d)

(a)

3. Fill in the blanks with appropriate words.

The principal quantum number n determines the __(i)__

And __(ii)__ of anorbital. With the increase in value of n, the numberofallowed __(iii)___ increases.
Azimuthalquantum number defines the __(iv)__ of the orbital. The number of subshells in a principal shell is
equal to the value __(v)__

(i) (ii) (iii) (iv) (v)

(a) Size energy orbitals shape n

(b) Size shape orbitals spin n–1

(c) Size energy orbitals shape n- 1

(d) Shape spin orbitals number n

4. Two values of spin quantum numbers i.e., +1/2 and -1/2 represent.
(a) Up and down spin of the electrons respectively

(b) Two quantum mechanic spin states which refer to the orientation of spin of the electron

(c) Clockwise and anti – clockwise spin of the electrons respectively

(d) Anti – clockwise and clockwise spin of the electrons respectively.

5. The number of radial nodes and angular nodes for d – orbital can be represented as
(a) (n -2) radial nodes + 1 angular node = (n -1) total nodes

(b) (n -1) radial nodes + 1 angular node = (n -1)total nodes

(c) (n – 3) radial nodes + 2 angular nodes = (n – l -1) total nodes

(d) (n -3) radial nodes + 2 angular nodes = (n – 1) total nodes

6. Three elements ‘X’, ‘Y’ and ‘Z’ have atomic numbers 18, 19 and 20 respectively. how many electrons are present in the M
shells of these elements?
(a) 8, 9, 10 (b) 8, 10, 13 (c) 8, 8, 8 (d) 8, 9, 12
7. Assuming that a 25 watt bulb emits monochromatic yellow light of wave length 0.57 μ. The rate of emission of quanta per
sec. will be
17 −1
5 . 89×1013 sec−1
(a) (b)7 . 28×10 sec
19 −1
5×1010 sec−1
(c) (d)7 . 18×10 sec

8. If theradius of 2nd Bohr orbit of hydrogen atom is r2. The radius of third Bohr orbit will be
4 9
r 4r r3 9 r2
9 2 (b) 2 (c) 4 (d)
(a)

9. Number of waves made by a Bohr electron in one complete revolution in 3rd orbit is
(a) 2 (b) 3 (c) 4 (d) 1

−1
10. The wave number of first line of Balmer series of hydrogen atom is 15200 cm . What is the wave number of first line of
3+
Balmer series of Li ion.
−1 −1
(a)15200 cm (b) 6080 cm
76000 cm−1 (d)1,36800 cm−1
(c)

11. The Bohr orbit radius for the hydrogen atom (n = 1) is approximately 0.530Å. The radius for the first excited state (n = 2)
orbit is (in Å)
(a) 0.13 (b) 1.06 (c) 4.77 (d) 2.12

12. The wave number of the shortest wavelength transition in Balmer series of atomic hydrogen will be
(a) 4215 Å (b) 1437Å (c) 3942Å (d) 3647Å

13. If the speed of electron in the Bohr's first orbit of hydrogen atom is x, the speed of the electron in the third Bohr's orbit is
(a) x/9 (b) x/3 (c) 3x (d) 9x

14. Of the following transitions in hydrogen atom, the one which gives an absorption line of lowest frequency is
(a) n=1 to n=2 (b)n=3 to n=8
(c)n=2 ton=1 (d)n=8 to n=3

15. The frequency of the line in the emission spectrum of hydrogen when the atoms of the gas contain electrons in the third
energy level are
14 16
(a)1 .268×10 Hz and2 .864×10 Hz
10 12
(b)3 .214×10 Hz and1 .124×10 Hz
12 15
(c)1 .806×10 Hz and6 . 204×10 Hz
14 15
(d)4 .568×10 Hz and2 . 924×10 Hz

−18
16. If the first ionisation energy of hydrogen is 2 .179×10 J per atom, the second ionisation energy of helium per atom is
(b)5.5250 kJ
−18
8 . 716×10 J
(a)
−18 −13
(c)7 . 616×10 J (d)8 . 016×10 J
 −25
17. An electron is moving with a kinetic energy of 4.55 × 10 J. What will be de-Broglie wavelength for this electron
−7
(a) 5.28 × 10 m −7
(b) 7.28 ×10 m
−10 −5
(c) 2 × 10 m (d) 3 × 10 m

18.
The speed of the proton is one hundredth of the speed of light in vacuum. What is the de Broglie wavelength? Assume that
h= 6.626 × 10 −27 erg sec
one mole of protons has a mass equal to one gram,
−3 −3
3.31 × 10 Å (b)1.33 ×10 Å
(a)
−2
3.13 × 10 Å (d) 1.31 × 10 −2 Å
(c)

19. If the total energy of an electron in hydrogen like atom in excited state is –3.4 eV, then the de Broglie wavelength of the
electron is
(a) 6.6  10–10 (b) 3  10–10 (c) 5  109 (d) 9.3  10–12

20. The highest excited state that an unexcited hydrogen atom can reach when they are bombarded with 12.2 eV electron is:
(a) n = 1 (b) n = 2 (c) n = 3 (d) n = 4

21. If 10–17 J of light energy is needed by the interior of human eye to see an object. The photons of green light (  = 550nm)
needed to see the object are.
(a) 27 (b) 28 (c) 29 (d) 30

22. Which orbital has two angular nodal planes

(a)s (b) p (c) d (d) f

23. The wave number of the limiting line in Lyman series of hydrogen is 109678 cm –1. The wave number of the limiting line in
Balmer series of He+ would be -
(a) 54839 cm–1 (b) 219356 cm–1
–1
(c) 109678 cm (d) 438712 cm–1

24. Which of the following is not the characteristic of x-rays ?

(a)The radiation can ionise gases
(b) It causes ZnS to fluoresce
(c) Deflected by electric and magnetic field
(d) Have wavelength shorter than UV rays

25. Which of the following relates to photon both as wave function and as a stream of particles ?
(a)Interference (b) E = mc2 (c) Diffraction (d) E = h

26. The energy of an electron in the Ist orbit of H-atom is— 13.6 eV. The possible energy values of the excited state for electrons
in Bohr orbits of Li2+ ions is/are-
(a) –3.4 eV (b) –30.6 eV
(c) –13.6 eV (d) Both B & C are correct

27. Photoelectric work function of a metal 1 eV. If a light of wavelength 500 Å falls on the metal, the speed of the
photoelectron emitted approximately will be- ( h = 6.625 × 10–34 J s)
1
(a) Equal to velocity light (b) 10 × velocity of light
 1 1
(c) 100 × velocity of light (d) 1000 × velocity of light

28. Which of the following statements is correct ?

(a) (n – 1) d subshell has lower energy than ns subshell
(b) (n – 1) d subshell has higher energy than ns subshell
(c) (n + 1) d subshell has lower energy than nf subshell
(d) nf subshell has lower energy than (n + 2) s subshell

29. In Rutherford's scattering experiment an -particle is projected with K.E. = 4 MeV, minimum distance upto which this -
particle can reach to the nucleus of Cu nucleus- (atomic number of Cu = 29)
(a) 2.08 × 10–14 m (b) 2.08 × 10–15 m
–14
(c) 1.04 × 10 m (d) 1.04 × 10–15 m

30. An electron has velocity x ms–1. For a proton to have the same de-Broglie wavelength, the velocity will be approximately –
1840 x
(a) x (b) 1840 (c) 1840x (d) x

31. The ratio of velocity of the electron in 4th and 5th orbit of Be3+ would be –
(a) 5 : 4 (b) 4 : 5 (c) 25 : 16 (d) 16 : 25

24
and 12 Mg are -
23
32. 11 Na
(a) Isotopes (b) Isobars (c) Isodiapheres (d) Isotones.

33. The mass of a neutron is of the order of -

(a) 10–23 kg (b) 10–24 kg (c)10–26 kg (d)10–27 kg

34. The mass number of a nucleus is -

(a) Always less then its atomic number
(b) Always more than its atomic number
(c) Sometimesless and some times more thanitsatomicnumber
(d) Sometimesequaltoitsatomicnumber.

35. If threshold wavelength (º) for ejection of electron from a metal is 330 nm, then work function for the photoelectric
emission is
(a) 6 × 10–10 J (b) 1.2 × 10–18 J
–19
(c) 3 × 10 J (d) 6 × 10–19 J

36. The momentum of a photon having frequency

1.0 × 1015 s–1 is about
(a) 2.21 × 10–11 kg m s–1 (b) 2.21 × 10–27 kg m s–1
–19 –1
(c) 2.21 × 10 kg m s (d) 6.63 × 10–19 kg m s–1

37. What is the wavelength of the radiation with photon energy which is the mean value of photon energies of radiations with
wavelengths 1 = 4000 Å and 2 = 6000 Å ?
(a) 5000 Å (b) 5200 Å (c) 5600 Å (d) 4800 Å

38. Hydride ion is isoelectronic with -

(a) He+ (b) H+ (c) Be+ (d) He

39. If wavelenght of photon is 2.2 × 10–11 m, h = 6.6 × 10–34Js, then momentum of photon is -
 (a) 3 × 10–23 kg ms–1 (b) 3.33 × 1022 kg ms–1
(c) 1.452 × 10–44 kg ms–1 (d) 6.89 × 1043 kg ms–1

40. The frequency of yellow light having wavelength 600 nm is -

(a) 5.0 × 1014 Hz (b) 2.5 × 107 Hz
7
(c) 5.0 × 10 Hz (d) 2.5 × 1014 Hz

41. The maximum kinetic energy of the photoelectrons is found to be 6.63 × 10 –19 J when the metal is irradiated with a radiation
of frequency 3 × 1015 Hz. The threshold frequency of the metal is
(a) 1 × 1015 Hz (b) 3 × 1015 Hz
(c) 2 × 1016 Hz (d) 2 × 1015 Hz

42. If threshold wavelength (°) for ejection of electron from metal is 330 nm, then work function for the photoelectric emission
is -
(a) 6 × 10–10 J (b) 1.2 × 10–18 J
–19
(c) 3 × 10 J (d) 6 × 10–19 J

43. The numbers of d-electrons retained in Fe2+ (atomic number Fe = 26) ion is
(a) 3 (b) 4 (c) 5 (d) 6

44. Which of the following set of quantum numbers represents the highest energy of an atom ?
1
n = 3, l = 0, m = 0, s = + 2
(a)
1
n = 3, l = 1, m =1, s = + 2
(b)
1
n = 3, l = 2, m = 1, s = + 2
(c)
1
n = 4, l = 0, m = 0, s = + 2
(d)

45. The energy required to break one mole of Cl – Cl bonds in Cl2 is 242 kJ mol–1 . The longest wavelength of light capable of
breaking a single Cl – Cl bond is
(c = 3 × 108 m s–1 and NA = 6.02 × 1023mol–1)
(a) 594 nm (b) 640 nm (c) 700 nm (d) 494 nm

46. A gas absorbs a photon of 355 nm and emits at two wavelengths. If one of the emission is at 680 nm, the other is at :
(a) 1035 nm (b) 325 nm (c) 743 nm (d) 518 nm

47. The frequency of light emitted for the transition n = 4 to n = 2 of He +isequalto the transition in H atom corresponding to
which of the following?
(a) n = 2 to n = 1 (b) n = 3 to n = 2
(c) n = 4 to n = 3 (d) n = 3 to n = 1

48. The electrons identified by quantum numbers n and :

can be placed in order of increasing energy as :
 (a) n = 4, = 1 (b) n = 4, = 0
(c) n = 3, = 2 (d) n = 3, = 1

49. The total spin resulting from a d7 configuration is:

(a) 1 (b) 2 (c) 5/2 (d) 3/2

50. Consider the ground state of Cr atom (Z = 24). The numbers of electrons with the azimuthal quantum numbers, ℓ = 1 and 2
are, respectively :
(a) 16 and 5 (b) 12 and 5 (c) 16 and 4 (d) 12 and 4