SAFETY DATA SHEET

Silicone-free Heat Sink Compound

Section 1. Identification
GHS product identifier : Silicone-free Heat Sink Compound
Other means of : Not available.
identification
Product type : Solid.

Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Supplier's details : Manufacturer:

Techspray
8125 Cobb Center Drive
Kennesaw, GA 30152
Tel: 800-858-4043
1 703-527-3887

Emergency telephone : Chemtrec - 1-800-858-4043

number (with hours of CANTUC (Canadian Transportation): (613) 996-6666
operation) Emergency phone: (800) 858-4043
24/7

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B
substance or mixture
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 100%

GHS label elements

Signal word : Warning
Hazard statements : Causes eye irritation.
Precautionary statements
Prevention : Wear eye or face protection. Wash hands thoroughly after handling.
Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Not applicable.
Disposal : Not applicable.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

CAS number : Not applicable.
Product code : 1978-1, 1978-DP

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Section 3. Composition/information on ingredients

Ingredient name % CAS number
zinc oxide 65 - 70 1314-13-2
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. If irritation persists, get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention if adverse health
effects persist or are severe. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : May cause skin irritation.
Ingestion : May be irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
diarrhea

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
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Section 4. First aid measures

Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : No specific fire or explosion hazard.

from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
halogenated compounds
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate
personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA
filter will reduce dust dispersal. Place spilled material in a designated, labeled waste
container. Dispose of via a licensed waste disposal contractor.
Large spill : Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Avoid dust generation. Do not
dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,
labeled waste container. Dispose of via a licensed waste disposal contractor. Note:
see Section 1 for emergency contact information and Section 13 for waste disposal.

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Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid
contact with eyes, skin and clothing. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Empty
containers retain product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from
including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
incompatibilities (see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
zinc oxide NIOSH REL (United States, 10/2013).
CEIL: 15 mg/m³ Form: Dust
TWA: 5 mg/m³ 10 hours. Form: Dust and
fumes
STEL: 10 mg/m³ 15 minutes. Form: Fume
OSHA PEL (United States, 2/2013).
TWA: 5 mg/m³ 8 hours. Form: Fume
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
OSHA PEL 1989 (United States, 3/1989).
STEL: 10 mg/m³ 15 minutes. Form: Fume
TWA: 5 mg/m³ 8 hours. Form: Fume
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 10 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 4/2014).
STEL: 10 mg/m³ 15 minutes. Form:
Respirable fraction
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.

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Section 8. Exposure controls/personal protection

Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard if
a risk assessment indicates this is necessary. Respirator selection must be based on
known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.

Section 9. Physical and chemical properties

Appearance
Physical state : Solid. [Paste.]
Color : Gray.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : 204°C (399.2°F)
Flash point : Closed cup: 296°C (564.8°F)
Evaporation rate : 0.01 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : 0.013 kPa (0.1 mm Hg) [room temperature]
Vapor density : Not available.
Relative density : Not available.
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.

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Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : No specific data.

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Not available.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
zinc oxide Eyes - Mild irritant Rabbit - 24 hours 500 -
milligrams
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Sensitization
Not available.
Mutagenicity
Not available.

Carcinogenicity
Not available.

Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.

Aspiration hazard
Not available.

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : May cause skin irritation.
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Section 11. Toxicological information

Ingestion : May be irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
diarrhea

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.

General : No known significant effects or critical hazards.

Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
zinc oxide Acute EC50 0.042 mg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata - Exponential growth
phase
Acute LC50 98 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 1.1 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Chronic NOEC 0.017 mg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata - Exponential growth
phase

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Section 12. Ecological information

Persistence and degradability
Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
zinc oxide - 60960 high

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.

Section 14. Transport information

DOT TDG Mexico ADR/RID IMDG IATA
Classification Classification Classification
UN number Not regulated. Not regulated. Not regulated. Not regulated. Not regulated. Not regulated.

UN proper Nonhazardous Nonhazardous Nonhazardous Nonhazardous Nonhazardous Nonhazardous

shipping name
Transport - - - - - -
hazard class(es)

Packing group - - - - - -
Environmental No. No. No. No. No. No.
hazards
Additional - - - - - The
information environmentally
hazardous
substance
mark may
appear if
required by
other
transportation
regulations.

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Section 14. Transport information

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to Annex II of MARPOL
73/78 and the IBC Code

Section 15. Regulatory information

U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Not determined.
Clean Water Act (CWA) 307: zinc oxide

Clean Air Act Section 112 : Not listed

(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
SARA 311/312
Classification : Immediate (acute) health hazard
Composition/information on ingredients
Name % Fire Sudden Reactive Immediate Delayed
hazard release of (acute) (chronic)
pressure health health
hazard hazard
zinc oxide 65 - 70 No. No. No. Yes. No.

SARA 313
Product name CAS number %
Form R - Reporting zinc oxide 1314-13-2 65 - 70
requirements
Supplier notification zinc oxide 1314-13-2 65 - 70

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : The following components are listed: ZINC OXIDE FUME
New York : None of the components are listed.
New Jersey : The following components are listed: ZINC OXIDE
Pennsylvania : The following components are listed: ZINC OXIDE (ZNO)
International regulations

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Section 15. Regulatory information

Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

Montreal Protocol (Annexes A, B, C, E)

Not listed.

Stockholm Convention on Persistent Organic Pollutants

Not listed.
Rotterdam Convention on Prior Inform Consent (PIC)
Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals

Not listed.
International lists
National inventory
Australia : Not determined.
Canada : Not determined.
China : All components are listed or exempted.
Europe : Not determined.
Japan : Not determined.
Malaysia : Not determined.
New Zealand : All components are listed or exempted.
Philippines : Not determined.
Republic of Korea : All components are listed or exempted.
Taiwan : Not determined.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health 1

Flammability 0
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)

0 Flammability
Health 1 0 Instability/Reactivity
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.

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Section 16. Other information

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
History
Date of printing : 5/10/2015.
Date of issue/Date of : 5/10/2015.
revision
Date of previous issue : 3/28/2015.
Version : 1.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

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