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SAMPLE PAPER - III

SUB : CHEMISTRY
CLASS - XI
Time Allowed: 1 hr Maximum Marks : 70
General Instructions:
• All question are compulsory

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• Q 1 to 20 are very short answer objective type and each carries 1 mark each.
• Q 21 to 27 are short answer question and carry 2 marks each.
• Q 28 to 34 are also short answer question and carry 3 marks each.
• Q 35 to 37 are long answer questions and carry 5 marks each.
• There is no overall choice. However internal choice have been provided in some

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questions.
• Use of log tables if necessary. Use of calculators is not allowed.

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1. Which of the following d-orbital has double disc (body shooter shape)
(a) dxy (b) dz2 Ac (c) dx2 – y2 (d) dyz
2. Among the following, the compound that contains, ionic, covalent and Co-
ordinate linkage is
(a) NH4Cl (b) NH3 (c) NaCl (d) CO2
3. Which of the following is a state function
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(a) q (b) w (c) q + w (d) None of these
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4. Which of the following alkali metal ion has highest ionic mobility
(a) Li+ (b) Na+ (c) k+ (d) Cs+
5. The correct order of electron gain enthalpy with negative sign of F, Cl, Br
and I having atomic number 9, 17, 35 and 53 respectively is
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(a) I > Br > Ci > F (b) F > Cl > Br > I

(c) Cl > F > Br > I (d) Br > I > Cl > F
6. Arrange the following carbonations in order of their increasing stability
(CH3)3C+, CH3CH2+, (CH3)2CH+, CH3+
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7. The IUPAC name and symbol of element with Z = 120 is _________.

8. Direction for Question No. 9 to 10 : A statement of assertion (A) followed
by a statement of Reason (R) is given.
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(i) A and R both are correct, and R is correct explanation of A.

(ii) A and R both are correct, but R is not correct explanation of A.
(iii) A is true but R is false.
(iv) A and R both are false.
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 9. Assertion (A) : Enthalpy of graphite is lower than that of diamond.
Reason (R) : Enthalpy of graphite is greater than that of diamond.
10. Assertion (A) : Lower the critical temperature of the gas; more easily can
it be liqufied.
Reason (R) : Critical temperature is the temperature above which a gas
cannot be liquefied depending upon the pressure.

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11. If ten volumes of dihydrogen gas react with five volumes of dioxygen gas,
how much volume of water vapour would be produced?
OR
Calculate the number of atoms in 32.0 u of He.

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12. Why are alkali metals used in photoelectric cells?
OR

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Write electronic configuration of Cr3+ ion. (Atomic No. of Cr = 24)
13. Draw the shape of ClF3 molecule according to VSEPR theory?
14. Write the conjugate acid and conjugate base of H2O.
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Write the relation between solubility and solubility product of Cr2(SO4)3.
15. Consider the given standard reduction potentials of following elements A,
B, C & D and arrange them in order of their increasing reducing power.
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A = –3.71V, B = –0.76V, C = +0.34 V, D = +0.80 V
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OR
16. Write the cause of temporary and permanent hardness of water.
17. Why do magnesium and beryllium not import colour to the flame in the
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flame test?
18. Write IUPAC name of CH3 – CO – CH2 – CHO.
19. Out of Cis-But-2-ene and Trans-but-2-ene which has greater boiling point
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and why?
20. Define Biochemical oxygen demand.
21. (i) What is the lowest value of n that allows 'g' orbitals to exist?
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(ii) Why 4s orbital is filled before 3d?

OR
Calculate wave number for the longest wavelength transition in the Balmer
Series of hydrogen atom.

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 22. Explain why?
(i) ∆iH1 of 'N' is more than that of 'O'.
(ii) A cation is smaller than parent atom.
23. Balance the following redox reaction in acidic medium by ion electron
method.
Cr2O72–(aq.) + SO2(g) → Cr3+(aq.) + SO42–(aq.)

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24. Write chemical reactions to justify that H2O2 can act as an oxidising as well
as reducing agent.
OR
(i) What is water gast shift reaction?

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(ii) What do you mean by 20 vol. H2O2?

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25. In sulphur estimate, 0.157 g of an organic cmpound gave 0.4813 g of
barium sulphate. What is the percentage of sulphur in the compound?
26. Write chemical equations to covert:
(i) Ethyne to Ethanal
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(ii) Benzene to m-Nitrotoluene
27. Define smog. How is classical smog different from photochemical smog?
OR
Explain the following terms:
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(a) Green house effect
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(b) Green chemistry

28. Calcium carbonate reacts with aqueous HCl according to the reaction:
CaCO3(s) + 2HCl(aq.) → CaCl2(aq.) + CO2(g) + H2O(l)
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What mass of CaCO3 is required to react completely with 25 mL of 0.75

M HCl?
29. (i) State Hund's rule of maximum multiplicity of electrons.
(ii) The mass of an electron is 9.1 × 10–31 kg. If its K.E. 3.0 × 10–25 J,
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calculate its wavelength.

30. N2 is diamagnetic while O2 is paramagnetic. Explain on the basis of
molecular orbital theory.
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OR
Explain the structure of PCl5 according to hybridization. Why all P – Cl
bonds.

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 31. What will be the pressure exerted by a mixture of 3.2 g of methane and
4.4 g of carbon dioxide contained in 9 dm2 flask at 27°C.
OR
Calculate the compressibility factor for CO2, if one mole of it occupies 0.4
litre at 300K and 40 atm. Comment on the result.
32. The combustion of 1 mol of benzene takes place at 298K. After combustion

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CO2 and H2O are formed and 3267 kJ mol–1, ∆fHO(H2O) = –393 kJ mol–1.
OR
For the reaction : 2A(g) + B(g) → 2D(g), ∆UO = –10.5 kJ and ∆S° = –44.1
J K–1. Calculate ∆G° for the reaction, and predict whether the reaction will
occur spontaneously.

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33. Complete the following reaction equations:

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(i) Li(NO3)2 → ∆

(ii) BeCl2 + LiAlH4 →∆

∆
(iii) Ca(OH)2 + Cl2 →
34. (i)
and why?
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Out of NO2 – CH2 – O and CH3 – CH2 – O– which is more stable

(ii) Why is it necessary to prepare Lassaigne extract for detection of N, S

and halogens?
(iii) Define the term hyperconjugation.
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35. (i) State Le Chatelier's principle.
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(ii) Calculate the pH of 10–8 M HCl.

(iii) A sample of HI (g) is placed in flask at a pressure of 0.2 atm. At
equalibrium the partial pressure of HI (g) is 0.04 atm. What is the Kp
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for given equilibrium?

2HI (g)  H2(g) + I2(g)
OR
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(i) Define common ion effect.

(ii) Write the relationship between Kp and Kc for the reaction:
N2(g) + 3H2(g)  2NH3(g)
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(iii) Equal volume of 0.002 M solutions of sodium iodate and cupric

chlorate are mixed together. Will it lead to precipitation of copper
iodate? (For cupric iodate Ksp = 7.4 × 10–8)

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 36. (i) Draw the structure of Diborane indicating electron precise and
electron deficient bonds.
(ii) Give reason for the following :
(a) PbCl4 is powerful oxidising agent.
(b) Fullerenes are the purest allotropes of carbon.
(c) N – N bond dissociation enthalpy is less than P – P bond

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dissociation enthalpy.
OR
(i) What happens when (give chemical equation) :
(a) Borax is heated strongly.

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(b) BF3 is treated with LiH.
(ii) Give reason for the following :

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(a) NaBiO3 is good oxidising agent.
(b) Graphite acts as a good lubricant.
(c) Boric and acid is a weak acid.

37. (i)
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Propanal and pentan-3-one are the ozonolysis product of an alkene.
What is the structural formula and IUPAC name of alkene?
(ii) Give the main products of the reactions:
Anhydrous AlCl3
(a) C6H6 + CH3Cl
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Dry ether
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(b) CH3Cl + Na
(c) CH3 – CHCl – CH2 – CH3 + KOH(alc.) →
OR
(i) Give chemical euqation for each of the following :
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(a) Decarboxylation
(b) Friedel Craft acetylation
(ii) Addition of HBr to propene yields 2-Bromopropane, while
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in the presence of benzoyl peroxide, the same reaction yields

1-Bromopropane. Explain and give mechanism.
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