VITEEE

SOLVED PAPER 2017

(memory based)
GENERAL INSTRUCTIONS
• This question paper contains total 125 questions divided into four parts :
Part I : Physics Q. No - 1 to 40
Part II : Chemistry Q. No - 41 to 80
Part III : Mathematics Q. No - 81 to 120
Part IV : English Q. No - 121 to 125
• All questions are multiple choice questions with four options, only one of them is correct.
• For each correct response, the candidate will get 1 mark.
• There is no negative marking for the wrong answer.
• The test is of 2½ hours duration.

PART - I (PHYSICS) 4. Two bodies A and B having masses in the ratio

of 3 : 1 possess the same kinetic energy. The
1. A 5000 kg rocket is set for vertical firing. The ratio of linear momentum of B to A is
exhaust speed is 800 m/s. To give an initial (a) 1 : 3 (b) 3 : 1
upward acceleration of 20 m/s2, the amount of
(c) 1: 3 (d) 3 :1
gas ejected per second to supply the needed
thrust will be (Take g = 10 m/s2) 5. In which sequence the radioactive radiations are
emitted in the following nuclear reaction?
(a) 127.5 kg/s (b) 137.5 kg/s
A ¾¾
® A ¾¾
® A–4
(c) 155.5 kg/s (d) 187.5 kg/s ZX Z + 1Y Z–1K
2. The power dissipated in the circuit shown in the
figure is 30 Watts. The value of R is ¾¾ ®Z– 1 KA–4
(a) g, a, b (b) a, b, g
R
(c) b, g, a (d) b, a, g
6. Which of the following does not support the
wave nature of light?
5W (a) Interference (b) Diffraction
(c) Polarisation
10V
(d) Photoelectric effect
7. Six identical conducting rods are joined as
(a) 20 W (b) 15 W shown in figure. Points A and D are maintained
(c) 10 W (d) 30 W at 200°C and 20°C respectively. The temperature
3. If the kinetic energy of a moving particle is E, of junction B will be
then the de-Broglie wavelength is
2mE
(a) l = h 2mE (b) l =
h
h hE A B C D
(c) l= (d) l =
2mE 2mE
 (a) 120°C (b) 100°C 13. Light of wavelength 500 nm is incident on a metal
(c) 140°C (d) 80°C with work function 2.28 eV. The de Broglie
8. A hydrogen atom is in ground state. Then to get wavelength of the emitted electron is:
six lines in emission spectrum, wavelength of (a) < 2.8 × 10-9 m (b) ³ 2.8 × 10-9 m
incident radiation should be (c) £ 2.8 × 10-12 m (d) < 2.8 × 10-10 m
(a) 800 Å (b) 825 Å 14. Kerosene oil rises up in a wick of a lantern
(c) 975 Å (d) 1025 Å because of
9. A conducting circular loop of radius r carries a
(a) diffusion of the oil through the wick
constant current i. It is placed in a uniform
r r (b) capillary action
magnetic field B0 such that B0 is perpendicular (c) buoyant force of air
to the plane of the loop. The magnetic force (d) the gravitational pull of the wick
acting on the loop is 15. The current in a coil of L = 40 mH is to be
(a) ir B0 (b) 2p ir B0 increased uniformly from 1A to 11A in 4 milli sec.
(c) zero (d) p ir B0 The induced e.m.f. will be
10. A vessel of depth 2d cm is half filled with a liquid (a) 100 V (b) 0.4 V
of refractive index m1 and the upper half with a (c) 440 V (d) 40 V
liquid of refractive index m2. The apparent depth
16. An alternating voltage of 220 V, 50 Hz frequency
of the vessel seen perpendicularly is
is applied across a capacitor of capacitance 2
æ m1 m 2 ö æ 1 1 ö µF. The impedence of the circuit is
(a) ç ÷d (b) çç m + m ÷÷ d
çm +m ÷ p 1000
è 1 2 ø è 1 2ø
(a) (b)
5000 p
æ 1 1 ö æ 1 ö
ç ÷ ç ÷
ç m + m ÷ 2d (d) ç m m ÷ 2d
(c) 5000
è 1 2ø è 1 2ø (c) 500 p (d)
p
11. A smooth sphere of mass M moving with 17. The combination of gates shown below yields
velocity u directly collides elastically with
another sphere of mass m at rest. After collision,
their final velocities are V and v respectively. A
The value of v is
2uM 2um X
(a) (b)
m M
2u 2u B
(c) (d)
m M
1+ 1+
M m
(a) OR gate (b) NOT gate
12. Two capacitors C1 and C2 in a circuit are joined (c) XOR gate (d) NAND gate
as shown in figure. The potentials of points A
18. A hollow insulated conduction sphere is given
and B are V1 and V2 respectively. Then the
a positive charge of 10 mC. What will be the
potential of point D will be
electric field at the centre of the sphere if its
A B radius is 2 metres?
V1 D V2 (a) Zero (b) 5 mCm–2
C1 C2 –2
(c) 20 mCm (d) 8 mCm–2
(V1 + V2 ) C 2 V1 + C1V2 19. Two mercury drops (each of radius r) merge to
(a) (b) form a bigger drop. The surface energy of the
2 C1 + C 2
bigger drop, if T is the surface tension, is
C1V1 + C 2 V2
(c) (d) C 2 V1 + C1V2 (a) 25/3 pr2T (b) 4 pr2T
C1 + C 2 C1 + C 2 (c) 2 pr T
2 (d) 28/3 pr2T
20. Resistances 1 W, 2 W and 3 W are connected to 25. A milli voltmeter of 25 milli volt range is to be
form a triangle. If a 1.5 V cell of negligible internal converted into an ammeter of 25 ampere range.
resistance is connected across the 3 W resistor, The value (in ohm) of necessary shunt will be
the current flowing through this resistor will be (a) 0.001 (b) 0.01
(a) 0.25 A (b) 0.5 A (c) 1 (d) 0.05
(c) 1.0 A (d) 1.5 A 26. In young’s double-slit experiment, the intensity
21. A current carrying coil is subjected to a uniform of light at a point on the screen where the path
magnetic field. The coil will orient so that its difference is l is I, l being the wavelength of
plane becomes light used. The intensity at a point where the
l
(a) inclined at 45° to the magnetic field path difference is will be
(b) inclined at any arbitrary angle to the 4
I I
magnetic field (a) (b)
4 2
(c) parallel to the magnetic field
(c) I (d) zero
(d) perpendicular to the magnetic field
27. Which of the following is a self adjusting force?
22. The value of tan (90° – q) in the graph gives (a) Static friction (b) Limiting friction
(c) Dynamic friction (d) Sliding friction
28. Which of the following are not electromagnetic
waves?
(a) Cosmic rays (b) Gamma rays
(c) b-rays (d) X-rays
Strain

29. Graph of specific heat at constant volume for a

monatomic gas is
q
Y Y
Stress
3R
(a) Young's modulus of elasticity (a) cv (b) cv
(b) compressibility X
O O X
(c) shear strain T T
(d) tensile strength Y 3 Y
—R
23. An electron makes a transition from an excited 2
state to the ground state of a hydrogen - like (c) cv (d) cv
atom. Then O X O X
T T
(a) kinetic energy decreases, potential energy 30. A charge +q is at a distance L/2 above a square
increases but total energy remains same of side L. Then what is the flux linked with the
(b) kinetic energy and total energy decrease surface?
but potential energy increases q 2q
(c) its kinetic energy increases but potential (a) 4e 0 (b) 3e
0
energy and total energy decrease
(d) kinetic energy, potential energy and total q 6q
(c) 6e 0 (d) e
energy decrease 0
24. An A.C. source is connected to a resistive circuit. 31. The potential energy of a system increases if
Which of the following is true? work is done
(a) Current leads ahead of voltage in phase (a) upon the system by a non conservative
(b) Current lags behind voltage in phase force
(b) by the system against a conservative force
(c) Current and voltage are in same phase
(c) by the system against a non conservative
(d) Any of the above may be true depending force
upon the value of resistance. (d) upon the system by a conservative force
32. Two capacitors when connected in series have 39. Transfer characteristics [output voltage (V0) vs
a capacitance of 3 mF, and when connected in input voltage (Vi)] for a base biased transistor in
parallel have a capacitance of 16 mF. Their CE configuration is as shown in the figure. For
individual capacities are using transistor as a switch, it is used
(a) 1 mF, 2 mF (b) 6 mF, 2 mF
V0 I II
(c) 12 mF, 4 mF (d) 3 mF, 16 mF III
33. Resonance frequency of LCR series a.c. circuit
is f0. Now the capacitance is made 4 times, then
the new resonance frequency will become
(a) f0/4 (b) 2f0 Vi
(c) f0 (d) f0/2.
34. If the light is polarised by reflection, then the (a) in region (III)
(b) both in region (I) and (III)
angle between reflected and refracted light is (c) in region (II)
(a) 180º (b) 90º (d) in region (I)
(c) 45º (d) 36º 40. A bar magnet of magnetic moment M, is placed in
35. The velocity of efflux of a liquid through an a magnetic field of induction B. The torque exerted
orifice in the bottom of the tank does not depend on it is
r r r r
upon (a) M . B (b) - M . B
(a) size of orifice r r r r
(b) height of liquid (c) M ´ B (d) - B. M
(c) acceleration due to gravity
PART - II (CHEMISTRY)
(d) density of liquid
36. On a smooth plane surface (figure) two block A 41. Schottky defect in crystals is observed when
and B are accelerated up by applying a force 15 (a) unequal number of cations and anions are
missing from the lattice
N on A. If mass of B is twice that of A, the force
(b) equal number of cations and anions are
on B is
missing from the lattice
(c) an ion leaves its normal site and occupies an
15 N B interstitial site
A
(d) density of the crystal is increased
42. The cyclobutyl methylamine with nitrous acid
(a) 30 N (b) 15 N gives
(c) 10 N (d) 5 N CH2 OH
37. A potentiometer wire, 10 m long, has a resistance (a) (b)
of 40W. It is connected in series with a resistance
box and a 2 V storage cell. If the potential gradient (c) (d) All of these
along the wire 0.1 m is V/cm, the resistance
unplugged in the box is 43. The exothermic formation of CIF3 is represented
(a) 260 W (b) 760 W by the equation :
CI 2(g ) + 3F2(g ) 2ClF3 (g ) ; Δ H = – 329 kJ
(c) 960 W (d) 1060 W
Which of the following will increase the quantity
38. A prism has a refracting angle of 60º. When
of CIF3 in an equilibrium mixture of
placed in the position of minimum deviation, it
produces a deviation of 30º. The angle of CI 2 , F2 and CIF3 ?
incidence is (a) Adding F2
(a) 30º (b) 45º (b) Increasing the volume of the container
(c) Removing Cl2
(c) 15º (d) 60º
(d) Increasing the temperature
44. For the reaction 47. What is Z in the following sequence of reactions?
2NO2(g) 2 NO(g) + O2(g) , Zn
Phenol¾¾®X¾¾ ¾
CH Cl
3¾®Y¾¾ ¾¾® Z Alkaline
dust Anhyd. AlCl3 KMnO 4
( K c = 1.8 ´ 10 -6 at 184°C ) (R = 0.0831 kJ/ (mol. K)
(a) Benzene (b) Toluene
When K p and K c are compared at 184°C, it is (c) Benzaldehyde (d) Benzoic acid
found that 48. Which of the following oxy-acids has the
(a) Whether K p is greater than, less than or maximum number of hydrogens directly attached
to phosphorus?
equal to K c depends upon the total gas
(a) H4P2O7 (b) H3PO2
pressure
(c) H3PO3 (d) H3PO4
(b) K p = K c 49. The number of geometrical isomers of
(c) K p is less than K c CH3CH=CH–CH=CH–CH=CHCl is
(a) 2 (b) 4
(d) K p is greater than K c
(c) 6 (d) 8
CH3 50. If ‘a’ stands for the edge length of the cubic
systems : simple cubic, body centred cubic and
45. (CH3 CO)2 O
A
Br2 /CH3COOH
B face centred cubic, then the ratio of radii of the
spheres in these systems will be respectively,
+
H /H2 O
X 1 3 1
NH2 (a) a: a: a
What is X? 2 4 2 2
CH3 CH3 1 1
(b) a : 3a : a
Br 2 2
(a) (b)
1 3 3
Br (c) a: a: a
2 2 2
NH2 NH2
(d) 1a : 3a : 2a
CH3 CH3 51. For a first order reaction A®P, the temperature
COCH3 (T) dependent rate constant (k) was found to
(c) (d) 1
COCH3 follow the equation log k = – (2000) + 6.0 . The
T
NH2 NH2 pre-exponential factor A and the activation energy
46. A compound MpXq has cubic close packing (ccp) Ea, respectively, are
arrangement of X. Its unit cell structure is shown (a) 1.0 × 106 s–1 and 9.2 kJ mol–1
below. The empirical formula of the compound is (b) 6.0 s–1 and 16.6 kJ mol–1
(c) 1.0 × 106 s–1 and 16.6 kJ mol–1
(d) 1.0 × 106 s–1 and 38.3 kJ mol–1
52. 1-Propanol and 2-propanol can be distinguished
M by
X (a) oxidation with alkaline KMnO4 followed by
reaction with Fehling solution
(b) oxidation with acidic dichromate followed by
reaction with Fehling solution
(c) oxidation by heating with copper followed
by reaction with Fehling solution
(a) MX (b) MX2 (d) oxidation with concentrated H2SO4 followed
(c) M2X (d) M5 X14 by reaction with Fehling solution
53. Which group contains coloured ions out of (a) 750 K (b) 1000 K
1. Cu 2+ 2. Ti 4+ (c) 1250 K (d) 500 K
58. An organic compound (A) on reduction gives
3. Co 2+ 4. Fe 2 + compound (B). (B) on treatment with CHCl3 and
(a) 1, 2, 3, 4 (b) 1, 3, 4 alcoholic KOH gives (C). (C) on catalytic
(c) 2, 3 (d) 1, 2 reduction gives N-methylaniline. The compound
54. The half life period of a first order chemical A is
reaction is 6.93 minutes. The time required for the
completion of 99% of the chemical reaction will (a) Methylamine (b) Nitromethane
be (log 2 = 0.301) (c) Aniline (d) Nitrobenzene
(a) 23.03 minutes (b) 46.06 minutes
59. The standard reduction potential for Cu 2 + /Cu
(c) 460.6 minutes (d) 230.03 minutes
55. A mixture of benzaldehyde and formaldehyde on is + 0.34. Calculate the reduction potential at pH
heating with aqueous NaOH solution gives = 14 for the above couple. (Ksp Cu (OH ) 2
(a) benzyl alcohol and sodium formate
= 1 × 10 -19 )
(b) sodium benzoate and methyl alcohol
(c) sodium benzoate and sodium formate (a) – 0.22 V (b) + 0.22 V
(d) benzyl alcohol and methyl alcohol (c) – 0.44 V (d) + 0.44 V
56. In the following reaction sequence, the correct 60. A substance C4H10O yields on oxidation a
structures of E, F and G are compound, C4H8O which gives an oxime and a
O O positive iodoform test. The original substance
on treatment with conc. H2SO4 gives C4H8. The
structure of the compound is
Ph * OH (a) CH3CH2CH2CH2OH
(b) CH3CHOHCH2CH3
Heat I
¾¾¾
®[E] ¾¾¾®
2
NaOH
[F] + [G] (c) (CH3)3COH
[* implies 13C labelled carbon) (d) CH3CH2–O–CH2CH3
O O 61. The emf of a particular voltaic cell with the cell
(a) E= * F= * – + reaction Hg 22 + + H 2 2Hg + 2H +
CH3 O Na G = CHI3
Ph Ph
is 0.65 V. The maximum electrical work of this cell
O O
when 0.5 g of H 2 is consumed.
(b) E= F= * – +
* O Na G = CHI3
Ph CH3 Ph (a) – 3.12 × 10 4 J (b) –1.25´105 J
O O
(c) 25.0 ´ 10 6 J (d) None
(c) E= F=
– + *
* O Na G = CHI3 62. The number of aldol reaction(s) that occurs in
Ph CH3 Ph
the given transformation is :
O O
CH3CHO + 4HCHO
(d) E= F=
– + *
* O Na G = CH3I OH
Ph CH3 Ph OH
conc. aq. NaOH
¾¾¾¾¾¾¾
®
57. Standard entropies of X2 , Y2 and XY3 are 60,
30 and 50 JK–1mol–1 respectively. For the reaction HO
OH
1 3
X 2 + Y2 ƒ XY3 , DH = – 30 kJ to be at (a) 1 (b) 2
2 2 (c) 3 (d) 4
equilibrium, the temperature should be:
63. Which of the following is not intermediate in the of a quantum of light with frequency of 8 × 1015
acid catalysed reaction of benzaldehyde with 2 s –1 ?
equivalent of methanol to give acetal ? (a) 5 × 10–18 (b) 4 × 101
7
(c) 3 × 10 (d) 2 × 10–25
OCH3 + OH 2 68. The number of stereoisomers possible for a
HO H HO H compound of the molecular formula
(a) (b) CH3 – CH = CH – CH(OH) – Me is:
(b) 2 (c) 4
(d) 6 (d) 3
+ 69. The optically active tartaric acid is named as
Å
H - O- CH 3
H - C = O- CH 3
D - (+) - tartaric acid because it has a positive
HO H (a) optical rotation and is drived from D - glucose
(c) (d) (b) pH in organic solvent
(c) optical rotation and is derived from D - (+) -
64. Iron crystallizes in several modifications. At about glyceraldehyde
911°C, the bcc ' a ' form undergoes a trasition to (d) optical r otation when substituted by
fcc ' g ' form. If the distance between the two deuterium
nearest neighbours is the same in the two forms 70. Consider the reaction : N 2 + 3H 2 ® 2 NH 3
at the transition temperature, the ratio of the
carried out at constant temperature and pressure.
density of iron in fcc form (r2 ) to that of iron of
If DH and DU are the enthalpy and internal
bcc form (r1 ) at the transition temperature energy changes for the reaction, which of the
r1 following expressions is true ?
(a) = 0.918 (b) r1 = 0.718
r2 r2 (a) DH > DU (b) DH < DU
(c) DH = DU (d) DH = 0
r r
(c) 1 = 0.518 (d) 1 = 0.318 71. What is D in the following sequence of reactions ?
r2 r2
NaBH HBr
O¾¾ ¾¾4® ( i) Mg, Et 2O
A¾¾¾® B¾¾¾ ¾¾ ¾®
65. The half life of the first order reaction CH OH
3 ( ii ) H 2C = O
( iii ) H3O +
CH 3 .CHO ( g ) ¾
¾® CH 4 ( g ) + CO (g )
PCC
C ¾¾¾® D
If initial pressure of CH 3CHO (g) is 80 mm Hg CH 2 Cl 2

and the total pressure at the end of 20 minutes is CHO COOH

(a) (b)
120 mm Hg
(a) 80 min (b) 120 min OH CH 3
(c) 20 min (d) 40 min (c) (d)
CHO OH
66. A compound is soluble in conc. H2SO4. It does 72. Knowing that the chemistry of lanthanoids(Ln)
not decolourise bromine in carbon tetrachloride is dominated by its + 3 oxidation state, which of
but is oxidised by chromic anhydride in aqueous the following statements is incorrect?
sulphuric acid within two seconds, turning (a) The ionic size of Ln (III) decrease in general
orange solution to blue, green and then opaque. with increasing atomic number
The original compound is (b) Ln (III) compounds are generally colourless.
(a) a primary alcohol (b) a tertiary alcohol (c) Ln (III) hydroxide are mainly basic in
(c) an alkane (d) an ether character.
67. The values of Planck's constant is 6.63 × 10–34 Js. (d) Because of the large size of the Ln (III) ions
The velocity of light is 3.0 × 108 m s–1. Which the bonding in its compounds is
value is closest to the wavelength in nanometres predominantly ionic in character.
73. What is the R and S configuration for each stereogenic 77. Which of the following has maximum number of
centre in this sugar from top to bottom ? lone pairs associated with Xe ?
O H (a) XeF4 (b) XeF6
(c) XeF2 (d) XeO3
H OH
HO H 78. Which one of the following statements is not
H OH true regarding (+) Lactose ?
CH 2 OH (a) On hydrolysis (+) Lactose gives equal
(a) R, R, S (b) R, S, S amount of D(+) glucose and D(+) galactose.
(c) R, S, R (d) S, S, R
(b) (+) Lactose is a b-glycoside formed by the
74. Saponification of coconut oil yields glycerol and
(a) palmitic acid (b) sodium palmitate union of a molecule of D(+) glucose and a
(c) oleic acid (d) stearic acid molecule of D(+) galactose.
75. A certain reaction is non spontaneous at 298K. (c) (+) Lactose is a reducing sugar and does not
The entropy change during the reaction is 121 exhibit mutarotation.
J K -1 . Is the reaction is endothermic or (d) (+) Lactose, C12 H22 O11 contains 8-OH
groups.
exothermic ? The minimum value of DH for the 79. If one strand of DNA has the sequence
reaction is
ATGCTTGA, the sequence in the complimentary
(a) endothermic, DH = 36.06 kJ
strand would be
(b) exothermic, DH = – 36.06 kJ
(a) TACGAACT (b) TCCGAACT
(c) endothermic, DH = 60.12 kJ
(c) TACGTACT (d) TACGTAGT
(d) exothermic, DH = – 60.12 kJ 80. The starting reagents needed to make the azo
76. p -cresol reacts with chloroform in alkaline
compound shown below
medium to give the compound A which adds
hydrogen cyanide to form, the compound B. The CH 3CH 2 N=N OH
latter on acidic hydrolysis gives chiral carboxylic
acid. The structure of the carboxylic acid is NH 2

CH 3
(a) + ethylamine
(a)
CH 2 COOH OH
OH C2 H5 OH
CH 3
CH 2 COOH (b) +
(b)
NH 2
OH
NH 2 NH 2
CH 3
(c) +
(c)
CH(OH)COOH
OH C 2 H5
OH
CH 3 NH 2 OH
CH(OH)COOH
(d) (d) +

OH C 2 H5
 87. The acceleration of a sphere falling through a
PART - III (MATHEMATICS)
liquid is (30 – 3v) cm/s2 where v is its speed in cm/
s. The maximum possible velocity of the sphere
81. sin–1(sin 5) > x2 – 4x holds if
and the time when it is achieved are
(a) x = 2 – 9 – 2p (a) 10 cm/s after 10 second
(b) x = 2 + 9 – 2p (b) 10 cm/s instantly
(c) 10 cm/s, will never be achieved
(c) x > 2 + 9 – 2p (d) 30 cm/s, after 30 second
(d) x Î (2 – 9 – 2 p , 2 + 9 – 2 p ) 88. A straight line parallel to the line 2x – y + 5 = 0 is
82. A value of c for which conclusion of Mean Value also a tangent to the curve y2 = 4x + 5. Then the
Theorem holds for the function f (x) = loge x on point of contact is
the interval [1, 3] is (a) (2, l) (b) ( –1, 1)
(a) log3 e (b) loge3
(c) (1, 3) (d) (3, 4)
1
(c) 2 log3e (d) log3e p /2
2 sin x
83. Negation of the proposition : If we control
89. Value of ò sin x + cos x
dx is
0
population growth, we prosper
(a) If we do not control population growth, we
p -p
prosper (a) (b)
(b) If we control population growth, we do not 2 2
prosper
p
(c) We control population but we do not (c) (d) None of these
prosper 4
(d) We do not control population, but we
1
prosper 90. The range of the function f (x) = is
2 - cos3x
84. The equation z z + (2 - 3i) z + (2 + 3i) z + 4 = 0
represents a circle of radius (a) (-2, ¥) (b) [-2,3]
(a) 2 (b) 3
(c) 4 (d) 6 é1 ù æ1 ö
(c) êë 3 ,1úû (d) ç 2 ,1÷
85. The function f(x) = sin x – kx – c, where k and è ø
c are constants, decreases always when 1
(a) k > 1 (b) k ³ 1 91. The area bounded by y –1 = |x|, y = 0 and |x| =
2
(c) k < 1 (d) k £ 1 will be :
1 1 3 3 3
86. Equation = + cos q represents (a) (b)
r 8 8 4 2
(a) A rectangular hyperbola
(b) A hyperbola 5
(c) (d) None of these
(c) An ellipse 4
(d) A parabola
92. The value of x obtained from the equation 96. Let A be the centre of the circle x2 + y2 – 2x–4y –
20 = 0, and B( 1,7) and D(4,–2) are points on the
x+a b g circle then, if tangents be drawn at B and D,
g x +b a =0 which meet at C, then area of quadrilateral ABCD
will be
a b x+g is -
(a) 150 (b) 75
(a) 0 and -(a + b + g ) (c) 75/2 (d) None of these
1
(b) 0 and a + b + g 97. ò0 [f ( x)g"( x ) - f " (x ) g (x )] dx is equal to :
(c) 1 and (a - b - g)
[Given f(0) = g(0) = 0]
2 2 2 (a) f(1) g(1) – f(1)g’(1)
(d) 0 and a + b + g
(b) f(1) g’(1) + f’(1)g(1)
93. The solution of the differential equation (c) f(1) g’(1) – f’(1)g(1)
dy y (d) none of these
log x + = sin 2x is
dx x 7-i
98. If z = then z14 =
1 3 - 4i
(a) y log | x |= C - cos x (a) 27 (b) 27 i
2
1 (c) 214 i (d) - 27 i
(b) y log | x |= C + cos 2x
2 99. The difference between greatest and least value
1 é 3p ù
(c) y log | x |= C - cos 2x of f (x) = 2 sin x + sin 2x, x Î ê0, ú is –
2 ë 2û
1
(d) xylog | x |= C - cos 2x 3 3 3 3
2 (a) (b) -2
2 2
æ x2 xö
94. lim ç - ÷= 3 3
x ®¥ è 3x - 2 3 ÷ø
ç (c) +2 (d) None of these
2
1 2 100. A and B are two independent witnesses (i.e. there
(a) (b)
3 3 is no collision between them) in a case. The
-2 2 probability that A will speak the truth is x and
(c) (d) the probability that B will speak the truth is y. A
3 9
r r r r r r and B agree in a certain statement. The
95. If ((a ´ b ) ´ (c ´ d )).( a ´ d ) = 0 , then which of probability that the statement is true is
the following is always true ?
r r x–y xy
(a) ar, b , cr, d are necessarily coplanar (a) (b)
x+y 1 + x + y + xy
r r
(b) either a or d must lie in the plane of
r r x–y xy
b and c (c) (d)
1 – x – y + 2 xy 1 – x – y + 2 xy
r r
(c) either b or c must lie in the plane of
101. A and B are events such that P(A È B)=3/4,
r r
a and d P(A Ç B)=1/4, P( A ) =2/3 then P ( A Ç B) is
r r (a) 5/12 (b) 3/8
(d) either a or b must lie in the plane of
r r (c) 5/8 (d) 1/4
c and d
102. The line which passes through the origin and
intersect the two lines X 1 2 3 4 5 6 7 8
p(X) 0.15 0.23 0.12 0.10 0.20 0.08 0.07 0.05
x - 1 y + 3 z - 5 x - 4 y + 3 z - 14
= = , = = , is
2 4 3 2 3 4 For the events E = {X is a prime number} and
x y z x y z F = {X < 4}, then P(E È F) is
(a) = = (b) = =
1 -3 5 -1 3 5 (a) 0.50 (b) 0.77
x y z x y z (c) 0.35 (d) 0.87
(c) = = (d) = =
1 3 -5 1 4 -5 1 1 7
108. The value of tan -1 + tan -1 + tan -1 is
p/4
2 3 8
103. If u n = ò 0 tan n q dq then un + un–2 is :
7
(a) tan -1 (b) cot -1 15
8
1 1
(a) (b) 15
n -1 n +1 (c) tan -1 15 (d) tan -1
24
1 1 109. The parabola having its focus at (3, 2) and
(c) (d)
2n - 1 2n + 1 directrix along the y-axis has its vertex at
104. Ten different letters of an alphabet are given,
æ3 ö
words with five letters are formed from these (a) (2, 2) (b) ç , 2÷
è2 ø
given letters. Then the number of words which
have at least one letter repeated is
æ1 ö æ2 ö
(a) 69760 (b) 30240 (c) ç , 2÷ (d) ç , 2÷
è2 ø è3 ø
(c) 99784 (d) None of these
105. The area bounded by f (x) = x2, 0 £ x £ 1, é -1 2 5 ù
g(x) = - x + 2,1£ x £ 2 and x - axis is 110. The rank of the matrix êê 2 -4 a - 4ú is
ú
ëê 1 -2 a + 1ûú
3 4
(a) (b) (a) 1 if a = 6 (b) 2 if a = 1
2 3
(c) 3 if a = 2 (d) 1 if a = 4
8
(c) (d) None of these
3 cos x 1 0
111. If f (x ) = 1 2 cos x 1 , then
x y
106. The condition that the line + = 1 be a 0 1 2 cos x
p q
normal to the parabola y2 = 4ax is] p/2

(a) 3
p = 2ap + aq2 2 (b) 3 2
p = 2aq + ap 2
ò f (x)dx is equal to
0
(c) q 3 = 2ap 2 + aq 2 (d) None of these
1 1
107. A random variable X has the probability (a) (b) –
4 3
distribution
1
(c) (d) 1
2
112. The distance of the point (1, –2, 3) from the plane 117. The volume V and depth x of water in a vessel
x - y + z = 5 measured parallel to the line 2
are connected by the relation V = 5x – x and
x y z -1 6
= = is
2 3 -6 the volume of water is increasing , at the rate of
5 cm3/sec, when x = 2 cm. The rate at which the
(a) 1 (b) 2
depth of water is increasing, is
(c) 4 (d) 2 3
5 1
113. The tangent lines to the curve y2 = 4ax at points (a) cm / sec (b) cm / sec
18 4
where x = a, are
(a) parallel (b) perpendicular 5
(c) cm / sec (d) None of these
(c) inclined at 60º (d) inclined at 30º 16
114. If the eccentricity of the hyperbola
11 8. If vectors aiˆ + ˆj + kˆ, iˆ + bjˆ + kˆ and iˆ + ˆj + ckˆ
2 2 2
x - y cos ec a = 25 is 5 times the (a ¹ b ¹ c ¹ 1) are coplanar, then find
1 1 1
+ + .
eccentricity of the ellipse x 2 cos ec 2 a + y 2 = 5 , 1- a 1 - b 1- c
then a is equal to : (a) 0 (b) 1
(c) –1 (d) 2
3
(a) tan -1
2 (b) sin -1
4
é3 - 2 4 ù
ê ú
119. If matrix A = ê1 2 - 1ú and
-1 2 -1 2
(c) tan (d) sin êë0 1 1 úû
5 5

115. The conditional ( p Ù q) Þ p is 1

A -=
1
adj (A) , then k is
(a) A tautology k
(b) A fallacy i.e., contradiction (a) 7 (b) – 7
(c) Neither tautology nor fallacy (c) 15 (d) – 11
(d) None of these 120. The angle between a pair of tangents drawn
116. The set of points of discontinuity of the function from a point T to the circle
x 2 + y 2 + 4 x - 6 y + 9 sin 2 a + 13 cos 2 a = 0 is 2a .
(2 sin x ) 2 n
f(x) = lim is given by The equation of the locus of the point T is
n ®¥ 3 n - (2 cos x ) 2 n
(a) x 2 + y 2 + 4x - 6y + 4 = 0
ì p ü
(a) R (b) ínp ± , n Î I ý (b) x 2 + y 2 + 4x - 6y - 9 = 0
î 3 þ
(c) x 2 + y 2 + 4x - 6y - 4 = 0
ì p ü
(c) ínp ± , n Î I ý (d) None of these
î 6 þ (d) x 2 + y 2 + 4x - 6y + 9 = 0
 PART - IV (ENGLISH) Directions (Q. 124) : In the question below a sentence
is given, a part of which is printed in bold and
Directions (Qs. 121-123): Study the paragraph and underline. This part may contain a grammatical error.
answer the questions that follow: Each sentence is followed by phrases a, b, c and d.
At this stage of civilisation, when many nations are Find out which phrase should replace the phrase given
brought into close and vital contact for good and evil, in bold/underline to correct the error, if there is any to
it is essential, as never before, that their gross make the sentence grammatically meaningful and
ignorance of one another should be diminished, that correct.
they should begin to understand a little of one another's 124. There are any number of skilled writers who can
historical experience and resulting mentality. It is the develop content and create marketing materials
fault of the English to expect the people of other with a keen eye to using proven methods, but
countries to react as they do, to political and also to developing new and innovative techniques.
international situations. Our genuine goodwill and (a) with a keen eye to using proven methods,
good intentions are often brought to nothing, because but also to developing new and innovative
we expect other people to be like us. This would be techniques.
corrected if we knew the history, not necessarily in (b) with a keen eye for using proven methods,
detail but in broad outlines, of the social and political and also to developing new and innovative
conditions which have given to each nation its present techniques.
character. (c) with a keen eye not only to using proven
121. The character of a nation is the result of its methods, but also to developing new and
(a) gross ignorance innovative techniques.
(b) cultural heritage (d) with a keen eye to using proven methods,
(c) socio-political conditions but to developing new and innovative
(d) mentality techniques.
122. According to the author Mentality' of a nation is 125. Choose the best pronunciation of the word,
mainly product of its Sorbet from the following options.
(a) present character (a) Sore-bet
(b) international position (b) Sore-bay
(c) politics (c) Sorb rhymes with orb
(d) history (d) Shore-bay
123. The need for a greater understanding between
nations
(a) is more today than ever before
(b) was always there
(c) is no longer there
(d) will always be there
 SOLUTIONS
PART - I (PHYSICS) PB mB vB
=
1. (d) Given : Mass of rocket (m) = 5000 Kg PA mA vA
Exhaust speed (v) = 800 m/s
Acceleration of rocket (a) = 20 m/s2 mA
mB mB 1
Gravitational acceleration (g) = 10 m/s2 = = =
We know that upward force mA mB mA 3
F = m (g + a) = 5000 (10 +20)
= 5000 × 30 = 150000 N. 5. (d)
We also know that amount of gas ejected 6. (d) Photoelectric effect does not support the
wave nature of light.
æ dm ö F 150000
ç ÷= = = 187.5 kg / s 7. (c) The equivalent electrical circuit of the
è dt ø v 800
arrangement is shown in figure.
2. (c) The power dissipated in the circuit.
2R
V2
P= ...(i)
Req B
A R C R D
v = 10 volt 2R
1 1 1 5+ R Temperature difference between the end
= + =
Req R 5 5R points A and D = 200 – 20 = 180°C
As the resistances for the three parts are
æ 5R ö equal, the temperature difference must be
Req = çè ÷
5 + Rø distribuited equally in the three parts (= 180/
P = 30 W 3 = 60°C)
Substituting the values in equation (i) \ Temperature of B = 200°C – 60° = 140°C.
8. (c) Number of possible spectral lines emitted
(10) 2
30 = when an electron jumps back to ground
æ 5R ö
çè ÷ n(n - 1)
5 + Rø state from n th orbit =
2
15 R n(n - 1)
= 10 Þ 15R = 50 + 10R Here, =6Þn =4
5+ R 2
5R = 50 Þ R = 10 W Wavelength l from transition from n = 1 to
1 n = 4 is given by,
3. (c) E = mv 2 or mv = 2m E
2 1 æ1 1 ö 16
= R ç - 2÷ Þl = = 975 Å
h h l è1 4 ø 15R
so l = =
mv 2m E 9. (c) The magnetic field is perpendicular to the
plane of the paper. Let us consider two
1 2 1 2 diametrically opposite elements. By
4. (c) As mA v A = mB v B
2 2 Fleming's Left hand rule on element AB the
direction of force will be Leftwards and the
vA mB
= magnitude will be
;
vB mA dF = Idl B sin 90° = IdlB
 x x x x x x x 20
´ 10-34
3
x xB x x Cxdl x x =
2 ´ 9 ´10 -31 ´ 0.2 ´1.6 ´10 -19
dF dl dF
A D
x x x x Ix x x 25
lmin = × 10–9
x x x x x x x 9
= 2.80 × 10–9 nm \ l ³ 2.8 × 10–9 m
On element CD, the direction of force will
be towards right on the plane of the papper 14. (b) Kerosene oil rises up in wick of a lantern
and the magnitude will be dF = IdlB. because of capillary action. If the surface
10. (b) Apparent depth = d/m1 + d/m2 tension of oil is zero, then it will not rise, so
11. (c) By law of conservation of momentum, oil rises up in a wick of a lantern due to
Mu = MV + mv surface tension.
-3
....(i) LdI 40 ´10 (11 - 1)
15. (a) e= = = 100V
| v1 - v 2 | dt 4 ´10-3
Also e = Þ Mu = Mv - MV 16. (d) Impedence of a capacitor is XC = 1/wC
| u1 - u 2 |
1 1 5000
....(ii) XC = = = .
2 pfC 2 p ´ 50 ´ 2 ´ 10 - 6 p
From (i) and (ii), 2Mu = (M + m)v
17. (a) The final boolean expression is,
2uM 2u
Þv =
M+m
Þ v=
m ( )
X = A . B = A + B = A + B Þ OR gate
1+ 18. (a) Charge resides on the outer surface of a
M
conducting hollow sphere of radius R. We
12. (c) Consider the potential at D be ‘V’. consider a spherical surface of radius r < R.
Potential drop across C1 is (V – V1) and C2 By Gauss theorem
i s ++ +++
++ +
(V2 – V) +
+ +
+ +
\ q 1 = C1(V - V1 ), q 2 = C2 (V2 - V) + R +
+ O +
As q1 = q2 [capacitors are in series] + S +
+ r +
E +
\ C1 (V - V1) = C2 (V2 - V) +
+ +
+ +
C1V1 + C2 V2
++
+ + ++
V= rr
C1 + C2 1
ò
s
E.ds = ´ charge
e0
enclosed or
13. (b) Given : work function f of metal = 2.28 eV
Wavelength of light l = 500 nm = 500 × 10– 2 1
9m E ´ 4pr= ´0 ÞE =0
e0
hc i.e electric field inside a hollow sphere is
KEmax = –f zero.
l
19. (d) Let R be the radius of the bigger drop, then
6.6 ´ 10-34 ´ 3 ´ 108 Volume of bigger drop = 2 × volume of small
KEmax = – 2.82 drop
5 ´ 10-7
4 3 4
KEmax = 2.48 – 2.28 = 0.2 eV pR = 2 ´ pr 3 Þ R = 21/ 3 r
3 3
h h Surface energy of bigger drop,
lmin = =
p 2m ( KE )max E = 4pR 2T = 4 ´ 2 2 / 3 pr 2T = 28 / 3 pr 2T
20. (b) Equivalent resistance between A and B = 26. (b) For path difference l, phase
series combination of 1 W and 2 W in parallel
æ 2p 2p ö
with 3 W resistor.. difference = 2p ç Q = x = .l = 2p ÷
è l l ø
Þ I = I0 + I0 + 2I0 cos 2p
Þ I = 4I0 (\ cos 2p = 1)
l p
For x = , phase difference =
4 2
p
\ I' = I1 + I 2 + 2 I1 I 2 cos
2
I I
If I1 = I2 = I0 then I ' = 2I0 = 2. =
1 1 1 2 4 2
= + = or R = 1.5 W.
R 3 3 3 27. (a) Static friction is a self adjusting force in
\ Current in the circuit is I = V/R = 1.5/1.5 = magnitude and direction.
1A. 28. (a) Cosmic rays are coming from outer space,
Since the resistance in arm ACB = resistance having high energy charged particles, like
in arm AB = 3 W, the current divides equally a-particle, proton etc. b-rays are stream of
in the two arms. Hence the current through high energy electrons, coming from the
the 3 W resistor = I/2 = 0.5 A. nucleus of radioactive atoms.
21. (d)
29. (c) For a monatomic gas
stress
22. (a) tan(90° - q) = 3
strain Cv = R
2
ze 2 k ze 2 So correct graph is
23. (c) U = –K ; T.E = –
r 2 r
k ze 2 ­ 3 / 2R
K.E = . Here r decreases
2 r Cv
24. (c) When resistance is connected to A.C
source, then current & voltage are in same
phase. T®
25. (a) Galvanometer is converted into ammeter, by
connected a shunt, in parallel with it. q
30. (c)
G L/2
I q
L L/2

L L
S L
The given square of side L may be
GS VG 25 ´ 10-3 considered as one of the faces of a cube
==
G+ S I 25 with edge L. Then given charge q will be
considered to be placed at the centre of the
GS
= 0.001W cube. Then according to Gauss's theorem,
G+S the magnitude of the electric flux through
Here S << G so S = 0.001 W the faces (six) of the cube is given by
 f = q/e0 36. (c) The acceleration of both the blocks =
Hence, electric flux through one face of the
cube for the given square will be 15 5
=
1 q 3x x
f' = f =
6 6e 0 5
31. (d) When work is done upon a system by a \ Force on B = ´ 2x = 10 N
x
conservative force then its potential energy
increases. 37. (b) Potential gradient along wire
C1 C 2 potential difference along wire
32. (c) Cs = =3 =
C1 + C 2 length of wire
C p = C1 + C 2 = 16 \ C1 C 2 = 48
I ´ 40
2
or, 0.1 ´10 -3 = V / cm
C1 - C 2 = (C1 + C 2 ) - 4 C1 C 2 1000

= 16 2 - 4 ´ 48 = 64 = 8 1
or, Current in wire, I= A
C1 + C2 = 16 mF 400
C1 - C2 = 8 mF
Þ 2C1 = 24mF Þ C1 = 12mF 2 1
or, = or R = 800 - 40 = 760 W
48 40 + R 400
\ C2 = = 4mF
12
A + d m 60 + 30
33. (d) In LCR series circuit, resonance frequency 38. (b) i= = = 45 º
f0 is given by 2 2
39. (b) I ® ON
1 1 1
Lw = Þ w2 = \ w= = 2pf0 II ® OFF
Cw LC LC
In IInd state it is used as a amplifier it is
1 1 active region.
\ f0 = or f 0a
2p LC C r r
When the capacitance of the circuit is made 40. (c) t = M B sin q = M ´ B
4 times, its resonant frequency become f 0' PART - II (CHEMISTRY)
f0' C f0
\ = or f 0' = 41. (b) It is stoichiometric defect and it is observed
f0 4C 2 when equal number of cations and anions
34. (b) On polarisation by reflection, the reflected are missing from the lattice site.
and refracted waves are at 90º to each other.
35. (a) v = velocity of efflux through an orifice OH
|
= CH 2 NH 2 :N = O
:

2gH 42. (d)

v= 0
H OH
H | | HÅ
CH 2 - Å N - N - O ¾¾¾®
v |
:

H
It is independent of the size of orifice.
 45. (b)
H OH
| |
CH 2 - Å N - N :- O ¾-¾
2 H 2O
¾ ¾® CH3 CH3
| |
H OH (CH 3CO) 2O Br2/CH3COOH

Å
CH 2 - N º N : ¾
¾® NH2 NHCOCH3

CH3 CH3
+
CH 2 + : N º N: +
Br /CH COOH H
+
-H
Br Br
| CH 2
| NHCOCH3 NH2
|
| (–NHCOCH3 is more electron-releasing than
|
| Å –CH3)
|¾¾ - H+
® ¾ ¾¾ ® 1
46. (b) No. of M atoms = ´ 4+1=1+1=2
OH - 4
1 1
OH No. of X atoms = ×6+ ×8 =3+1 =4
2 8
So, formula = M2X4 = MX2
47. (c)
43. (a) The reaction given is an exothermic reaction OH
thus according to Le chatalier’s principle CH3Cl, anhy. AlCl3
Zn
lowering of temperature, addition of F2 and dust Friedel-Craft reac.
Cl2 favour the forward direction and hence
Phenol Benzene, X
the production of ClF3.
44. (d) For the reaction:-
ˆˆ†
2NO2 ( g ) ‡ˆˆ 2NO(g) + O2 (g) CH3 COOH

Given Kc = 1.8 × 10–6 at 184 ºC CH Cl, anhy. AlCl KMnO4

Friedel-Craft reac.
R = 0.00831 kJ/mol. K
Dn g
Toluene,Y Benzoic acid, Z
K p = K c ( RT )
48. (b)
Dn g = 3 - 2 = 1
OH OH
Kp= 1.8 × 10–6 × 0.00831 × 457 (a) H4P2O7 ÞO P O P O
= 6.836 × 10–6
OH OH
Hence it is clear that Kp > Kc
Pyrophosphoric acid
 O Ea
51. (d) log k = log A - …(1)
P 2.303RT
(b) H3PO2 Þ OH H
H
1
Hypophosphorous acid Also given log k = 6.0 - (2000)
T
O …(2)
(c) H3PO3 Þ HO – P – OH On comparing equations, (1) and (2)
H log A = 6.0 Þ A = 106 s–1
Phosphorous acid Ea
and 2.303 R = 2000 ;
O
(d) H3PO4 Þ HO – P – OH Þ Ea = 2000 × 2.303 × 8.314
OH = 38.29 kJ mol–1
orthophosphoric acid 52. (c)
49. (d) The given structure has three double bonds
whose each carbon atom is differently (a)
substituted hence number of geometrical
alk. KMnO4
isomers will be 2n = 23’ = 8, where n is the CH 3CH 2CH 2OH ¾¾ ¾¾ ¾¾ ¾® CH 3CH 2CHO
or K 2Cr2O7 / H +
number of double bonds whose each carbon
atom is differently substituted. Fehling sol.
CH3CH 2 CH 2 OH ¾¾¾¾¾¾¾ ® CH3CH 2 CHO ¾¾ ® CH3CH 2 COOH ¾¾¾¾¾® No reaction
50. (a) Following generalization can be easily derived
for various types of lattice arrangements in (b)
cubic cells between the edge length (a) of
alk. KMnO4
the cell and r the radius of the sphere. CH3CHOHCH3 ¾¾¾¾¾¾¾ ® CH3COCH3
or K 2Cr2O7 /H +
a
For simple cubic : a = 2r or r =
2 ¾¾ ® CH 3COOH ¾¾¾¾
Feh sol.
® No reaction
For body centred cubic :
(c) CH 3CH 2 CH 2OH ¾¾® Cu
CH 3CH 2 CHO
4 3
a= r or r = a
3 4 Fehling
¾¾¾¾ ® Cu 2O ¯
solution (red)
For face centred cubic :
1
a = 2 2r or r = a Cu
2 2 CH 3CHOHCH 3 ¾¾® CH 3COCH3
Thus the ratio of radii of spheres for these
Fehling
will be ¾¾¾¾
® No reaction
solution
simple : bcc : fcc
(d) CH3CH 2CH 2OH or
a 3 1
= : a: a i.e. Conc. H2SO4
2 4 2 2 CH3CHOHCH3 ¾¾¾¾¾¾ ® CH 3CH = CH 2
option (a) is correct answer.
53. (b) Cu 2 + [ Ar ]3d 9 , Ti 4 + [ Ar ]3d 0 1 3
57. (a) ΔS for the reaction X 2 + Y2 ƒ XY3
2 2
Co 2 + [ Ar ]3d 7 , Fe2 + [ Ar ]3d 6
ΔS = 50 – (30 + 60) = – 40 J
1,3,4 are coloured ions hence the answer is b.
54. (b) For first order reaction, For equilibrium DG = 0 = DH – T DS

0.693 0.693 DH -30000

k= = T= = = 750 K
t1/ 2 6.93 DS -40
58. (d)
2.303 100
k= log
t 100 - 99
NO2 NH2
0.693 2.303 100
= log
6.93 t 1 reduction
¾¾ ¾ ¾®
CHCl
¾¾ ¾
¾3® C
alc. KOH
0.693 2.303 ´ 2
=
6.93 t NC NHCH3
t = 46.06 min
H / Catalyst
55. (a) Benzaldyde and formaldehyde, both do not ¾¾2 ¾¾ ¾
¾®
have a - hydrogen atom, so both will undergo
Cannizzaro reaction; here formaldehyde will N-Methylaniline
always be oxidised to formate while the other
aldehyde (C6H5CHO or any other aldehyde
not having a-H, viz- Me3CCHO) will always 59. (a) When pH = 14 [H + ] = 10-14
be reduced to correspondin g alcohol
(crossed Cannizzaro reaction) and [OH - ] = 1 M

a NaOH
Ksp = [Cu 2 + ] [OH - ]2 = 10 -19
CHO + HCHO ¾¾ ¾
¾®
10 -19
\ [Cu 2+ ] = = 10 -19
Benzaldehyde Formaldehyde [OH - ]2
a - + The half cell reaction
CH2OH + HCOO Na
Cu 2+ + 2e - ¾
¾® Cu
Benzyl alcohol sod. formate 0 .059 1
E = E° – log
56. (c) O
O O 2 [ Cu 2+ ]
C Heat C
¾¾¾® * 0.059 1
Ph * OH - CO 2 CH3 = 0.34 – log -19 = – 0.22 V
Ph 2
(b - keto acid) 10
(E)
Conc.H SO Oxi
O 60. (b) C4H8 ¬¾¾¾¾¾
2 4¾ C H O ¾¾¾
4 10 ®
(-H 2O)
I /NaOH
¾¾¾¾
2
® (–) (+)
*
Ph ONa + CHI3 C4H8O (R- COCH3 )
(F) (G) Thus C4H8O should be CH3CH2COCH3,
hence C4H10O should be CH3CH2CHOHCH3
61. (a) Wmax = – n.FE; H
|
Wmax = – 2 × 96500 × 0.65 = – 1.25 ´ 10 5 J Ph - C O CH 3 -H 2 O

: :
0.5g H 2 = 0.25 mole.
|
Å OH 2
Hence,
H
Wmax = 1.25 ´ 10 5 ´ 0.25 = –3.12 ´ 10 4 J CH 3
| Å

: :
– j
Ph O
a C O CH 3
62. (c) CH3 – CHO + HCHO ¾¾¾¾
®
OH H

:
1st aldol
condensation
H
a CH2 OH
|
CH2 CHO –
a

: :
OH / HCHO Ph - C O CH 3
2nd aldol
CH CHO | - H+
CH2 OH condensation O
CH2 OH Å
CH 3 H
CH2OH
–
OH / HCHO
3rd aldol
HOCH2 C CHO H
condensation |
CH2OH

: :
Ph - C O CH 3
|
O
: :
CH2OH |
– CH 3
OH / HCHO
HOCH2 C CH2OH
Cannizzaro
reaction 64. (a) In a – form distance between nearest
CH2OH

H 3a1
neighbour atom is .
| 2
63. (b) Ph - C = O + H +
In g form distance between nearest
H
| CH 3 neighbour atom is a 2 .
j - CÅ O
: :

Ph 2
| H
OH
3 a1 a 2
\ = (given)
H 2 2
| Å
CH 3
j-C O - H+
Ph a2 3
| =
:

H or
OH a1 2

H 3 3
| r1 z1 æ a2 ö 1 æ 3 ö÷
+ H+ = ç ÷ = ç = 0.918
j-C ça ÷
: :

Ph O CH 3 r2 z2 è 1ø 2 çè 2 ÷ø
|
OH
 *
65. (c) CH 3CHO (g ) ¾
¾® CH 4 (g) + CO (g) 68. (b) CH 3 – CH = CH – CHCH 3
|
OH
When t = 0 p 0 0 0
exhibits both geometrical as well as optical
0
When t = t p - p p p isomerism.
cis - R cis - S
\ p 0 - p + p + p = 120 mm Hg trans - R trans - S
or, p 0 + p = 120 mm Hg; 69. (c) Positive sign is for optical rotation (dextro
rotatory) and D - is for configuration. It is
p = 120 – 80 = 40 mm Hg
derived from
1 p0 1 80 1 CHO
k= ln = ln = ln 2
0
t p -p 20 80 - 40 20 |
H– C – OH
D (+) glyceraldehyde
|
ln2 CH2OH
Again, t1 / 2 =
k
CHO
ln2 |
\ t1 / 2 = ´ 20 = 20 min. L (–)glyceraldehyde is HO– C – H
ln2
|
66. (a) Solubility of the compound in conc. H2SO4 CH2OH
indicates that it can be an alkene, alcohol or
70. (b) DH = DU + DnRT for
an ether. The inability to discharge bromine
colour indicates absence of an alkene. Hence N 2 + 3H 2 ¾
¾® 2 NH 3
the compound is an alcohol which should be Dng = 2 – 4 = – 2
primary because it is readily (within 2
seconds) oxidised by CrO3 in sulphuric acid. \D H = D U - 2 RT or DU = D H+ 2R T \D U > D H

ch c NaBH
67. (b) E = hu = ;and u = 71. (a) O ¾¾ ¾¾
4®
OH
l l CH 3OH

HBr (i) Mg. Et O

¾¾
¾® Br ¾¾¾¾¾
2¾®
3.0 ´108
8 ´1015 = (ii ) H 2C = O
l
CH 2 OH
3.0 ´ 108
\ l= = 0.37 ´ 10-7 PCC
8 ´ 1015 ¾¾ ¾¾® CHO
CH 2Cl 2

72. (b) Most of the Ln 3+ compounds except La3+

= 37.5 ´ 10-9 m = 4 ´ 101 nm
and Lu3+ are coloured due to the presence of
f-electrons.
 O H O F
C 2
H OH O - C - H
73. (c) HO H 4 H - C - OH 1
H OH
CH 2 OH HO - C - H
77. (c) XeF2 : Xe
H - C - OH 3
CH 2 OH

2 1 F
3lp
4 C 1 º 3 C 2 R configurations

3 4
Arrange the groups in order of priority by
following the text. F F
74. (b) Saponification (alkaline hydrolysis) of oils
and fats gives glycerol and sodium salt of Xe
fatty acids, which is sodium palmitate in the
present question XeF4 : F F
75. (a) For non spontaneous reaction
DG = + ve 2lp
DG = DH – T DS and
DS = 121 J K -1
F
For DG = + ve F
DH has to be positive. Hence the reaction is
endothermic.
XeF6 : F Xe F
The minimum value of DH can be obtained
by putting DG = 0
F
DH = TDS = 298 × 121 J F
= 36.06 kJ
76. (c)
CH3 CH3
CHCl3 + NaOH HCN
Reimer Tiemman reaction C=O Xe
OH OH H
XeO3 : O O
CH3 CH3 O
OH HOH
1lp
C CN CH(OH).COOH

OH H OH Hence XeF2 has maximum no. of lone pairs

Cyanohydrin
of electrons.
 82. (c) Using Lagrange's Mean Value Theorem
78. (c) Let f(x) be a function defined on [a, b]
H OH
CH2OH f (b) - f (a)
HO
O then, f '(c) = ....(i)
OH H H b-a
H O
OH H H
H H H O OH c Î [a, b]
H OH CH2OH
1
\ Given f(x) = logex \ f'(x) =
x
(Lactose) \ equation (i) become
All reducing sugar shows mutarotation.
1 f (3) - f (1)
79. (a) On the basis of structure of guanine and =
c 3 -1
complementary bases present in them, we
can say that if the sequence of bases in one 1 log e 3 - log e 1 log e3 2
Þ = = Þ c=
strand of DNA is I, then the sequence in the c 2 2 log e 3
second strand should be II
Þ c = 2 log3e
A:T : G : C :T :T : G :A I 83. (c) p : we control population, q : we prosper
T : A : C : G : A : A : C : T II \ we have p Þ q
Its negation is ~ (p Þ q) i.e. p Ù ~ q
80. (b) C2H5 — NH 2
i.e., we control population but we do not
NaNO - HCl prosper.
¾¾ ¾ ¾
2 ¾¾®
C2 H5 N = N – Cl 84. (b) Consider the equation
0 - 5°C
zz + (2 - 3i ) z + (2 + 3i ) z + 4 = 0 ...(1)
C2H5 N = N – Cl + OH Let z = x + iy and z = x – iy, z z = x2 + y2
Put value of z, z and z z in equation (1),
® C2H5 N=N OH. we get
(x2 + y2) + (2 – 3i) (x + iy) + (2 + 3i) (x – iy)
PART - III (MATHEMATICS) +4=0
3p 5p Þ 4x + 6y + 4 + x2 + y2 = 0
81. (d) <5<
2 2 Now, we make it perfect square
Þ x2 + y2 + 4x + 6y + 4 + 4 + 9 = 4 + 9
Þ sin–1 (sin 5) = 5 – 2p
Þ (x + 2)2 + (y + 3)2 = 9
Given sin–1 (sin 5) > x2 – 4x
This represents a circle of radius 3.
Þ x2 – 4x + 4 < 9 – 2p 85. (b) Let f (x) = sin x – kx – c where k and c
Þ (x – 2)2 < 9 – 2p are constants
f '(x) = cos x – k
Þ – 9 – 2p < x – 2 < 9 – 2 p
\ f decreases if cos x £ k
Þ 2 – 9 – 2p < x < 2 + 9 – 2p Thus, f (x) = sin x – kx – c decrease
always when
k > 1.
86. (b) Given, equation is Given line is 2x – y + 5 = 0
Þ y = 2x + 5
1 1 3 8
= + cos θ or = 1 + 3cos θ slope of line is 2. Therefore,
r 8 8 r
2
l = 2 Þ y =1
which is the form of = 1 + e cos θ y
r
Q e = 3 > 0, put y = 1 in the equation of curve, we get
\ Given equation is a hyperbola. 1 = 4x + 5
87. (c) The differential equation of the motion is x=–1
Hence, point of contact is (– 1, 1)
dv
= 30 - 3v ....(i)
dt p /2
sin x
dv
89. (c) Let I = ò sin x + cos x
dx … (i)
0
Þ = dt .
30 - 3v
Then, I =
Integrating we get
p /2
sin(p / 2 - x)
1
- log (30 - 3v) = t + C ò sin(p / 2 - x) + cos( p / 2 - x)
dx
3 0

Þ log (30 - 3v) = -3(t + c) p /2

cos x
Þ 30 - 3v = e -3t -3c
= Ae -3 t
, A =e -3c Þ I= ò cos x + sin x
dx … (ii)
0

Þ 3v = 30 - Ae -3 t ....(ii) Adding (i) and (ii), we get

2I
dv
For maximum velocity = 0
dt p /2 p /2
sin x cos x
Þ 30 - 3v = 0 from (i) ò =
cos x + sin x
dx + ò sin x + cos x
dx
0 0
30
\v = = 10 cm / s p/2 p/2
3 sin x + cosx p /2 p
which is the maximum velocity ò =
sin x + cosx
dx = ò 1.dx =[x]0 = -0
2
0 0
dv
However from (ii) = 3Ae -3t p /2
dt p sin x p
Þ I=
4
Þ ò sin x + cos x
dx =
4
dv 0
Clearly = 0 if t ® ¥
dt 90. (c) We have
\ The maximum velocity will be achieved after
– 1 £ cos 3x £ 1 Þ – 1 £ – cos 3x £ 1
infinite time in other words, the maximum
velocity will hever be reached. Add ‘2’ on both side
88. (b) Given curve is y2 = 4x + 5 1 £ 2 – cos 3x £ 3
on differentiating, we get
1 1
dy dy 2 Þ 1³ ³ .
2y =4Þ = 2 - cos 3x 3
dx dx y
91. (c) The given lines are,
1 β γ 1 β γ
y – 1 = x, x ³ 0; y – 1 = – x, x < 0
1 x +β α =0 Þ 0 x α - γ =0
1 1
y = 0; x=- , x < 0; x = , x ³ 0 1 β γ 0 0 x
2 2
so that the area bounded is as shown in the
Þ x2 = 0 Þ x = 0
figure.
\ Solutions of the equation are x = 0,
-(a + b + g )

dy y sin 2x
93. (c) + =
dx x log x log x

dx
ò x log x
I.F. = e

1
ò dt
\ I.F. = e t = elog t = t = log | x |
12
Required area = 2 ò0 (1 + x ) dx solution is given by

12
y (I.F.) = ò Q.(I.F.) dx + C
æ x 2 ö÷ æ1 1ö 5
= 2ç x + = 2ç + ÷ = sin 2x
ç 2 ÷ è 2 8ø 4
è ø0 y log | x | = ò log | x |
(log | x |) dx + C

x +α β γ cos 2x
92. (a) Given γ x +β α =0 =- +C
2
α β x+γ
é x2 xù
94. (d) Consider lim ê - ú
Operate C1 ® C1 + C 2 + C 3 x ®¥ êë 3x - 2 3 úû

x +α+β+γ β γ
é 3x 2 - x (3x - 2) ù
x +α+β+γ x +β α =0 = x ®¥ ê 3(3x - 2) ú
lim
x +α+β+γ β x+γ êë úû

2x 2x
1 β γ = lim = lim
x ®¥ 3(3 x - 2) x ®¥ é 2ù
= ( x + α + β + γ) 1 x + β α =0 3 x ê3 - ú
ë xû
1 β x+γ

2 1 2 1 2
Þ x + α + β + γ = 0 Þ x = -(α + β + γ) = lim = ´ =
x ®¥ 3 æ 2ö 3 3-0 9
Again if ç3- ÷
è x ø
 r r r
95. (c) ((a ´ b ) ´ (c ´ d )).( a ´ d ) = 0 7 - i 3 + 4i
98. (d) z= ´
rrr r rrr r r r 3 - 4i 3 + 4 i
([a c d ] b - [b c d ] a ).(a ´ d ) = 0
rr r rr r 21 + 25i + 4 25(1 + i)
[a c d ][b a d ] = 0 = = = (1 + i )
16 + 9 25
r r r
Either c or b must lie in the plane of a z14 = (1 + i )14 = [(1 + i )2 ]7 = (2i)7
r
and d .
= 2 7 i 7 = -2 7 i
96. (b)
99. (c) f (x) = 2 sin x + sin 2x
f ' (x) = 2 cos x + 2 cos 2x = 2 (cos x + cos 2x)
B (1, 7) \ f ' (x) = 0 Þ 2cos2x + cos x – 1 = 0
-1 ± 3 1 p
cos x = = -1, \ x = p,
(1, 2) C 4 2 3
A
æ 3p ö
Now, f (0) = 0, f çè ÷ø = -2
2
D (4, – 2)
æ pö 3 3 3 3
f (p) = 0, f ç ÷ = 2 + =
Here, centre is A (1,2), and Tangent at B è 3ø 2 2 2
(1,7) is \ difference between greatest value and
x.1 + y.7 – 1 (x + 1) – 2 (y + 7) – 20 = 0 least value
or y = 7 ...(1)
3 3
Tangent at D (4,–2) is = +2
3x – 4y – 20 = 0 ...(2) 2
Solving (1) and (2), we get C is (16, 7) 100. (d) A and B will agree in a certain statement if
Area ABCD = 2 (Area of D ABC) both speak truth or both tell a lie. We define
1
following events
= 2× AB × BC E1 = A and B both speak truth Þ P(E1) = xy
2
AB × BC = 5 × 15 = 75 units E2 = A and B both tell a lie
97. (c) Integrating by parts. Þ P (E2) = (1 – x ) (1 – y)
E = A and B agree in a certain statement
ò f (x )g"(x ) dx - ò f "(x ) g(x ) dx Clearly, P(E / E1 ) = 1 and P(E / E 2 ) = 1
= f ( x )g ' ( x ) - ò f ' ( x ) g ' ( x ) dx The required probability is P(E1 / E ) .

- f ' ( x ) g ( x ) + ò f ' ( x ) g ' ( x )dx Using Baye’s theorem

P(E1 / E )
= f ( x ) g' ( x ) - f ' ( x ) g( x )
1 1 P(E1 )P(E / E1 )
=
Hence, ò0 f (x ) g" ( x) dx - ò0 f " (x )g ( x ) dx P(E1 )P(E / E1 ) + P(E 2 )P(E / E 2 )

= f (1)g' (1) - f ' (1)g(1) - f (0)g' (0) + f ' (0)g(0) xy.1 xy

= =
xy.1 + (1 – x )(1 – y).1 1 – x – y + 2 xy
= f (1)g' (1) - f ' (1)g(1)
101. (a) P (A È B) = P (A) + P (B) – P (A Ç B);
p/4

ò sec q tan n -2 q d q
2
3 1 =
Þ =1 – P( A ) + P(B) –
4 4 0

2 2 p/4
Þ 1=1– + P(B) Þ P(B) = ;
3 3 – ò tan n -2 q dq
0
2
Now, P( A Ç B ) = P(B) – P ( A Ç B ) = –
3 p/4
= ò sec 2 q tan n - 2 q dq - u n - 2
1 5 0
= .
4 12
p/4
x y z Þ un + un – 2 = ò sec 2 q tan n - 2 q dq
102. (a) Let the line be = = … (i)
a b c 0

If line (i) intersects with the line p/4

tan n -1 q 1
x -1 y + 3 z - 5 = n -1 =
= = , then n -1
2 4 3 0

104. (a) Total number of words that can be formed

a b c = 105. Number of words in which no letter
2 4 3 =0 is repeated = 10P5. So, number of words in
4 -3 14 which at least one letter is repeated = 105 –
10P = 69760.
5
Þ 9a – 7b – 10c = 0 …(ii) 105. (d) Required area = Area of OAB + Area of ABC
from (i) and (ii) , we have

a b c g (x) = – x + 2
= =
1 -3 5
3 f (x) = x2
x y z 2
\ The line is = =
1 -3 5 1 A
C
p/4 O B1 2 3
103. (a) Given: un = ò tan n q dq
0

p/4
1 2
= ò tan 2 q tan n -2 q dq
0 ò
Now, Area of OAB = f (x) dx + g(x)dx ò
0 1
p/4

ò (sec q - 1) tan n -2 q dq
2 1 2
=
0 ò 2
ò
= x dx + (- x + 2) dx
0 1
 1 2 1 1 7
x3 é -x 2 ù 108. (c) tan -1 + tan -1 + tan -1
= +ê + 2x ú 2 3 8
3 2
0 ëê ûú1
é 1 1 7 1 1 7 ù
1 é æ -4 ö æ -1 ö ù ê + + - ´ ´ ú
= + êç + 4÷ - ç + 2÷ ú =ê 2 3 8 2 3 8 ú
3 ëè 2 ø è 2 øû 1 1 1 7 7 1
ê1 - ´ - ´ - ´ ú
ë 2 3 3 8 8 2û
1 é æ 3ö ù
= + ê(-2 + 4) - ç ÷ ú
3 ë è 2ø û
é -1 -1 -1
êQ tan x + tan y + tan z
1 1 5 ë
= + = sq unit
3 2 6
æ x + y + z - xyz ö ù
= tan -1 ç ú
106. (a) The line
x y
+ = 1 will be a normal to the è 1 - xy - yz - zx ø÷ û
p q
parabola y2 = 4ax if, for some value of m, it é 41 7 ù
-
-1 ê 24 48 ú
is identical with
= tan ê 1 7
y = mx – 2am – am3 i.e. mx – y = (2am +
ê1 - - 7ú
am3) - ú
ë 6 24 16 û
Comparing coefficients, we get
m - 1 2am + am 3
= = Þ mp = – q, \ é 75 ù
1/ p 1/ q 1 ê ú æ 75 ö
= tan -1 ê 48 ú = tan -1 ç
ê1 - 43 ú è 48 - 43 ÷ø
q
m=– and mp = m (2a + am2) ë 48 û
p

2
æ -q ö é 75 ù
or P = 2a + am 2 = 2a + a çç ÷÷ = tan -1 ê ú = tan -1 15
è p ø ë5û
109. (b) Vertex of the parabola is a point which lies
aq 2
or p = 2a + on the axis of the parabola, which is a line
p2 ^ to the directrix through the focus, i.e., y =
or p3 = 2ap2 + aq2, 2 and equidistant from the focus and
Which is the required condition.
107. (b) P(E) = P ( 2 or 3 or 5 or 7) æ3 ö
directrix x = 0, so that the vertex is ç , 2 ÷ .
= 0.23 + 0.12 + 0.20 + 0.07 = 0.62 è2 ø

P ( F ) = P (1 or 2 or 3) Y
= 0.15 + 0.23 + 0.12 = 0.50
P ( E Ç F ) = P(2 or 3) y=2
A S (3,2)
= 0.23 + 0.12 = 0.35
O X
\ P( EUF ) = P( E ) + P ( F ) - P ( E Ç F )
= 0.62 + 0.50 - 0.35 = 0.77
110. (b) Let 113. (b) The given equation of the curve is y2 = 4ax
....(1)
é -1 2 5 ù é -1 2 5 ù
A = ê 2 -4 a - 4 ú ~ ê 0 0 a + 6 ú Differentiating both sides of (1) with respect
ê ú ê ú
êë 1 -2 a + 1úû êë 0 0 a + 6úû to x, we get

[R 2 ® R 2 + 2R1, R 3 ® R 3 + R1 ] dy dy 4a 2a
2y = 4a ; Þ = = ...(2)
dx dx 2 y y
Clearly rank of A is 1 if a = –6

-1 2 5 If y be the angle which the tangent to the

Also, for a = 1, | A |= 2 -4 -3 = 0 curve at (x, y) makes with the positive
1 -2 2
dy
direction of x-axis then tan y = or
dx
2 5
and = -6 + 20 = 14 ¹ 0
-4 -3 2a
tan y = ....(3), [using (2)]
\ rank of A is 2 if a = 1 y
111. (b) f ( x ) = 4 cos 3 x - cos x - 2 cos x = cos 3x At x = a, then from (1), y2 = 4a.a = 4a2 Þ y
[Expansion of determinant] = ± 2a.
p/2 p/2 Hence, we get two points (a, 2a) and (a, –
sin 3x ù 1
\ ò f ( x )dx =
3 úû 0
=-
3 2a) on the curve.
0
112. (a) Equation of the line through (1, –2, 3) At (a, 2a) x = a, y = 2a and let y = y1 .

x y z -1 2a
parallel to the line = = is \ from (3), tan y1 = = 1 = tan 45°;
2 3 -6 2a
x -1 y + 2 z - 3
= = = r (say) ...(1) Þ y1 = 45°.
2 3 -6
Then any point on (1) is (2r + 1, 3r – 2, –6r At (a, - 2a), x = a, y = -2a and let y = y2.
+ 3)
If this point lies on the plane x – y + z = 5
2a
then \ from (3), tan y 2 = = -1 = tan135°;
-2a
1
(2r + 1) – (3r – 2) + (–6r + 3) = 5 Þ r =
7 or y2 = 135°.

æ9 11 15 ö Hence the required angle between tangents

Hence the point is ç , - , ÷
è7 7 7ø
to (1) at (a, 2a) and (a, –2a) = y 2 – y1 = 135°–
Distance between (1, –2, 3) an d
45° = 90°.
æ9 11 15 ö This shows that the tangent lines to (1) at
ç ,- , ÷
è7 7 7ø (a, 2a) and (a, –2a) are perpendicular to each
other.
æ 4 9 36 ö æ 49 ö
= ç + + ÷= ç ÷= 1
è 49 49 49 ø è 49 ø
 x2 y2 dV
114. (a) Eccentrcity of - =1 is dx
25 25 sin 2 a Þ = dt
dt æ xö
çè 5 – ÷ø
1 + sin 2 a . 3

x2 y2 æ dx ö 5 15
Eccentricity of + =1 is Þç ÷ = = cm / sec .
è dt ø x = 2 5 – 2 13
5 sin 2 a 5
3
1 - sin 2 a 118. (b) Since vectors are coplanar

Given, 1 + sin 2 a = 5 1 - sin 2 a a 1 1

1 b 1
\ =0
2 2 1 1 c
Þ sin a =
3

2 a 1 1
Þ a = sin -1 = tan -1 2 1- a b -1 0
3 Þ = 0 [Using R2 – R1,
0 1 - b c -1
115. (a)
p q p Ù q ( p Ù q) Þ p R3 – R2]
T T T T Þ a (b – 1)(c – 1) – (1 – a) {(c – 1) – (1 –b)} = 0
T F F T Þ a (1 – b)(1 – c) + (1 – a) (1 – c) + (1 – a) (1 – b)
F T F T =0
F F F T Þ (a – 1 + 1) (1 – b) (1 – c) + (1 – a) (1 – c)
+ (1 – a) (1 – b)= 0
Þ (1 – b) (1 – c) + (1 – a) (1 – c) + (1 – a) (1 – b)
\ ( p Ù q) Þ p is a tautology..
= (1 – a) (1 – b) (1 – c)
(2 sin x ) 2n 1 1 1
116. (c) We have, f ( x ) = lim Þ + + =1
n ® ¥ 3n - (2 cos x ) 2 n 1- a 1 - b 1- c

(2sin x)2n é 3 -2 4 ù
= lim 119. (c) If A = ê1 2 -1ú
n ®¥ ( 3)2n - (2 cos x)2n ëê0 1 1 úû
f(x) is discontinuous when
1
and A -1 = adj(A) ......(i)
( 3 ) 2 n - (2 cos x ) 2 n = 0 k

3 p adj(A)
i.e. cos x = ± Þ x = np ± Also, we know A -1 = .......(ii)
2 6 |A|
\ By comparing (i) and (ii)
x2 dV dx x dx
117. (d) V = 5x – Þ =5 × |A| = k
6 dt dt 3 dt
 3 -2 4 Þ h 2 + k 2 + 4 h - 6k + 9 sin 2 a
Þ | A |= 1 2 -1
0 1 1 +13cos 2 a = 4 cos 2 a

= 3 (2 + 1) + 2 (1 + 0) + 4 (1 – 0) Þ h 2 + k 2 + 4 h - 6k + 9 = 0
= 9 + 2 + 4 = 15 \ Locus of T is x 2 + y 2 + 4x - 6 y + 9 = 0
120. (d) Radius of circle
PART - IV (ENGLISH)
= 4 + 9 - 9 sin a - 13 cos a = 2 | sin a |
2 2
121. (c)
If T be (h, k) then as in Q. 44 122. (d)
2 | sin a | 123. (a)
tana =
124. (c)
h 2 + k 2 + 4h - 6k + 9 sin2 a +13cos2 a
125. (b) The best pronunciation of the word 'sorbet'
is sore-bay.