Chem 162 Practice Exam 1 - Answers

Chem 162 Spring 2024
Practice Exam 1
This exam covers the material discussed in the Gases, Liquids, and Solids Modules, which is
information generally covered in Chs. 9 – 10 in your textbook. It has 11 questions and is
worth X points. In order to receive full credit on a problem, you must show all
computational work.
This exam is a closed-book, closed-notes exam. You may use your periodic table, a writing
instrument, and a scientific calculator. No other materials will be allowed and must be fully
placed away in your bag before you may begin the exam. You will have 50 minutes to
complete the exam. Once you have completed the exam, return it and your work to your
instructor.
You are responsible for your own work on your exam. Academic dishonesty will result in a
grade of zero (0) for all applicable problems.
Potentially Useful Information
Equations
𝑘𝑒 (𝑞1 ⋅ 𝑞2 ) Pgas = ∆ℎ𝜌𝑔 Pi = Xi ⋅ 𝑃𝑡𝑜𝑡𝑎𝑙
𝐹𝑐𝑜𝑢𝑙𝑜𝑚𝑏 =
𝑟2 𝑚𝑜𝑙𝑒𝑠 𝑖
Pgas = Patm ± ∆ℎ𝜌𝑔
∆𝐻𝑣𝑎𝑝 Xi =
−( ) 𝑚𝑜𝑙𝑒𝑠 𝑡𝑜𝑡𝑎𝑙
𝑃𝑣𝑎𝑝 = 𝐴 ⋅ 𝑒 𝑅⋅𝑇 P1 V1 = P2 V2
∆𝐻𝑣𝑎𝑝 𝑃𝑡𝑜𝑡𝑎𝑙 = ∑ 𝑃𝑖
V1 V2
ln(𝑃𝑣𝑎𝑝 ) = 𝑙𝑛𝐴 − =
𝑅⋅𝑇 T1 T2 1
𝑃2 ∆𝐻𝑣𝑎𝑝 1 1 𝐾𝐸𝑎𝑣𝑔 = 𝑚𝑣 2
ln ( ) = ( − ) P1 P2 2 𝑎𝑣𝑔
𝑃1 𝑅 𝑇1 𝑇2 =
T1 T2 3 𝑅
𝑞 = 𝑚 ⋅ 𝑐𝑝ℎ ⋅ ∆𝑇𝑝ℎ 𝐾𝐸𝑎𝑣𝑔 = ( ) 𝑇
V1 V2 2 𝑁𝐴
𝑞 = 𝑛 ⋅ ∆𝐻𝑝ℎ.𝑐ℎ. =
n1 n2
𝑎2 + 𝑏 2 = 𝑐 2 3𝑅𝑇
𝑃𝑉 = 𝑛𝑅𝑇 𝑢𝑟𝑚𝑠 = √
ℳ
4𝑟
𝑎 = 2𝑟, 𝑎 = , 𝑎 = 2𝑟√2 𝑃1 𝑉1 𝑃2 𝑉2
√3 = 𝑟𝑎𝑡𝑒1 · √ℳ1 = 𝑟𝑎𝑡𝑒2 · √ℳ2
𝑛1 𝑇1 𝑛2 𝑇2
𝑚
𝜌= ℳ𝑃 𝑛2 𝑎
𝑉 𝜌= (𝑃 + 2 ) (𝑉 − 𝑛𝑏) = 𝑛𝑅𝑇
𝑅𝑇 𝑉
𝑛𝜆 = 2𝑑𝑠𝑖𝑛𝜃
𝐶 + 273.15 = 𝐾
Constants and Conversions

𝐿 ⋅ 𝑎𝑡𝑚 𝐽 𝑔
𝑅 = 0.08206 = 8.3145 𝜌𝐻2 𝑂 = 0.99823
𝑚𝑜𝑙 ⋅ 𝐾 𝑚𝑜𝑙 ⋅ 𝐾 𝑚𝐿
𝑘𝐽 𝑇𝑏𝑝,𝑆𝐹6 = −50.8 ℃
∆𝐻𝑠𝑢𝑏,𝑆𝐹6 = 23.2
𝑚𝑜𝑙 𝑇𝑠𝑝,𝑆𝐹6 = −63.8 ℃
𝑘𝐽
∆𝐻𝑣𝑎𝑝,𝑆𝐹6 = 18.1 1 𝑚𝐿 = 1 𝑐𝑚3
𝑚𝑜𝑙
𝑘𝐽 1 𝐿 = 1 𝑑𝑚3
∆𝐻𝑓𝑢𝑠,𝑆𝐹6 = 5.1
𝑚𝑜𝑙 1 × 108 Å = 1 𝑐𝑚
𝐽
𝑐𝑆𝐹6 (𝑔) = 0.658 1 𝑎𝑡𝑚 = 0.101325 𝑀𝑃𝑎
𝑔⋅℃
1 𝑎𝑡𝑚 = 760 𝑡𝑜𝑟𝑟
1. If you wanted to classify sulfur hexafluoride in its solid form, as what type of solid
should you classify it? Circle your answer.
a. Ionic
b. Metallic
c. Molecular
d. Network Covalent
2. The density of solid SF6 is 2.377 g/mL. The unit cell edge length is 5.88772 Å. SF6
crystalizes in a cubic formation. Based on this information, what is the most likely
cubic structure that SF6 crystalizes in?
𝑩𝑪𝑪
3. SF6 is soluble in hexanes, but not very soluble in water. Explain why this is true.
Your answer here should discuss how IMFs affect solubility.

You obtain the following data doing a study on SF6:
• Patm = 763.5 torr
• Tgas = 24.7 °C
• Mass of empty 100 mL flask = 69.740 g.
• Mass of 100 mL flask filled to the top with liquid water = 181.4 g.
4. How many moles of sulfur hexafluoride were likely contained in the flask given your
data?
𝒏 = 𝟎. 𝟎𝟎𝟒𝟔𝟎𝟎 𝒎𝒐𝒍𝒆𝒔
5. How much heat would need to be released in order to cool down the SF6 gas in your
sample to a solid at –63.8 °C.
𝒒𝒕𝒐𝒕 = 𝟎. 𝟏𝟒𝟓𝟖 𝒌𝑱
6. This question will not be pre-published.

7. Which phase change(s) does SF6 undergo at atmospheric pressure?
𝒔𝒖𝒃𝒍𝒊𝒎𝒂𝒕𝒊𝒐𝒏
8. What is the minimum pressure (in atm) that is needed to condense SF6 into a liquid?
𝑷 ~ 𝟐𝟐𝒂𝒕𝒎. 𝑨𝒔 𝒍𝒐𝒏𝒈 𝒂𝒔 𝒚𝒐𝒖𝒓 𝒂𝒏𝒔𝒘𝒆𝒓 𝒊𝒔 𝒘𝒊𝒕𝒉 ± 𝟏𝟎 𝒂𝒕𝒎, 𝒕𝒉𝒂𝒕 𝒊𝒔 𝒇𝒊𝒏𝒆.
9. The boiling point of sulfur hexafluoride at 0.8 MPa is –23.2 °C. What would be the
boiling point in °C of sulfur hexafluoride at 2.0 MPa? Calculate this quantity rather
than estimate it.
𝑻 = 𝟕. 𝟎 ℃
10. Predict what observations you would make about liquid SF6 for each of the
following properties. Explain briefly how you came to your predictions.
a. Viscosity
Your answer should discuss how IMFs affect viscosity.
b. Surface Tension
Your answer should discuss how IMFs affect surface tension.
11. What types of compounds would be soluble in liquid SF6?
Non-polar molecular substances would be soluble in SF6 (l).

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Chem 162 Spring 2024

Constants and Conversions

Your answer here should discuss how IMFs affect solubility.

6. This question will not be pre-published.

𝑷 ~ 𝟐𝟐𝒂𝒕𝒎. 𝑨𝒔 𝒍𝒐𝒏𝒈 𝒂𝒔 𝒚𝒐𝒖𝒓 𝒂𝒏𝒔𝒘𝒆𝒓 𝒊𝒔 𝒘𝒊𝒕𝒉 ± 𝟏𝟎 𝒂𝒕𝒎, 𝒕𝒉𝒂𝒕 𝒊𝒔 𝒇𝒊𝒏𝒆.

Your answer should discuss how IMFs affect viscosity.

Your answer should discuss how IMFs affect surface tension.

11. What types of compounds would be soluble in liquid SF6?

Non-polar molecular substances would be soluble in SF6 (l).

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