c8 Waterquality
c8 Waterquality
Learning Objectives
By the end of this chapter, students will be able to:
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3. Describe solutions to water-related problems
4. Demonstrate knowledge of some of the major regulations related to water in the
USA.
Chapter Outline
Learning Objectives
8.1 Introduction
8.2 Water Scarcity and Shortage
8.3 Water Scarcity and Availability
8.4 Water pollution
8.4.1 Types of Water Pollution
8.4.2 Sources of surface water pollution
8.4.2.1 Chemical Pollution
8.4.2.2 Physical surface water pollution
8.4.2.3 Biological Pollution
8.5 Groundwater Pollution
8.6 Water Management
8.6.1 Watershed Management
8.6.2 The regulatory approach
8.7 A Closer Look at the Clean Water Act
8.8 Water Quality Assessment
8.9 Water in Crisis (case studies)
Test Your Understanding
Bibliography
8.1 Introduction
As described in Chapter 7, water is a very important commodity for human life and survival.
We need to consume it to stay alive and use it to clean our food, utensils, clothes, bodies, and
surrounding to prevent disease. Unfortunately, this same water is responsible for about 80% of
all diseases in developing countries and over three million deaths a year globally. It is therefore
very important that we understand why this important commodity can be vital and at the same
time cause so much harm. This chapter is devoted to the availability and quality of water. Water
quality will be defined as the physical, chemical and biological properties of water that impact
its intended use. This definition recognizes that quality designations of any given water can vary
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depending on water purpose it is serving. A single water body may have different quality
designations depending on the intended uses. For instance, water considered good quality for
fishing is not necessarily good for swimming or drinking. It is for this reason that different
regulations and standards have been created for the different water uses. These standards are
created to ensure that there is no water shortage due to mismanagement, overuse, and
contamination.
Both groundwater and surface water withdrawals had increased over time until 1980 when
the withdrawals peaked and stabilized. Water withdrawals in the US show a major divide
between the western and eastern parts of the country. The western part withdraws most of the
water for agriculture, as these are the farm areas while eastern half withdraws most of its water
for Thermoelectric cooling and industry (Figure 8.2). California and Texas account for over 20%
of all water withdrawn. In fact, California consumes more water than is available within the
state and is therefore forced to get water from the other states. Despite this deficiency almost
everyone in California has access to clean and safe drinking water. Contrast this to Lusaka, the
capital city of Zambia, which has more water available than is withdrawn but more than a third
of its population has no access to safe drinking water.
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Figure 8.1: Trends in fresh and saline water withdrawals in response to population growth (A) surface
water withdrawals (B) Groundwater withdrawal trends
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Figure 8.2: US water withdrawals by category for the calendar year 2015 (Image credit: USGS)
Figure 8.3: Communities in southeast Kenya without easy access to safe drinking water. (top left)
Groundwater in the area is too salty for consumption. (top right) Maasai women in Amboseli National
Park collecting water from a wetland. (bottom left) Women in Magwede village in SE Kenya walking long
distances to get water from a Kiosk. (bottom right) Children collecting water in Bungule Village from a
water kiosk that is only open for about an hour every day. Photo credit: Jonathan Levy, Sam Mutiti and
Christine Mutiti
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Contamination can both be natural due to geologic or meteorological events and anthropogenic
(human causes). Human sources of contamination can be categorized as either point source or
nonpoint source. Point-source pollution is water pollution coming from a single point, such as
a sewage-outflow pipe. Non-point source (NPS) pollution is pollution discharged over a wide
land area such as agricultural runoff and urban stormwater runoff, not from one specific
location. Non-point source pollution contamination occurs when rainwater, snowmelt, or
irrigation washes off plowed fields, city streets, or suburban backyards and carry pollutants into
the water sources. As this runoff moves across the land surface, it picks up soil particles and
pollutants, such as nutrients, metals and pesticides.
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mine tailings area runoff). However, some inorganic contaminants such as chlorine and related
derivatives are produced from point sources, ironically employed in water treatment facilities.
Moreover, some of the large dischargers of heavy metals to aquatic environments are fixed
point industrial plants.
High concentrations of nitrogen (N) and phosphorus (P) in water can cause eutrophication.
You see this whenever you notice the greenish tint to the water in your local streams and rivers
during low-flow times, or if you have ever seen a green farm pond. These nutrients are
primarily coming from treated wastewater (laden with P and N) being dumped into mainly
rivers from sewage plants. Another source of high nutrients are, agricultural areas where
farmers allow livestock direct access to streams and ponds. Urban and suburban areas where
there is intense fertilizer application for esthetics. Public and private landscapes (homes,
gardens, golf courses) with fertilizer runoff.
Increased supply of nutrients into an aquatic system leads to alterations of the primary
production from low to high. Algal blooms are natural events and all algae can bloom.
Cyanobacteria (Blue green algae) are not always harmful but can produce toxins when
conditions allow. The frequency at which conditions for toxic algal blooms’ occurrence have
become common lately in coastal areas of the US. Harmful algal blooms are possible under
prolonged sunlight in summer, high surface water temperatures, and when water stays static in
the presence of fertilizer runoff from the surrounding areas. When a bloom occurs, it can be
difficult to identify whether or not it is toxic (if you see dead fish it is probably toxic, Figure 8.4).
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Figure 8.4: Eutrophication process representation leading to algal blooms (Feem re-elaboration from
Arpa Umbria, 2009)
The N and P act as fertilizers in the water and promote algae blooms. As the algae die, they
are decomposed by aerobic bacteria in the water. These bacteria use up the oxygen in the
water and the low dissolved oxygen (DO) levels can results in “fish kills” where large numbers of
fish, and other aquatic life, die because of suffocation (Figure 8.5 and 8.6).
Figure 8.5: Lake Sinclair, Georgia. Left image: recreational area with expected accumulation of algae;
Right image: water clarity loss measured with a Secchi Disk due to an algal bloom. Photos credit Kalina
Manoylov.
Figure 8.6: Visible algal blooms leading to Fish Kills in some cases. A: Minnewashta Lake, IA, photo credit:
Kalina Manoylov GCSU; B: photo credit Jennifer L. Graham at USGS.
The dead zone in the Gulf of Mexico is a huge area of low DO (less than 2 mg/L or ppm) that
has a large negative impact on the fishing industry along the Gulf Coast near the mouth of the
Mississippi River (Figure 8.7). The dead zone occurs annually when fertilizers, from farm fields in
the Midwest, wash down the Mississippi river.
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Figure 8.7: The dead zone in the Gulf of Mexico 2017, Top photo: Showing the watershed of the
Mississippi river. Bottom image: oxygen levels in the Gulf of Mexico. (Image Source: NOAA. ORG)
Improper storage and use of automotive fluids produce common organic chemicals causing
water pollution. These chemicals include methanol and ethanol (present in wiper fluid);
gasoline and oil compounds such as octane, nonane (overfilling of gasoline tanks); most of these
are considered non-point sources since their pathway to watercourses is mainly overland flow.
However, leaking underground and above ground storage tanks can be considered point
sources for some of these chemicals, and even more toxic organic compounds such as
perchloroethylene. Grease and fats (such as lubrication and restaurant effluent) can be either
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point or non-point sources depending upon whether the restaurant releases grease into the
wastewater collection system (point source) or disposes of such organics on the exterior ground
surface or transports to large landfills. Table 8.1 shows a summary of some common chemical
pollutants and their sources.
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Figure 8.8: Trash washed up on the beach (left photo) and seal tangles up and being struggled by plastic
trash in the ocean (right photo). Photo Credit: NOAA Libraries
Finally, power plants and other industrial facilities that use natural water bodies for cooling
can cause thermal pollution (Figure 8.9) in surface water. Thermal pollution can change the
ecology of the water bodies and harm living things. The warm water discharged is usually only
used for cooling in the plant and does not contain other contaminants.
Figure 8.9: Schematic of the plant causing thermal pollution (Credit: USEPA)
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Figure 8.10: Contaminated groundwater from a septic tank (Image Credit: USGS)
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is runoff with low pH and high concentrations of iron and other heavy metals that are harmful
to aquatic life.
In the case of urban stormwater control, good urban planning and design can minimize
stormwater runoff. By reducing impermeable surfaces (pavement that doesn’t allow water
through), then cities can reduce the amount of surface water runoff the carries pollutants into
surface water and causes flooding. Additionally, the use of native plant and xeriscape
techniques reduces water use and water runoff, and minimizes the need for pesticides and
nutrients. Regarding street maintenance, a periodic use of street sweeping can reduce the
sediment, chemical and rubbish load into the storm sewer system
The two common approaches to water management fall under either voluntary programs or
the regulatory programs. The regulatory approach has been very successful in controlling and
reducing point source pollution, which was the focus of regulations when they were first
introduced. Voluntary programs, together with new amendments to regulations, have had great
success in increasing conservation and reducing diffuse nonpoint source pollution. One of the
most widely used voluntary programs is Watershed Management while the regulatory
approach in the US is centered on the Clean Water Act (CWA).
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interstate groundwater and surface waters. Through this regulation funding was made
available to states and local governments for water quality management.
One of the major water-related regulations in the US is the Clean Water Act (CWA) of 1972.
The regulation was very comprehensive with lots of programs that empowered the
Environmental Protection Agency (EPA) to create goals, and objective laws for its
implementation. The legislation has programs for both point and nonpoint source pollution.
One other major piece of regulation governing water was the 1974 Safe Drinking Water Act
(SDWA).
In 1974, amended in 1986, the SDWA was enacted to establish standards for many
chemical constituents for public water supplied by water agencies. In the regulation, maximum
contaminant level goals (MCLG), which are non-enforceable and maximum contaminant levels
(MCLs) that are enforceable where created. MCLG are what would be ideal and desirable while
MCL are what should be attained in any drinking water supplied by a public municipal agency.
For any carcinogen, the MCLG is 0 even though many contaminants have MCLs and detection
limits in the parts per billion (ppb) range. Some of them (e.g. dioxin) have MCLs in the parts per
trillion (ppt). To give you a sense of how small this ppt is, it is the same as 0.4 mm divided by
348 470 Km (238,900 miles) which the distance from Earth to the moon.
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The act covers both point sources (discharge from sources such as pipes) and nonpoint
sources (pollution from diffuse sources such as stormwater runoff). Point sources are explicitly
covered under section 402, National Pollutant Discharge Elimination System (NPDES). This
section requires industries and municipalities to get permits from the EPA before discharging
into US waters. The permits require the use of control technology to reduce and prevent
pollution.
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Colorimetry: measuring wavelengths when light is passed through a liquid to measure color changes
that correspond to specific values. These can use either a colorimeter such as Hach Colorimeter or
Spectrophotometer
Stoichiometry: reacting chemicals together and using titrations to determine the neutral point of either
the acid or the base
Ion specific electrodes: measuring the potential between two electrodes to determine concentrations of
specific ions. The electrodes can be single ion handheld probe or multi-parameter hand instruments
such as, Extech meters and YSI multi-parameter systems.
Chromatography: physically separating solutes and suspended substances in a liquid based on their
adsorption and absorption characteristics
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• Mutiti, S., Levy, J., Mutiti, C., & Gaturu, N. U. S. (2010). Assessing ground water
development potential using Landsat imagery. Groundwater, 48(2), 295-305.
• Steam Electric Power Generating Effluent Guidelines – 2015: Final Rule
• The World Oceans. 2015. 5 Oceans of the World. http://theworldsoceans.com/
Retrieved July 30th 2015.
• Thomas V. Cech Principles of Water Resources: History, Development, Management,
and Policy, 3rd Edition. Wiley and Sons Inc. 2009. Print
• U.S. Department of the Interior, U.S. Geological Survey
This page is: http://sofia.usgs.gov/publications/reports/rali/eqpollution.html Last
updated: 04 September 2013 @ 02:04 PM(TJE)
• USGS Water-Use Web Team. 2015. http://water.usgs.gov/watuse/wuglossary.html.
Page Last Modified: Wednesday, 11-Mar-2015
• Visualizations by Horace Mitchell Released on September 12, 2016
• Withgott, j. & Laposata, m. Essential Environment; the science behind the stories. 4th
Edition. New York City, New York. Pearson 2012. Print
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