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Solutions to JEE Main - 1 | JEE-2022

PHYSICS
SECTION-1
1.(D) N  F  mg cos  . . . .(i)
f  mg sin  0 . . . .(ii)
For limiting case, force applied is minimum.
  F  mg cos    mg sin 
mg sin 
F  mg cos 

 sin 
F  mg   cos  
  
 sin 37 
F  100   cos 37 
 1/ 2 
 3 4
F  100  2     200 N
 5 5

2.(D) T2 cosβ  mg . . . .(i)

T2 sin β  F  mg . . . .(ii)
From equations (i) and (ii), β  45

T2 cosβ  mg  T1 cos α . . . .(iii) and T2 sinβ  T1 sin α . . . .(iv)

Dividing equation (iv) and (iii)
tan α  1 / 2  sin α  1/ 5
1 1
From equation (iv), T2  T1  5T2  2T1.
2 5
 
  ba 5
3.(A) ˆ ˆ
Let that vector be C . Then C  C C  ba  C   ˆi  ˆj  a 2
1
4.(C) sman, bus  uman, bus t  aman, bus t 2
2
1
16  8t   2t 2 (equation relative to bus)
2
t = 4s
5.(C)
u sin   g  2
6.(B) tan 30 
u cos 
1 u sin 
and Tf 3  3  u sin   3g
2 g

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1 3g  2 g
   u cos   3 g
3 u cos 
 tan   3   60 , u  2 3g  20 3 m / s

2 dy dx d2y dx
7.(B) y  ax ,  a(2 x )  2acx , 2
 2ac  2ac 2
dt dt dt dt
 
a y  2ac 2 , ax  0 , a  a x iˆ  a y ˆj  a  2ac 2 ˆj  (B)

8.(B)
9.(A) The velocity v acquired by the parachutist after 10 s
v  u  gt  0  10  10  100 m/s
1 1
Then, s1  ut  gt 2  0   10  102  500 m
2 2
The distance travelled by the parachutist under retardation, s2  2495  500  1995 m
Let vg be his velocity on reaching the ground.
Then vg2  v 2  2as2 or vg2  (100) 2  2  (2.5)  1995 or vg  5 m/s

10.(A) Particle comes to rest when slope of x  t curve becomes zero (6 times)

distance area under v-t graph 1  1 

11.(C) Average speed      (1  2)  1  1.5 m/s
time time 1 2 
12.(A) From the graph acceleration  t
 Velocity  t 2
 Graph would be a parabola opening upwards for time t1 & opening downwards thereafter.
vf
vdv
13.(B) a   a ds   vdv
ds vi

v 2f  vi2
 area under a-s curve   0.4
2
2
v 2f   0.8   2  0.4 ; v f  1. 2 m / s


14.(A) v  3 x 2  x m / s
dv  dv 
av  v x 2  14 m / s ;  13 m / s   14  13  182 m/s
dx  dx x 2 
 

15.(A) Displacement perpendicular to inclined plane,

1 2v sin  2  5  3 / 5 3
0  v sin  t  g cos  t 2  t   
2 g cos  10  4 / 5 4
dx dy
16.(D)  ky ;  kx
dt dt
dy x
Dividing both equation & integrating, we get    ydy   xdx
dx y
y2 = x2 + constant

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d 6t 3
17.(B) at  6t m/s 2  R  6t ;    t2
dt R 4
2 t
d 3 2 3 2
dt

4
t   d  4   t dt  t = 2s
0 0

 at  12 m/s 2 and ar   2 R  36 ; a  at2  ar2  12 2   36 2  12 1  9 2

1
18.(B) V y  u y  a y t ; 0  5  g cos30t  t sec .
3

19.(C) Let applied force is F4  Fx iˆ  Fy ˆj

To prevent the particle P from moving, net force on the particle will be zero.
  Fx  0
or  Fx  Fx  150  200cos30  0
 Fx  150  100 3  (150  170)  320 N
and Fy  0
 
It means F4 is directed opposite to F1.
   
20.(C) a  b is perpendicular to the plane of a and b
 
unit vector along a  b ,
iˆ ˆj kˆ
2 2 1
  1 2 2
ab
 nˆ    
| a || b | ( 4  4  1 1  4  4)
iˆ( 4  2)  ˆj (4  1)  kˆ (4  2)

9
6 3 6 2 1 2
  iˆ  ˆj  kˆ   iˆ  ˆj  kˆ
9 9 9 3 3 3

SECTION-2

1.(2) Initial velocity is v  v0 cos 45iˆ  v0 sin 45 ˆj

1 ˆ 1 ˆ
5 2 i 5 2 j  5iˆ  5 ˆj
2 2

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The final velocity

v f  v0 cos 45iˆ  v0 sin 45 ˆj
1 ˆ 1 ˆ
 5 2  i 5 2 j  5iˆ  5 ˆj
2 2
 The change in velocity is
v  v f  vi

 ( 5iˆ  5 ˆj )  (5iˆ  5 ˆj )  10iˆ  | v | 10 ms 1

2.(5) u = 7 m/s and a = 4 m/s2

a
Distance traveled in nth second = u  ( 2n  1)
2
4
Distance traveled in 5th second = 7  [2(5)  1]  25m  5  5m  x  5
2
3.(9) Given that u = 0 (the particle starts from rest)
dv
At any time t : v  kt  2t . a   2 m/s2 (constant acceleration)
dt
1 1
Now s  ut  at 2  0  3   2  (3)2  9 m
2 2
2  10
4.(2) t   2sec
10
   
5.(1) If a and b are perpendicular, a  b  0
or 2x  3  1  0  x 1

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Chemistry

SECTION-1
1.(C) According to (n  ) rule, correct order of energy will be :
3s < 3d < 4p
4s < 3d < 4p
3d < 4p < 5s
4p < 5s < 4d
2.(B) Configuration of Cu 2 will be :
1s 2 , 2s2 2p6 ,3s 2 3p6 3d9

3.(C) Order of I.E. : C > B > Si > Al

4.(C) Order of electronegativity : O > N > Br > S
5.(A) Order of atomic radius :
Na > Li > Be > B
6.(D) There is smallest difference in first I.E. in Fe, Co, Ni because electron is removed from 4s in all three.

7.(C) Let mass of compound to be 100 gm.

Re Cl
63.6gm 36.4gm
63.6 36.4
moles 
186 35.5
= 0.342 = 1.025
1 : 3
Empirical formula of compound will be : ReCl3
8.(D) SnO 2  2H 2  Sn  2H 2O
2gm 
2 4
mol mol
151 151

4
 22.4lit.
151
 0.593lit.

9.(B)  P 3
P 
Total electrons  15 18
Unpaired electrons  3 0

10.(D) Correct order of metallic character will be :

Si > P > S
As > P > N
Br < Se < As

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z2
11.(B) E  13.6 ev/atom
n2
On increasing value of n, E increases but energy difference between successive energy levels
decreases.

12.(A) C7 H 6O3  C 4 H 6O3 

 C9 H 8 O 4  C 2 H 4 O 2
1gm

1 1
mol   mol
138.12 138.12
1
  180.15  1.304gm
138.12
0.85
% yield =  100  65.18%
1.304
13.(C) Atomic radius
14.(B) 2p will be next higher energy subshell.
For 2p, n = 2
 1
15.(D) Order of I.E.  C < O < N
16.(B) Al and Ga have mostly similar chemical properties.
I.E
1  M   I.E
2  M 2
17.(C) M(g)  (g) (g)

Na   1s 2 , 2s2 2p6 (inert gas configuration)

So removal of one more e  from Na  will be difficult Hence its I.E. will be higher.
18.(A) Transition from n  3  n  1, will produce a photon with highest energy among given options.

19.(D) The emission spectrum of hydrogen atom in visible region consists of a series of lines that are closer
at higher energies.
20.(B) XZ plane is Nodal plane in p y orbital.

SECTION-2

1.(3) 2SO 2 (g)  O 2 (g)  2SO3 (g)

Under identical conditions of T and P, equal volume of all gases contains equal number of molecules
So 2V of SO 2 requires V volume of O 2 to give 2 V volume of SO3
So 3 dm3 of SO 2 requires 1.5 dm 3 of O 2 to give 3 dm3 of SO3
Volume of O 2 given  2 dm 3
So O 2 is present in excess and SO 2 is the limiting reagent
Volume of SO3 formed  3dm 3

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2.(6) Fe 2O3 (s)  3C(s)  2Fe(s)  3CO(g)

1 mol of Fe 2O3 requires 3 mol of C
So 6 mol of Fe 2O3 will require 18 mol of C
But only 9 mol of C is present.
So the limiting reagent is carbon
3 mol of C gives 2 mole of Fe
So 9 mol of C will give 6 mol of Fe
 theoretical yield of Fe = 6 mol

3.(72) 2 mol of Ag  ions are present in 1 mole of Ag 2S

g 1.24 1.24
Moles of Ag 2S formed     0.005
M 0 (108  2)  32 248
So mol of Ag  ions that must have been present = 0.01 mol
Mass of 0.01 mol Ag  ions = 0.01  108  1.08 g
Mass of Silver
% of silver in the ore   100
Mass of Ore
1.08
  100  72%
1.5
4.(15) Fe  1s 2 , 2s2 2p6 ,3s 2 3p 6 ,4s2 3d 6
Number of orbitals which contain one or more electrons
1  1  3  1  3  1  5  15

5.(12) Second excited state for H-atom is n = 3

For monoelectronic species energy depends only on n
So energy of 3s = 3p = 3d
Number of degenerate orbitals = 9
Second excited state for H  ion = 2 p
For polyelectronic species, energy increases in the order : 1s  2s  2p
Number of degenerate orbitals = 3
Total degenerate orbitals = 9 + 3 = 12

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Mathematics

SECTION-1
t t
2 tan  1  tan 2
1.(B) 2 2 1
t 5
1  tan 2
2
t 
tan    
2
10  5  5 2  1   2
6 2  10  4  0
6(  2)  2(  2)  0
  2,   1 / 3
t 1
tan 
2 3
As   t  2
3
2.(B) cos A   ( A is angle of  hence in 2nd quadrant)
5
9 x 2  27 x  20  0
9 x 2  15 x  12 x  20  0
3 x(3 x  5)  4(3x  5)  0
4 5
x , x sec A
3 3
4
tan A  
3

3.(C) 3  3  3  3
If       0
2 x3  x  1  0 (, ,  ) (      0)
1
  
2
3
3  3   3  
2
4.(C) xy  2sin t cos t
x sin t

y cos t
x 2  2sin 2 t , y 2  2cos 2 t
x2  y 2  2

sin   2sin  cos 

5.(C)  tan 
cos   2cos2 

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6.(C) 16(cos 2 A  cos3 A)

16(2cos2 A  1  4cos3 A  3cos A)
 9 27 3  3 
16  2   1  4   
 16 64 4 
18  16  27  36
38  27  11

7.(A) 2  2    20
  8
64  48    0   16

8.(B) x 2  mx  n  0 (, )
    m,   n
x 2  px  q  0 (3 , 3 )
3  3   p   p  (  )3  3(  )
 p  ( m)3  3n( m)
p  m3  3mn

9.(B) a  a  4d  26  a  2d  13  a  13  2d
(a  d ) ( a  3d )  160
(13  d ) (13  d )  160

d 2  169  160
d 2  9  d  3 or  3
a  7 or 19
6 6
s6  (14  15) or (38  15)
2 2
 3  29 or 3  23
87 or 69

10.(B) 2  2sin 2   3sin   0

2sin 2   3sin   2  0

2t 2  3t  2  0

2t 2  4t  t  2  0
2t (t  2)  1(t  2)  0
1 1
t  sin   
2 2
 5  
   ,  ,   , 2 
6 6 6 6
Sum  2

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11.(D) a, b, c, d  GP
a, ar , ar 2 , ar 3
a  ar 3  112 a(28)  112
ar  ar 2  48 a4
1  r 3 112 7 4(36  1)
  s6   2(728)
r (1  r ) 48 3 (3  1)
1  r2  r 7
  1456
r 3
3r 2  3r  3  7 r
3r 2  10r  3  0
r 3
1 2 3 20
12.(A) s  1
 2
 3
 ....
2 2 220
2
s 1 2 19 20
 2
 3  .... 20  21
2 2 2 2 2
s 1 1 1 1 2
  2  3  ..... 20  21
2 2 2 2 2 2
20
1  1 
1    
s 2   2   20
  21
2 1 2
2
1
s  2
10 11
219  19  2  19
2 2
sin (2  )
13.(B) 3 Apply C & D
sin 
sin (2  )  sin  4

sin (2  )  sin  2
2sin (  ) cos 
2
2 cos (  ) sin 
tan (  )
2
tan 

13 13  23 13  23...153 1 15  16
14.(A)   ....  (1  2  ...15)
1 1 2 1  2  3...15 2 4
k 2 ( k  1) 2
4 ( k  1) k
Tk  
k (k  1) 2
2
 k2 k 
sk    
 2 2
 
(15)(16)(31) 15  16 15  16
 
12 4 4
sk m  620

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15.(C) x 2  mx  1  3x 2  3x  3
2 x 2  (3  m) n  2  0
D0
(3  m) 2  16  0
4  m  3  4
1  m  7
x 2  mx  1
 3
x2  n  1
4 x 2  (3  m) x  4  0
D0
(m  3) 2  64  0  m  ( 11, 5)

a, b, c  G.P
16.(C)
a ar ar 2
2b  2c  a  b  c  a
b  c  2a
ar  ar 2  2a
r2  r  2  0
(r  2) (r  1)  0
r  2

1 d d d 
17.(A)     .... 
d  a1a2 a2 a3 a3a4 
1 1 1 1 1 
     ... 
d  a1 a2 a2 a3 
1
a1d

18.(D) HCF (91, n)  1

 n is multiple of 7 or 13
14
105, 112, 196 (105  116)  2107
2
8
Or 104, 127, ....195  (104  195)
2
But 182 common to 1196 both
Sum = 3121

a, b, c
19.(D)
a ar ar 2
3a, 7b, 15c are A.P.
14ar  3a  15ar 2
15r 2  14r  3  0

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15r 2  9r  5r  3  0
3r (5r  3)  (5r  3)  0
3 1
r , r
5 3
7 a 5a 3a
3 a, , ,
3 3 3

20.(B) x 2  ( a  b) x  1  a  b  0 has real & distinct root

D0
(a  b) 2  4(1  a  b)  0
b 2  2ab  4b  a 2  4a  4  0  b  R
b 2  2b(2  a)  a 2  4a  4  0  b  R
D0
4(2  a) 2  4(a 2  4a  4)  0
16a  16  16a  16  0
32a  32  a  1

SECTION-2
1
1.(7) sec x 
1  cos x
 sec x  2
1
cos x  (0, 2)  [ ]
2
 
x , 2 
3 3
4
x2  x1 
3
  
2.(3) cos x cos  sin x sin    cos x
3 3
3cos x 3
E  sin x
2 2
9 3 12
EMax     3
4 4 4

3.(11) Ax 2  4 x  1  0 (,  )
x 2  4 x  A  0 (1 / , 1 /  )
2a  2d  4  a  d  2
Bx 2  6 x  1  0 (, )
x 2  6 x  B  0 (1 / , 1 /  )
, ,  ,   H.P.
1 1 1 1
, , - A.P.
   
B  8, A  3, A  B  7

Solutions | Page 12 JEE Main-1 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success

 2c c4
4.(23) f ( x)   x 2  x 
 c5 c 5

f (0)  0, f (2)  0, f (3)  0

c4
 0, c  (, 4)  (5, )
c5
4c c4 4c  20  4c  c  4 c  24
4  0  0 0 c  (5,24)
c 5 c5 c 5 c 5
6c c4 9c  45  6c  c  4
9  0  0
c 5 c5 c 5
4c  49
0
c 5
 49   49 
c  ( ,5)   ,   find c   ,24  c largest = 23
 4   4 

5.(25) 3 x 2  10 x  25  0 (tan A, tan B)

10 25
tan A  tan B  , tan A tan B  
3 3
10
5
tan( A  B)  3 
25 14
1
3
5 5
sin ( A  B )  
196  25 221
 25  3 70 25  116 
  10     25
 221 221 221 

Solutions | Page 13 JEE Main-1 | JEE 2022