IPANKAJ AGARWAL EDUCARE PVT. LTD.

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CHEMISTRY FOR (I.I.T. J.E.E.).-By-Pankaj Agarwal (e.rech.1L.L.T./K.)

Assignment ON Redox reactions

Sn KOH (X), which of the following is correctfor (X):

01. KNO,+ + gas
(b) diatomic paramagnetic
(a) Diatomic diamagnetic
(d) tetraatomic paramagnetic.
tetraatomic diamagnetic

02. In which of the following NH, will be produced: NH3t Mg(OH72

+ H,O
(a) NaNO, + A l +
NaOH NH3 tNaAIG(b) Mg, N,
(d) None.
(e both
gas produced is
:
03. Na NO, + Na
(c) NO, (d) O
(a) NO gb) N,
04M. KNO,(s) + K(S) >N2t620
NO2NO2 +02
heat
KNO +

+ A KOH NH3 + KAXO2

KNO
in the above reactions are respectively:
The gases produced colourless, pungent smell
paramagnetic,
colourless 6) Diamagnetic,
a Diatomic, diamagnetic.
basic in nature (o Odourless,odourless,
(Coiourless,Diatomic,
gas produced is:
05. KNO, + K None of these.
(d)
(c) NO
(b) NO
(alOH)2 2 PH3+ Ca[Hz F02)2
a) N with Ca(OH),nives:
Pyt
on reaction
96. h i t e phosphorous
(b) PH
(a) Ca(H, Po,) (both (b) & (c). 5a br2 tb4D
Ba[oH)2
solution gives: bl2
(c) Ca(H,PO,),
Conc. baryta
with hot and 6atOH)2 + Ba BrO
07. Br, o n reaction (b) BaOBr
Ba Br, + Ba Br0, + Ba Br.
(a) d) Ba(Br0,),
(OBr), disproportionation:

c) Ba Br, +Ba treatment

with NaOH
undergoes

non metal on ( a bromine.

08. Which of the following (c) red P
(b) oxygen
(a) black P
condition gives
water in cold calcium iodate
with lime +
reaction calcium hypoiodite
09. I, on (b)
calcium
iodide +
calcium
icdate
calcium
iodide + calcium hypo iodite
(a)
calcium
periodate
d)
iodide +
calcium
(c)
will occur in
10.
D i s p r o p o r t i o n a t i o n

(b)Ba(OH),
+ C
(a)
NaOH + P4 J a ) All.

(c)Ca(OH), + S
11. P (white) on reaction with causticsoda solution gives:
(a) acidic salt along with colourless (b) normal salt along with coloured gas
gas
(c) acidic salt along with coloured gas colourless gas.
d) normal salt along with
a n orange colour liquid on reaction with of hot Na, co, solution gives a mixture oftwo salts (A)

and (B) and a gas (G).

(A)+(B) H,SO
+
liquid (L)
which of the following is are correct?

á) (A) is NaBr
6) (B) is Na BrO,
A) +
(B)+ H,SO, Br2
d) metal in (G) forms two oxides one of which is anhydride of formic acid
non
.

13. whit Phosphaens)

Yellow phosphorous on treatment with Baryta (ba(OHn)
water gives:

(a) P.O+ Ba(H,PO,) (6) Ba, (Po,), + PH,

)PH, + Ba(H,PO,), (d) Ba, (PO,), +
P.O
14. Which of the
following non metal on treatment with NaoH undergoes disproportionation:
(a) black P (b) oxygen (c) red P Jd) bromine.
15M.Excess sulphur, on boiling with base, forms a
compound in which oxidation state of sulphur is:
a-1,0, 0,0,-1 b+2
(c)-2 -2/5
16. Which of the following, on reaction with caustic potash, forms colourless, paramagnetic gas ?

(a) Zn (c) C (d Al.

17M. Chlorine on reaction with dry slaked lime forms
a a compound which is used as oxidising agent.

(p a compound in which chlorine is in + 1 as well as in1 state.

( a compound, which on reaction with ammonia forms diatomic gas.

(d) a compound in which chlorine is in + 5 state.

18. A greenish yellow colour gas (A), on heatng with sodium carbonate, forms a mixture oftwo

salts and a gas (G) the mixture on acidification yields gas (A) again. Idetify (A) and (G):

(a) C,, co CL,co,

(c) co, C (d) Br,,cO.
9. Consider the
following reactions, in how many of
i) these GAS is
Na, Co, + heat produced:
X
i) B, H, + water
iv) K, Cr 0, +
H3B03+ H2
H,0, +
H,So, Cold/ether
v) Ba CO
heat
vi) Al, C water CH4
vil) Ca, P2 water PH3
vii) P OH PH3 t HzPo|
ix) K, Cr 0, (n03 t V2
heat Kz(nO4 +
20M. NaNO, + Na Gas (X)
Na NO + heat
Gas (Y)
(X) and (Y) are:

(a) Colourless, coloured Diamagnetic, paramagnetic.

(c) triatomic, diatonmic d) odourless, colourless.
21M. Zn +NaOH Gas (A)

Zn +conc. H, so,> Gas (B)

which ofthe following is/are correct:

4s) (A) is diatomic, colourless (b) (A) is diamagnetic.
(B) is triatomic, colourless (d) (B) can decclourise acidified K, Cr,0,.
Gas (A)
22M. Na NO, +Na

Ag+dil. HNO, Gas (B)

which of the following is/are incorrect:

á) (A) is diamagnetic ( B ) is paramagnetic.

have different atomicity (d) The bond order of (A) and (5) is saine.
(c) (A) and (B)
green residue (A) which on treatment with KOH/
23. Ammonium dichromate on heating gives
a

KNO mixture gives:

(b) K, Cr,0, + KNO0,
Cr + NO
(a) K, O,
Jd) K, Cr O, + KN0,.
NO
(c) K, Cr 0, +
is
not produce N, gas by thermal decomposition
24.The compound that does
) (NH,),So (c) Ba(N,), (d) (NH,),Cr,O,
(a) NH,NO,
25. Reduction involves:
(b) addition of oxygen
gain of electrons
(d) loss of electrons.
increse in oxidation number
(c)
 values Choose
C S or some redox couples are qiven below. On the basis of these
correct option:
E values Br, | Agt I Ag(s) +0.80
Br =
+1.90; =

Cu2t I Cu(s) = +0.34; I,(s)I = +0.54

(a) Cu will reduce Br (b) Cu will reduce Ag

(c)Cu will reduce I d)Cu will reduce Br

27. On the basis of standard electrode potential of redox couples given below find out which of tne

following is the strongest oxidising agent.

E values Fe3t Fe?t = +0.77; I,(s) I = +0.54 ;

Cu2I Cu(s) = +0.34; Agt I Ag(s) = +0.80

(a) Fe3+ (b) 1,() (c) Cu a) Ag

28. In the reaction: CI, +20H OCI + Ci+ H,O
(a) OH is oexidising and Ci is reducing agent (b) Cl, is oxidising and OHT is reducing agent

(c) OH is both oxidising and reducing agent ) Ci,isboth oxidising and reducing agent.
29. The increasing electron releasing tendencies of Cu, Ag, Fe and Zn are in the order:

(b) Cu, Ag, Fe, Zn

() Ag, Cu, Fe, Zn
(c) Zn, Cu, Fe, Ag (d) Fe, Zn, Cu, Ag.

30. The following four colourless salt solutions are placed in seprate test tubes and a strip of

will finally turn blue ?

copper is placed in each. Which of the following solutions

(a) NaCI L6) AgNo, (c) ZnSo (d) Cd(NO,),

because of
31. When Zn is added to CuS0, solution, copper is precipitated
of Zn
(b) hydrolysis of Cuso
(a) reduction
()oxidation of Zn (d) reduction of SO,2 ions.

32. Identify disproportionation reaction:

4HCI
+ 20, Cco, + 2H,o (b)CH, + 4Cl, CCl+
(a) CH, NO, +NO+H,O
(c) 2F + 20H 2F + H,O + OF d) 2N0, + 20H
?
is not an example of redox reaction
233. Which of the following
(b)Fe,0 + 3CO
2Fe +3CO,
CuO + H Cu + H,O
(a) La BaCl, + H,SO, Baso, + 2HCI
2KF
(c) 2K + Fz between which redox reaction is not
electrode potential, find out the pair
34, Using the standard

feasible
Fe3t | Fe2t = +0.77; I,(s) | I = +0.54
EOvalues +0.80 V
Cu2 Cu(s) =+0.34; Agt I Ag(s) =

(b) Agt and

Cu (c) Fe3t and Cu ( Ag and Fe'*.
Fe3t and I
(a)
 n the reaction;

3Br, + 6CO2+ 3H,O 5Br+ BrO,+ 6HCO,

(a) Br, is oxidised and carbonate is reduced Bromine is reduced and water
is oxidised
(b)
oxidised
(c) Bromine is neither reduced nor oxidised Bromine is both reduced and
.

)
and Z are 0.52, -3.03
36. The standard reduction potential values of the three metalic cations X, Y
metal isS?
and-1.18 V respectively. The order of reducing power of the corresponding
(b) X> Y >z
a)Y>Z>x
(c) Z> Y >X (d)Z> X >Y.
the
and 1M Z" at 25°C. If
37. A gas (X) at 1 atm is bubbled through a solution containing 1M Y
reduction potential of X > Y> Z then:

b)Y will oxidise

Z and not X
(a) Y will oxidize X and not Z

z (d) Y will reduce both Xand Z.

(c) Y will oxidize bot1 X and
redox reactions ?
38M. Which of the following
are

+ 2HCI ( ) Zn + 2HCI ZnCl, + H

HSo, Baso,
(a)BaCl, +
K[Ag(CN),].
6H,0 Co,+60, (d)KCN+ AgCN
(c)6CO, +

as will as reducing agent?

both as an oxidising
39M.Which of the following act
)HNO, (d) H,S
(a) HNO, H,0, following reaction
s t a t e m e n t s are not correct for the
40M.Which of the following

4,0 2Mn0, + 31, + gOH

2MnO
are s a m e
oxidation number of
Mn in Mno," and MnO,
á)
acts as an oxidising agent.
(b) Mno
reduced
)Hi,O has been
oxidation number
of iodide has
increased from I to I,.
(d)
given reaction
statements with reference to the
correct
41. Identify the
P+3OH + 3H,0 PH, +3H,PO,

is undergoing
reduction only
Phosphorous
(a)
oxidation only
Phosphorous
is undergoing
(b)
aswell as
reduction
oxidation
is undergoing
c)Phosphorous
nor reduction.
oxidation
is undergoing neither
(d) Hydrogen