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33.
33
Scheme
1.11.
Synthesis
of
[18]N2O4.
Catalytic
hydrogenation
of
the
precursor
macrocycle
leads
to
the
final
product
Selecting
a leaving group is somewhat easier than selecting a protecting group as there is a greater variety of
choices. Chlorides and bromides are widely used as they are inexpensive and easily obtainable.
However, the most popular choice has been the tosylates as they are very reactive (more than iodide)
and also very easy to make.66 Mesylates have been also used, especially in macrobicycle synthesis32,
53 but generally tosylates are more stable (being less reactive than mesylates). Moreover, when it
comes to alkyl compounds, tosylates are often solid materials that can be easily recrystallized, in
contrast with alkyl halides which are liquid and therefore have to be distilled. For example,
diethylene glycol ditosylate is a crystalline solid with melting point 87-89 o C.67 In contrast,
diethylene glycol diiodide is a liquid with a boiling point 78-84 o C at 0.8-0.9 Torr.68 O O II OON
N N OO N O O NH OO NH O O + BnBn Bn Bn MeCN, Na2CO3 NaI, 75% H2 , EtOH Pd(OH)2
92% H H 9 Dr Inger Mewburn On Twitter When What Your Phd Student When you complete your
first draft of the paper, it may give you feeling of relaxation and satisfaction, but it is not the final
stage. After this, you need to proofread your writing with utmost care and there may be
requirements for edit in several sections of your writing. Proofread and edit, both are extremely
critical and crucial activities, they should be done very carefully. To understand them better, refer
below-mentioned points: Being called ‘doctor’ must be a fancy of many university students, but as
much is the hardship to get the tag of ‘doctor’. The biggest task that any doctorate student faces is
writing the doctoral thesis. It is said that nobody is going to read your entire doctoral thesis! But
still, to get that highest academic degree you need to make sure no stone is unturned while writing
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thesis. And one of the ways for you to make sure that your thesis is of quality is to hand over the job
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writing a custom essay, research paper or a thesis to ProfEssays.com. All in all, writing a thesis paper
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knowledge and develop your writing and investigating skills. Your order will be assigned to the
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writers with the highest rate among the customers. A preview of the PDF is not available Leverage
Edu 3rd floor, Our website uses cookies to offer you the most relevant experience and optimal
performance. Thesis Title Page Sample Lamasa Jasonkellyphoto Co Your mastery in your thesis will
be shown by your convincing and well-founded argument. So that you can formulate a good
statement, you should read piles of books, magazines, journals, articles, and internet sources. It is
also expected that you give proper credit to your sources. Your thesis should be delivered not in an
interrogative manner, but in a declarative manner. You have to let your panel know that you have
answered the very problem of your thesis. Otherwise, you will leave an impression to the panel that
you are simply dodging the main point of your thesis and are lacking in ability. You can’t initially
decide to buy a PhD thesis when you learned that you are going to be making a PhD thesis. There
are still students that are self-motivated and believe that they have to come up a PhD thesis with
their own efforts. You have to see to it that buying a PhD thesis is your last resort when all attempts
are exhausted. Besides, you already have undergone undergraduate and master thesis. The format
used in master thesis is practically the same in a PhD thesis. Research Degrees 2010 11 Kingston
University London 3. 3 ABSTRACT The synthesis of six monocyclic polyamines (60, 61, 62, 115,
116 and 117) was achieved by the dipod-dipod cyclization reaction between 1,3-bis-bromomethyl-
benzene and aliphatic tosylated polyamines, followed by reduction of the resulting monocyclic
tosylamides. The crystal structures of five monocyclic tosylamides, two monocyclic polyamines and
fifteen monocyclic polyammonium salts are reported. It was found that the largest of the monocyclic
polyammonium species synthesized in this project behave as ditopic receptors towards halide
species. A supramolecular ‘Russian doll’ of the type positively charged species-anionic species-neutral
species- anionic species-positively charged species-etc was also crystallized from compound 62 and
hydriodic acid. The basicity behaviour of the monocyclic polyamines was studied by means of pH
titrations. pH titrations in the presence of sodium halides were also conducted but no significant
binding of halide species was found. The synthesis of three bicyclic (126, 127 and 128) polyamines
was achieved by the tripod-tripod cyclization reaction between 1,3,5-tris-bromomethyl-benzene and
aliphatic tripodal tosylated polyamines, followed by the reduction of the resulting bicyclic
tosylamides. The crystal structures of two bicyclic tosylamides, two bicyclic polyamines and six
bicyclic polyammonium salts are reported. An unusual intramolecular NH··· interaction, the first of
its kind for an artificial supramolecular system is observed for compound 126 and it is studied by
means of X-ray crystallography, potentiometry, NMR studies and theoretical studies. X-ray studies
revealed the formation of inclusive 1:1 complexes of 127 with fluoride, chloride, bromide and
iodide. Many similarities between the anion binding coordination modes of 127 and Dietrich’s
octaazacryptand were found. Potentiometric titrations showed very high binding constants for
fluoride and chloride with a F- /Cl- selectivity of more than five logarithmic units. No binding was
observed for either bromide or nitrate, something which is attributed to the higher pH under which
potentiometric studies were performed, in comparison with the pH under which crystallizations were
performed. Content may be subject to copyright. It is important to follow the academic
communication, as research paper is one of the essential parts of academic writing. The style of
writing needs to be strictly formal and must contain all the resources from where you have taken
assistance. + 1-888-827-0150 Thesis Front Page Design Lamasa Jasonkellyphoto Co Template For
Latex Phd Thesis Title Page E2 80 93 Texblog Plagiarism Dissertation Front Page Format Latex
Thesis Title Template A preview of the PDF is not available 50% found this document not useful,
Mark this document as not useful 19. 19 Abbreviations Ar (NMR) aromatic b (NMR) broad CDCl3
deuterated chloroform CD3CN deuterated acetonitrile d (NMR) doublet DFT density functional
theory DMSO-d6 deuterated dimethyl sulfoxide D2O deuterated water FAB fast atom bombardment
HRMS high resolution mass spectrometry wavelength J coupling constant m (NMR) multiplet MHz
megahertz mL millilitre MP2 Møller-Plesset 2 MS mass spectroscopy NMR nuclear magnetic
resonance K protonation constant Ks binding constant pt (NMR) pseudo-triplet s (NMR) singlet t
(NMR) triplet VT (NMR) variable temperature Dep diethoxyphosphoryl Bus tert-butylsulfonyl AMP
adenosine monophosphate ADP adenosine diphosphate ATP adenosine triphosphate pH -log[H]
DNNS dinonyl naphthalene sulfonate Plot number, 1- C, Raipur Khadar, Sector 126, Noida, Uttar
Pradesh 201313 One app for all your study abroad needs Thesis Sharelatex Online Latex Editor
Know More 35. 35 Scheme 1.13. An external template is a center or group which after facilitating
the
cyclization reaction, is then eliminated This contrasts to an internal template (endo-template) by
which a smaller ring is ring- enlarged to include all the pre-existing parts of the molecule. Such an
example is the synthesis of [12]N3 (11) from a tricyclic orthoamide (scheme 1.14). The subsequent
cleavage of C=N and C-N bonds affords the target compound.70 A classic example of an external
metal-templated synthesis is that of 12 in which Ni2+ is used (scheme 1.15).71 Subsequent
demetallation may be achieved either by adding acid, by a ligand exchange process or following
reduction of the metal if it has a suitable redox couple.
The next chapter will discuss your research question in detail as it was presented in your PhD thesis
statement. This includes stating the problem, how you will go about finding the answer to the
problem, and the predictions that you have of the outcome of the research. This chapter should
discuss the study that you are doing and what you are looking to prove through your research
question. 43. 43 In contrast with 18-6H+ , 6Cl- (figure 1.6),83 the macrocycle ring crystallizes in a
boat form (which is also the case for the tetrachloride salt of 1584 as well as 2785 ), maintaining an
ellipsoidal shape.55 However, no bromide is incorporated in the macrocyclic cavity. The interaction
of 15 with NAD+ and NADP+ was studied in aqueous solution by using pH-metric titration, cyclic
voltammetry and NMR spectroscopy. NADP+ is selectively bound by the receptor over NAD+ due
to its extra phosphate moiety which interacts strongly with two adjacent ammonium groups present
in the tetraprotonated receptor.86 Figure 1.5. Boat conformation and hydrogen bonding interactions
between the fully protonated [21]N5O2 and bromide Figure 1.6. Ligand conformation and hydrogen
bonding for [22]N6- 6H+ , 6Cl- . The ligand is planar with one chloride above and one below the
plane Always select a topic that is relevant and latest, for conducting your research study. The topic
must be from your core field. Ntnu Phd Thesis Latex Template Sharelatex Online Latex 16. 16 List
of Schemes Chapter 1 Scheme 1.1. From Supramolecular Chemistry to Polyamine-Based Organic
Macrocyclic Hosts for Anion Recognition. Scheme 1.2. Generalized procedure for the synthesis
(dipode coupling) of macrocyclic polyamines based on the formation of C-N bonds. X can be a
strong nucleophile group such as -NH2, -NH-Bn or -NH-Ts. L can be a good leaving group such as a
halide or -O-Ts. Reduction or deprotection follows which affords the desired product. Scheme 1.3.
The Richman-Atkins cyclization,27 a typical example of a dipode coupling cyclization. Scheme 1.4.
Schematic representation of synthetic alternatives to dipode coupling affording macrocyclic
polyamines. Scheme 1.5. In the single capping version of the ‘crab-like’ cyclization, reaction of a bis-
-chloroacetamide takes place with a primary amine. Scheme 1.6. The formation of tetraoxo[24]aneN8
as a byproduct of the dipode coupling reaction that leads to dioxo[12]aneN4. Scheme 1.7. Schematic
representation of synthetic strategies for the preparation of macrobicyclic species. Scheme 1.8.
Synthesis of an octaaza-cryptand by one-step macrobicyclization. Scheme 1.9. Double capping
synthesis of NaBr cryptands. Scheme 1.10. The high dilution principle. Low concentrations favor the
formation of the macrocyclic product. Scheme 1.11. Synthesis of [18]N2O4. Catalytic
hydrogenation of the precursor macrocycle leads to the final product. Scheme 1.12. An example of
the use of diethoxyphosphoryl as a protecting- activating group in the synthesis of
polyazacyclophanes. Scheme 1.13. An external template is a center or group which after facilitating
the cyclization reaction, is then eliminated. Scheme 1.14. Synthesis of [12]N3 from a tricyclic
orthoamide by virtue of an endo-template effect. 49. 49 Figure 1.12. X-ray crystal structure of the
salt [30]N10-10H+ ·3[Pd(Cl)4]-2 ·4Cl- . One [Pd(Cl)4]-2 anion is held inside the cavity by two
bifurcated hydrogen bonds (one crystallographically unique), H···Cl1: 2.413 Å, H···Cl2: 2.308 Å
The acid-base properties as well as the photochemical reactivity of the complexes formed between
[Co(CN)5(SO3)]4- and the polyammonium macrocyclic receptors 16-8H+ , 17-10H+ and 21-8H+
were also studied. This particular anion ([Co(CN)5(SO3)]4- ) has attracted interest because it
contains two different ligands both having basic properties and being able to form hydrogen bonds
with the macrocycle. The results showed that in the case of the 21-8H+ , the cyanides are involved in
hydrogen bonding but the sulfites are not. Both ligands are involved in hydrogen bonding with the
other two macrocycles.104 . 1.3.3 Cryptands The development of strategies for the synthesis of
cryptands32, 44, 105 began with the work of Lehn’s group published shortly after the discovery of
the katapinands by Park and Simmons.76 These molecules were used as hosts for cations in the first
place44, 105-107 but their potential as hosts for anionic species and especially ข่าวสารและบทความ
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และอยากตามทันเทรนด์ปัจจุบัน Dissertation Acknowledgements And Dedications The Bible Exa
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birmingham. 39. 39 Scheme 1.17. Encapsulation of halide anions by diammonium catapinands, the
first artificial organic hosts for anionic species 1.3.2 Corands Azacorands (the nitrogen analogues of
crown ethers)78 and azaoxacorands are possibly the most well studied class of macrocyclic
polyamine receptors for anionic species. They have attracted the interest of researchers since the early
1980’s as these substances are cyclic analogues of biological polyamines such as histamine,
spermidine and putrescine and could therefore interact with biomolecules. Some of these
macrocycles can be seen in figure 1.2 (azacorands) and figure 1.3 (azaoxacorands). N N N H NH
(CH2)n (CH2)n (CH2)n n=7-10 (CH2)n (CH2)n (CH2)n n=7-10 X-+ + Phd Thesis
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Stack Exchange Plagiarism 47. 47 Figure 1.10. Bridged bis(macrocyclic pentaamines) Figure 1.11.
Inclusion of nitrate into the macrocyclic pocket of the polyprotonated form of 27 Several protonated
macrocycles have been found to form a number of “supercomplexes” with coordination complex
anions such as [Co(CN)6]3- , [Fe(CN)6]4- and [PtCl6]2- . X-ray crystallographic analysis has shown
that in most cases, the anions bridge between the macrocycles, and little anion selectivity is
observed. This indicates that binding takes place primarily by coulombic attractions. The expression
“supercomplex” 99, 100 is used to describe the second-sphere coordination between the above
anions and polyammonium macrocyclic receptors. These supercomplexes may be considered as
complexes of complexes. The central NH N H N NH NH NH N H N NH NH O O H H R R = R =
(CH2)3 34: 35: The thesis should be formatted to be printed on 8.5 x 11-inch paper within your PDF.
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Of A Phd Dissertation 51. 51 Figure 1.15. Schematic representation of the binding versatility of the
soccer ball ligand. This ligand binds NH4 + when unprotonated (a), water when neutral (b) and a
chloride when protonated (c) The ligand 37, also called ‘bis-tren’ is possibly one of the most
extensively studied cryptands as an anion complexon. The binding of chloride by bis-tren in aqueous
solutions was measured by several techniques, including 35 Cl NMR and suggested that a chloride
anion is located inside the cavity.111 The same conclusion (formulation of a 1:1 complex) was
derived for the azide cryptate by NMR data.112 These findings were confirmed by the crystal
structures of the anion cryptates formed by the fully protonated bis-tren ligand with F- , Cl- , Br- and
N3 - .113 In the case of the N3 - complex (figure 1.16), linear recognition is observed resulting from
the
high degree of size and shape complementarity between the cavity of the protonated ligand and the
linear triatomic N3 - . H N + H H H N N N N H O H H H N + N N N + H Cl H H H N + N + N +
N + O O O O O O O O O O O O O O O O O O 36a 36b 36c A preview of the PDF is not available
Dissertation Front Page Format Latex Thesis Title Template 36. 36 Scheme 1.14. Synthesis of [12]N3
from a tricyclic orthoamide by virtue of an endo- template effect Scheme 1.15. Metal-templated
synthesis of [14]N4 An impressive template effect was observed in the synthesis of [2.2.2] cryptand
(13) by Kulstad and Malmsten (scheme 1.16).48, 49 Reaction of 1,8-diamino-3,6- dioxaoctane and
1-iodo-8-chloro-3,6-dioxaoctane yielded the cryptand whereas reaction of the same amine with 1,8-
diiodo-3,6-dioxaoctane afforded the diaza-18- crown-6. In the former reaction the iodide reacted
much faster than the chloride affording an intermediate amine with three branches. This intermediate
was then cyclized into the cryptand. On the other hand, the diiodo starting material reacts N NN Br
Br N N N N H NH NH 1. NaH, THF 2. + BF4 1. LiAlH4 2. H3O+ 3. BF4 11 _ _ 3. OH _ N N N N
H H H H NH2 N NH2 N H H N N NH2 N H H Ni Ni2+, H2O 2+ 1. OHC-CHO 2. BH4 - 3. CN- +
[Ni(CN)4]2- 12 H2 73. 73 Figure 1.41. Quaternary ammonium salts as hosts for anionic species
These organic ligands have very good solubility in water and exhibit a purely electrostatic ion-ion
interaction forming 1:1 complexes with guests in aqueous solution but with relatively low affinities.
The
highest stability constants were measured for bromide and iodide, apparently due to better steric fit
and
the
lower solvation energies of these anions. The receptor 76 was prepared as the tetraiodide salt and its
crystal structure was reported.153 One of the four crystallographically unique iodides was bound at
the
center of the electron deficient cavity, equidistant from the four positively charged nitrogen atoms
(figure 1.42). NN N N CH3 CH3 CH3 CH3 O N O N O N NN N N CH3 CH3 CH3 CH3 CH3 NN
N N CH3 CH3 CH3 NN N N CH3 CH3 CH3 X X X X X X + + + + X X X X X X + + + + X X
X X X X + + + + X X X X X X + + + + 76: -(CH2)6- 77: -(CH2)8- 78: -(CH2)6- 79: -(CH2)8- 81: -
(CH2)8- 80: -(CH2)6- : Tomp Io Template For Writing A Phd Thesis In Markdown Thesis
Presentation Powerpoint Template For Dissertation 70. 70 Figure 1.38. Dome-shaped cyclophanes
exhibit three-fold symmetry, suited for the binding of the nitrate anion The binding properties of the
cubic cyclophane 72 towards an anionic guest, ANS (8-anilinonaphthalene-1-sulfonate) were
examined by fluorescence studies (figure 1.39).149 This cyclophane is made of six faces, each being
constructed with the [3.3.3]azaparacyclophane ring. It was found to be soluble in acidic aqueous
media at pH = 4 (in which its tetracationic form is dominant) while all the amino nitrogens are
protonated in a pH region below 2.5. A 1:1 host-guest interaction was established with a drastic
change of the binding constant in the pH region 2.5-4.0, showing a maximum value at 3.7 (logKs
5.7). NH N HN H R R N N N 70: R = -(CH2)3- 71: R = -(CH2)4- R One prime difference between
the
two can answer dissertation vs thesis in the best way. The difference is, thesis writing starts in the last
two years of your Ph,D. There is no need of preparing a thesis while studying a master’s degree
already. However, to possess a doctorate’s degree you are required to do dissertation writing. The
original gathered content is required to show in your research material while preparing a thesis.
While, in the dissertation, all the new discoveries from existing findings are made as the unique and
final research work. Hence, after discussing both the concepts, it can be summarized that dissertation
is
opinion based while the thesis is subject research based. Research is always ahead of author’s
viewpoint in a thesis. 3.3 Statistical Analysis
………………………………………………………………………..62 While pursuing your subject
on
the
undergraduate and postgraduate level, have you ever thought about pushing the academic… Read
More Poughkeepsie, NY at Ciboney Cafe with Matt Jordan Band 17. 17 Scheme 1.15. Metal-
templated synthesis of [14]N4. Scheme 1.16. Template effect in the synthesis of a cryptand. Scheme
1.17. Encapsulation of halide anions by diammonium catapinands, the first artificial organic hosts for
anionic species. Chapter 2 Scheme 2.1. Formation of the starting materials (B). For S, see figure 2.7.
Scheme 2.2. The reaction that leads to the formation of the precursor macrocycles. For precursor
macrocycles, see figure 2.8. Scheme 2.3. Detosylation leads to the formation of the target
compounds. Chapter 3 Scheme 3.1. Synthesis of starting material (A). Scheme 3.2. Synthesis of
starting materials (B). Scheme 3.3. The reaction that leads to the formation of the precursor
macrocycles. The precursor macrocycles can be seen in figure 3.1. 50% 62. 62 An interesting
example of a preorganized macrocyclic host based on a bicyclic guanidinium subunit with the
purpose of binding tetrahedral oxoanions such as phosphates, is 52 (figure 1.30). This receptor was
obtained in a one-pot synthesis and contains the chiral bicyclic guanidinium subunit (figure 1.24) in
a macrocyclic framework. Overall, six binding units are arranged in such a way as to wrap around
the
anion by means of six hydrogen bonds tightly orientated in towards the center of the cavity.131
However, NMR evidence showed that despite the fact that phosphates are bound tightly, they do not
enter the cavity. In contrast, the chloride complex was found to have a perfect C2 symmetry at any
temperature indicating encapsulation of the anion. Figure 1.30. A preorganized macrocycle
containing a bicyclic guanidinium subunit with six convergent hydrogen bonds for anion recognition
1.3.5 Cyclophanes Cyclophanes represent the central class of receptor molecules for any kind of
guest species.132 The rigidity and electromagnetic properties of the systems based on the arene units
have
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NH MeMe O O O O + 52 © 2008-2024 ResearchGate GmbH. All rights reserved. Thesis writing –
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Title Page Apa 9. 9 List of Figures Chapter 1 Figure 1.1. A list of commonly used protecting
/ activating and leaving groups used in macrocyclic polyamine synthesis. Figure 1.2. Some of the
most common azacorands for anion binding. Figure 1.3. Some of the most common azaoxacorands
for anion binding. Figure 1.4. AMP, ADP, ATP, NAD and NADP are a few examples of biological
molecules that have been in the center of attention for supramolecular chemists for many years.
Figure 1.5. Boat conformation and hydrogen bonding interactions between the fully protonated
[21]N5O2 and bromide. Figure 1.6. Ligand conformation and hydrogen bonding for [22]N6- 6H+ ,
6Cl- . The ligand is planar with one chloride above and one below the plane. Figure 1.7. The lariat
macrocycles 29 and 30, bearing acridine moieties. Figure 1.8. Figure 1.9. Two optically active hexa-
azamacrocycles with C2 and D2 symmetry respectively, synthesized from an enzymatically prepared
material. Figure 1.10. Bridged bis(macrocyclic pentaamines). Figure 1.11. Inclusion of nitrate into
the macrocyclic pocket of the polyprotonated form of 27. Figure 1.12. X-ray crystal structure of the
salt [30]N10-10H+ ·3[Pd(Cl)4]-2 ·4Cl- . One [Pd(Cl)4]-2 anion is held inside the cavity by two
bifurcated hydrogen bonds (one crystallographically unique), H···Cl1: 2.413 Å, H···Cl2: 2.308 Å.
Figure 1.13. Commonly used cryptands for anion complexation. Figure 1.14. The ‘soccer ball’ ligand
possesses a tetrahedral recognition site and great versatility depending on the pH of the medium.
Figure 1.15. Schematic representation of the binding versatility of the soccer ball ligand. This ligand
binds NH4 + when unprotonated (a), water when neutral (b) and a chloride when protonated (c).
Figure 1.16. Linear recognition of the hexaprotonated bis-tren ligand towards the N3 - anion which
lies on the bridgehead N-N axis. To bring more clarity to the difference between a research paper and
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Participants…………………………………………………………………………………….49 22.
22 1.1.2 The choice of polyamine-based macrocycles as hosts for anionic guests Many imaginative
approaches have been taken in order to tackle the inherent difficulties in anion binding and an
impressive amount of work has been put into the synthesis and study of various types of systems.
Irrespective of their formal charge or their binding site, these systems can be categorized in two
major classes depending on their structure: acyclic (podands) and cyclic (or macrocyclic) receptors
(scheme 1.1). Scheme 1.1. From Supramolecular Chemistry to Polyamine-Based Organic Macrocyclic
Hosts for Anion Recognition Podands are chain-like hosts with a number of binding units situated at
intervals along their length whereas in cyclic receptors the binding units are arranged around a closed
ring. The cyclic receptors offer the advantage of being more preorganized and therefore potentially
more efficient as anion hosts due to the thermodynamic stability of their complexes (chelate and
macrocyclic or macrobicyclic effect).19 In the development of macrocyclic systems as receptors for
anionic (and cationic) species the amine moiety has played a key role.20 It has been
SUPRAMOLECULAR CHEMISTRY ANION RECOGNITION MACROCYCLIC
HOSTSACYCLIC HOSTS ORGANOMETALLIC HOSTS ORGANIC HOSTS POLYAMINE-
BASED HOSTS Phd thesis front pages. Begin abstract on page roman numeral two. A proforma for
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……………………………………………………………………………………….26 Copyright ©
2003-2024 Professays.com. All Rights Reserved. Free Revision 54. 54 The receptors 39 and 40,
closely related to bis-tren, (figure 1.19) have been shown to form inclusive complexes with the ClO4
- (figure 1.20) and the SiF6 - (figure 1.21) anions respectively.116 In the later case, the cryptate was
formed from the reaction of the cryptand with HBF4. Unexpectedly, the encryptated anion turned
out to be SiF6 - which derived from action of HBF4 on the glass reaction vessel. Encapsulation of
perchlorate and nitrate within the hexaprotonated host 39 was later confirmed by potentiometric and
NMR titration methods.117 A 1:1 complexation stoichiometry for both anions proved to be
dominant with high complexation constants (log K = 3.4 and 3.7 for perchlorate and nitrate
respectively). Comparison of the stability constants for anion binding between 19 and the bicyclic
analogue 38 demonstrates a definite macrobicyclic effect.118 More specifically, the protonated
cryptand forms stable and selective complexes with halides and the stability sequence was found to
be I- >Br- >Cl- . This trend is opposite to that observed for bis-tren and can be explained by the
structural features of the ligands. Indeed, the structure of 38 is based on two wider N[(CH2)3NH2]
tripod units linked together by -(CH2)3- chains resulting in a higher and more spherical cavity.
Moreover, 38 forms stronger complexes with oxalate2- and malonate2- showing a high selectivity
between them. Figure 1.19. The hexaprotonated forms of the macrocycles 39 and 40 have displayed
complete encapsulation of ClO4 - and SiF6 - respectively O N N H O O N H N N H N H NN H H
H H N N H N N H N N N N H N H N N 39 40 Your mastery in your thesis will be shown by your
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