Metullargy CHEMHACK
Metullargy CHEMHACK
Metullargy CHEMHACK
GENERAL PRINCIPLES OF
ISOLATION OF ELEMENTS
OCCURRENCE OF METALS
CONCENTRATION OF ORES
20. Name the 4 methods of conc. of ore -
21. Upward/downward stream of running water is used in hydraulic washing.
22. Magnetic separation is used in case of _____ ores.
23. Froth flotation method is used to remove gangue from ______ ores. (JEE)
24. Ex of collectors - (3)
25. Froth stabilisers ex - (2)
26. What collectors do ?
27. In case of an ore containing ZnS and PbS, the depressant used is ______
28. It prevent ZnS/PbS from coming to the froth but allows ZnS/PbS to come with the froth.
ANSWERS 1
GENERAL PRINCIPLES OF ISOLATION OF ELEMENTS 65
29. ______ saw that the Cu bearing compounds were caught in the soapsuds and so they came to the top.
30. ______ is often used if the ore is soluble in some suitable solvent.
31. Impurities present in bauxite are - (3)
32. In leaching, bauxite is treated with conc. solution of _____ at ____-____ K and ___-___ bar pressure.
33. Al₂O₃ + NaOH → (JEE)
34. Na[Al(OH)₄] (aq) + CO₂ (g)→
35. Al₂O₃.xH₂O (s) (on heating at 1470K)→
36. In metallurgy of Au and Ag, the metal is leached with ____ or ____.
37. M + CN⁻ + O₂ →
38. [M(CN)₂] + Zn →
EXTRACTION OF CRUDE METAL FROM CONCENTRATED ORE
39. The isolation of metals from conc. ore involves steps - (2)
40. Conversion to oxide is done by - (2) (JEE 2021)
→
41. Fe₂O₃.xH₂O + Δ
42. ZnCO₃ + Δ →
→
43. CaCO₃.MgCO₃ + Δ
44. In roasting, metal is heated above its melting point. T/F
45. ZnS + O₂ →
46. PbS + O₂ →
47. Cu₂S + O₂ →
48. Copper matte contains ____ and ____
49. FeO + SiO₂ →
50. What is ‘pyrometallurgy’ ?
51. The ΔH and ΔS values for ant chemical rxn remain nearly constant on change in temperature. T/F
52. Arrange the metals (given in ellingham diagram of NCERT) in order of their reducing power. (NEET)
→
53. Fe₃O₄ + CO Fe + CO₂. This rxn takes place at temp. -
54. At 500 - 800 K, the reactions that take place are - (4)
55. At 900 - 1500 K, the reactions that takes place are - (3)
56. Ex of slag is -
57. Pig iron contains ___% impurities. (NEET)
58. Cast iron is made by melting ______ with ______ and _____ using hot air blast. (JEE)
59. Cast iron have ___ % carbon content.
60. Cast iron is hard/soft.
61. Cast iron is brittle/resilient.
ANSWERS 1 ANSWERS 2
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ANSWERS 3
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ANSWERS
OCCURRENCE OF METALS 23. Sulphide ores
1. Viable sources of metal 24. Pine oils, fatty acids and xanthates
2. Gangue 25. Cresols, aniline
3. Extraction and isolation of metals from ores 26. Enhance non-wettability of the mineral particles
involves 27. NaCN
I. Concentration of the ore 28. ZnS, PbS
II. Isolation of the metal from its conc. ore 29. Washerwoman
III. Purification of the metal 30. Leaching
4. Al 31. SiO₂, iron oxides and TiO₂
5. Al 32. NaOH, 473-523 K and 35-36 bar pressure
6. Cr, Co 33. Na[Al(OH)₄]
7. Fe 34. Al₂O₃.xH₂O + NaHCO₃
8. AlOₓ(OH)₃₋₂ₓ 35. Al₂O₃ + x.H₂O
9. Kaolinite 36. NaCN or KCN
10. Fe₂O₃ 37. [M(CN)₂]⁻ + OH⁻
11. Fe₃O₄ 38. [Zn(CN)₄]²⁻ + M
12. Siderite EXTRACTION OF METAL FROM ORE
13. FeS₂ 39. Isolation of metals from conc. ore involves
14. Copper pyrites I. conversion to oxide
15. Malachite II. reduction of the oxide to metal
16. Cu₂S 40. Calcination and Roasting
17. Sphalerite, ZnS 41. Fe₂O₃ + xH₂O
18. ZnCO₃ 42. ZnO + CO₂
19. Zincite 43. CaO + MgO + CO₂
CONCENTRATION OF ORES 44. F
20. Methods of conc. of ore 45. ZnO + SO₂
I. Hydraulic washing 46. PbO + SO₂
II. Magnetic separation 47. Cu₂O + SO₂
III. Froth flotation method 48. Cu₂S and FeS
IV. Leaching 49. FeSiO₃
21. Upward 50. the branch of science and technology concerned
22. Iron with the use of high temperatures to extract and
QUESTIONS 1 QUESTIONS 2
GENERAL PRINCIPLES OF ISOLATION OF ELEMENTS 69
purify metals IV. solidified copper obtained
51. T 71. Reactions that take place in the furnace
52. Cu < Fe < Zn < Al < Mg →
2FeS + 3O₂ 2FeO + 2SO₂
53. 500-800 K →
FeO + SiO₂ FeSiO₃
54. At 500 - 800 K →
2Cu₂S + 3O₂ 2Cu₂O + 2SO₂
→
I. Fe₂O₃ + CO 2Fe₃O₄ + CO₂ →
2Cu₂O + Cu₂S 6Cu + SO₂
→
II. Fe₃O₄ + 4CO 3FeO + 4CO₂ 72. SO₂
→
III. Fe₂O₃ + CO 2FeO + CO₂ 73. Coke
→
IV. CaCO₃ CaO + CO₂ 74. T
75. Zn
55. At 900 - 1500 K
→
I. C + CO₂ 2CO ELECTROCHEMICAL PRINCIPLES
→
II. FeO + CO Fe + CO₂ 76. T
→
III. CaO + SiO₂ CaSiO₃ 77. Na₃AlF₆, CaF₂
56. FeSiO₃ 78. Cathode - Steel vessel with lining of C,
57. 4% Anode - Graphite
58. Pig iron with scrap iron and coke 79. Hall-Heroult process
59. 3% →
80. Al₂O₃ + C Al + CO₂
60. Hard 81. 2 kg
61. Brittle →
82. C + O²⁻ CO + 2e⁻
62. Wrought iron →
83. C + 2O²⁻ CO2 + 4e⁻
63. Malleable iron 84. Acid or bacteria
64. It is prepared from cast iron by oxidising impurities 85. Scrap iron or H₂
in a reverberatory furnace 86. F
65. Haematite 87. Extraction Au and Ag
66. Limestone I. Leaching the metal with CN⁻
67. S, Si, P →
4Au(s) + 8CN⁻ (aq) + O₂ (g) 4[Au(CN)₂]⁻(aq)
68. Rollers II. Recovering metal through displacement rxn
69. Cu₂S or C(coke) →
2[Au(CN)₂]⁻ + Zn 2Au + [Zn(CN)₄]²⁻
70. Extraction of Cu 88. Zn
I. Ore heated in reverberatory furnace after REFINING
mixing with SiO₂ 89. Methods of refining
II. Copper matte is produced as FeO slags of as (a) Distillation
FeSiO₃ (b) Liquation
III. Copper matte is charged into silica lined (c) Electrolysis
converter (d) Zone refining
QUESTIONS 2 QUESTIONS 3
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QUESTIONS 3 QUESTIONS 4