Zavitaev 2006
Zavitaev 2006
Zavitaev 2006
ELECTRONIC PROPERTIES
OF SOLIDS
Abstract—The electric conductivity of a cylindrical metal wire in a longitudinal magnetic field is analyzed
with regard to the specular–diffuse boundary condition for electrons. Based on the analytic solution obtained,
a theoretical interpretation is given to the experimental data on the magnetoresistance of a thin cylindrical wire.
An efficient method for determining the specular reflection coefficient of metal surfaces is proposed.
PACS numbers: 78.67.-n
DOI: 10.1134/S1063776106110124
768
DEPENDENCE OF THE ELECTRIC CONDUCTIVITY OF A THIN CYLINDRICAL WIRE 769
This field gives rise to a high-frequency current of is a velocity vector that turns into the vector v⊥ under
density the specular reflection of the wire from the internal sur-
face; and q is the specular reflection coefficient (the
2d ( mv )
3
m 3 probability of specular reflection), 0 ≤ q ≤ 1.
∫ - = 2e ⎛ ----⎞ v f 1 d v ,
∫
3
j = e vf --------------------- (2)
h
3 ⎝ h ⎠ When q = 0, we obtain the condition of diffuse
reflection of conduction electrons from the internal sur-
where e is the electron charge and h is the Planck con- face of a metal wire; when q = 1, we obtain the condi-
stant. Here, we use the standard normalization of the tion of purely specular reflection. When q ≠ 0 and q ≠ 1,
distribution function f, in which the density of electron we have different types of mixed (specular–diffuse)
states is equal to 2/h3. For the equilibrium function reflection of electrons.
f0(ε), we will use the following step-function approxi- We will solve the kinetic equation (3) subject to the
mation [9]: boundary condition (4) by the method of characteris-
tics [12].
⎧ 1, 0 ≤ ε ≤ εF , The boundary condition (4) allows one to trace the
f 0( ε ) = θ( εF – ε ) = ⎨ variation of the function f1 along a specularly reflected
⎩ 0, ε F < ε,
trajectory. At the point of reflection t' = tn , the function
f1(t') has a jump
where εF = m v F /2 is the Fermi energy (vF is the Fermi
2
⎛ d--------
f 1⎞ f
= – -----1 . where
⎝ dt ⎠ s τ
1 ∂f0
To determine the function f1 uniquely, one should ν = --- – iω, A = ev z E z --------.
τ ∂ε
define boundary conditions for this function on the
cylindrical surface of the wire. As such conditions, we
take the condition of specular–diffuse reflection of Let us solve this equation on the interval (tn – 1, tn).
electrons from this surface [2]: At the initial moment (t' = 0), we have
f 1 ( r ⊥, v ⊥, v z ) = q f 1 ( r ⊥, v '⊥, v z ) (4) A
f 1 ( t n – 1 + 0 ) = C – ---, (6)
ν
with
whence we determine the value of the constant C:
r ⊥ = R, r ⊥ ⋅ v ⊥ < 0,
A
C = --- + f 1 ( t n – 1 + 0 ).
where r⊥ and v⊥ are the components of the radius vector ν
r and the velocity v of an electron in the plane perpen-
dicular to the symmetry axis of the wire; vz is the com- Now, we obtain a relation between the initial values
ponent of the electron velocity along the wire axis; v '⊥ of the function f1 on two adjacent segments of the tra-
Applying condition (5), we find where rB = mv⊥/eB is the radius of the arc and ϕ is the
central angle corresponding to this arc.
A – νT – νT
f 1 ( t n + 0 ) = q – --- ( 1 – e ) + f 1 ( t n – 1 + 0 )e . When calculating integral (2), it is convenient to
ν
pass to cylindrical coordinates both in the space of
coordinates (r⊥ , γ, z; the polar axis is the axis z and the
Using this recurrence relation, we express f1(tn – 1 + 0)
vector E0 is parallel to axis z) and in the space of veloc-
in terms of f1(tn – 2 + 0), etc., and arrive at an expression
ities (v⊥, α, vz; the polar axis is the axis vz). The wire
for f1(tn + 0) in terms of the sum of an infinite geometric
axis coincides with axis z. In the cylindrical coordi-
series with the ratio qexp(–νT). Summing this series, nates, the field (1) has only the z component:
we obtain
– νT – iωt
qA ( 1 – e ) E = Ez ez , Ez = E0 e .
f 1 ( t n + 0 ) = – -----------------------------
– νT
-.
ν ( 1 – qe )
Accordingly, the current (2) also has only the z compo-
To determine a concrete expression for the solution nent (the current lines are straight lines parallel to the z
to Eq. (3), we use the initial condition (6). For t' = 0, we axis):
obtain
– νt'
( q – 1 )e
2
3ne
∫z v z δ ( ε – ε F ) -------------------------
2 3
– νT j z = ----------------E - + 1 d v.
qA ( 1 – e ) A 4πv F ν
3
1 – qe
– νT
- = C – ---,
– -----------------------------
ν ( 1 – qe )
– νT ν
Here, we took into account that the concentration of
whence conduction electrons in metals is given by
– νT
A q(1 – e ) A 1–q 2
C = --- 1 – -------------------------
- = --- --------------------- . m 34 3
n = 2 ⎛ ----⎞ f 0 d v = 2 ⎛ ----⎞ --- πv F .
m
ν ν 1 – qe –νT ∫
– νT 3
1 – qe ⎝ h⎠ ⎝ h⎠ 3
Thus,
Using the properties of the δ function, we obtain
f 1 ( t' ) = --- ⎛ ---------------------
A 1 – q ⎞ –νt' A
e – --- 2
ν ⎝ 1 – qe –νT⎠ ν δ ( ε – ε F ) = ---- δ ( v z + v ⊥ – v F )
2 2 2
(7) m
– νt'
A ( q – 1 )e
= – --- -------------------------
-+1 . 2
ν 1 – qe –νT = ---- δ [ v z – ( v F – v ⊥ ) ]
2 2 2
m
The parameter t' in (7) has the meaning of the trav-
2
= ---- δ [ ( v z – v F – v ⊥ ) ( v z + v F – v ⊥ ) ]
2 2 2 2
eling time of an electron with velocity v along the tra-
jectory from the boundary on which reflection occurs to m
a point r. The parameter T is the period of the electron,
i.e., the time interval between two successive collisions 1
= ----------------------------
of the electron with the surface of the wire. 2 2
m vF – v⊥
Determination of the parameters t' and T is the key
moment in this problem since, due to the longitudinal
× [δ(v z – v F – v ⊥) + δ(v z + v F – v ⊥)].
2 2 2 2
magnetic field, part of electrons move along helical tra-
jectories between two successive reflections from the
wire surface, while the trajectories of other electrons do In view of the symmetry of the problem, the integra-
not intersect the boundary of the wire (t' ∞)! tion over the entire range of velocities vz is replaced by
v δ ⎛ v – v F – v ⊥⎞
2 2 2
3ne E z 2 z ⎝ z ⎠
2
rB
j z = ----------------
4πv F ν m
3
- ---
- ∫
----------------------------------------------------
2 2
-
ψ0
vF – v⊥ R ϕ
( q – 1 )e
– νt' ϕ0
× -------------------------
3
– νT
- + 1 d v.
1 – qe r⊥ 2π – α x
In order to integrate expression (10), we must relate r ⊥ + δ exp ( iϕ 0 ) = R exp ( iψ 0 ) + r B exp [ i(ϕ 0 + ϕ) ]. (11)
the angle ϕ (the central angle of the arc of the circle
along which an electron moves in the case when its tra-
jectory intersects the boundary of the wire) and the When the coordinate axes are directed as indicated
angle ϕ* (in terms of which the period T of an electron above, we have ϕ = α – ϕ0 – π/2 (all the angles are mea-
is expressed) to the angle α (the angle between the vec- sured counterclockwise). This relation between the
tors r⊥ and v⊥) in the space of velocities. angles ϕ, ϕ0 , and α can easily be obtained by differenti-
ating the equation of circle z = z0 + rBexp[i(ϕ0 + ϕ)] with the surface of the wire, is equal to
respect to the parameter t' with regard to relation (8):
r B ϕ* ∆
∂z - = ---ϕ*,
T = ----------- ϕ* = 2π ( ϕ 2 – ϕ 1 ).
------ = iv ⊥ exp [ i ( ϕ + ϕ 0 ) ] v⊥ µ
∂t'
π Here, ϕ1 ≡ ϕ and ϕ2 are the roots of Eq. (12) that deter-
= v ⊥ exp i ⎛ ϕ + ϕ 0 + ---⎞ = v ⊥ exp ( iα ).
⎝ 2⎠ mine the points of intersection of the electron trajectory
with the boundary of the wire; moreover,
Using expression (11), we obtain
2ρξµ cos α – D
r ⊥ + r B cos ϕ 0 = R cos ψ 0 + r B cos ( ϕ 0 + ϕ ), ϕ 1 = 2 arccot ----------------------------------------
- ,
µ (ξ – 1)
2 2
( q – 1 ) exp ( – ∆ϕ/µ )
r ⊥ + 2r B – 2r B r ⊥ sin α – R × ------------------------------------------------ + 1 dρdα.
2 2 2
= --------------------------------------------------------------
-, 1 – q exp ( – ∆ϕ*/µ )
2r B
or, in dimensionless variables, Then, we formally apply Ohm’s law in the form I = GU,
where U is the voltage across the ends of the wire, and
obtain a formula for calculating the conductivity G of
( ρ – ξµ sin α ) cos ϕ + ξµ cos α sin ϕ the wire (the electric field inside the wire is uniform;
ξ µ + 2ρ – 2ρξµ sin α – µ (12)
2 2 2 2 therefore, U = EzL):
= --------------------------------------------------------------------- .
2ρ 1 1 2π
2 3
3ne R
∫
G = ------------------- ξ dξ ∫∫ρ 1–ρ
2
Applying the standard method to Eq. (12), we obtain mv F L∆
0 0 0 (13)
2ρξµ cos α – D ( q – 1 ) exp ( – ∆ϕ/µ )
ϕ = 2 arctan ----------------------------------------
- , × ------------------------------------------------ + 1 dρdα.
µ (ξ – 1)
2 2
1 – q exp ( – ∆ϕ*/µ )
where S, mΩ
2 3 8 1
3ne R
G 0 = -----------------, 2
mv F L 7
1 1 2π 6
1
P ( λ, Ω, µ, q ) = --- ξ dξ ∫ ∫∫ρ 1–ρ
2
3
∆ 5
0 0 0 (15) 4
4
( q – 1 ) exp ( – ϕ∆/µ )
× ------------------------------------------------ + 1 dρdα.
1 – q exp ( – ϕ*∆/µ ) 3 5
M A
8 0.8
(b)
(a)
7 3
0.7
6 0.6
2
5 0.5
3
4 0.4
2
3 0.3
1
1
2 0.2
1 0.1
0 0.2 0.4 0.6 0.8 1.0 0 0.2 0.4 0.6 0.8 1.0
q q
Fig. 3. (a) Modulus M and (b) argument A (phase) of the dimensionless integral conductivity of a wire as a function of the reflection
coefficient q of electrons: (1) λ = Ω = µ = 0.1; (2) λ = Ω = 0.1, µ = 1; and (3) λ = Ω = 0.1, µ = 2.