FOAM CONC.

AFFF 3 PCT (F-25)

Revision: 16/08/2012

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier

Product Name:
Datasheet Number: 777692 2. 0. 0
Product Part Number: 777691 (200 liter), 777692 (20 liter)
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway, Tel:+47 67 584550
1.2 Relevant identified uses of the substance or mixture and uses advised against
Fire fighting foam concentrate
1.3 Details of the supplier of the safety data sheet
Name of Supplier: For quotations contact your local Customer Services
Address of Supplier: Wilhelmsen Ships Service AS
Willem Barentszstraat 50
3165AB Rotterdam
The Netherlands
Telephone: +31 10 4877 777
Fax: +31 10 4877 888
Responsible Person: , Product HSE Manager, Tel.: +31 10 4877775
Email: [email protected]
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture

- Harmful if swallowed (R22)
- Irritating to eyes (R36)
- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations.
- Refer to current The Dangerous Substances Directive (67/548/EEC)
2.2 Label elements

Harmful
Risk Phrases
- Harmful if swallowed (R22)

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2 Hazards identification (....)
- Irritating to eyes (R36)
Safety Phrases
- Avoid contact with skin and eyes (S24/25)
2.3 Other hazards
- Odour: Characteristic odour
- Appearance: Liquid, brown
- Contact with skin: May cause redness and irritation
- Inhalation: Vapours or aerosols may cause irritation of eyes, nose and respiratory tract

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases* Symbols

2-2 (butoxyethoxy) ethanol 10-15% 112-34-5 203-961-6 R36 Xn
Ethanediol 10-15% 107-21-1 203-473-3 R22 Xi

*See Section 16

4 First aid measures

4.1 Description of first aid measures

- IF ON SKIN: Wash with plenty of soap and water.
- Contaminated clothing should be laundered before reuse
- When in doubt or symptoms persist, seek medical attention
-
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- If substance has got into eyes, immediately wash out with plenty of water for at least 15 minutes
- Irrigate eyes thoroughly whilst lifting eyelids
-
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- Give water or milk to drink
- Never make an unconscious person vomit or drink fluids
- When in doubt or symptoms persist, seek medical attention
-
- Inhalation is unlikely to occur
- Remove patient to fresh air
- When in doubt or symptoms persist, seek medical attention
4.2 Most important symptoms and effects, both acute and delayed
- Possible redness and irritation of affected areas
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
- The ingestion of significant quantities may cause gastro-intestinal disturbances
4.3 Indication of immediate medical attention and special treatment needed

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5 Fire-fighting measures

5.1 Extinguishing media

- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- Not applicable
5.3 Advice for firefighters
- Prevent run off water from entering drains if possible

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

- Wear protective clothing as per section 8
6.2 Environmental Precautions
- Do not flush spilt material into any public water system
6.3 Methods and material for containment and cleaning up
- Absorb spillage in suitable inert material
- Sweep or shovel-up spillage and remove to a safe place
- Ventilate the area and wash spill site after material pick-up is complete
6.4 Reference to other sections
- None

7 Handling and storage

7.1 Precautions for safe handling

- See Section 8
- Do not get in eyes, on skin, or on clothing.
7.2 Conditions for safe storage, including any incompatibilities
- Protect from frost
- Store between -10 and 45 °C
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters

- 2-2 (butoxyethoxy) ethanol
Lowest value OES / LTEL 10 ppm ^ 50 mg/m3 (CAS:112-34-5)
Lowest value OES / STEL 15 ppm ^ 100 mg/m3 (CAS:112-34-5)
- Ethanediol
TLV (TWA) 10 ppm, 26 mg/m3 (CAS: 107-21-1)
8.2 Exposure controls
- No special precautions are required for this product

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8 Exposure controls/personal protection (....)

Occupational exposure controls

- Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber are
recommended)

Goggles Gloves Suit

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties

- Odour: Characteristic odour
- Appearance: Liquid, brown
- pH 6.5 - 8.5 at 100 % concentration
- Boiling point ~ 100 °C at 760 mm /Hg
- Completely soluble in water
- Viscosity 5 - 15 cST @ 20 deg C
9.2 Other information
- None

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- Considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- No special precautions are required for this product
10.5 Incompatible materials
- None
10.6 Hazardous Decomposition Products
- No hazardous decomposition products known

11 Toxicological information

11.1 Information on toxicological effects

- LD50 (oral,rat) >2000 mg/kg
Inhalation
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract

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11 Toxicological information (....)

Contact with skin

- In cases of severe exposure, redness and irritation may develop
Contact with eyes
- Causes irritation
Ingestion
- May cause gastro-intestinal disturbances
- The ingestion of significant quantities may cause diarrhoea
Carcinogenicity
- No evidence of carcinogenic effects

12 Ecological information

12.1 Toxicity
- LC50 (fish) >1000 mg/l (96 hr)
12.2 Persistence and degradability
- The components in this product are readily biodegradable.
12.3 Bioaccumulation Potential
- Bioaccumulation of the components in this product is insignificant.
12.4 Mobility in soil
- Completely soluble in water
12.5 Results of PBT and vPvB assessment
- Not a PBT according to REACH Annex XIII
12.6 Other Adverse Effects
- No environmental problems are expected when the product is used / handled correctly.

13 Disposal considerations

13.1 Waste treatment methods

- Disposal should be in accordance with local, state or national legislation
- Do not discharge into drains or the environment, dispose to an authorised waste collection point
Classification
- EU Waste class: 16-03-05
- EU Waste class: 15-01-10

14 Transport information

14.1 UN Number
- n/a
14.2 UN Proper Shipping Name
- n/a

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14 Transport information (....)

14.3 Transport hazard class(es)

- n/a
14.4 Packing group
- n/a
14.5 Environmental hazards
- On available data, substance is not harmful to the environment
14.6 Special precautions for user
- Not classified as hazardous for transport
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
Other information

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
- This Safety Data Sheet is provided in compliance with The Dangerous Substances Directive
(67/548/EEC)
- Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous substances and
preparations
- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations.
15.2 Chemical Safety Assessment

None

16 Other information

Text of R and S phrase codes used in this safety data sheet:- R22: Harmful if swallowed; R36: Irritating to eyes.
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES

For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice

Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011

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16 Other information (....)

Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480

The most up-to-date version of this MSDS can be found on www.wilhelmsen.com/shipsservice