Surface Chemistry Adsorption 1. Which of the following interface can never be obtained? (@) Liquid-Liquid _(b) Solid-Solid (©) Liquid-Gas (a) Gas-Gas 2. When a chalk stick is dipped in ink, then (a) the coloured pigments in the ink gets absorbed in the chalk (b) the solvent gets adsorbed at the surface of chalk (©) the inside of the chalk will remain as white while the surface will have coloured pigments. (@) the inside of the chalk will have coloured pigments while the surface will remain white. 3. Physical adsorption is appreciable at (@) higher temperature (b) lower temperature (6) at room temperature (a) 100°C. 4, The rate of chemisorption (a) decreases with increase of pressure. (b) is independent of pressure (©) ismaximum at one atmospheric pressure. (d) increases with increase of pressure. 5. Chromatography is a technique based on (@) solubilities of solute (b) adsorption of solute, EXERCISE | (JEE MAIN) (©) chemical adsorption followed by dispersion, (d) differential adsorption of different constituents of a mixture, Which of the following is not a characteristic of chemisorption? (a) Adsorption is irreversible. (b) Adsorption decreases with increase in, temperature, (©) Adsorption is specifi. (4) Adsorption increases with increase in surface area. Which one of the following is not a correct statement? (a) Physical adsorption is reversible in nature. () Physical adsorption involves van der Waals forces (©) Rate of physical adsorption increases with inctease of pressure on the adsorbate, (@) High activation energy is involved in physical adsorption. Which gas will be adsorbed on a solid to greater extent? (a) A gas having non-polar molecules (b) A gas having higher critical temperature. (©) A gas having lowest critical temperature, (@) A gas having higher critical pressure. 13¢3 (elk) |1343 Cel) aa Oz: 9, The nature of bonding forces in adsorption is (a) purely physical like van der Waals force. (b) purely chemical (©) both, physical and chemical always (@) none of these 10, Which one of the following is not applicable to chemisorption? (a) High magnitude of AZT. (b) Occurs at higher temperature (©) Itis reversible. (@) It forms mono layer. 11, Which characteristic of adsorption is wrong? (a) Physical adsorption decreases with increase in temperature (b) Physical adsorption increases with increase in temperature. (©) Physical adsorption is a reversible process. (a) Adsorption is limited only to the surface, 12. Sorption is the term used when (2) only adsorption takes place. (b) only absorption takes place. (©) adsorption and absorption simultaneously, (d) desorption takes place. 13, The volumes of gases H,, CH,, CO, and NH, adsorbed by 1 g of charcoal at 288 K are in the order (a) H, > CH,> CO, > NH, (b) CH,> CO, > NH, >H, (©) CO, >NH,>H,>CH, (d) NH, > CO, > CH, > H, 14, Which plot isthe chemisorption? @) |) adsorption isobar for 1S. 16. W. 18. 19, 20. © Sls @ T In the Freundlich adsorption isotherm, the slope of the straight line graph between log (x/m) and log P for the adsorption of a gas on solid is (@ k (b) log k On @) Un Which one of the following characteristics is not correct for physical adsorption of a gas on solid? (a) Adsorption is reversible. (b) Adsorption temperature. (©) Absorption is spontaneous. (d) Both enthalpy and entropy of adsorption are negative, increases with increase in ‘The enthalpy of adsorption in physisorption lies in the range of (a) (40-400) kW/mot (b) (80-240) ki/mol (©) 20-40) kJ/mol (d) (1-10) kS/mol In physical adsorption, the forces associated are (a) ionic bond (b) covalent bond (©) van der Waals forces (d) all of these How many layers are adsorbed in chemical adsorption? @. @3 (b) 2 (@) Lor more Rate of physisorption increases with (a) decrease in temperature, (b) increase in temperature. (©) decrease in pressure. (@) decrease in surface areaCatalysis a. 22, 23. 24, 25. 26. 27. 28. Which one of the following is not an example of homogeneous catalysis? (a) Formation of SO, in the chamber process. (b) Formation of $0, in the contact process. (©) Hydrolysis of an ester in the presence of acid. (d) Decomposition of KCIO, in the presence of MnO, The decomposition of hydrogen peroxide can be slowed down by the addition of a small amount of acetamide. The latter acts as (a) inhibitor (©) moderator (b) promoter (@) poison Efficiency of the catalyst depends on its (a) molecular mass (b) number of free valencies (©) physical state (d) amount used Which of the following types of metals make the most efficient catalysts? (a) Transition metals (b) Alkali metals, (©) Alkaline earth metals (@) Radioactive metals In the reaction KMn0, + H,SO, + H,C,0, > products, Mn“ ions act as (2) positive catalyst (©) auto catalyst (b) negative catalyst (d) enzyme catalyst In the Haber process of synthesis of NH, (a) Mo acts as a catalyst and Fe as a promoter. (b) Fe acts as a catalyst and Mo as a promoter. (©) Feacts as inhibitor and Mo as a catalyst. (d) Fe acts as promoter and Mo as auto-catalyst. TEL minimizes the knocking effect when mixed with petrol. It acts as, {a) positive catalyst (©) auto-catalyst (b) negative catalyst (d) induced catalyst Platinized asbestos is used as a catalyst in the manufacture of H,SO,. It is an example of (a) homogencous catalyst (b) heterogeneous catalyst (©) auto-catalyst (d) induced catalyst 29. 3. 32. 33. The catalyst used in the manufacture of hydrogen. by Bosch’s process is (a) Fe,0, (©) Fe,0, + Cr,0, () C,0, (ad) Cu Tn the Ostwald’s process for the manufacture of HINO, the catalyst used is (a) Fe © V0; (b) Pt (@ Mo Ina reversible reaction, a catalyst (a) increases the rate of forward reaction only. (b) increases therate of forward reaction to a greater extent than that of the backward reaction. (©) increases the rate of forward reaction and decteases than that of the backward reaction, (@) increases the rate of forward and backward reaction by the same factor. ‘The decomposition of H,0, may be checked by adding a small quantity of phosphoric acid. It is an example of (a) neutralization (b) negative catalysis (c) positive catalysis (@) catalytic poisoning In the manufacture of HSO, by contact process, the presence of As,O, acts as (a) catalytic promoter (©) induced catalyst (b) catalytic poison (d) auto catalyst Air can oxidize sodium sulphate in aqueous solution but cannot do so in the case of sodium arsenite. However, if, air is passed through a solution containing both sodium sulphite and sodium arsenite then both are oxidized. This is an example of (a) positive catalysis (6) induced catalysis (b) negative catalysis (d) auto catalysis ‘A catalyst is a substance which (a) increases the equilibrium concentration of the product (b) changes the equilibrium constant of the reaction, (©) shortens the time to reach equilibrium, (@) supplies energy to the reaction, 13¢3 (elk) |1343 Cel) aa Or: 36. A catalyst (a) increases the free energy change in the (©) The catalyst forms an intermediate with the reactants at the surface. reaction (d) There is no change in the energy of activation, (decreases the free enemy change in the 39, ta the case of autocatasi reaction, (©) does not increase and decreases the free energy (@} reactant catalyses change in the reaction (b) heat produced in the reaction catalyses. (@) can either decrease or increase the free energy (6) product catalyses. change depending on what catalyst we use. (4) solvent catalyses 37, The work of enzymes in living system is 40, Zeolites are used as a catalyst in (a) oxygen transfer: (a) petrochemical industries during cracking. (b) to provide immunity. (b) in the preparation of H1,S0, (6) to catalyse biochemical reactions (6) in the hydrolysis of ester. (@) to provide energy (@) All the above. 38. Which is not correct for heterogeneous catalysis? (2) Thecatalyst decreases the energy of activation, (b) The surface of catalyst plays an important role. Colloids 41, Butter is a colloid formed when (©) the blood reacts and forms a solid which seals (a) liquid fat is dispersed in liquid fat the blood vessel (@) liquid fat is dispersed in water. (8 the blood is eoagulated and thus, the Wood (©) water is dispersed in liquid fat. ‘esse is seale (d) solid fat is dispersed in water. 46, Fe" ions coagulate blood. This shows that blood contains colloidal particles bearing 42. Lyophobie colloids are . \ wt (@) negative charge. (wero (© she oi () postive charge 8 8 (c) no charge. 43. Sulphur sol contains (d) either positive or negative charge. G) discrete sulphur atoms 47, Gold number is a measure of (b) discrete sulphur molecules ‘h vot sald present in the vtloidal (0) water disposed in solid slp () he amount of gold present in the oto (d) large aggregates of sulphur molecules (b) the amount of gold required to break the 44, When fieshly precipitated Fe(OH), is boiled with colloid water in the presence of few drops of dil. HCl, a (c) the amount of gold required to protect the hydrated ferric oxide sol is obtained. The method colloid is termed as (a) the protective power of lyophilic colloid a) electro dispersion _(b) peptization © - © pert 48, On addition of one ml solution of 10% NaCl to (©) ultra filtration (@) dialysis 45. Bleeding is stopped by the application of ferric chloride. This is because (a) the blood starts flowing in opposite direction. (b) the fertic chloride seals the blood vessel. 10 ml red gold sol in the presence of 0.0025 g of starch, the coagulation is just prevented. The gold, umber of starch is (a) 25 (©) 0.25 (b) 2.5 (@) 0,02549. 50. si. 52. 53. 54. 58. 56. All colloidal solution shows {a) very high osmotic pressure (b) high osmotic pressure (c) low osmotic pressure (@) no osmotic pressure ‘The gold numbers of A, B, Cand D are 0.04, 0.002, 10 and 25, respectively. The protective powers of A,B, Cand D, respectively, are in the order (@) A>B>C>D (b) B>ASCoD (c) D>C>B>A (d) C>A>B>D ‘The charge of As,S, sol is due to the absorbed (@) He () OF oF @ The movement of dispersion medium in an electric field when the dispersed particles are prevented from moving is called (a) cataphoresis, (b) electrophoresis (©) electro-osmosis (@) brownian movement ‘To coagulate gelatin sol, which of the following is most effective? (a) NaCl (9 AlCl, (b) Na,PO, (d) Alcohol ‘The potential difference between the fixed charged layer and the diffused layer having opposite charge is called (a) colloidal potential (b) zeta potential (0) electrostatic potential (@) electrode potential An examples of micelle is (a) As,0, solution (b) ruby glass (©) Na,CO, solution (@) concentrated sodium stearate solution ‘A freshly prepared Fe(OH), precipitate is peptized by adding FeC!, solution. The charge on the colloidal particle is due to preferential absorption of (a) Crions (©) OH ions (b) Fe"** ions (d) Hions 57. 59. al. a. 63. 64 Hardy-Schulze rule state that (a) non-clectrolytes have better coagulating action on colloids than electrolytes. (b) sols are coagulated by effective ions whose charge is opposite to that of sol and the ions of higher charge are much more effective than the ions of lower charge. (©) charge of the ions has no effect on the coagulation of a sol. (@) sols are coagulated only by those ions whose charge is similar to that of the sol. Among the following, which is the correct statement about milk? (a) Milk is an emulsion of liquid fat in water. (b) Milk in the emulsion of protein in water. (©) Milk is stabilized by protein. (a) Milk is stabilized by fat Colloidal particles carry charge. This can be shown by which of the following effect? (a) Tyndall effect (b) Electrophoresis (© Brownian movement (4) Dialysis Which of the following is most effective in causing the coagulation of ferric hydroxide sol? (a) KCl (b) KNO, (© K,So, (4) K,Fe(CN), On adding AgNO, solution into KI solution, a negatively charged colloidal sol is obtained when they are in (a) 100 ml of 0.1 M AgNO, + 100 ml of 0.1 M KI (b) 100 ml of 0.1 M AgNO, + 50 ml of 0.2 M KI (©) 100 ml of 0.1 M AgNO, + 50 ml of 0.1 M KI (A) 100ml of 0.1 M AgNO, + 100ml of 0.15 MKI Substances whose solutions can readily diffuse through animal membranes are called (a) colloids (b) crystalloids (©) electrolytes (@) non-clectrolytes ‘The size of the colloidal particles is in between (@) 17% and 10-%em_——(b) 10 and 10" em (©) 104 and 107 em (@) 107 and 107 cm If dispersed phase is liquid and the dispersion medium is solid, the colloid is known as (a) sol (©) gel (©) emulsion (@) foam 13¢3 (elk) |1343 Cel) aa Oz: 65. 66. or. 68 69. 70. n. 2. An emulsion is a colloidal solution consisting of 73. a) two solids. (b) two liquids, (0) two gases. (@) one solid and one liquid. Peptization is a process of 7. (a) precipitating the colloidal particles. (b) purifying the colloidal sol (6) dispersing the precipitate into colloidal sol (4) movement of colloidal particles towards the opposite charged electrodes 75. Colloids are purified by (a) Brownian motion __(b) precipitation (c) dialysis (@) filtration 76. ‘Which of the following substance gives a positively charged sol? (a) Gold (b) Arsenious sulphide (0) Starch 77. (@) Ferric hydroxide Blood may be purified by (a) dialysis (b) electro-osmosis 7 (©) coagulation (@) filtration ‘Tanning of leather is (a) colouring of leather by chemicals. (b) drying process to make the leather hard 79. (©) polishing of leather to make it look attractive (d) coagulative hardening of the leather by chemicals. Surface tension of lyophilic sol is, (a) lower than that of dispersion medium, (b) more than that of dispersion medium. (©) equal than that of dispersion medium, (@) any of these, depending on the dispersion medium, ‘Which of the following forms a colloidal solution in water? (a) Nacl (©) Starch (b) Glucose (@) Barium nitrate When dilute aqueous solution of AgNO, (excess) is added to KI solution, positively charged sol particles of Agl are formed due to the adsorption of which of the following ion? (@) K’ (b) Ag’ or (a) NO> Which one of the following substances is not used for preparing lyophilic sols? (a) Metal sulphide (b) Gum (c) Gelatin (d) Starch Which of the following is not a colloidal system? (b) Muddy water (d) Bread (a) Sugar in water (©) Conerete ‘Tyndall effect in colloidal solution is due to (a) absorption of light (b) scattering of light (6) reflection of light. (4) presence of electrically charged particles. Which of the following substances will have least CMC value? (a) CyCOOK (©) CyH,,NH,C1 (b) CyHyySO,Na (@) C,Hy;COONa In the styrene foam, the dispersed phase and dispersion medium are, respectively, (a) gas, gas (b) gas, solid (©) solid, solid (4) liquid, solid What happens when a lyophilic sol is added to a lyophobie sol? (a) Lyophilic sol gets protected by the lyophobie sol. (b) Lyophobic sol is coagulated (©) Lyophilic sol is coagulated. (a) Lyophobie sol is protected by the lyophobic sol. Lyophilic sols are more stable than lyophobic sols because (a) the colloidal particles have positive charge. (b) the colloidal particles have no charge. (©) the colloidal particles are highly solvated. (d) there are strong electrostatic repulsions between the charged colloidal particles,Section A (Only one Correct) 1 Which among the following statements is false? {a) Increase in pressure increases the amount of adsorption. (b) Increase in temperature may decrease the mount of adsorption, ‘he adsorption may be monolayered or multilayered, (d) Particle size of the adsorbent will not affect the amount of adsorption. © Adsorption of gases on solid surface is exothermic because (a) chemical bonds are always formed, (b) adsorbate decreases the surface energy of adsorbent. (©) entropy increases. (d) free energy increases Graph between log. ( Jase log Pisa straight line at an angle 45° with intercept on y-axis, 0.3010. ‘The amount (in g) of the gas absorbed per g of the adsorbent when pressure is 0.2 atm is (assume that the adsorption obey Freundlich isotherm) (a) 04 (b) 0.6 © 08 (a) 02 Desorption of a gas from metal surface follows first- order kinetics, The rate constant of desorption can be given by Arthenius equation. If the desorption of hydrogen on manganese is found to increases 10 times on increasing the temperature from 600 to1000, K, the activation energy of desorption is (In 10=2.3) (a) 6.0 kcal/mol (b) 6.9 kcal/mol (©) 3.0 keal/mol (@) $7.4 kcal/mol According to Freundlich adsorption isotherm, which of the following is correct? (a) X= pie wA—P @ ~=P (@) All the above are correct for different ranges of pressure. EXERCISE II (JEE ADVANCED) 6. At 70 K, the adsorption of N,(g) at iron surface obeys Freundlich adsorption isotherm. ‘The following data is collected experimentally Pi 4 Ey a Zon oss Here, ~ is the mass (in g) of N,(g) adsorbed per g of iron at P bar pressure, The moles of N,(e) adsorbed per g iron at 36 bar and 70 K is 6 3 OF © i 3 3 O5 © so 7. The following information is available for the reaction RP. rate=r rale=r rale=ry rale= rate =r rale = 75 rate If ry (a) Snclyer (©) SnCl/H™ (b) SnClyo"" (@ Snciysn* When some special substances such as protein particles, blood corpuscles, ete., are separated by a permeable membrane. The process is called (b) ditfusion (@) endosmosis (a) dialysis (©) exosmosis21. 22. 23. 24. 25, 26. The simplest way to check whether a system is colloidal is by which of the following method? (a) Tyndall effect (b) Brownian movement (©) Electrodialysis (@) Finding out particle size Which one of the following colloidal solution is positive sol? {a) Blood (b) Clay sol (©) Smoke (a) Gelatin in strongly acidic solution ‘When a lyophobic colloidal solution is observed in ‘Tyndall effect, we can see (a) the size of colloidal particles (b) the light scattered by colloidal particles, (©) the shape of colloidal particles. (@) the size of particles of dispersion medium, Identify the statement which is correct with respect to surface phenomenon, (a) Osmotic pressure of rubber sol will be same as that of sucrose solution having same mass mixed in the same mass of water (b) A gas may show physisorption at low temperature and chemisorption at high temperature (©) Soap sol of sodium palmitate will coagulate near cathode in electrophoresis. (4) Gold sol on mixing with starch sol causes stabilization of starch sol. Which of the following reaction is not used in the preparation of colloidal solution? (a) 2H,S + $0, + 38 +2H,0 (b) 2Mg + CO, > 2Mgo+C (©) FeCl, + 3H,0 > Fe(OH), + 3HCI (d) 2AuCI, + 38nCl, > 2Au+ 381, ‘A quantity of 1.9 x 10 g of the metal having density 19 g/ml is dispersed in 1 L of water to give a sol having spherical metal particles of radius 10 nm. The approximate number of metal sol particles per cm’ of the sol is 27. 29. (b) 4x10” (@) 28x10? (@) 2.39 x 10” (© 19x10 Among the following, the surfactant that will form micelles in aqueous solution at the lowest molar concentration at ambient conditions is (a) CHy(CH,),.N'(CH,),Br” (b) CHCHL),,080,-Na* (€) CHy(CH,),COO"Na* (a) CH,(CH,),N"(CH,)3Br- Among the electrolytes Na,S0,, CaCl, Al(SO,), and NH,Cl, the most effective coagulating agent for Sb,S, is (a) Na,SO, (©) Al(S0), (b) Cac, (@) NHC. Methylene blue, from its aqueous solution, is adsorbed on activated charcoal at 25°C, For this process, which of the following statement is correct? (a) The adsorption requires activation at 25°C. (b) The adsorption is accompanied by a decrease in enthalpy. (©) The adsorption increases with increase in temperature, (d) The adsorption is irreversible Match the columns. Column T Column I (P) Scattering of light (Q) Purification of colloidal solution (®) Addition of an lectrolyte (S) Precipitation of colloidal solution ( Coagulation (2) Peptization (3) Tyndall effect (4) Dialysis 1234 @P QRS Ss RP Q ORSQP @QRPS 134 ely a)EXERCISE II Qn: Section B (One or More than one Correct) L 2 5. ‘Which of the following statement(s) is/are correct 6. regarding adsorption? (a) Activated adsorption is highly specific. (b) van der Waals adsorption is reversible. (©) Adsorption is always exothermic. (d) Adsorption is an iso-entropic process. Adsorption is accompanied by (a) decrease in entropy of the system. (b) dectease in enthalpy of the system, (©) decrease in free energy of the system. (d) decrease in surface energy of adsorbent. 2 On increasing temperature at constant pressure, the amount of gas adsorbed at the surface per unit mass of adsorbent (a) decreases in case of physisorption. (b) decreases in case of chemisorption. (©) increases in case of chemisorption. (d) increases in case of physisorption, Which of the following statement(s) regarding adsorption is/are not correct? (a) Surface particles of adsorbent are not in the same environment as the particles inside the bulk. 9. (b) During adsoxption, there is always decrease in the residual forces on the surface. (©) At equilibrium in adsorption, the values of AlTand AS become equal. (a) The extent of adsorption increases with increase in surface area per unit mass of adsorbent. Which of the following statement(s) incorrect regarding activated adsorption? is/are (@) Its extent increases with increase in pressure and it may change to multilayer adsorption at high pressure, (b) Its extent with decrease in temperature and it may change to multilayer adsorption at low temperature (©) Its extent increases with increase in surface area of adsorbent (d) When oxygen is adsorbed at graphite surface, none of the gas leaves the surface on strong heating. 10, Which of the following statement is correct with regard to adsorption of a gas on solid surface? (a) Adsorption is always exothermic, (b) Physisorption may transform into chemisorption at high temperature. (©) Physisorption increases with increasing temperature but chemisorption decreases with increasing temperature. (@) Chemisorption is more exothermic than physisorption however, itis relatively slow due to higher energy of activation, Zeolites (a) are microporous aluminosilicates. (b) have the general formula M,,,(AlO,), SiO, ‘mH1,0 (©) have pore sizes between 260 pm to 740 pm. (4) acts as shape-selective catalyst. Which of the following acts as negative catalyst? (a) Tetraethyl lead as antiknock compound. (b) Glycerol in decomposition of H,0;. (6) Ethanol in the oxidation of chloroform. (@) Lindlar’s catalyst According to adsorption theory of catalysis, the reaction rate increases, because (a) adsorption produces heat which increases the rate of reaction (b) in the process of adsorption, the kinetic energy of the molecules increases. (©) the concentration of reactants at the active centres becomes high due to adsorption. (@) the activation energy of the reaction becomes high due to adsorption. Identify the incorrect following. (a) On changing the catalyst in a heterogeneous catalysis, the product of reaction may change. (b) Enzyme catalysed reactions are elementary (single step) reactions (©) Lactobacilli enzyme is responsible for the conversion of milk into curd. (@) A catalytic promoter may increase the reaction rate even in the absence of catalyst. statement(s) from theuu. 2. 1B. 14. Which of the following option(s) is/are correct regarding catalytic activity? {a) Conversion of proteins into amino acids by hydrolysis in intestine is catalysed by the enzyme pancreatic trypsin. (b) In case of fever, the activity of biochemical catalyst gets adversely affected. (©) In heterogeneous catalysis, the reactants must get adsorbed reasonably strong on the catalyst surface but not so strongly that desorption of product becomes impossible. (d) In the decomposition of methyl urea, enzyme urease acts as a catalyst. Enzymes are highly efficient catalyst. An enzyme ‘catalase’ increases the rate of decomposition of H,0,(aq) into HO0() and 0,(g) e”” times at 300 K. The activation energy of enzyme catalysed reaction is 2.0 kcal/mol. Which of the following information(s) is/are correct assuming that the value of pre-exponential factor is unaifected by temperature change or use of catalyst and the activation energy is independent of temperature. (a) The activation energy of uncatalysed reaction is 140 keal/mol, (b) Uncatalysed reaction is an elementary (single step) reaction. (©) Catalysed reaction is a complex (multi step) reaction. (@) On increasing the temperature, the ratio of rates of catalysed and uncatalysed reactions becomes Jess thane” During electro-osmosis of Fe(OH); sol, (a) sol particles move towards anode. (b) sol particles move towards cathode, (©) the dispersion medium move towards anode. (d) the sol particles do not move in either direction, Colloidal particles in a sol can be coagulated by (a) heating. (b) addition of electrolyte (©) addition of oppositely charged sol. (d) addition of dispersion medium. 15. 16. 11, 18. The nature of electric charge on colloidal particles can be experimentally determined by which of the following process? (a) Brownian movement (©) Electro-osmosis (b) Electrophoresis (@) Ultramicroscope Identify the statement(s) which is/are not correct with respect to the surface phenomenon, (a) If on adding electrolyte in an emulsion, the conductivity decreases, then it will be oil in water type enmulsion, (b) Tyndall effect is observed when the refractive indices of the dispersed phase and dispersion medium differ largely. (©) Macromolecular colloids are Iyophobic in nature, (A) Gases which can react with the adsorbents generally show chemisorption. generally Select the correct statement(s) from the following, (a) If the critical micelle concentration (CMC) of a soap is 10° M, then 10~' M solution of this soap will have colloidal nature. (b) Charge on the colloidal particles may be determined with the help of dialysis. (©) Peptization is the process of conversion of a colloidal sol into precipitate by adding some electrolyte. (a) When some oil-soluble dye is added in the water in oil emulsion, the background becomes coloured. For the coagulation of a particular colloidal solution, the order of coagulation power of some electrolytes is in the order Na,PO, > BaSO, > AICly, Which of the following information(s) may be correct for such colloid? (a) In clectro-osmosis, the dispersion medium move towards the anode, (b) Diffused layer around colloidal particles in the electric double layer mostly contains negatively charged particles. (©) It may be basic dye such as methylene blue. (@) It may be metal sol. 134 ely a)EXERCISE II QE: 19. 20. 21 The following experimental data is obtained for the osmotic pressure of the solution by adding different moles of Cy;HyCOONa in sufficient water to get 1.0 L solution in each case. Moles of ‘ CyfyCOONa © POF 907008 O04 FF em — 9 002 004 0.058 0.075 litre) Select the correct information(s) regarding the nature of solution (a) At0.02 M concentration, the solution behaves as true solution. (b) At 0.04 M concentration, the solution behaves as colloidal solution, (©) The critical micelle concentration (CMC) of CyJHysCOONa is in between 0.02 M and 0.03 M. (d) At 0.05 M_ concentration, of CyHyCOONa and water homogeneous. the mixture will be Select the incorrect statement related to colloids. (a) Muddy water can be coagulated more effectively by alums as compared to NaCl. (b) Surface tension of lyophilic colloids is less than that of dispersion medium, (©) When excess of AgNO, is added in aqueous KI solution and the sol is subjected to electrophoresis, coagulation occurs near the anode, (@) Cloud bursting in atmosphere occurs due to large amount of water present in the cloud, ‘Which of the following statement is incorrect? (a) The conductivity of a soap solution decreases sharply at CMC (b) Tyndall etfect is more effective in gold sol in comparison to the rubber sol. (©) The elevation in boiling point of an alcoholic solution of sulphur is less than that of its sol in water if mass of sulphur present per unit volume of mixture is same in both cases, (d) CMC value of CH,(CH,),NH,CI will be less than that of CH,(CH,),COONa. 2. 25. Which of the following statement is correct? (a) Potassium ferrocyanide can cause greater coagulation in a basic dye as compared to Na, HPO, (b) A starch aquasol can act as protective colloid for Fe(OH), sol (©) The slope of the Freundlich adsorption isotherm (log~ vs log?) keeps on changing m for a long range of pressure and is constant over a limited range of pressure. (4) Higher the zeta potential, greater is the stability of colloid. Which of the following will show Tyndall effect? (a) Aqueous solution of sodium stearate above critical micelle concentration (CMC). (b) Aqueous solution of sodium stearate below critical micelle concentration (CMC). (6) Aqueous solution of sodium stearate above Krafft temperature (d) Aqueous solution of sugar. Choose the correct reason(s) for the stability of the lyophobic colloidal particles (a) Preferential adsorption of ions on their surface from the solution. (b) Preferential adsorption of solvent on their surface from the solution, (©) Attraction between different particles having opposite charges on their surface. (@) Potential difference between the fixed layer and the diffused layer of opposite charges around the colloidal particles. The dispersed phase in colloidal iron(II) hydroxide and colloidal gold is positively and negatively charged, respectively. Which of the following statement(s) is/are not correct? (a) Magnesium chloride solution coagulates the gold sol more readily than the iron(II) hydroxide sol, (b) Sodium sulphate solution causes coagulation in both sols, (©) Mixing of the sols has no effect (@ Coagulation in both sols can be brought about by electrophoresis,Section C (Comprehensions) Comprehension 1 ‘Whenever a mixture of gases is allowed to come in contact with a particular adsorbent under the same conditions, the rela- tively stronger adsorbate is adsorbed to greater extent irrespective ofits amount present. For example, H,0 is adsorbed on silica gel to greater extent than N, or O,, This shows that some adsorbates are preferentially adsorbed. It is also observed that the preferentially adsorbable adsorbents can displace a weakly adsorbable adsorbate from the surface of an adsorbent. 1. Which of the following gas is adsorbable to the ‘maximum extent? (a) He (b) Ne (© Ar (a) Xe 2, Which of the following gas can displace all the remaining gases? fa) 0; @ co 3. When the temperature is increased, (a) the extent of adsorption increases. (b) the extent of adsorption decreases. (©) the extent of adsorption remains unchanged (d) the extent of adsorption first decreases and then increases. © N, @ H, Comprehension I A chemist was studying the phenomenon of adsorption by placing blood charcoal in KCI solution. HelShe observed the difference in behaviour with dilute KCI solution and with concentrated KCI solution. He/She also made a detailed study of the adsorption of gases on solid adsorbents. He/She observed that at the same temperature, dif- ferent amounts of gases, like NH, SO,, CO;, HCI were adsorbed by the same amount of the adsorbent. He/She further studied the effect of temperature on adsorption and observed that in some cases, adsorption showed a regular trend while in some other cases, the trend was not regular. 4, Which of the following result, the chemist must §. The correct order of adsorption of gases studied have observed about his studies with KCI solution? {a) Dilute KCl solution shows no adsorption, whereas concentrated KCI solution shows adsorption. (b) Concentrated KCI solution shows no adsorption, whereas dilute KCI solution shows adsorption (©) Dilute KCI solution shows positive adsorption, whereas concentrated KCI shows negative adsorption (@) Concentrated KCI shows positive adsorptio: whereas dilute KCI shows negative adsorption. will be (a) NH, > SO, > CO,> HCL (b) CO, > SO, > NH, > HCI (@) SO, > NH, > HC1> CO, (d) HC1> $0, > NH, > 6. Which of the following is correct? (a) Adsorption is always exothermic. (b) Adsorption is always endothermic, (©) Physical adsorption is endothermic, whereas chemical adsorption is exothermic. (d) Chemical adsorption is endothermic, whereas physical adsorption is exothermic, Comprehension III Specific surface area of a solid adsorbent is the surface area of the unit mass of the adsorbent. For any adsorbent, the specific surface area may be increased by taking the adsorbent in powdered form or by increasing the pores in the solid. 7. If the unit mass of a solid taken as a cube of volume 8 em® is powdered into identical 10"? cubes, then the specific surface area of the solid increases by (a) 10 times (©) 10 times (b) 10° times (@) 10° times 134 ely a)EXERCISE II Dow A volume of 112 em’ hydrogen gas is adsorbed uniformly at the surface of 5 g palladium at 273°C (a) 12% 10" em’ig (b) 6.0 10" em'/g and 2 atm. If the effective surface area of each hydrogen molecule is 0.4 nm’, then the specific surface area of palladium is (Nj, = 6 x 109) (o) 2.4% 108 om/g (@) 6x10 emg Comprehension IV ‘The adsorption of a gas at a metal surface is called occlusion. The extent of gas adsorbed at metal surface at a certain temperature depends on the pressure as x gp ‘here K and n are constants for a particular combination of gas and metal at fixed temperature and ~ is the mass of ‘gas adsorbed per unit mass of metal. For hydrogen gas at platinum surface, the following graph is obtained. Jogi (2) Gand = 0.25 rr logipP(/atm) 9. The correct values of “K’ and ‘n’ are, respectively, (2) 200g ) 408 (a) 1.0, 0.25 (b) 10.0, 4.0 (©) 20g (d) 4g (©) 10.0, 0.25 (@) 0.10,40 11, The pressure at which 810 g of hydrogen gas will adsorb on the surface of 1.0 g platinum is (a) 2atm (b) 9atm (© 3atm (a) 4atm 10. The mass of hydrogen gas adsorbed on the surface of 10g platinum at 16 atm is Comprehension V ‘The clouds consist of charged particles of water dispersed in air. Some of them are 4vely charged and some are —vely charged. When 4vely charged clouds come closer, they cause lightening and thundering, whereas when 4vely and —vely charged clouds come closer, they cause heavy rain by aggregation of minute particles. It is possible to cause artificial rain by throwing electrified sand or silver iodide from an aeroplane and thus coagulating the mist hanging in air. 12, When excess of AgNO, is treated with KI solution, 14, Smoke screens consist of Agl forms (@) fine particles of TiO, dispersed in air by (a) positively charged sol aeroplane. (b) negatively charged sol (b) fine particles of Agl dispersed in air by (©) neutral sol aeroplane. (d) true solution (©) fine particles of AlLOs dispersed in air by aeroplane. 13. Agl helps in artificial rain because (@ fine particles of carbon dispersed in air by {a) it helps in condensation process aeroplane. (@) it helps in dispersion process (o) it helps in coagulation (@) allof these‘The charge on colloidal particle is due to the selective adsorption of ions present in the dispersion medium. The adsorbed ion on the colloidal particles is responsible for the development of electric charge. For example, the selective adsorption of H' ions lead to the development of positive charge on the colloidal particles and the selective adsorption of OH- ions lead to the development of negative charge on the colloidal particles. ‘Comprehension VI 15. A colloidal solution of ferric hydroxide sol is 17. Which of the following ion forms primary prepared by the hydrolysis of FeCl,, The colloidal electrical double layer on the colloidal particle of patticles of ferric hydroxide is AsS.? (a) positively charged (a) As* (b) S (b) negatively charged © (@ o- (©) neutral (d) none of these 16, The colloidal solution of AgNO, in Agl can be represented as (a) Ag Ag’. (b) Agl, Ag’, NO- (© Ag’NOy,Agl — () AgNO, Ag’, Comprehension VII ‘The protective power of the Iyophilic colloids is expressed in terms of gold number, a term introduced by Zsigmondy. Gold number is the number of milligrams of the protective colloid which prevents the coagulation of 10 ml of red gold sol, when 1 ml of a 10% solution of sodium chloride is added to it. Thus, smaller the gold number of the lyophilic colloid, the greater is its protective power. 18. On addition of 1 ml of 10% solution of NaCl to 20. Which of the following statements is true? 10 mil red gold sol in the presence of 0.025 g of the starch, the coagulation is just prevented. The gold number of starch is (a) Lower the gold number, more will be its protective power (b) Higher the gold number, more will be its (@) 0.025 () 0.25 protective power © 25 (a) 25 (6) Higher the coagulation value, more will be its coagulation power (@) Higher the coagulation value, less will be its coagulating power 19, Gold number gives an indication of (a) protective nature of colloid. (b) purity of gold in suspension. (©) charge on a colloidal solution of gold. (4) mole of gold per litre of colloidal solution. Section D (Assertion - Reason) The following questions consist of two statements. (4) _If Statement I is INCORRECT, but Statement I Mark the answer as follows. is CORRECT. (a) If both statements are CORRECT, and Statement 1, Statement I: When a finely divided active carbon Tis the CORRECT explanation of Statement I. or clay is stirred into a dilute solution of dye, the (b) If both statements are CORRECT, and Statement intensity of colour in the solution is decreased. Hl is NOT the CORRECT explanation of ‘Statement II: The dye is adsorbed on the solid Statement I surface, (©) If Statement I is CORRECT, but Statement I is INCORRECT, 134 ely a)EXERCISE II @r: 2 10, Statement I: The particles at the surface of solid have higher average energy than the particles in the bulk of solid, Statement I: Due to adsorption, the surface energy of solid decreases, Statement I: Adsorption always decreases with increase in temperature, Statement dependent. Tl: Adsorption is _ temperature Statement I: For adsorption, AG, AS and AH, all have negative values, Statement I: Adsorption is a spontaneous exothermic process in which randomness decreases due to force of attraction between adsorbent and adsorbate, Statement I: A gas with higher critical temperature gets adsorbed to more extent than a gas with lower critical temperature. Statement I: The easily liquefiable gases get adsorbed to greater extent. Statement I: A catalyst provides an alternative path to the reaction in which conversion of reactants into products takes place quickly Statement II: The catalyst forms an activated complex of lower potential energy than the uncatalysed reaction, due to which more number of molecules become able to cross the energy barrier per unit time. Statement I: Lyophilic colloids are known as reversible sols Statement II: Lyophilic sols are liquid loving, Statement I: Addition of small amount of AgNO, to excess of KI solution gives negative sol, whereas addition of small amount of KI to excess of AgNO, solution gives positive sol of Agi Statement Il: The sol particles adsorb the common ions present in solution and acquire their charge. Statement I: Sol particles show Tyndall effect. Statement II: The scattering of light ocours due to suitable size of sol particles, Statement I: The micelle formed by sodium stearate in water has COO” groups at the surface. Statement II: Surface tension of water is reduced by the addition of stearate, u 2 13. 14. 1s, 16, 17. 18. 19. 20. Statement I: A colloidal solution of cellulose nitrate in water cannot be prepared directly. Statement I: Lyophilic sols can be prepared directly by mixing the substance with the dispersion medium. Statement I: Colloidal sols scatter light while true solutions do not Statement I: The particles in the colloidal sol move much slower than that of the true solution. Statement I: Colloidal solution is electrically neutral, Statement I: Due to similar nature of the charge carried by the particles of dispersed phase in Iyophobic colloids, they repel each other and do not combine to form bigger particles Statement I: Isoelectric point is pH at which colloids can move towards either of electrode Statement II: At isoelectric point, particles become electrically neutral colloidal Statement I: When AgNO, is added in excess of KI, colloidal particles gets attracted towards anode in electrophoresis Statement II: Colloidal particles adsorb common ions (excess) and thus become charged. Statement I: A colloid gets coagulated by addition of an clectrolyte Statement I: The rate of coagulation depends on the magnitude and sign of the charge of the coagulant ion, Statement I: Fe* can be used for coagulation of ‘As,S, so ‘Statement II: Fe** reacts with As,S; to give Fe,S,. Statement I: The conversion of fresh precipitate to colloidal state is called peptization. Statement II: It is caused by addition of common ions, which neutralizes the charge on colloidal particles Statement I: Proteins, starch and rubber are Iyophilic colloids. Statement I: They have strong interaction with the dispersion medium, Statement I: Micelles are formed by surfactant molecules above the critical micellar concentration (CMO). Statement I: The conductivity of a solution having surfactant molecules decreases sharply at the CMCSection E (Column Match) 1. Match the columns Column Colma Column I (Colloidal Dispersed Dispersion solution) phase) medium) (A) Colloidion — (P) Water (U) Ethanol (B) Fog (Q) Cellulose (V) Oil (© Buter ——@) Fat OW) Air ©) Milk (X) Water 2. Match the columns, ‘Column (A) Cottrell precipitation (B) Electrophoresis (Q) Precipitation of colloidal particles by addition of electrolytes. (%) Removal of pollutants from industrial waste gases (S) Movement of charged colloidal particles towards oppositely charged electrode (©) Hemodialysis (D) Coagulation ‘Match the columns. ‘Column I Column I (A) Removal of water by (P) Absorption silica gel (B) Removal of water by anhydrous CaCl. (© Surface phenomena (@ Adsorption (®) Evaporation of liquid. (D) Bulk phenomena (8) Boiling of liqu ‘Match the columns. ‘Column I Column I (Reaction) (Suitable enzyme catalyst) (A) Starch > Maltose (@) Urease (B) Sucrose > Glucose + Fructose (©) Urea + Ammonia + CO, (Q) Diastase (R) Zymase (D) Giucose + Ethanol + CO, _(S) Invertase Section F (Subjective) Single-digit Integer Type 1, Molecular formula of starch can be represented as (COs), If the gold number of one such starch is 6.48 and 0.01 millimoles of this starch is required to be added in 10 ml of ted gold so] to just prevent coagulation by adding 1 ml of 10% sodium chloride solution, then the value of nis 2. Adsorption of hydrogen gas over palladium surface obey Freundlich’s adsorption isotherm as shown in the graph. The mass (in g) of hydrogen gas adsorbed on the surface of 1.0 g palladium at a pressure of 8.1 x 10" atm is logioP ‘The desorption of gas molecules from the adsorbent surface obeys Arrhenius equation. The average time (in sec) up to which a N, molecule may remain adsorbed at Pt-surface at 400 K is (Asthenius parameters for desorption are: 4 = 1.25 108s, B, = 16 keal/mol; o*” = 5 x 10°) 134 ely a)EXERCISE II @r: 4, Among the following colloids, the number of colloids having negatively charged colloidal particles is: Soap solution of sodium palmitate, sol of AgCl obtained on dissolving excess AgNO, into KCI solution, gold sol, Fe(OH), sol, silicic acid sol, basic dye, acidic dye, metal sulphide sol, sol of AgCl obtained by dissolving excess KCI in AgNO, solution 5. Nitrogen gas adsorbed on charcoal to the extent of 0.387 cm'vg at a pressure of 1.6 atm and at temperature of 200 K, but at 250 K the same amount of adsorption was achieved only when the pressure was increased to 32 atm. The magnitude of molar enthalpy of adsorption (in kcal/mol) of nitrogen on charcoal is (In 20 = 3.0) 6. A quantity of 1.0 g of charcoal adsorbs 100 ml 0.8 M CH,COOH to form a monolayer, and thereby the molarity of CH,COOH reduces to 0.49 M, The surface area (in 107? m’) of the charcoal adsorbed by each molecule of acetic acid is (Surface area of charcoal = 3,0 10? m’/g) (Nj = 6 x 10"), 10, Twenty per cent of surface sites are occupied by Nj molecules, The density of surface site is 6.023 x 10! cm” and the total surface area is 1000 cm’, The catalyst is heated to 300 K while N, is completely desorbed into a pressure of 0.001 atm. and volume of 2.46 cm’. The number of active sites occupied by cach N, molecule is A monolayer of N, molecules (eifective area 0.15 nv’) is absorbed on the surface of 1.00 g of Fel ‘ALO, catalyst at 77K, the boiling point of liquid nitrogen, Upon warming, the nitrogen occupies 2.24 em’ at 0°C and 760 tort. The surface area of catalyst (in m’) is (Avogadro's number Ny = 6x10”) ‘The minimum number of phases in a colloidal system is ‘The chemisorption of hydrogen on manganese is activated, but only weakly, so careful measurements, have shown that it proceeds 20 times faster at 1000 K than at 600 K. The activation energy for chemisorption (in kcal/mol) is (e* = 20) Four-digit Integer Type 1. A volume of 585 ml of 1%(wiw) NaCl solution of density 1.2 giml is required for complete coagulation of 200 ml of a gold sol in two hours. ‘The coagulation value of NaCl (in millimole/L) is 2. A solution of palmitic acid (Molar mass = 256 mol) in benzene contains 5.12 g of acid per dm When this solution is dropped on a water surface the benzene evaporates and the palmitic acid forms a monomolecular film of the solid type. If we wish to cover an area of 480 cm? with a monolayer, then what volume (in mm’) of palmitic acid solution should be used? The area covered by one palmitic acid molecule may be taken to be 0.2 nm’, (N = 6x10) 2 3. A volume of 74cm" hydrogen gas (measured at 7 0°C and | atm) forms a uniform monolayer at 25 g 5 0.16 copper. The density of liquid hydrogen is —" gf om’. The specific surface area of copper (in m’/g) is(Nq=6x 10) 4, The average time for which an oxygen atom remains adsorbed to a tungsten surface is 0.36 s at 2500 K and 0.72 s at 2000 K. The activation energy for desorption (in keal/mol) is (In 2 = 0.7) The activation energy for the desorption of hydrogen gas from iron and charcoal surfaces are 8.0 and 20.0 kcal/mol, respectively. Assume that the pre-exponential factor have the same value of 10" 5" in both and the ratio of half-lives of hydrogen molecules at the iron and charcoal surfaces is 1:e* at 327°C, the value of x is Tt was found that 0.10 mg of an adsorbate covered 0,06 m* of a solid surface. If the molar mass of the adsorbate is 0.25 kg/mol, then the effective area of each adsorbate molecule (in 10" m°) is (Ng=6.0% 10"), ‘A sample of charcoal weighing 6.00 g was brought into contact with a gas contained in a vessel of 1.52 litre capacity at 27°C. The pressure of the gas was found to fall from 700 to 400 mm of Hg. The volume of the gas in ml) reduced to 0°C and | atm that is adsorbed per gram of adsorbent under the experimental condition is (neglect the volume of the solid)8 AtO°C and | atm pressure, the volume of nitrogen gas required to cover asampleof silica gel, assuming Langmuir monolayer adsorption is found to be 168 com'/g of the gel. The surface area (in m’) per gram of silica gel is (the area occupied by each nitrogen molecule is 0.16 nm’) (Nq~ 6% 10°) 9 ‘The AH of adsorption at constant amount of vapour adsorbed is called the isosteric enthalpy of adsorption Agi. The adsorption of N, on charcoal amounted to 0.894 cm’ (STP)/g at (0.4 atm and 200 K) and (at 59.2 atm and TK). If Apff = -16.628 ki/mol, then the value of Tis (in 148 = 5) 10, The mechanism of enzyme catalysed reaction is given by Michaelis and Menten as follows. Step L E+S == ES (Fast) Step Il: ES 2 P+ E (Slow) The rate of product formation may be given as HP, KREIS store [By is the total ad K,+K,+K IS) enzyme concentration, For an enzyme-substrate system obeying simple Michaelis and Menten mechanism, the rate of product formation when the substrate concentration is very large has the limiting value 0.02 Ms", At a substrate concentration of 250 mg/dm’, the rate is half this value. The value of Ky/K.; (in dm'kg) assuming that Ky<P,V;D5R,X 2. ASR:BSS;C>P;D+Q 3. AVQBOP;CIQRDIPS 4, A3Q:B9S;C>P:DOR Section F (Subjective) Single-digit Integer Type 14 20 3@ 46 356 66) 72 8) 9%) 100) Fourdigit Integer Type 1, (0600) 2. (0020) 3. (0015) 4, (0014) 5, (0010) 6. (0025) 7. (0091) 8. (0720) 9. (0400) 10. (4000)HINTS AND EXPLANATIONS EXERCISE | (EE MAIN) Adsorption 1. Gaseous mixtures are homogeneous and hence, 12. Theory based there is no interface 13, Greater the polarity or polarizability, greater will 2. Solute of ink gets adsorbed but solvent gets be the extent of adsorption. Hence, H, < CH, < absorbed in chalk. CO, < NE, 14, Chemisorption increases with increase in Physisorption is favourable at low temperature a hsisorP » temperature, but not linearly. 4 M()+X(g) 9M -X(s) . 15. =k. pl” Rate of forward reaction: r= Py) m x 1 5. ‘Theory based os, log = log k +7 log P 6. Chemisorption increases with increase in = Slope = temperature. n 7. Forphysisorption, activation energy is not needed. 16, Physisorption decreases or increasing temp, 8. Gases having higher critical temperature have 17. Adfpsynuomion =~(20—40)KJ/mol greater intermolecular forces. 18, van der Waal type weak intermolecular forces only. 9. Bither van der Waal type forces or chemical bonds 19. Chemisorption is monolayer 10, Chemisorption is irreversible. 20. Rate increases with increase in temperature, but 11. Physisorption decreases on increasing temperature the extent of adsorption decreases Catalysis rm 2. 280,(e)+0s(g)=*280,(2) (Contact — 26, Feis the catalyst and Mo is the promotor. rocess) Process) 27. Informative 22, Negative catalyst = Inhibitor 28, Informative 23. Greater the free valency, greater will be the involvement of catalyst 29, Informative 24, ‘Transition metals. For better catalysis, the extent 30. Informative of adsorption should be high but the bonds : formed between adsorbate and adsorbent should 3! Theory based not be enough stronger: 32. Theory based 25. Auto catalyst 33. Informative Ps ra i} Ey Zz < ES a x a a Zz d PS Fa Fs =Py ra i} = < ra Ed Py a Pd is a] Zz Eg Py 4 FS Fx Om: 34. Theory based 37. Informative 35. Catalyst has no effect on equilibrium constant and 38, Catalyst decreases the activation energy. hence, equilibrium composition. 39. Theory based 36. Catalyst does not change the reactants and products and hence, no change in A,H, 4,8, A,G, ete 40. Informative Colloids 41, Butter is a colloidal system in which water is 61, For negative charge on colloidal particles dispersed in liquid or sold fat. [Ag ]< 7] 42, Theory based 62. Definition of erystalloids. 43. Informative 63. 1 to 1000 nm 44. Theory based 64. Definition of gel 45. FeCl, coagulates blood. 65. Definition of emulsion 46. Blood is negatively charged colloid. Haemoglobin 66. Definition of peptisation is positively charged 61. Informative 47. Smaller the gold number, greater is the protective power of Iyophilie colloid 6. Metal onide and lydrordes are positively changed 48. Gold number = 0.0025 x 1000 = 2.5, 69, Informative 49. Colloidal solutions show lower value of any of the colligative property 70. Informative 50, Smaller the gold number, greater is the protective 71 Theory based power of lyophilic colloid 72, NaCl, Glucose and Ba(NO,), forms true solution 51. Informative in water 52, Definition of electro-osmosis. 7B. As Ag" ions arin exes they get adsorbed more preferentially 53. Natural colloids are mostly negatively charged 74, Metal sulphides are water insoluble and cannot be $4. Definition of zeta potential. lyophilic 55. Informative 75. Sugar in water is true solution, 56. Fe** is common ion. 16. Theory based 57. Theory based 77. Larger the size of molecule, smaller is the CMC value. 58. Informative 78. Informative 59. Charge on colloidal particles may be determined experimentally by electrophoresis or electro- 79, Protective action osmosis, 80. Theory based 60. Ferric hydroxide sol is positively charged and anion should carry higher chargeEXERCISE II (JEE ADVANCED) Section A (Only one Correct) 1. Greater the specific surface area of adsorbent, gteater will be the extent of adsorption 2. Adsorption decreases the surface energy. 3. 2aK Pr stog*=togK+1togP From question, log K= 0.3010 = log, => K=2 And 4 =tand5*=1-30=1 %n2xP=2%02-04 => E, = 6900 calimol 5. For a particular combination of adsorbent, adsorbate and temperature, only one value of ‘n is permissible. 1 6 Sexpe s02-Kxa a) 05=Kx05)* @ 0.8=Kx(64)" B) From (1), @)and @), K=shand n=2 \ (2) = Kx(36)" =06 7 ia Hence, moles of N, adsorbed per gm of iron = 26. 2 140 10. uw 2 1B, 14. 15. 16, 17. 18, 19. 20. 2. 2. 1, <1 => Ais the catalyst ¥, <1 = Bis the catalyst. =r, => Cand D are not catalysts. Dis catalytic poison. 1, Cis catalytic promotor. A catalyst always involve in the reaction, Enzymes are specific, A catalyst does not initiate the reaction. Theory based Catalyst does not alter the equilibrium position, Homogencous catalysis, because the physical states of both reactant and catalyst is aqueous (liquid). Activation energy is decreased. Catalyst lowers the activation energy. Catalysis occurs through chemisorption Viscosity is higher and surface tension is smaller than water. K, as it reacts vigorously in water. SnCl, formed by reaction will adsorb some common CI ions Informative ‘True solution or suspension does not show Tyndall effect. Blood, clay and smoke are negative sol. In strong acidic solution, gelatin adsorbs some H' ions and become positive. Theory Informative Informative Ps ra i} Ey Zz < ES a x a a Zz d PS 2 Fs =ry ra Q E Ea Zz < s a Pd inf a Zz < Py g F4 = Qn: - 27, Larger the carbon chain, normally smaller is 9 5 26. Volume of metal used = #297 = 10%? cMc. 4 28. Sulphide sol have negative charge on colloidal » x5 x (0x10 em)? =10-%em* particles 29. Adsorption is physisorption. = =239x10! 30, Theory based Hence, number of particles per em? 9x10!2 239%10" 93910" 1000 Section B (One or More than one Correct) 1. Entropy decreased in adsorption. 45. Electrophoresis and clectro-osmosis are the cory base experimental methods to determine charge on 2. Theory based colloidal particles. 3. Theor; cory based 16. Informative 4, AH can never be equal to AS. ‘ 17. Below CMG, the solution is true solution. 5. (a)Chemisorption does not change into physisorption at higher pressure, 18, POS >Soy >cr (b) CO or CO, gases leave the surfaces. => Sol particles are positively charged. 6. Theory based 19. RCOONa = RCOO- +Na* 7. Informative As true solution, one mole of RCOONa will 8. In Lindlar’s catalyst, catalytic poison is used become two moles in solution. But, as micelle formation starts, the total number of particles 9. Theory based start decreasing due to association, 10. All catalytic reaction is multistep reaction 20, Due to excess Agt, sol particles will be positively 11. Informative charged. b Kx 0 Ae ceva 21. (a) Itis due to sharp decrease in number of ions - = FT (b) Tyndall efect is better shown by lyophobic met colloid. 2 Keal (©) Colloidal solutions have lower value of RT 300 colligative properties. 1000 (d) Larger the carbon chain, normally lower 14 Keal/mol CMC value, (), (© Reaction: 21,0,(aq) —> 2H,00)+04g) is 22+ (a) Basic dye is positively charged and hence, fist order. Fe(CN) > HPO} (@) Rate of uncatalysed reaction increases to (©)Slope should not change in Freundlich's greater extent on increasing temperature because isotherm, its activation energy is high 23. Tyndall effect is shown by colloids. 13, Sol particles axe restricted to move. Solvent particles move in opposite direction to the 24. Theory based expected movement of sol particles. Fe(OH), sol 25, Charge : Mg** (2 unit) > CT (1 unit) is positively charged. 14, Informative Hence, better coagulation for negatively charged. gold sol,Section C (Comprehensions) Comprehension 1 1, Polarizability is maximum in Xe 3. Adsorption decreases on increasing temperature 2. COispolarand hence, more preferential adsorption, Comprehension II 4, In case of concentrated KCI, KCI adsorbs on 5. Greater critical temperature, greater the extent of blood charcoal surface, but in case of dilute KCl, adsorption. blood charcoal dissolves in KCI solution. 6. Adsorption is always exothermic. Comprehension III 7. Initial surface area, 4, = 6%(2 em)? = 24 em? 8, Number of H, molecules 8m’ 2x0.112 28 yz c sar 2X01 6x10" = 3x10 Final volume of each eube = “5 oases - Final sidelength of eacheube = (810! em)!” Specific surface area =2x104 em 3x10" x04 (10 em)? Hence, final surface area of each cube, Sem Ay = 6x (2x 104 em)? = 24x 107 em? =24x10° em? /em Final total surface area _ 24x10 x10" _ 5g Tnitial surface area ~~ ‘Comprehension IV 9. top(=}=toza+4 logP 10, © =10x(16)"* =20 stope-}=025n=4 => x= 20x10 = 200 gm x 810 in and for x-intercept, toe(=)=0 Me Tg = 1OxtPy > P=3atm = log. Py Zz Q Ey Z 4 a x fay [=] Z Ea Py g Fs z2 Z 9 EA z < a a Pd a ray Z < Py 4 S = Om: Comprehension V 12. Positively charged due to adsorption of Ag’ ions, 14, Informative 13, Theory based Comprehension VI 15. Positively charged duc to adsorption of Fe** ions. 16. S* ions get adsorbed. Aal, Ag’, NOs 16. t ayer ited aye Comprehension Vil 18. Gold number = 0.025 x 1000= 25 20, Theory based 19, Theory based Section D (Assertion — Reason) 1, Colour become less intense due to adsorption. 11, Cellulose nitrate sol is lyophilic 2. Surface particles have higher energy due to 12, Scattering is not related to speed of particles ‘unbalanced forces 13, Theory based 3. Word'always'isnot suitable because chemisorption increased with increase in temperature 14, Theory based 4. Theory based 15. Colloidal particles are negatively charged due to adsorption of I’ ions and hence, it moves towards 5. Theory based anode 6. Theory based 16, Theory based 7, Theory based 17. Informative 8. Theory based 18, Peptization occurs due to adsorption of common 9. Theory based = 19. Natural colloids are normally lyophilic 10. Theory based 20. Theory based Section E (Column Match) 1. Informative 3. Informative 2, Informative 4, InformativeSection F (Subjective) Single-digit Integer Type 1, 648 = (0.01x107 x162n)x10" 6. Number of CH,COOH molecules adsorbed sn=4 —100%(0.5=0.49) 61628 g 10H 2. tog -logk +4-1ogP r000 log = log K += Io; in Ie Surface area of each molecule From the given graph, log K= 1,0 K=10 221 ctor! 25 n=4 oxlo eo 7. Number of N, molecules Now gp RP" 0.001 x2.46%107* ™ BOOT PAG IO” 56,023 x10" = 6.02310 x sya 0.082300 = A =10x(8.1x10"} 10 +. Number of active sites per molecule xs3 2 este 1000.x6,02310!* x 70 100 _, a 602310" bo ET 1 8, Number of N, molecules absorbed (1.25 x108 1) ce Fh 22axt08 = 22X10" 6x10" = 6x10" 4. Soap solution of sodium palmitate, gold sol, silicic 224 acid sol, acidic dye, metal sulphide sol, sol of AgCl «Specific surfac bby excess KCI in AgNO,, ipecific surface area = 6x10" «0.15% (10)? = 5 inf = Bia PR if 9. Colloid is a heterogeneous system => min = 2 phases or, Ink = AB (1 4 10 wean F(t 1 ) R (200 250, R (600 1000 = AH, g, = 6000 cal/mol 2 => E, = 9000 cal/mol, ra Q it Integer Type 7 Zz 1. Mass of NaCl used 2. Number of palmitic acid molecules needed cs = (585%1.2)x1/100 = 5.8551.2. gm =e 4 o2xa ie Moles of NaCl used = 285%! 9 19 Moles of palamitic acid molecules 585 "7 24x10" ig? ed ©. Coagulation value oxio™ rm) , e «. Volume of solution needed Fa 012x108 2 = = Foran 7 600 millimolelitre Lda 197 — 21075 dm? = 20 mm? = 5127256Dow us m3 3. The radius of hyd ecule =( x erate oop ake (2) us 2 3 s =|— x2] =25x10-%m 6x10 x 218” 4 = Number of hydrogen molecules at the surface per gm Cu = 241m, 6x10 _ 24x10" ~ 22400 "25 @ . Specific surface area of Cu 24x10 Xx (2.5x10" ? = 150000 em?/gm = 15 m?/gm 4 tot k Now, tn“ =1n4 hob 036 no38 On (a-as) R (25007 2000 = E,= 14000 cal/mo! 5, llvalee _ Ketanoar Ae OMOEA Crdeascon — Kee Lo axa ~ IT Aer e 6. Number of adsorbate molecules 0.10107 0.25x10° 6x10" = 2.4107 - Eifective surface area = Py ra i} = < ra Ed s a Pd is a] Zz Eg Py 2 FS = 10. Moles of gas adsorbed per gm of charcoal = 200 = 400) «1.52 © T60X RX 300%6 Volume of gas adsorbed per gm of charcoal 300x1.52 273 F6OXRX300%6 1 (at 0°C and 1 atm) = = 0,091 litre Specific surface area of silica gel __16s, © 22400 AaB A RTT tes 1 334 (200-7 6X10" x0.16 x (107 720m" /em_ K,Ks[EoMS]_ _ KiK:[Eo IS] Ky+K+ KS) Ky + KAS) Fot rage Ki] Ky 1, RRL mae K,[S] From question, Kyla) _ KiKs{EoIlS] 2 Ka +Kis] > Ky+KS]=2K15] [E,]= 002M