Undersaturated Oil Viscosity Correlation
Undersaturated Oil Viscosity Correlation
Undersaturated Oil Viscosity Correlation
A large database comprised of 1,399 oils and 10,248 data made use of this equation form and correlated α with
points was constructed to evaluate existing correlation bubblepoint viscosity. Khan19 and Orbey-Sandler24 also
methods. Pressure differentials up to 25,000 psi and viscosity utilized the Barus form of equation but instead determined
in excess of 1000 cp are included in the database to ensure constants for the viscosity-pressure coefficient. The API4
viscosity at both typical conditions and the extreme conditions found results similar to Kouzel and provided an update to that
such as those encountered in deep water is represented. The method. Various correlation forms suggested by Hershey and
data was obtained from both public Hopkins15 and Roelands27 as well as other formulations in
sources5,7,9,10,12,14,17,22,23,25,29,31 and internal reports26. This data Table A-1 were tested against the database and it was
is summarized in the table below. concluded that the Barus form equation showed the most
promise.
Property Minimum Maximum
Oil gravity, °API 6 61.2 Data from the database was plotted using the functional
Gas-oil ratio, scf/STB 0 4630.6 equation form offered by Eqn. 6, as shown in Fig. 3. The data
Dead oil viscosity, cp 0.204 14,200 actually represents several slopes representing different ranges
Temperature, °F 32 425 of bubblepoint viscosity. Fig. 4 illustrates this for three coarse
Pressure, psia 115 25,015 data groupings. If a more detailed examination is made of the
Bubblepoint pressure, psia 14.5 11,195 slopes, a definite relationship with bubble point oil viscosity is
Pressure differential, psi 9 25,000 observed, as shown in Fig. 5. The relationships proposed by
Bubblepoint viscosity, cp 0.063 14,200 Kouzel, the API, Khan and Orbey-Sandler are provided for
Undersaturated viscosity, cp 0.067 24,180 reference in this plot. The results would indicate that a
method such as Orbey-Sandler might provide accurate results
In some instances, the data obtained from public sources was for oil with a bubblepoint viscosity less than 1 cp, but would
incomplete so the table above is reflective of the information be increasingly inaccurate as bubblepoint viscosity increased.
available. In addition to crude oil data, lubricant oils,
Canadian bitumen, n-decane, n-undecane, n-dodecane, n- The Barus equation was originally limited in applicability to
tetradecane, n-pentadecane, n-hexadecane, n-octadecane, n- lower pressure differentials. Kouzel suggested a limit of 5000
butylbenzene, n-hexylbenzene, and n-octylbenzene are psi while the API update to his equation contradicted the
represented in the database. The data is plotted as a function recommendation and specified a limit of 20,000 psi. Orbey-
of pressure in Fig. 2. In general, the data is linear with log of Sandler determined a limit of 5800 psi which is closer in
viscosity; however, some downward curvature is noted at agreement to Kouzel.
pressure differentials above 5000 psi. Furthermore, the slope
of the lines increases as bubblepoint viscosity increases. Examination of the equation shows that it can be linearized by
adding an exponent, β, to the pressure term to account for the
Correlation Development slight downward curvature observed at higher pressure
A total of 18 methods have appeared in the literature. differentials.
Methods fall into a category that either use pressure ratio
μ o = μ ob eα ( p − pb ) ............................................................ (7)
β
(pressure divided by bubblepoint pressure) or pressure
differential (pressure minus bubblepoint pressure) as the
primary correlating parameter. In addition, bubblepoint Values of β averaged approximately 0.9 for the entire
viscosity is a common correlating parameter. Some methods database. However, if only high pressure differential data is
also use solution gas-oil ratio, oil API gravity and dead oil used, a trend is observed as shown in Fig. 6, even though there
viscosity as correlating parameters. One of the more widely is still significant scatter present.
used equation forms for correlating undersaturated oil
viscosity was proposed by Barus6 in 1893. The equation A nonlinear regression routine was used to determine the final
describes a linear relationship resulting from a semilog plot form of the Bergman-Sutton method based on Eqn. 7. The
(Fig. 2) of undersaturated oil viscosity with pressure. coefficient, α, and exponent, β, are defined as
μ o = μ ob eα ( p − pb ) ..............................................................(5) α = 6.5698×10 −7 ln (μ ob )2 −
......................... (8)
1.48211×10 −5 ln(μ ob )+ 2.27877 ×10 −4
This equation can be rearranged as follows where the term, α,
is the viscosity-pressure coefficient which is simply the slope
of the viscosity ratio – pressure differential relationship. β = 2.24623×10−2 ln (μob ) + 0.873204 ................................ (9)
viscosity. Methods with a data point count of less than 10,248 Conclusions
require additional data such as dead oil viscosity, API gravity 1. A comprehensive database of undersaturated crude oil
or solution gas-oil ratio. Unfortunately, this data was not viscosity has been created for evaluating the accuracy of
always available from published sources so these methods existing methods and developing improved viscosity
could not be tested against the full database. Furthermore, estimation methods.
results from the Abdul-Majeed1 method were found to be 2. Methods using pressure ratio as a correlating parameter
severely degraded below a gas-oil ratio of 50 scf/STB (see were found to be not as accurate for determining the
note Table 3). The results below this value were excluded to pressure effect on the viscosity of undersaturated crude
provide a meaningful comparison of statistics. Additionally, oils. This is most apparent for undersaturated crude oils
methods proposed by Kartoatmodjo17,18 and De Ghetto10 that are gas free or have low saturation pressure.
resulted in negative viscosity values for cases involving high 3. Methods developed by Kartoatmodjo and De Ghetto can
bubblepoint viscosity and high pressure differentials. evaluate a negative viscosity under situations of high
bubblepoint viscosity and high pressure differential.
Errors for methods that use pressure ratio as a correlating Extreme caution should be exercised if these methods are
parameter tend to show higher errors than methods that use used for general application in computer programs.
pressure differential as a correlating parameter. Tables 2 and 4. A new method has been proposed which provides more
3 provide a summary of correlation evaluations for accurate results over a wider range of bubblepoint
bubblepoint pressures greater than and less than 50 psia viscosity and pressure differentials than existing methods.
respectively. In the latter case, a significant portion of the data The new method derives undersaturated viscosity using
is comprised of gas free oils with a bubblepoint pressure set to only bubblepoint viscosity and pressure differential. The
atmospheric pressure. The Bergman-Sutton method performs correlation can be satisfactorily used on oils that contain
well in both environments. solution gas or are gas free. The data used to derive the
correlation included samples with bubblepoint viscosity
Tables 4 and 5 examine the effect of temperature on from less than 0.1 cp to in excess of 14,000 cp. Accuracy
correlation accuracy. This was actually more of a test of data is maintained over this wide range of values.
quality. Many of the oils found in the Gulf of Mexico exhibit 5. As a practical limit, a maximum pressure differential of
a cloud point of approximately 100 °F. Below this 20,000 psi is recommended. Although there is an
temperature wax crystals appear which can disrupt viscosity increased error at higher differentials, the Bergman-
measurements and result in non-Newtonian behavior in the oil. Sutton method still offers superior results than those
The average absolute error for the Bergman-Sutton method in obtained from all of the currently available published
these cases was found to increase from 3.64% (for data above correlations.
100°F) to 5.56% (for cooler temperatures). It is felt that this
change is not significantly impacted by measurement issues Acknowledgment
below cloud point. The authors would like to thank the management of Marathon
Oil Company and BP America for permission to publish this
Tables 6-9 provide correlation statistics for various ranges of paper. Finally, the primary author would like to thank his
bubblepoint viscosity. The Bergman-Sutton method is found wife, Nancy. Without her patience and understanding, this
to be more accurate for all of the viscosity ranges investigated. would have never been written.
g = acceleration due to gravity, ft/sec2 and Temperatures up to 473 K,” Int. J. of Thermophysics,
h = net reservoir thickness, ft Vol. 25 (2004) 1339-1352.
k = effective permeability, md 10. De Ghetto, G., Paone, F. and Villa, M.: “Reliability
L = length, ft Analysis on PVT Correlations,” paper SPE 28904
p = pressure, psia presented at the European Petroleum Conference in
pb = bubblepoint pressure, psia London U.K. (Oct. 25-27, 1994).
pr = average reservoir pressure, psia 11. Dindoruk, B. and Christman, P.G.: “PVT Properties and
p wfs = flowing sandface pressure, psia Viscosity Correlations for Gulf of Mexico Oils,” paper
qo = oil flow rate, STBPD SPE 71633 presented at the 2001 SPE ATCE in New
re = drainage radius, ft Orleans, LA (Sept 30-Oct 3, 2001).
Re = Reynolds Number 12. Ducoulombier, D., Zhou, H., Boned, C., Peyrelasse, J.
Rs = solution gas-oil ratio, scf/STB Saint-Guirons, H., and Xans, P.: “Pressure and
rw = wellbore radius, ft Temperature Dependence of the Viscosity of Liquid
s = skin factor Hydrocarbons,” J. Phys. Chem., Vol. 90, No. 8 (1986)
T = temperature, ˚F 1692-1700.
v = velocity, ft/sec 13. Elsharkawy, A.M. and Alikhan, A.A.: “Models For
α = Barus equation viscosity-pressure coefficient Predicting The Viscosity of Middle East Crude Oils,”
β = pressure exponent Fuel (June, 1999) 891-903.
γAPI = oil API gravity 14. Farshad, F.F., Leblanc, J.L., Garber, J.D. and Osorio,
ρo = oil density, lbm/ft3 J.G.: “Empirical PVT Correlations For Colombian Crude
μod = dead oil viscosity, cp Oils,” unsolicited paper SPE 24538 (June, 1992).
μob = bubblepoint oil viscosity, cp 15. Hershey, M.D. and Hopkins, R.F.: Viscosity of
Lubricants Under Pressure, ASME, New York, NY
μo = oil viscosity, cp
(1954).
θ = angle, degrees from vertical
16. Hossain, M.S., Sarica, C., Zhang, H.Q., Rhyne, L., and
Greenhill, K.L.: “Assessment and Development of
Heavy-Oil Viscosity Correlations,” SPE/PS-CIM/CHOA
References
97907 PS2005-407 presented at the 2005 SPE
1. Abdul-Majeed, G.H., Kattan, R.R. and Salman, N.H.:
International Thermal Operations and Heavy Oil
“New Correlation for Estimating the Viscosity of
Symposium, Calgary, Canada (Nov. 103, 2005).
Undersaturated Crude Oils,” J. Cdn. Pet. Tech. (May-
17. Kartoatmodjo, R.S.T.: “New Correlations for Estimating
June, 1990) 80-85.
Hydrocarbon Liquid Properties,” MS Thesis, University
2. Al-Khafaji, A.H., Abdul-Majeed, G.H. and Hassoon, S.F.:
of Tulsa (1990).
“Viscosity Correlation For Dead, Live and
18. Kartoatmodjo, R.S.T. and Schmidt, Z.: “New Correlations
Undersaturated Crude Oils,” J. Pet. Res. (Dec., 1987) 1-
For Crude Oil Physical Properties,” Unsolicited Paper
16.
SPE 23556 (Sept, 1991).
3. Almehaideb, R.A.: “Improved PVT Correlations for UAE
19. Khan, S.A., Al-Marhoun, M.A., Duffuaa, S.O., and Abu-
Crude Oils,” paper SPE 37691 presented at the 1997
Khamsin. S.A.: “Viscosity Correlations for Saudi
Middle East Oil Conference and Exhibition in Manama,
Arabian Crude Oils,” paper SPE 15720 presented at the
Bahrain (Mar. 17-20, 1997).
5th SPE Middle East Oil Show in Manama, Bahrain (Mar
4. API Technical Data Book – Petroleum Refining: API,
7-10, 1987).
Washington DC 6th ed, (April, 1997) Chap 11.
20. Kouzel, B.: “How Pressure Affects Liquid Viscosity,”
5. ASME Pressure-Viscosity Report: Viscosity and Density
Hyd. Proc., (March 1965) 120.
of Over 40 Lubricating Fluids of Known Composition at
21. Labedi, R.M.: “PVT Correlations of the African Crudes,”
Pressures to 150,000 psi and Temperatures to 435 F, Vol.
PhD Thesis, Colorado School of Mines (May, 1982).
I and II, ASME, New York, NY (1953).
22. Mehrotra, A.K. and Svrcek, W.Y.: “Viscosity of
6. Barus, C.: “Isothermals, Isopiestics and Isometrics
Compressed Athabasca Bitumen,” The Cdn. J. of Chem.
Relative To Viscosity,” The American Journal of Science,
Eng. (Oct., 1986) 844-847.
Vol. XLV, No. 266 (1893) 87-96.
23. Mehrotra, A.K. and Svrcek, W.Y.: “Viscosity of
7. Beal, C.: “The Viscosity of Air, Water, Natural Gas,
Compressed Cold Lake Bitumen,” The Cdn. J. of Chem.
Crude Oil and Its Associated Gases at Oil Field
Eng. (Aug., 1987) 672-675.
Temperatures and Pressures,” SPE Reprint Series No. 3
24. Orbey, H. and Sandler, S.I.: “The Prediction of the
Oil and Gas Property Evaluation and Reserve Estimates,
Viscosity of Liquid Hydrocarbons and Their Mixtures as
SPE, Richardson, TX (1970) 114-127.
a Function of Temperature and Pressure,” The Cdn. J. of
8. Brill, J.P. and Mukherjee, H.: Multiphase Flow in Wells,
Chem. Eng. (June, 1993) 437-446.
Monograph 17, SPE, Richardson, TX (1999).
25. Petrosky, G.E., Jr.: “PVT Correlations for Gulf of
9. Caudwell, D.R., Trusler, J.P.M., Vesovic, V., and
Mexico Crude Oils,” M.S. Thesis, University of
Wakeham, W.A.: “The Viscosity and Density of n-
Southwestern Louisiana (1990).
Dodecane and n-Octadecane at Pressures up to 200 MPa
26. Reservoir Fluid Database (RFDbase), GeoMark Research,
Inc., Houston, TX (2006).
SPE 103144 5
27. Roelands, C.J.A.: “Correlational Aspects of the 32. Vazquez, M.E. and Beggs, H.D.: “Correlations for Fluid
Viscosity-Temperature-Pressure Relationship of Physical Property Prediction,” J. Pet. Tech. (June, 1980)
Lubricating Oils,” PhD Thesis, University of Delft, The 968-970.
Netherlands (1963).
28. Standing, M.B,: Volumetric and Phase Behavior of Oil SI Metric Conversion Factors
Hydrocarbon Systems, 9th Printing, Society of Petroleum 141.4/(131.5+°API) = g/cm3
Engineers of AIME, Dallas, TX (1981). bbl × 0.1589873 = m3
29. Stephan, K. and Lucas, K.: Viscosity of Dense Fluids, ft3 × 0.02831685 = m3
Plenham Press, New York, NY (1979). cp × 1.0E−03* = Pa•s
30. Sutton, R.P..: Petroleum Engineering Handbook, (°F–32)/1.8* = °C
General Engineering, Vol. 1, J. Fanchi and L.W. Lake psi × 6.894757E+00 = kPa
(eds.) Society of Petroleum Engineers, Richardson, TX °R × 5/9* = °K
(2006) 257-331. *Conversion factor is exact
31. Vazquez, M.E.: “Correlations for Fluid Physical Property
Prediction,” M.S. Thesis, The University of Tulsa (1976).
No. of μo μob
Author Correlation Origin Data Range Range p Range pb Range ARE SD AARE
Points (cp) (cp) (psia) (psia) (%) (%) (%)
Beal
7,28
μ o = μ ob + [0.001 ( p − pb )] 0.024 μ ob
1. 6
( 0.56
+ 0.038 μ ob ) USA 26
0.16 to
315
0.142
to 127
na na 2.7 na na
(1946)
⎛ p ⎞
Labedi
21 0.7374
μ o = μ ob + 0.0483 μ od ⎜ − 1⎟⎟ 0.098 715 to
⎜ Nigeria and Angola 31 na na -6.8 41.07 na
(1982) ⎝ p b ⎠ to 10.9 4,794
μ o = μ ob e9.6 x10 ( p − pb )
19
Khan −5 0.13 to 0.13 to 107 to
Saudi Arabia 1,503 na 0.094 2.999 1.915
71.0 77.4 4,315
(1987)
X 1 = log (μ ob ) 0.211
25
Petrosky 0.22 to 1,600 to 1,574 to
X 2 = − 1.0146 + 1.3322 X 1 − 0.4876 X 12 − 1.15036 X 13 Gulf of Mexico 404
4.09
to
10,250 9,552
-0.19 4.22 2.91
(1990) 3.546
μ o = μ ob + 1.3449 × 10 −3
(p − p b )10 X2
Indonesia, N.
μ o = 1.00081 μ ob + 1.127 × 10 −3 ( p − p b )
Kartoatmodjo 0.168 0.168
17,18 America, Middle 25 to
3,588 to to 25 to 4,775 -4.29 na 6.88
(− 6.517 ×10 )
and Schmidt 6,015
−3 1.8148 1.59
(1991) μ ob + 0.038 μ ob East, and Latin 517.03 184.86
America
Orbey and
24
μ o = μ ob e α ( p − pb ) Pure component
Sandler
α = 6.76×10 −5 psi -1 parriffinic hydrocarbons data nC6-nC18, 0.225 0.217 740 to
(1993) 377 14.5 na na 4.8
α = 7.24 ×10 -5 psi -1 akylbenzes and cyclic hydrocarbons Alkylbenzenes and to 7.3 to 3.1 14,504
Cyclic
α = 6.89 ×10 -5 psi -1 average Hydrocarbons
No. of μo μob
Author Correlation Origin Data Range Range p Range pb Range ARE SD AARE
Points (cp) (cp) (psia) (psia) (%) (%) (%)
Extra heavy oil (°API ≤ 10)
⎛ p ⎞ 10 −2.19 μ od
1.055 0.3132
pb
μ o = μ ob − ⎜⎜1 − ⎟
⎝ pb ⎟⎠ 10 (0.0099 γ API )
Heavy oil (10 < °API ≤ 22.3)
μ o = 0.9886 μ ob + 0.002763 ( p − pb )×
xh 3.4
xh 4.0 h 7.2
De Ghetto
10 (− 0.01153 μ 1.7933
ob
1.5939
+ 0.0316 μ ob ) Mediterranean
Basin, Africa, .13 to
h 6.0 m 3.7
Light oil (°API > 31.1) 195 na na na m 3.5 lght na
Persian Gulf and 354.6
(1994) lght 6.3 16.8
⎛ p ⎞ 10 −3.8055 μ od
1.4131 0.6957
pb North Sea agip 6.4 agip
μ o = μ ob − ⎜⎜1 − ⎟
⎝ pb ⎟⎠ 10 (−0.00288 γ API ) 6.6
Agip Model
⎛ p ⎞ 10 −1.9 μ od
0.7423 0.5026
pb
μ o = μ ob − ⎜⎜1 − ⎟⎟
(0.0243 γ API )
⎝ pb ⎠ 10
3
⎛ p ⎞
(0.134819 + 1.94345×10 −4
Rs − 1.93106 ×10 −9 Rs2 )
Almehaideb United Arab
μ o = μ ob ⎜⎜ ⎟
⎟
328 na na na na na 4.07 2.885
(1997) ⎝ pb ⎠ Emirates
10 −2.0771 ( p − pb ) μ od
13
Elsharkawy 1.19279 0.2 to 1,287 to
254 na na -0.9 6.2 4.9
μ o = μ ob + 0.40712 0.7941
Middle East 5.7 10,000
(1999) μ ob pb
Hossain
16
μ o = μ ob + [0.004481 ( p − pb )]
(2005) (0.555955 μ 1.068099
ob
1.063547
− 0.527737 μ ob ) Worldwide
390
3 to
517
3.6 to
360
300 to
3,400
121 to 6,272 na na 52.5
Table 2 - Statistical accuracy of viscosity methods for bubblepoint pressure > 50 psia (ie reservoir fluid systems)
SPE 103144 9
Table 3 – Statistical accuracy of viscosity methods for bubblepoint pressure < 50 psia
(Note: Abdul-Majeed was not evaluated as all data had a GOR < 50 scf/STB.
Including this data, the method has an average error of 33,445%.)
Table 9 - Statistical accuracy of viscosity methods for bubblepoint viscosity > 100 cp
Table 10 - Statistical accuracy of viscosity methods for pressure differential 10,000-25,000 psi
13 SPE 103144
Fig. 3 – Barus viscosity relationship Fig. 4 – Bubblepoint viscosity effect on Barus viscosity
relationship
Fig. 5 – Comparison of “Barus-type” methods with measured Fig. 6 – Pressure exponent to linearize viscosity equation (data
viscosity data from experiments with pressure differential in excess of
12,000 psi)
Fig. 7 – Error in calculated viscosity from Beal method Fig. 8 – Error in calculated viscosity from Kouzel method
14 SPE 103144
Fig. 9 – Error in calculated viscosity from Vazquez & Beggs Fig. 10 – Error in calculated viscosity from Labedi (Libya)
method method
Fig. 11 – Error in calculated viscosity from Labedi Fig. 12 – Error in calculated viscosity from Khan method
(Nigeria/Angola) method
Fig. 13 – Error in calculated viscosity from Al-Khafaji method Fig. 14 – Error in calculated viscosity from Abdul-Majeed
method
SPE 103144 15
Fig. 15 – Error in calculated viscosity from Petrosky method Fig. 16 – Error in calculated viscosity from Kartoatmodjo &
Schmidt method
Fig. 17 – Error in calculated viscosity from Orbey & Sandler Fig. 18 – Error in calculated viscosity from De Ghetto method
method
Fig. 19 – Error in calculated viscosity from De Ghetto - Agip Fig. 20 – Error in calculated viscosity from Almehaideb
method method
16 SPE 103144
Fig. 21 – Error in calculated viscosity from method Kouzel Fig. 22 – Error in calculated viscosity from Elsharkawy
API method method
Fig. 23 – Error in calculated viscosity from Dindoruk & Fig. 24 – Error in calculated viscosity from Hossain method
Christman method
Fig. 25 – Error in calculated viscosity from Bergman & Sutton Fig. 26 – Accuracy of Beal method
method
SPE 103144 17
Fig. 27 – Accuracy of Kouzel method Fig. 28 – Accuracy of Vazquez & Beggs method
Fig. 29 – Accuracy of Labedi (Libya) method Fig. 30 – Accuracy of Labedi (Nigeria/Angola) method
Fig. 35 – Accuracy of Kartoatmodjo & Schmidt method Fig. 36 – Accuracy of Orbey & Sandler method
Fig. 41 – Accuracy of Elsharkawy method Fig. 42 – Accuracy of Dindoruk & Christman method
Fig. 43 – Accuracy of Hossain method Fig. 44 – Accuracy of Bergman & Sutton method
20 SPE 103144
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