TheRegi onalI

nspect
orateofPedagogyforSci
ence
Educati
on, i
ncoll
aborat
ionwit
ht heSout
hWest SUBJECT PAPER
ChemistryTeachers’
Associat
ion(SOWECTA)andthe CODENUMBER NUMBER
Teachers’ResourceUni
t(TRU)Buea.

Sout
hWestRegi
onal
MockExams,
Mar
ch2021 715 2
GENERALCERTI
FICATEOFEDUCATI
ONEXAMI
NATI
ON

ADVANCED LEVEL SUBJECTTI

TLEANDSYLLABUS

CHEMI
STRY
DATE

Candi
dat
eName:
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_ THURSDAY,
18/
03/
2021,
AFTERNOON

Candi
dat
eNumber
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FOREXAMI
NER’
SUSEONLY FOREXAMI
NER’
S
USEONLY
NameofExami
ner
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ONLY

Signat
ureof
Examiner:.
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Thr
eehour
s
Openwi
det
hef
lapat
tachedt
othi
sbookl
etandent
ert
hei
nfor
mat
ionr
equi
redi
ntheboxesoft
he
fl
ap.

Answerallquesti
ons.Themarkall
ocat
ioni
sindi
cat
edforeachquest
ion.
Eachquestioncarr
ies20marks.
Blankspacesinthi
squesti
onbookl
etmaybeusedforr
oughwor k.
Incalcul
ati
onsy
ouar
eadv
isedt
oshowal
lthest
epsi
nyourwor
king,
giv
ingy
ouranswerateach
stage.

Al
lnecessar
yworkingmustbeshown.Nomarkswil
lbeawardedf
oranswer
swi
thoutbr
ief
st
atementsshowi
nghowt heanswer
shavebeenobt
ained.
Cal
culat
orsareal
l
owed.

Usef
ulDat
a
One(
1)at
mospher
e(1at 01x105Nm-2.Mol
m)=1Pa=1. argasv
olume=24000cm3atr
tp.
mdm-3K-1mol
-
1
314JK-1mol
-
1
Mol
argasconst
antR=0.
082at (
OrR=8. )

Rel
ati
veat
omi
cmasses(
RAM)
:C=12;
O=16.
0;H=1.
0

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Tur
nov
er

SECTI
ONA:
PHYSI
CALANDGENERALCHEMI
STRY

1.)(a)Def inet hefoll

owingt erms:
i
)Amol eofasubst ance
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_ ______ _
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_ _
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________
______
_ __
__ _
______
_ _
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__ _
___
______
______
____
____
___ _
_ ______ _
___
_ _
____________
____
________
______
_ __
__ _
______
_ _
___
__ _
___
______
______
____
____
___ _
_ ______ _
___
_ _
_________
i
i)Molarmass
____
___ _
_ ______ _
___
_ _
____________
____
________
______
_ __
__ _
______
_ _
___
__ _
___
______
______
____
____
___ _
_ ______ _
___
_ _
____________
____
________
_____(2mks)
b)Inanexper imenttodet erminethemol armassofav olati
l
eor gani
cl i
qui
dX, 0.
46goft he
l
iqui
dwasi njectedintoagr aduatedglasssy r
inge.Onv apori
sation,i
toccupiedav ol
umeof
3 o
240cm at20Cand760mmHg.
i
)Howwoul dy ouknowi ftheliqui
dhasbeencompl etel
yv apori
zed?
____
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_ ______ _
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_ _
____________
____
________
______
_ __
__ _
______
_ _
___
__
____
___ _
_ ______ _
___
_ _
____________
____
________
______
_ __
__ _
______
_ _
___
__
i
i)Calculatet hemol armassofX:
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_ ______ _
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_ _
____________
____
________
______
_ __
__ _
______
_ _
___
__ _
___
______
______
____
____
___ _
_ ______ _
___
_ _
____________
____
________
______
_ __
__ _
______
_ _
___
__ _
___
______
______
____
____
___ _
_ ______ _
___
_ _
____________
____
________
______
_ __
__ _
______
_ _
___
__ _
___
______
______
____
____
___ _
_ ______ _
___
_ _
____________
____
________
______
_ __
__ _
______
_ _
___
__ _
___
______
______
____
____
___ _
_ ______ _
___
_ _
____________
____
________
______
_ __
__ _
___(3mks)
c)Chemi calbondsandi ntermolecul
arforcesar ebindingforceswhi chaff
ecttheshapes
andpr opertiesofsubst ances.
i
)Identifythebondt ypesandt heshapesofthespeci esinthetablebelow

Speci
es Bondt
ype Shape

BF3

NH¬3

i
i)AlCl
3readil
ydimer i
sesinthegaseousphase.Dr awthestr
uctureoft
hedimerandlabel
thedif
ferentty
pesofbondspr esent.
______
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_____
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______
_______
_________
_______
_______
_ _
______
____
____
____
_____
_____
___
___
____
_____
______
___
_
____
_____
_____
___
___
____
_____
______
___
i
ii)Waterandhy drogensulphi
dear ethefir
sttwohydri
desofgroupVIoft
heperi
odictabl
e.
Explai
nwhyt hef i
rsti
saliquidwhilethelatt
erisagasatr.
t.
p.
______
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____
_____
______
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______
_______
_________
_______
_______
_ _
______
____
____
____
_____
_____
___
___
____
_____
______
___

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 _______
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___( 5mks)
o
d)Thesat uratedv apourpr essur eat100Cofhept aneandoct aneare791mmHgand352
mmHgr espectively.Calculat e:
i
)Themol efractionofeachcomponenti nami xt
ureof25. 0gofhept aneand35. 0gof
octane.
___
_ __
___ ______________
_ _
__ __ __
_____
____ __
___ ___
__________
________
_____
_______
________
____
___
_ __
___ ______________
_ _
__ __ __
_____
____ __
___ ___
__________
________
_____
_______
________
____
___
_ __
___ ______________
_ _
__ __ __
_____
___
i
i)Thepar ti
alpressur eofeachcomponenti nt hemi xture.
____________________________ _____
_____
_ ___________
__ _
_______
________
_____
_______
________
__
____________________________ _____
_____
_ ___________
__ _
_______
________
_____
_______
________
__
____________________________ _____
_____
_ ___________
__ _
_______
________
_____
_______
________
__
___
_______(4mks)
e)i
)Whatdoy ouunder standbypHofasol ution?
____________________________ _____
_____
_ ___________
__ _
_______
________
_____
_______
________
__
__________
__ _
_______
________
_____
_______
________
__
i
i)Calculatet hepHof :
A)aO. 1M sol utionofH2SO4
____________________________ _____
_____
_ ___________
__ _
_______
________
_____
_______
________
__
____________________________ _____
_____
_ ___________
__ _
_______
________
_____
_______
________
__
_ _
_______
________
_____
_______
________
__
3 3
B)asol utionpr eparedbymi xing75cm of0. 1MHCl and25cm of0. 1M NaOHsol uti
ons.
____________________________ _____
_____
_ ___________
__ _
_______
________
_____
_______
________
__
____________________________ _____
_____
_ ___________
__ _
_______
________
_____
_______
________
__
____________________________ _____
_____
_ ___________
__ _
_______
________
_____
_______
________
__
____________________________ _____
_____
_ ___________
__ _
_______
________
_____
_______
________
__
_______________
_ __ ___
_____
___ ____
_ ____
__________
________
_____
_______
___( 4mks)

f
)i)Thefol
l
owi
ngdatawasobtainedforthereact
ion:A +B C.
-
3 -3
Experi
ment I
nit
ial
[A]/
moldm Ini
ti
al[B]/moldm I
nit
ial
rat
e( dm-3s-1)
mol

1 0.
100 0.
100 5×10‒6
5.

2 0.
200 0.
100 2×10‒5
2.

3 0.
100 0.
300 65×10‒5
1.

4 0.
100 0.
600 30×10‒5
3.

i
)Determi
net heorderofthereacti
onwit
hrespectto[
A]
_
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_____
___
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___
___
___
___
___
___
___
___
__
_
____
_ _
___
_ _
__ _
___
_ _
_____
____
_ __
_____
___
___
_______
___
_____
___
___
___
___
___
___
___
___
___
___
__
_
____
_ _
___
_ _
__ _
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_ _
_____
____
_
i
i
)Determinetheorderofthereacti
onwithr
espectto[B]
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____
____
______
_____
_ _
_ _
____
_________
__ _
__ ___
______
___
_______
_______
_____
_____
_______
_ _
____
____
____
______
_____
_ _
_ _
____
_________
__ _
__ ___
__
i
ii)Whatistheov er
allorderofther eacti
on?____
_______
_ _
_____
_____
_____
________
i
v )Writ
ether at
eexpressionfort hereacti
on.
______
_____
_ _
_ _
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_________
__ _
__ ___
______
___
_______
_______
_____
_____
_______
_ _
____
____
____
______
_____
_ _
_ _
____
_________
__ _
__ ___
______
___
____(4mks)
(Total=20marks)
2.)a)Anat om iscomposedoft hr eefundamentalpart
icl
es.Completethetablebelowwith
respecttotheseparti
cles.
Nameofpar ti
cle Rel ati
v emass Discoveredby Experi
mentused

1.
0 Chadwi
ck

pr
oton di
schar
get
ube

(
2mks)
b)Thef
oll
owi
ngi
nfor
mat
ionwasobt
ainedf
rom aspect
romet
ert
raceofazi
ncsampl
e.
eAbundance

4
yunis
t

3
ar
v

2
i
r
at
bit

1
Rel
Ar

I
sot
opi
cmass
64 65 66 67 68

Usethei nformati
onanddet er
minetherel
ati
veatomicmassofZi
nc.
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___
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___
___
_____
_____
____
___
____
__ _
__ _
_ _
____
______
_____
_ _
___
_____
____
_____
____
____
___
___
____
___
___
___
_____
_____
____
___
____
__ _
__ _
_ _
____
______
_____
_ _
___
_____
____
_____
____
____
___
___
____
___
___
___
_____
_____
____
___
__
_____
__(2mks)
c)Belowi spartoftheurani
um decayseri
es.
238 a 234 b 234 c
92
U→ 90
Th→ 91
Pa→ X
i
)Whichpart
icl
eisemit
tedinaandb. ?
___
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_ _
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___
_ _
___
____
___
___
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___
i
i
)Ifabetapart
icl
eisemit
tedinprocessc,i
dent
if
ythei
sotopeX.
_
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(
3mks)
d)(i
)Nameanytwowaysofcl
osepacki
ngofident
icalat
oms,
sucht
hatt
heenv
ironmentof
eachat
om i
sthesamewit
hthatoft
heother
.
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(i
i)Inanx- r
aydi ffracti
onexper i
mentonaSodi um chloridecryst
al,af i
rstorderdiffract
ed
0
rayoccur redatanangl eof22. 77.Gi venthatt hewav el
engthoft hex- r
aysis0. 153nm,
calculat
et hedistancebet weent helayersofthei onsinthecrystal
.
______________
_ ____________
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_ _____
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_________
___________
_
______________
_ ____________
___ __
_______
________
_ _____
________
________
_________
___________
_
______________
_ ____________
___ __
_______
________
_ _____
________
________
_________
___________
_
_______
__( 3mks)
e)i)Def i
nethef ollowing:
A)St andardent halpyofat omi zati
onofanel ement .
_______
___ __
_______
________
_ _____
________
________
_________
___________
_
______________
_ ____________
___ __
_______
________
_ _____
________
________
_________
___________
_
______
______ __
________
______
___________
___________
B)Bondener gyt erm.
_________
___ __
_______
________
_ _____
________
________
_________
___________
_
____
___ __
_______
________
_ _____
________
________
_________
___________
_
C)Lat ti
ceener gy.
_______
___ __
_______
________
_ _____
________
________
_________
___________
_
_______
___ __
_______
________
_ _____
________
________
_________
___________
_
i
i)Wr it
eanequat iont hatrepresentsthestandardent halpyofatomizationofmet hane
__________
_ _
____ ________
_____________
______
_ _
___ ___
________
______
_____

i
ii)Givent hatt hest andardenthalpyofatomi zati
onofmet haneis+1662KJ/ mol
,calculat
e
theaver agebondener gyoftheC- Hbondi nmet hane.
___________ __
__ _
____ __
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
____
_ _
______________
_____
_______
__ __
_____
________
_
___________ __
__ _
____ __
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
___________ __
__ _
____ __
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
_
_ __
_ _
______
_______
___ _
_____
__( 6mks)
f)i
)Statet heequi li
brium law.
__
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
__
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
__
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
i
i)Theest er,ethylethanoatemaybepr oducedbyt her eacti
on:
CH3COOH(aq)+CH3CH2OH(aq)⇌ CH3COOCH2CH3(aq)+H2O(l)
Givent hati ni
ti
ally,onemol eofeachofCH3COOHandCH3CH2OHwer emi xedtogetherina
1Lcont ainerandt hatatequi l
ibri
um,0. 8molofCH3COOH wasf oundt o bepr esent.
Calculatet hev al
ueoft heequil
i
brium constant,Kc,andst ateit
sunits
__
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
__
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
__
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
__
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
__
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
__
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
__
_ _
____
_______
_________
_ _
______________
_____
_______
__ __
_____
________
_
5
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 ____
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____
___
(3mks)
g)Consi
dert
heel ectrodepot entialsystemsbelow
El
ect rodepot enti
al system Eº/Vol
ts
2+ –
A Fe ( aq)+2e⇌ Fe( s) -
0.44
– –
B Cl2(aq)+2e⇌2Cl( aq) +1.36
+ –
C O2( g)+4H ( aq)+4e ⇌2H2O( l
) +1.23

i
)Wri
teacelldi
agram f
ort
hecel
lfor
medwhent
hehal
f-
cel
l
sAandCar
ecoupl
ed.Cal
cul
ate
t
hee.
m.f.ofthecell
for
med.

___
________
_____
________
_____
______
______
_ _
_____
_____
______
_____
_____
_______
_ _
_____
_______
___
________
_____
________
_____
______
______
_ _
_____
_____
______
_____
_____
_______
_ _
_____
_______
___
________
_____
________
_____
_
i
i)Explai
nwhychl ori
negascannotbest oredinanironvessel.
_____
__ _
_____
______
_______
_____
______
________
_____
_____
______
_____
_____
_________
_____
_____
_____
_____
_____
______
_____
_____
_________
_____
_____
(
3mks)
(Total=20mar ks)
SECTIONB: I
NORGANI CCHEMI STRY
3.)Thisquest ionconcer nstheel ement sacr ossperiods2and3, groupIVandt hechemi st
ry
oftheel ement ssulphurandni trogen.
a.(i
)Def neel
i ect r
onegat ivi
tyofanel ement .
_____________
_ _____
_ _
__ _______
_ ____
_ __
__ _
__ __
_ _
_________
_ _
_____
____________
_ _
_____
______
__
_____________
_ _____
_ _
__ _______
_ ____
_ __
__ _
__ __
_ _
___
i
i)St at
eandexpl ai
nt het rendi nelectronegat ivi
tyfrom leftt
or i
ghtacr ossper i
od2oft he
Periodi
cTabl e.
_____________
_ _____
_ _
__ _______
_ ____
_ __
__ _
__ __
_ _
_________
_ _
_____
____________
_ _
_____
______
__
_____________
_ _____
_ _
__ _______
_ ____
_ __
__ _
__ __
_ _
_________
_ _
_____
____________
_ _
_____
______
__
_____________
_ _____
_ _
__ _______
(
3mks)
b)Fort heper i
ods2and3oxi des, gi
v ethef ormulaof :
i
)Anamphot ericoxidei nperiod3_ _
i
i)Aneut ral
oxi deinper iod2_ _
i
ii)Aper iod2oxi dewhi chcausesaci drainoxi de___
_ ___
______
_________
__ __
_____
(
3mks)
c)i)Def i
nef i
rstionisationener gy.
_____________
_ _____
_ _
__ _______
_ ____
_ __
__ _
__ __
_ _
_________
_ _
_____
____________
_ _
_____
______
__
_____________
_ _____
_ _
__ _______
_ ____
_ __
__ _
__ __
_ _
_________
_ _
_____
____________
_ _
_____
______
__
_____________
_ _____
_ _
__ _______
i
i)Sketchagr aphoff irstionisati
onener gyacr ossper i
ods2and3oft heper iodict
able
(Lit
hium t oArgon) .
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_______
___ _
____
_____
_ _
_ _
__________
_________
_______
_ _
_ _
_____
_____
______
_____
_____
_____
__
___
_______
___ _
____
_____
_ _
_ _
__________
_________
_______
_ _
_ _
_____
_____
______
_____
_____
_____
__
___
_______
___ _
____
_____
_ _
_ _
__________
_________
_______
_ _
_ _
_____
_____
______
_____
_____
_____
__
___
_______
___ _
____
_____
_ _
_ _
__________
_________
_______
_ _
_ _
_____
_____
______
_____
_____
_____
__
___
_______
___ _
____
_____
_ _
_ _
__________
_________
_______
_ _
_ _
_____
_____
______
_____
_____
_____
__
___
_______
___ _
____
_____
_ _
_ _
__________
_________
_______
_ _
_ _
_____
_____
______
_____
_____
_____
__
___
_______
___ _
____
__
(
3mks)
d)Thisquest i
onconcernstheel ementsofgr oupIVor14( C,Si
,Ge,Sn,Pb)
i
)Writ
eoutt hegeneralouterelectroni
cconf i
gurati
onoft hegroupIVelements.
_________
___ _
______
_ _
_______
_ _
_________
_____
_____
______
_____
_____
_____
i
i)Giv
eanexampl eofagr oupI Vcompoundt hatis;
A:Astrongr educi
ngoxide.__________
__________
______
_ _
_ _
_____
______
_____
__
B:Acov al
entchlori
dewhi chdoesnothy drol
yseinwat er:___
_____
______
_____
_____

i
ii
)Wr it
ebalancedchemi calequati
onstoshowt heamphot
eri
cnatur
eofPbO2
___
_ _
________
____
_____
___ __
______
________
_____
___
___
___
___
_____
____
___
___
___
___
___
___
___
__
___
_ _
________
____
_____
___ __
______
________
_____
___
___
___
___
_____
____
___
___
___
___
___
___
___
__
___
_ _
________
____
_____
___ __
______
________
_____
___
___
___
___
_____
____
___
___
___
___
___
___
___
__
___
_ _
_____(5mks)
e)i
)Gi vetwousesofni t
ricacid.
___
_ _
________
____
_____
___ __
______
________
_____
___
___
___
___
_____
____
___
___
___
___
___
___
___
__
___
_ _
________
____
_____
___ __
______
________
_____
___
___
___
___
_____
____
___
___
___
___
___
___
___
__
___
_ _
________
____
_____
___ __
___
___
_ _
________
____
_____
___ __
______
________
_____
___
___
___
___
_____
____
___
i
i)TheHaberpr ocessisusedt oconv er
tNitr
ogenandHydr
ogentoammonia.
Givethesourcesoftherawmat eri
als.
___
_ _
________
____
_____
___ __
______
________
_____
___
___
___
___
_____
____
___
___
___
___
___
___
___
__
___
_ _
________
____
_____
___ __
______
________
_____
___
___
___
___
_____
____
___
___
___
___
___
___
___
__
___
_ _
________
____
_____
___ __
___

i
i
i)Gi
veanamedcompoundofSulphurwithoxi
dati
onstateof+6.
_
____
____
___
_____
____
____
___
___
___
_______
___
____
_______
____
____
____
___
i
v)Wri
teanequati
ontoshowhowsulphurdi
oxi
debringsaboutaci
drai
n.
_
____
____
___
_____
____
____
___
___
___
_______
___
____
_______
____
____
____
___
___
___
_ _
____
_____
_ __
_
____
____
___
_____
____
____
___
___
___
_______
___
____
__
(
6mks)
(
Total=20mar ks)

4)a)Theel
ementsLi,Na,K,
Be, MgandCaares-
blockelement
s.
i
)Whyar et
heycal
leds-bl
ockelements?
____
____
___
___
______
_____
_____
____
_____
___
___
___
______
_____
___
___
___
___
___
___
___
___
___
___
_
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___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
_
i
i)Usingequationsonl y,
showhowSodi um andBer eactwithwat er.
A)Na+H2O: ___________
_______
_______
_______
______
_______
_ _
________
___
_______
______
___________
________
_______
_______
______
_______
__________
_
B)Be+H2O: ______
__________
_______
_______
______
_______
__________
_____
_______
______
___________
________
_______
_______
______
_______
__________
_
i
ii
)St at
eandexpl ai
nt hetrendinsolubil
it
yofgroupIIsulphatesdownt hegroup.
Trend:_____
________
__ _
_______
_______
_______
______
_______
__________
____
Explanati
on:______
__________
______
________
______
______
_________
_ _
______
_______
______
___________
________
_______
_______
______
_______
__________
_____
___
____
___
___
___
_______
______
___________
________
_______
_______
____
(
5mks)
b)Thi squest i
onconcer nst hegr oupVI Ielement sorHal ogens( F2,Cl
2,Br2,
I2)
.
Giv etwor easonswhyf luor i
neexhi bi
tsonl yoneoxi dat i
onstatei nall
itscompoundswhereas
theot herhalogensshowsev eraloxi dationst ates.
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ _________
__ _
_ ___
______
_ _
_____
___
___
_____
__
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ _________
__ _
_ ___
______
_ _
_____
___
___
_____
__
____ _
______________
_ _
_ _
_ _____ __
(2mks)
c)Wr i
teabal ancedequat ionf ort hel abor ator ypr epar ati
onof ;
i
)Hy drogenchl ori
de( HCl )from Sodi um chl oride.
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ _________
__ _
_ ___
______
_ _
_____
___
___
_____
__
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ __
i
i)Hy drogeni odide(HI)from Sodi um i odi de.
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ _________
__ _
_ ___
______
_ _
_____
___
___
_____
__
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ __
i
ii)Explainwhyy ourequat i
onsi n(i)and( ii
)ar esi mi larordifferent.
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ _________
__ _
_ ___
______
_ _
_____
___
___
_____
__
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ _________
__ _
_ ___
______
_ _
_____
___
___
_____
__
____ _
______________
_ _
_ _
_ _____ __
(
3mks).
d)Accountf orthef ol
lowi ng:
i
)Hy drogenf l
uorideisamuchweakeraci dt hanexpect edinaqueoussol uti
ons.
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ _________
__ _
_ ___
______
_ _
_____
___
___
_____
__
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ _________
__ _
_ ___
______
_ _
_____
___
___
_____
__
____ _
______________
_ _
_ _
_ _____ __
i
i)Hy droiodicacidisast rongeraci dt hanhy drochl oricacidinaqueoussol uti
on.
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ _________
__ _
_ ___
______
_ _
_____
___
___
_____
__
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ _________
__ _
_ ___
______
_ _
_____
___
___
_____
__
____ _
______________
_ _
_ _
_ _____ __( 2mks)
e)Wr i
tebalancedequat ionsf orthef ollowi ngr eactions
i
)I odineandhotconcent ratedPot assium hy dr oxide.
____ _
______________
_ _
_ _
_ _____ ______ _
_ _
_ ____ ______ _________
__ _
_ ___
______
_ _
_____
___
___
_____
__
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_____
_ _
______
____
_ _
________
__ _
____
_ _
_ _
__ _
_____
____
i
i)Chlori
neanddilutePotassium hydroxide.
_
_____
_ _
______
____
_ _
________
__ _
____
_ _
_ _
__ _
_____
_______
____
___
___
_____
_ _
___
_____
_ _
____
_ _
___
_
_
_____
_ _
______
____
_ _
________
__ _
____
_ _
_ _
__ _
_____
____
(
2mks)
f
)Transit
ionmetalsarelocatedbetweengr oupsIIandII
Iel
ementsofthePeri
odicTable.
i
)Whyar eZincandScandi um notconsideredast ransi
ti
onmetal
s?
_
_____
_ _
______
____
_ _
________
__ _
____
_ _
_ _
__ _
_____
_______
____
___
___
_____
_ _
___
_____
_ _
____
_ _
___
_
_____
_ _
______
____
_ _
________
__ _
____
_ _
_ _
__ _
_____
_______
____
___
___
_____
_ _
___
_____
_ _
____
_ _
___
_
_____
_ _
______
____
_ _
________
__

i
i)Iti
seasyt ooxidiseFe2+intoFe3+butnotMn2+i ntoMn3+.Explain
_____
_____
_ __
_________
__ ___
______
______
__ _
__ _
__ __
______
_ _
_____
__ _
_____
__________
_______
_ __
_____
_____
_ __
_________
__ ___
______
______
__ _
__ _
__ __
______
_ _
_____
__ _
_____
__________
_______
_ __
_____
_____
_ __
_________
__ ___
___
i
ii
)Whati sal i
gand?
_____
_____
_ __
_________
__ ___
______
______
__ _
__ _
__ __
______
_ _
_____
__ _
_____
__________
_______
_ __
_____
_____
_ __
_________
__ ___
______
______
__ _
__ _
__ __
______
_ _
_____
__ _
_____
__________
_______
_ __
_____
_____
_ __
_________
__ ___
___
i
v)Whatpr opert
yenabl essomet ransi
tionmet alionsort hei
rcompoundst obeusedas
homogeneouscat alyst
si nsomer eacti
ons?
_____
_____
_ __
_________
__ ___
______
______
__ _
__ _
__ __
______
_ _
_____
__ _
_____
__________
_______
_ __
_____
_____
_ __
_________
__ ___
______
______
__ _
__ _
__ __
_
(4mks)
+ -
g)Cobaltformsacompl excompoundwi tht hef ormula[Co(NH3)4Cl
2]Cl
(i
)Whatist hecoor di
nationnumberofcobal tinthecompl ex?_______
_____
_ _
_______
i
i)Wr i
tet
heequat ionfort hereact
ionbetweent hecompl excompoundandSi lvernit
rate.
_____
_____
_ __
_________
__ ___
______
______
__ _
__ _
__ __
______
_ _
_____
__ _
_____
__________
_______
_ __
_____
_____
_ __
_________
__ ___
______
______
__ _
__ _
__ __
_
i
ii
)Whatt ypeofisomer ism couldbeexhibitedbyt hiscompound?
_____
_____
_ __
_________
__ ___
______
______
__ _
__ _
__ __
______
_ _
_____
__ _
__(
3mks)
(Total=20mar ks)
SECTIONC: ORGANI CCHEMI STRY
5.)a)2.648gofanor ganiccompoundhascomposi ti
onas0. 80gofcar bon,0.198gof
hydrogen,0.
47gofni t
rogenand1.18gofchl
orine.I
fthemolarmassoft hecompoundwas
foundtobe79. 5g/mol,cal
cul
atetheempi
ri
calformulaandhencet hemolecul
arformulaof
thecompound.
i
)Empi ri
calfor
mula:
______
______
_____
____
______
_____
____
___
___
____
__ _
____
_____
____
__ _
_____
_____
____
______
_____
______
______
_____
____
______
_____
____
___
___
____
__ _
____
_____
____
__ _
_____
_____
____
______
_____
______
______
_____
____
______
_____
____
___
___
____
__ _
____
_____
____
__ _
_____
_____
____
______
_____
______
______
_____
____
______
_____
____
___
___
____
__ _
____
_____
____
__ _
_____
_____
____
______
_____

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___
_____
__ __
_____
____
___
___
___
___
___
___
___
___
___
___
___
___
__
i
i
)Molecularfor
mul a:
_
___
_____
__ __
_____
____
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
__
_
___
_____
__ __
_____
____
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
__
_
___
_____
__ __
_____
____
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
__
_
___
_____
_( 3mks)

b)Briefl
ydescribehowt hepresenceoft hefoll
owingelement scanbeconf ir
medi nan
organiccompoundaf t
erthesodi um f
usiontest:
i
)Chl ori
ne.
_________
________
____ _
______
___ _
_ _
___
_ __
______
______
_ _
_____
_ __
____ _
______
_ _
_ __
_____
____
___
_________
________
____ _
______
___ _
_ _
___
_ __
______
______
_ _
_____
_ __
____ _
______
_ _
_ __
_____
____
___
_________
________
____ _
______
__
i
i)Nitrogen.
_________
________
____ _
______
___ _
_ _
___
_ __
______
______
_ _
_____
_ __
____ _
______
_ _
_ __
_____
____
___
_________
________
____ _
______
___ _
_ _
___
_ __
______
______
_ _
_____
_ __
____ _
______
_ _
_ __
_____
____
___
_________
________
____ _
______
__
(
4mks)
c)Statethespect r
oscopi cmet hodwhi chissuit
ablefortheidenti
ficati
onoft hefoll
owingaspect
s
i
nor ganiccompounds:
i
)Mul ti
plebonds:_ _
_ __
_ _
___
__ __
_ _
_______
_____
______
_ _
_____
_ __
_ _
__ _
______
_ _
_ __
_____
_____
i
i)Theposi ti
onofhy drogenat oms:
_________
________
____ _
______
___ _
_ _
___
_ __
______
______
_ _
_____
_ __
____ _
___
(
2mks)
d)Wr it
eoutt hestructuresoftwoopt ical
lyacti
veisomer swiththest r
ucturalformul
a:
CH3CHOHCOOH.
_________
________
____ _
______
___ _
_ _
___
_ __
______
______
_ _
_____
_ __
____ _
______
_ _
_ __
_____
____
___
_________
________
____ _
______
___ _
_ _
___
_ __
______
______
_ _
_____
_ __
____ _
______
_ _
_ __
_____
____
___
_________
________
____ _
______
___ _
_ _
___
_ __
______
______
_ _
_____
_ __
____ _
______
_ _
_ __
_____
____
___
_________
________
____ _
______
___ _
_ _
___
_ __
______
______
_ _
_____
_ __
____ _
______
_ _
_ __
__(2mks)
e)Youar egiventhef ol
lowingcompounds:

CH3CHCH2, C6H6 and CH3CH2CHBr

CH3

i
)Uset heor gani
ccompoundsabov etowrit
esui t
ableequationsthatwil
lill
ustr
atethe
fol
lowingt ypesoforganicreact
ionsandnamet hemajorproducts.
A)Electrophili
caddit
ionreacti
on:____
____
____
______
_____
______
______
_____
____
_
___
_ _
___ __
__ _
_____
______
_______
_____
____
____
______
_____
______
______
_____
B)Electrophili
csubsti
tut
ionreacti
on:
___
_ _
___ __
__ _
_____
______
_______
_____
____
____
______
_____
______
______
_____
____
______
____
____
___
_ _
___ __
__ _
_____
______
_______
_____
____
____
______
C)Nucl eophili
csubsti
tuti
onreacti
on:

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___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
__
_
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
_

i
i
)Writ
ear eact
ionforthenit
rat
ionofBenzene.
_
___
_____
______
____
_ _
_____
_____
_ _
___
____
______
___
___
___
___
___
___
___
___
___
___
___
___
___
___
__
_
___
_____
______
____
_ _
_____
_____
_ _
___
____
______
___
_

Gi
vethemechani
sm fort
hereact
ion.
__
___
____
___
_____
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_____
___
_____
_ _
____
___
___
___
___
___
___
___
___
___
___
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___
___
___
___
____
__
__
___
____
___
_____
___
_____
___
_____
_ _
____
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
____
__
__
___
____
___
_____
___
_____
___
_____
_ _
____
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
____
__
__
___
____
___
_____
___
_____
___
_____
_ _
____
___
___
___
___
___
___
___
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___
___
__(9mks)

(
Tot
al=20mar
ks)
6.
)a)Consi
dert
her
eact
ionsequencebel
ow;

i NaNO2/
HCl i
A:
C6H5NO2 B:
C6H5NH2 C D:
C6H5OH
0OC
i
i
i
v
E:
C6H5CN F
i
)Gi
vet
her
eagent
sandr
eact
ioncondi
ti
onsf
ort
hepr
ocessesbel
ow.

Pr
ocess Reagent React
ionCondi
ti
on

i
)

i
i
)

i
i
i)

i
v)

i
i
)Giv
ethefor
mul
aandnameofcompoundsCandF.
Compound For
mula Name

(
6mks)
b)Considertheorgani
ccompounds:
A:C6H5OH B: C6H5CH2OH C: C6H5COOH D: CH3CH=CH2E:
CH3C≡CH
Howcany oudist
ingui
shchemicall
ybetweencompounds:
i
)AandB?
___
_______
_ _
_____
_____
____
___
_________
___
____
____
_____
___
____
___
____
___
___
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___
___
___
_
___
_______
_ _
_____
_____
____
___
_________
___
____
____
_____
___
____
___
____
___
___
___
___
___
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___
_
11
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_
___
___
___
___
___
___
___
___
___
__

i
i)DandE?
_________
_ _
____
__ __
_______
_____
___ ___
______
_______ __
___________
______ _
____
______
___
_____
__
_________
_ _
____
__ __
_______
_____
___ ___
______
_______ __
___________
______ _
____
______
___
_____
__
_________
_ _
____
__ __
_______
____
i
ii
)AandC?
_________
_ _
____
__ __
_______
_____
___ ___
______
_______ __
___________
______ _
____
______
___
_____
__
_________
_ _
____
__ __
_______
_____
___ ___
______
_______ __
___________
______ _
____
______
___
_____
__
_________
_ _
____
__ __
_______
____
(
6mks)
c)i)Whati sazwi tt
eri
on?
_________
_ _
____
__ __
_______
_____
___ ___
______
_______ __
___________
______ _
____
______
___
_____
__
_________
_ _
____
__ __
_______
_____
___ ___
______
_______
i
i)Wr it
ethestructureofalani
ne( H2NCH( CH3)COOH)i naneut ralmedi um.
_________
_ _
____
__ __
_______
_____
___ ___
______
_______ __
___________
______ _
____
______
___
_____
__
_________
_ _
____
__ __
_______
_____
___ ___
______
_______
i
ii
)St atethephysicalmethodbywhi chami xtureofzwi tter
ionscanbesepar ated.
_________
_ _
____
__ __
_______
_____
___ ___
______
_______ __
___________
______ _
(
3mks)
d)CH3CH2CHO and CH3COCH3r eactwi t
h 2,4-dinit
rophenylhydrazine to gi
ve an or
ange
precipi
tate.
i
)Whatgener alnamei sgiventothistypeofr eaction?
_________
_ _
____
__ __
_______
_____
___ ___
______
_______ __
___________
______ _
i
i)Wr it
eanequat ionforthereacti
onbet ween2, 4-dini
trophenylhydrazineandCH3COCH3.
Statetheconditionforthereacti
on.
_
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___

_
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___
___(
3mks)
e)St
atesuit
abl
ereagent
sandreactioncondi t
ionsf ort hefollowi ngconv er
sions:
i
)CH3CH2BrtoCH3CH2CN.____
_______ _
_ _
_ _
_ ______________ _
_ _________ _
___
_
i
i)CH3CH2CONH2toCH3CH2NH2___
____
___
___
___
___
___
___
___
___
____
___
____
___
____
___
___
_(2mks)
(
Total=20mar
ks)
STOP!GOBACKANDCHECKYOURWORK.

12
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CPO/I
C-Sc