Section A- Q.1 to Q.

18 each Carry (1) Mark

Section B- Q-19 to Q.25 each Carry (2) Mark
Section C- Q.26 to Q.30 each Carry (3) Mark
Section D- Q.31 & Q.32 each Carry (4) Mark
Section E- Q.33 to Q.35 each Carry (5) Mark

Q.1 If the density of a solution is 3.12 gml ! The mass of 1.5 ml som in significant figure is ----

(a) 4.7 g (b) 4680x10-3 g (c) 4.680 g (d) 46.80 g

Q.2 Density of 2.05 M som. Of Acetic acid in water is 1.02 g ml Molality of the solution is.

(a) 1.14 m (b) 3.28 m (c) 2.28 m (d) 0.44 m

Q.3 The shortest wavelength of hydrogen spectrum of lag lyman series is

(a) 1000 A0 (b) 1200 A0 (c) 1100 A0 (d) 911.7 A0

Q.4 Atom of an element has ‘Z’ electrons and its atomic no. is 2Z+6 The number of neutron
are equel to
(a) Z (b) Z+6 (c) Z+3 (d) Z+1
Q.5 Which of the following have highest electron affinity.

(a) F& (b) O2& (c) O& (d) Na$

Q.6 Which of the following have max. number of Unpaired e& ?

(a) Mg2$ (b) Ti3$ (c) V3$ (d) Fe$2

Q.7 Which of the following dose not have zero dipole moment.

(a) CO2 (b) CS2 (c) SO2 (d) CCl4

Q.8 Which of these is most stuble.

(a) H2 (b) H2+ (c) H2 - (d) He2

Q.9 Which of the orbital is involved insp3d hybridization ?

(a) Dry (b) Drz (c) dx2-y2 (d) dz2

Q.10 Bond angle in Sf4 are

(a) 890, 1170 (b) 1200, 1800 (c) 450, 1180 (d) 1100, 900
Q.11 Which of the following is sp2 hybridised

(a) Co2 (b) So3 (c) N2o (d) Co

Q.12 5 moles of AB2 weighs125 g & 10 moles of A2 b2 weighs 300g molar man of A&B
respectively
(a) 5 , 10 (b) 10, 5 (c) 50, 100 (d) 100, 50 g/mol

Q.13 No. of nodes in 3p orbitals are

 (a) 0 (b) 1 (c) 2 (d) 3
Q.14 Element with max negative electron gain enthaipy

(a) F (b) O (c) Cl (d) N

In the following question (Q.15 to Q.18) a statement of assertion followed by a statement of

reason is given choose the correct answer out of the following.
(A) A&R both are correct & reason is correct explanation.
(B) A&R both are correct But ‘R’ is wrong.
(C) A is correct But R is Wrong.
(D) Ais wrong but R is Correct.
Q.15 A→ Two nodal planes are present in 3 dry.

B→ Number of angular ndes agnal to 2.

Q.16 A→ Electron gain enthalpy is more in orygen then sulphur.

B→ Inter electronic repulsion is more in orygen then sulphur.

Q.17 A→ H-S-H bond angle in h2s is less then H-O-H bond angle in water.
B→ ‘S’ is bigger in size then ‘O’

Q.18 A→ So2 is molecule, sp2 hybridised, one lone pair

B→ So3 is planer.

Q.19 State (I) law of multiple proportion (II) Avogadro’s law

Q.20 What is the maximum number of emission lines when the excited electron of H atom in
N=6 drops to the ground state.

Q.21 Which element is named by

(a) Lawrence Berkley laboratory
(b) Seaborg’s group.

Q.22 Write the significance of dipole moment.

Q.23 Draw the resonating structure of

(a) No2 (b) No3

Q.24 Write the general EC of s,p,d,f block elements.

Q.25 Calculate the cone. Of nidric acid in moles per liter in a sample which has density of 1.41
gml. And mass % of Nitric acid is 69% in it.
Q.26 State (a) Heisenberg uncertainity principle
 (b) Pauli’s exclusion principle.

Q.27 (a) Which out of NH3 and NF3 have ligher dipole moment and why.
(b) Bwhy Beh2 is non polar while Be-H bends are polar.

Q.28 Decribe the hybridization in Pcl5 and explain why Co-oxial bonds are bigger then
equatorial bonds.

Q.29 What is the difference between electron gain enthalpy and elecronegativity.

Q.30 The mass of an electron is 9.1x10 -31 leg.If its K.F is 3zx10-25 I calculate it’s wabelength.

Q.31 Read the passage given below and answer the following questions.
Group 3 to 12 are called d-block elements with general electronic configuration (n-1)d4-
10 ns 0-2 They are all metals. They mostly form colured ions, complexes, show varable
osidation states, paramagnetism and used as catalyst. Zn, Cd, Hg do not show most of
properties of transition elements due to completely filled d-orbitals.
Lanthanoids and actinoids belong to f-block elements because last electron enters f-
orbital with general electronic configuration (n-2)f4-14(n-1)d0-1ns2. They are all metals
called inner transition elements. The properties of elements within series are similar. All
actinoids are radioactive. The nelements after uranium are called Transuranic elements.
(i) Which of the following element belongs to 2d series ?
(a) Zn (b) Cd (c) Hg (d) Pd
(ii) Transition metals are
(a) more reactive tjam s-block (b) less reactive than s-b;ock
(c) more electropositive than p-block (d) Both (b) and (c)
(iii) Which of the following is radioactive ?
(a) La (b) Ce (c) Pm (d) Eu
(iv) Which of the following is not coloured ?
(a) Cu2+ (b)Cr3+ (c) Co2+ (d) Zn2+
(v) Which of the following Transuranic element?
(a) Ac (b) Th (c) Pa (d) Np

Q.32 Read the passage given below and answer the following questions :
Concentrations of solution can be expressed in terms of mass percentage, volume
percentage, mass/volume percentage. Molarity, molaliy and mole fractions are also
used to expres concentration of solution. Molality can be converted into molarity and
vice-versa if density of solution is given Mole fraction of solute can be converted into
molality and vice-varsa if we know molar mass of solbvent.
The following question are multiple choice questions. Choose the most appropriate
answer :
(i) The mole fraction of solute in 1 m aqueous solution is
1 18 1000 1000
a) 1+1000 b) 1000 c) 18 d) 1 + 18
18
 (ii) The number of H2O is molecules in 18 ml. of h2 O (Molar mass=18 g mol-1,
density of h2O-1 g/ml)

(a) 6.022x1022 (b) 6.022x1023

(b) (c) 6.022x1024 (d) 6.022x1025 molecules
(iii) Molality is defined as number of moles of solute per
(a) Kg of solution (b) kg of solvent
(c)Litre of solution (d) Litre of solvent
(iv) 1 M solution of NaNo3 has density 1.25 g cm-3 Calculate its molality.
(Mol. Weight of NaNo3= 85 g mol-1)
(a) 0.148 m (b) 0.648 m (c) 0.858 m (d) 0.985 m
(iv) The unit of molarity is
(a) Mol K-1 (b) mol/g (c) no unit (d) g/litre

Q.33 An electron in an H-atom in its ground state absorbs 1-5 times as much energy as the
minimum energy required for it to escope from the atom.
What is the wavelength of emitted electron.

Q.34 (a) What is resonance

(b) Using concept of hybridization explain the shape of
(i) c2 H4 (ii)C2H2 (ii) C2 H2 moleale
(C) State the type of hybrid orbital associated with
(i) p in pf5 (ii)Cl in Hcl04

A.35 Which is cheaper ?

40% Hcl at the rate of Rs. 6 per kg or 80% H2So4 at6 the rate of Rs. 3.5 per kg to
neutralize 17 kg of KOH