Chapter 4
Chapter 4
Assessment Guide
Dr PP Mpungose
Office: 2.20B, D6 Campus
E-mail: [email protected]
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SECTION 1: GENERAL INFORMATION ON THE CONCEPTS OF WATER
QUALITY
Familiarise
yourself with the Where does the What is water What is water
concept of water water come from? quality? pollution?
quality
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WHERE DOES
WATER COME
FROM ?
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WHAT IS WATER QUALITY ?
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WHAT IS WATER QUALITY ?
1. MICROBIOLOGICAL QUALITY:
• Refers to the presence of organisms that cannot be seen by the naked eye, such as
protozoa, bacteria and viruses.
• Many of these microbes are associated with the transmission of infectious waterborne
diseases such as gastro-enteritis and cholera.
• Since it is difficult and costly to detect these microbes (pathogens), it is common practice
to use microbiological indicators as an indication of recent faecal pollution and the
potential risk of infectious diseases from the water. Faecal and total coliforms are
commonly used as indicators to determine the microbiological quality of domestic water
supplies.
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WHAT IS WATER QUALITY ?
2. PHYSICAL QUALITY:
• Refers to water quality properties that may be determined by physical methods such as
conductivity, pH and turbidity measurement.
• The physical quality mainly affects the aesthetic quality (taste, odour and appearance) of
water.
3. CHEMICAL QUALITY:
• Refers to the nature and concentration of dissolved substances such as salts, metals
and organic chemicals.
• Many chemical substances in water are essential as part of the daily intake required, but
at high concentrations they make water unpalatable and cause illnesses.
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WHAT IS WATER POLLUTION?
Where human activity occurs, wastes may get into the water source. These wastes can pose
serious risks for domestic water users. Human activities that typically cause problems for
domestic water quality are:
• intensive irrigation,
• mining activities,
• industries, and
• dense human settlements (particularly if these settlements have poor sanitation facilities).
Domestic water quality is affected by nearby human activities which may pollute the water, as
well as by natural geological conditions in the area.
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WHO USES WATER ?
• The environment also requires water if it is to survive. This includes water for animals and
fish living in the water, as well as for plants growing in rivers or streams, or next to them.
The aquatic environment is part of the resource.
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WHAT IS DOMESTIC USE OF WATER ?
These are:
• for survival - drinking and food preparation,
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HOW DOES WATER QUALITY AFFECT THE DOMESTIC USER?
The health effects of water quality on the user can be divided into two types:
1. ACUTE EFFECTS: Effects that can be seen after a very short time.
2. CHRONIC EFFECTS: Effects that show only after the water has been used for a long time.
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SECTION 2: COLLECT AND PROCESS THE DATA
How frequently
Which substances
should the
must be included
substances be
in the assessment?
measured?
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COLLECTING AND PROCESSING THE DATA
2. COLLECT DATA
• Collect samples and analyse, or consult existing
databases.
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COLLECTING AND PROCESSING THE DATA:
DETERMINE THE MINIMUM DATA NEEDS
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THE WATER SUPPLY SYSTEM SHOWING THE POINTS THAT SHOULD BE SAMPLED TO
ASSESS DOMESTIC WATER QUALITY.
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COLLECTIMG AND PROCESSING THE DATA:
DETERMINE THE MINIMUM DATA NEEDS
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COLLECTING AND PROCESSING THE DATA:
DETERMINE THE MINIMUM DATA NEEDS
(b) What substances are important for domestic water users?
Table 1A: Substances which are general indicators of water quality
GROUP A
Electrical conductivity (total dissolved salts) Conductivity is an indicator of total dissolved salts (TDS), and also establishes if
the water is drinkable and capable of quenching thirst.
Faecal coliforms This is an indicator of the possible presence of disease-causing organisms. It
establishes if water is polluted with faecal matter.
pH value This has a marked effect on the taste of the water and also indicates possible
corrosion problems and potential copper, zinc and cadmium problems.
Turbidity This affects the appearance, and thus the aesthetic acceptability, of the water.
Turbidity is commonly high in surface waters.
Free available chlorine (Residual chlorine) This is a measure of the effectiveness of the disinfection of the water. Residual
chlorine is the chlorine concentration remaining at least 30 minutes after
disinfection. There should be residual chlorine in the water, but if concentrations
are too high it may impart an unpleasant taste and smell to the water.
Group A substances are indicators of potential problems and should be frequently tested at all points in the water supply system,
irrespective of the source of the water. (Free available (or residual) chlorine has to be measured only if the water has been treated with
chlorine-based disinfectants.)
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COLLECTING AND PROCESSING THE DATA:
DETERMINE THE MINIMUM DATA NEEDS
(b) What substances are important for domestic water users?
Table 1B: Substances which are commonly present at concentrations which may lead to health problems
GROUP B
Nitrate & nitrite These are common in groundwater (borehole) samples, particularly in areas of intensive agricultural
activity, or where pit toilets are used. Severe toxic effects are possible in infants.
Fluoride This is often elevated in groundwater in hot, arid areas. Can cause damage to the skeleton and the
marking of teeth.
Sulphate This is particularly common in mining areas. Causes diarrhoea, particularly in users not accustomed to
drinking water with high sulphate concentrations.
Chloride This is often elevated in hot, arid areas, and on the western and southern Cape coasts (particularly in
groundwater). May cause nausea and vomiting at very high concentrations.
Arsenic This may be present in groundwater, particularly in mining areas. Can lead to arsenic poisoning.
Total coliforms This provides an additional indicator of disease-causing organisms, and the effectiveness of
disinfection.
The presence/concentration of Group B substances should be determined before the water is supplied. The frequency of
testing depends on the source and the treatment applied. Note that substances of concern due to pollution sources in the
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area, may have to be added to Group B.
COLLECTING AND PROCESSING THE DATA:
DETERMINE THE MINIMUM DATA NEEDS
Table 1C: Substances which occur less frequently at concentrations of real concern to health
GROUP C
Cadmium This usually occurs along with zinc in acidic waters where it may have been dissolved
from appliances.
Copper This affects the colour of the water and can cause upset stomachs. Normally occurs only
when copper piping is used to carry water with a low pH value.
Group C substances should be tested for at point of use only in areas of the country where soft water of a low pH
value is used.
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COLLECTING AND PROCESSING THE DATA:
DETERMINE THE MINIMUM DATA NEEDS
(b) What substances are important for domestic water users?
Table 1D: Substances which may commonly be present at concentrations of aesthetic or economic concern in
domestic water sources
GROUP D
Manganese This is common reason for brown or black discolouration of fixtures and for stains in laundry. Can be common in bottom
waters of dams, or in mining areas.
Zinc This affects the taste of water. Usual cause is acidic water dissolving zinc from galvanised pipes or from appliances.
Iron This affects the taste of the water and may also cause a reddish brown discolouration. Can be common in bottom waters of
dams, or in mining areas. Can cause growth of slimes of iron reducing bacteria that ultimately appear as black flecks in the
water.
Potassium This affects the taste of the water and is bitter at elevated concentrations.
Sodium This affects the taste of the water. Often elevated in hot, arid areas and on the western and southern Cape coasts (particularly
in groundwater).
Calcium This can cause scaling and can reduce the lathering of soap.
Magnesium This affects the taste of the water. It is bitter at high concentrations. Common in some areas it adds to the effect of calcium.
Hardness, Total This is a combination of calcium and magnesium. It is associated with scaling and inhibition of soap lathering.
The presence of Group D substances should be determined at least when assessing the water for the first time.
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Thereafter they can be included when there is reason to believe that their concentrations may have changed.
COLLECTING AND PROCESSING THE DATA:
DETERMINE THE MINIMUM DATA NEEDS
These are:
• where are you assessing the water? (i.e., at the source, the treatment works, or
at the point of use),
• what is the source of the water? (i.e., river, stream, well, borehole, dam or
rainwater tank),
• what pollution problems may occur in the area?, and
• what problems have been experienced with similar sources in the vicinity?
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TABLE 2: THE SUBSTANCES WHICH MUST BE INCLUDED WHEN ASSESSING DOMESTIC WATER QUALITY AT DIFFERENT
POINTS IN THE SUPPLY SYSTEM, AND FROM DIFFERENT SOURCES
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HOW FREQUENTLY SHOULD THE SUBSTANCES BE MEASURED?
(d) Determine minimum data required.
The concentrations of the substances in water are never constant. In general, the more often a substance is measured,
the more reliable the assessment of the water quality will be.
Table 2: The minimum and recommended numbers of samples and sampling frequencies for different points in the water supply system
MINIMUM RECOMMENDED
SAMPLING POINT
Number of Sampling Number of samples Sampling frequency
Samples / year frequency / year
S River/stream/spring/well 4 3 - monthly 26 2 - weekly
O
U Dam 2 6 - monthly 12 1 - monthly
R
C Borehole 1 - 2 6 - monthly
E
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1 Depends on size of treatment works, the variability in the water quality and the number of people supplied with water.
COLLECTING AND PROCESSING THE DATA:
COLLECT THE DATA
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COLLECTING AND PROCESSING THE DATA:
PROCESS THE DATA
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THE PROCESSING OF THE WATER QUALITY DATA FOR THE ASSESSMENT.
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A STEP-BY-STEP PROCEDURE FOR CLASSIFYING WATER
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CLASSIFY THE WATER
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CLASSIFY THE WATER
The guidelines are presented in terms of a simple colour-coded classification system for the
substances outlined in the previous section as important for domestic users.
The classification is based on increasing concentrations of these substances, and allows for
classifying the:
• health effects of water used for drinking, as well as aesthetic effects of water used for
drinking,
• health and aesthetic effects of water used for food preparation,
• health and aesthetic effects of water used for bathing, and
• the health and aesthetic effects of water used for washing clothes.
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CLASS/COLOUR DESCRIPTION EFFECTS
Table 3: Structure of the classification system describing the effects of
the different classes of water on the various domestic uses of water Class 0 / blue Ideal water quality • Drinking Health: No effects, suitable for many generations.
• Drinking Aesthetic: Water is pleasing.
• Food preparation: No effects.
• Bathing: No effects.
• Laundry: No effects.
Class 1 / Green Good water quality • Drinking Health: Suitable for lifetime use. Rare instances of sub-clinical effects.
• Drinking Aesthetic: Some aesthetic effects may be apparent.
• Food preparation: Suitable for lifetime use.
• Bathing: Minor effects on bathing or on bath fixtures.
• Laundry: Minor effects on laundry or on fixtures.
Class 2 / Yellow Marginal water quality • Drinking Health: May be used without health effects by the majority of individuals of all ages, but may cause effects in some
individuals in sensitive groups. Some effects possible after lifetime use.
• Drinking Aesthetic: Poor taste and appearance are noticeable.
• Food preparation: May be used without health or aesthetic effects by the majority of individuals.
• Bathing: Slight effects on bathing or on bath fixtures.
• Laundry: Slight effects on laundry or on fixtures.
Class 3 / red Poor water quality • Drinking Health: Poses a risk of chronic health effects, especially in babies, children and the elderly.
• Drinking Aesthetic: Bad taste and appearance may lead to rejection of the water.
• Food preparation: Poses a risk of chronic health effects, especially in children and the elderly.
• Bathing: Significant effects on bathing or on bath fixtures.
• Laundry: Significant effects on laundry or on fixtures.
Class 4 / Purple Unacceptable water • Drinking Health: Severe acute health effects, even with short-term use.
quality • Drinking Aesthetic: Taste and appearance will lead to rejection of the water.
• Food preparation: Severe acute health effects, even with short-term use.
• Bathing: Serious effects on bathing or on bath fixtures.
• Laundry: Serious effects on laundry or on fixtures.
CLASSIFY THE WATER
• Water in the Yellow class may be safe for use under certain conditions, but should be used with
caution:
- It is most important to sample and assess the quality of water in the Yellow class regularly.
- Expert advice should be called upon to determine the real threat to sensitive users.
- Sensitive groups should also be informed when water falls into the Yellow class.
•Water falling into the Red class should be considered unsafe for use and should be treated.
Water in the Red class may be used for short-term emergency supply, but only where no
alternative supplies are available.
•Water falling into the Purple class should be considered unsafe for use and should be treated.
Water in the Purple class is unsafe even for short-term emergency use.
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CLASSIFY THE WATER
v People differ widely in their responses to water quality. What is safe for one person is not
necessarily safe for another. Even in the Blue (ideal) class, there may be a few individuals
who show some negative response. Where a few individuals may experience negative effects,
these individuals have been identified as "sensitive groups".
v Babies are generally more susceptible to poor water quality, and are identified as "sensitive”
for most substances. But it is important to note that not all babies will show negative effects,
and that normal, healthy babies will not necessarily be affected.
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CLASSIFY THE WATER
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CLASSIFY THE WATER
(e) How is water classified ?
STEP 1:
•Determine the class per substance for each of the domestic uses:
i. Check to see if the data is shown in the same units as used in the Guidelines (see part 2).
In most cases the concentrations in the tables are in milligrams per litre (mg/L]).
ii. Compare the maximum and average concentrations of each substance to the
concentration ranges in the left hand column of the Guidelines. The colour class of the
substance is then read off in the columns for each use of domestic water in the right hand
column.
iii. For some substances (those which have acute effects only) only the maximum value is
needed. For pH and for free available chlorine, both the maximum and minimum values
should be used. An example of how to do this is shown in the case study.
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CLASSIFY THE WATER
(e) How is water classified ?
STEP 2:
Determine the overall class of the water supply:
i. After comparing all the data to the guidelines, the worst class for a use (drinking, cooking or
laundry and other uses) is used to determine the substance class as shown in Table on the
next slide. The worst substance class will then determine the overall class of water supply.
An example of how to do this is shown in Table D1 (p 26).
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SUBSTANCE WORST CLASS PER USE SUBSTANCE CLASS
• Faecal coliforms
Green not used*** Green
• Total coliforms
(cause acute effects – use maximum value only)
Table 4: Classification of substances
3. As for 1, but use minimum value instead of maximum when pH values are below 7,
Free available chlorine, or chlorine is below 0,3 mg/L
pH
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SECTION 4: DETERMINE TREATABILITY
What other
How effective
What treatment is methods can be
should treatment
available? used to improve
be?
water quality
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DETERMINE TREATABILITY
2. DETERMINE TREATABILITY
a) Identify the first substance of concern (Yellow, Red or Purple class).
b) Identify possible treatment from Table on the next slide.
c) Determine if treatment is economically and technically feasible with respect to the user.
d) Identify next substance of concern and repeat steps (b) to (c) until all substances have
been accounted for.
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DETERMINE TREATABILITY
EXPENSIVE Easy • Treatment does not require trained people to administer (easy to administer).
• Chemicals or materials to treat the water are expensive.
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DETERMINE TREATABILITY
Table 6: Some available treatment options for the improvement of microbiological quality
TREATMENT
VARIABLE
Easy and expensive Difficult and cheap Difficult and expensive
Easy and cheap
• Ultrafiltration
• Boil water
• Ozone
Faecal coliforms & total • Add household bleach • Hypochlorites
• Fast sand filtration • Chlorine dioxide
coliforms • Expose to sunlight • Ultraviolet radiation
• Chlorine gas
• Slow sand filtration
• Chlorination
• Boil water
Excess Free available chlorine • Allow water to stand • Activated carbon filtration -
-
in an open container
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DETERMINE TREATABILITY
Table 7: Some available treatment options for the improvement of physical quality
TREATMENT
VARIABLE
Easy and cheap Easy and expensive Difficult and cheap Difficult and expensive
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DETERMINE TREATABILITY
Table 8: Some available treatment options for the improvement of chemical quality
TREATMENT
VARIABLE
Easy and cheap Easy and expensive Difficult and cheap Difficult and expensive
• Reverse osmosis
Chloride - • Ion exchange —
• Electrolysis
• Chemical precipitation, settlement and filtration
Copper - • Ion exchange —
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alumina
DETERMINE TREATABILITY
Table 8: Some available treatment options for the improvement of chemical quality (continued)
(continued) TREATMENT
VARIABLE
Easy and
Easy and cheap Difficult and cheap Difficult and expensive
(continued) expensive
• Precipitation with sodium carbonate, settlement and
Hardness, filtration. This must be done as an additional step to the
— • Ion exchange —
Total normal treatment process,
• Ion exchange
• Oxidation through
aeration. Operation is • Removal as part of normal treatment
• Precipitation, sedimentation and filtration. Strong oxidants
easy, but design requires process. High iron concentrations may
Iron • Ion exchange and/or high lime treatment.
expertise. require additional chlorine for end-
• Add bleach and filter point chlorination.
after allowing to settle.
• Precipitation with sodium carbonate, settlement and
— filtration. This must be done as an additional step to the
Magnesium • Boiling of water • Ion exchange
normal treatment process.
• Ion exchange
Nitrate/ • Denitrification with anaerobic biological reduction.
— —
Nitrite Ion exchange • Reverse osmosis
• Ion exchange
• Potassium
— — • Reverse osmosis
• Sodium • Ion exchange
• Electrolysis
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• Sulphate
SECTION 5: INTERPRETATION OF WATER QUALITY INFORMATION
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TYPICAL WATER QUALITY PROBLEMS IN SOUTH AFRICA
•However, elevated salt concentrations (TDS, sodium and chloride) are also common in many
parts of the country. In groundwater the most common problems are high nitrate/nitrite and
fluoride concentrations.
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TYPICAL WATER QUALITY PROBLEMS IN SOUTH AFRICA
1. Faecal pollution
• High faecal and total coliform counts (used as indicator organism to indicate recent faecal
pollution) occur in most surface water near dense human settlements.
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TYPICAL WATER QUALITY PROBLEMS IN SOUTH AFRICA
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human health. Generally, however, these toxins are also removed by the above processes.
SUBSTANCES OF CONCERN TO THE DOMESTIC WATER USER
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MICROBIOLOGICAL WATER QUALITY
GUIDELINES
PHYSICAL WATER QUALITY
GUIDELINES
CHEMICAL WATER QUALITY
GUIDELINES
CHEMICAL WATER QUALITY
GUIDELINES
CHEMICAL WATER QUALITY
GUIDELINES
THANK YOU…
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