FINAL JEE–MAIN EXAMINATION – JANUARY, 2024

(Held On Thursday 01st February, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

MATHEMATICS TEST PAPER WITH ANSWER

SECTION-A 1 x
4. If tanA = , tan B =
1. A bag contains 8 balls, whose colours are either x( x 2 + x + 1) x2 + x + 1
white or black. 4 balls are drawn at random
and
without replacement and it was found that 2 balls
1

are white and other 2 balls are black. The (
tan C = x −3 + x −2 + x −1 ) 2 , 0  A, B, C 
2
, then
probability that the bag contains equal number of
A + B is equal to :
white and black balls is:
(1) C (2)  − C
2 2
(1) (2) 
5 7 (3) 2 − C (4) −C
2
1 1
(3) (4)
7 5
5. If n is the number of ways five different employees
can sit into four indistinguishable offices where


any office may have any number of persons
4
2. The value of the integral xdx including zero, then n is equal to:
 sin 4
(2 x) + cos 4 (2 x)
equals :
(1) 47
0

2 2 2 2 (2) 53
(1) (2)
8 16 (3) 51
2 2 2 2 (4) 43
(3) (4)
32 64

6. Let S={ z  C : z − 1 = 1 and

 2 1  1 0 
If A =  , B = ( )
2 − 1 ( z + z ) − i ( z − z ) = 2 2 }. Let z1, z2
T
3. 1 1  , C = ABA and X
 −1 2   

= ATC2A, then det X is equal to :  S be such that z1 = max z and z2 = min z .

zs zs
(1) 243 2
Then 2z1 − z2 equals :
(2) 729
(3) 27 (1) 1 (2) 4
(4) 891 (3) 3 (4) 2

1
7. Let the median and the mean deviation about the 12. If the system of equations
median of 7 observation 170, 125, 230, 190, 210, a, b 2x + 3y – z = 5
x + y + 3z = –4
205
be 170 and respectively. Then the mean 3x – y + z = 7
7
has infinitely many solutions, then 13  is equal
deviation about the mean of these 7 observations is :
to
(1) 31 (2) 28 (1) 1110 (2) 1120
(3) 30 (4) 32 (3) 1210 (4) 1220

13. For 0 <  < /2, if the eccentricity of the hyperbola

8. Let a = −5iˆ + ˆj − 3kˆ, b = iˆ + 2 ˆj − 4kˆ and
x2 – y2cosec2 = 5 is 7 times eccentricity of the
c= ((( ) ) ) ( )
a  b  iˆ  iˆ  iˆ. Then c  −iˆ + ˆj + kˆ is ellipse x cosec  + y = 5, then the value of  is :
2 2 2

 5
equal to (1) (2)
6 12
(1) –12 (2) –10  
(3) (4)
(3) –13 (4) –15 3 4

14. Let y = y(x) be the solution of the differential

9. Let S = {x  R : ( 3 + 2) x + ( 3 − 2) x = 10}.
dy
equation = 2x (x + y)3 – x (x + y) – 1, y(0) = 1.
Then the number of elements in S is : dx
(1) 4 (2) 0 2
 1  1 
(3) 2 (4) 1 Then,  + y    equals :
 2  2 
4 3
(1) (2)
10. The area enclosed by the curves xy + 4y = 16 and 4+ e 3− e
x + y = 6 is equal to : 2 1
(3) (4)
(1) 28 – 30 loge 2 (2) 30 – 28 loge 2 1+ e 2− e

(3) 30 – 32 loge 2 (4) 32 – 30 loge 2

15. Let f : R → R be defined as

 a − b cos 2x
11. Let f : R → R and g : R → R be defined as  ; x0
 x2
log e x x0 
, f(x) =  x 2 + cx + 2 ; 0  x 1
f(x) =  − x and  2x + 1
 e , x0 ; x 1


 x , x0
g(x) =  x . Then, gof : R → R is :
 e , x0 If f is continuous everywhere in R and m is the
number of points where f is NOT differential then
(1) one-one but not onto
(2) neither one-one nor onto m + a + b + c equals :

(3) onto but not one-one (1) 1 (2) 4

(4) both one-one and onto (3) 3 (4) 2

2
 x2 y2 20. If the shortest distance between the lines
16. Let + = 1, a > b be an ellipse, whose
a2 b2 x −  y − 2 z −1 x − 3 y −1 z − 2
= = and = =
1 −2 1 1 1 −2 1
eccentricity is and the length of the latus
2 is 1, then the sum of all possible values of  is :
rectum is 14 . Then the square of the eccentricity
(1) 0 (2) 2 3
x2 y2
of − = 1 is :
a2 b2 (3) 3 3 (4) −2 3
(1) 3 (2) 7/2
(3) 3/2 (4) 5/2 SECTION-B
21. If x = x(t) is the solution of the differential
17. Let 3, a, b, c be in A.P. and 3, a – 1, b + l, c + 9 be
equation (t + 1)dx = (2x + (t + 1)4) dt, x(0) = 2,
in G.P. Then, the arithmetic mean of a, b and c is :
then, x(1) equals ___________.
(1) –4 (2) –1
(3) 13 (4) 11
22. The number of elements in the set
18. Let C : x2 + y2 = 4 and C’ : x2 + y2 - 4x + 9 = 0 be S = {(x, y, z) : x, y,z  Z, x + 2y + 3z = 42, x, y, z
two circles. If the set of all values of  so that the  0} equals __________.
circles C and C’ intersect at two distinct points, is
R– [a, b], then the point (8a + 12, 16b – 20) lies on
23. If the Coefficient of x30 in the expansion of
the curve :
6
(1) x2 + 2y2 – 5x + 6y = 3  1
1 +  (1 + x2)7 (1 – x3)8 ; x  0 is , then ||
2
(2) 5x – y = – 11 x
(3) x2 – 4y2 = 7 equals ___________.
2 2
(4) 6x + y = 42

24. Let 3, 7, 11, 15, ...., 403 and 2, 5, 8, 11, . . ., 404

 1
19. If 5f(x) + 4f   = x2 – 2,  x  0 and y = 9x2f(x), be two arithmetic progressions. Then the sum, of
 x
the common terms in them, is equal to _________.
then y is strictly increasing in :
 1   1 
(1)  0,    , 
 5  5  25. Let {x} denote the fractional part of x and

 1   1  cos −1 (1 − {x}2 )sin −1 (1 − {x})

(2)  − ,0   ,  f(x) = , x  0. If L
 5   5  {x} − {x}3

 1   1  and R respectively denotes the left hand limit and the

(3)  − ,0   0, 
 5   5 32
right hand limit of f(x) at x = 0, then (L2 + R2) is
 1   1  2
(4)  −,    0, 
 5  5 equal to ____________.

3
26. Let the line L : 2 x + y =  pass through the point 29. Let the line of the shortest distance between
of the intersection P (in the first quadrant) of the circle the lines
x2 + y2 = 3 and the parabola x2 = 2y. Let the line L ( ) (
L1 : r = ˆi + 2ˆj + 3kˆ +  ˆi − ˆj + kˆ and )
: r = ( 4iˆ + 5jˆ + 6kˆ ) +  ( ˆi + ˆj − kˆ )
touch two circles C1 and C2 of equal radius 2 3 . If
L2
the centres Q1 and Q2 of the circles C1 and C2 lie on the
intersect L1 and L2 at P and Q
y-axis, then the square of the area of the triangle
PQ1Q2 is equal to ___________. respectively. If ( , , ) is the mid point
of the line segment PQ, then 2(  +  + )

27. Let P = {z  : |z + 2 – 3i |  1} and is equal to ___________.

Q = {z  : z (l + i) + z (1 – i)  –8} . Let in
30. Let A= {1, 2, 3, . . 20}. Let R1 and R2 two
P Q, |z – 3 + 2i| be maximum and minimum at
relation on A such that
z1 and z2 respectively. If |z 1|2 + 2|z|2 =  +  2,
R1 = {(a, b) : b is divisible by a}
where ,  are integers, then  +  equals R2 = {(a, b) : a is an integral multiple of b}.
________. Then, number of elements in R 1 – R 2 is equal
to ________.
 8 2 cos xdx
28. If  =  +  loge (3 + 2
2
−
2 (1 + esin x )(1 + sin 4 x)

2 ), where ,  are integers, then 2 + 2 equals

___________.

4
 FINAL JEE–MAIN EXAMINATION – JANUARY, 2024
(Held On Thursday 01st February, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

PHYSICS TEST PAPER WITH ANSWER

SECTION-A 35. Two identical capacitors have same capacitance C.
31. With rise in temperature, the Young's modulus of One of them is charged to the potential V and other
elasticity to the potential 2V. The negative ends of both are
(1) changes erratically connected together. When the positive ends are
(2) decreases also joined together, the decrease in energy of the
(3) increases combined system is :
(4) remains unchanged 1
(1) CV 2 (2) 2 CV2
4
32. If R is the radius of the earth and the acceleration 1 3
due to gravity on the surface of earth is g = 2 m/s2, (3) CV 2 (4) CV 2
2 4
then the length of the second's pendulum at a
height h = 2R from the surface of earth will be,: 36. Two moles a monoatomic gas is mixed with six
2 1 moles of a diatomic gas. The molar specific heat of
(1) m (2) m
9 9 the mixture at constant volume is :
4 8 9 7
(3) m (4) m (1) R (2) R
9 9 4 4
3 5
(3) R (4) R
33. In the given circuit if the power rating of Zener 2 2
diode is 10 mW, the value of series resistance Rs to
regulate the input unregulated supply is : 37. A ball of mass 0.5 kg is attached to a string of
RS
length 50 cm. The ball is rotated on a horizontal
+
circular path about its vertical axis. The maximum
Vs RL = 1k  tension that the string can bear is 400 N. The
Vz = 5V
8V maximum possible value of angular velocity of the
– ball in rad/s is,:
(1) 5k (2) 10 (1) 1600 (2) 40
(3) 1k (4) 10k (3) 1000 (4) 20

34. The reading in the ideal voltmeter (V) shown in the 38. A parallel plate capacitor has a capacitance
given circuit diagram is : C = 200 pF. It is connected to 230 V ac supply
0.2 0.2 0.2
with an angular frequency 300 rad/s. The rms
5V 5V 5V value of conduction current in the circuit and
0.2
5V V
displacement current in the capacitor respectively
0.2 5V
are :
0.2 0.2 0.2
(1) 1.38 A and 1.38 A
5V 5V 5V (2) 14.3 A and 143 A
(1) 5V (2) 10V (3) 13.8 A and 138 A
(3) 0 V (4) 3V (4) 13.8 A and 13.8 A

5
39. The pressure and volume of an ideal gas are related 44. The radius (r), length (l) and resistance (R) of a
as PV3/2 = K (Constant). The work done when metal wire was measured in the laboratory as
the gas is taken from state A (P1, V1, T1) to state r = (0.35 ± 0.05) cm
B (P2, V2, T2) is : R = (100 ± 10) ohm
(1) 2(P1V1 – P2V2) l = (15 ± 0.2) cm
(2) 2(P2V2 – P1V1) The percentage error in resistivity of the material
(3) 2( P1 V1 − P2 V2 ) of the wire is :
(1) 25.6% (2) 39.9%
(4) 2(P2 V2 − P1 V1 ) (3) 37.3% (4) 35.6%

40. A galvanometer has a resistance of 50  and it 45. The dimensional formula of angular impulse is :
allows maximum current of 5 mA. It can be (1) [M L–2 T–1]
converted into voltmeter to measure upto 100 V by (2) [M L2 T–2]
connecting in series a resistor of resistance (3) [M L T–1]
(1) 5975  (4) [M L2 T–1]
(2) 20050 
(3) 19950  46. A simple pendulum of length 1 m has a wooden
(4) 19500  bob of mass 1 kg. It is struck by a bullet of mass
10–2 kg moving with a speed of 2 × 102 ms–1. The
41. The de Broglie wavelengths of a proton and an  bullet gets embedded into the bob. The height to
which the bob rises before swinging back is.
particle are  and 2  respectively. The ratio of the
(use g = 10 m/s2)
velocities of proton and  particle will be :
(1) 0.30 m (2) 0.20 m
(1) 1 : 8 (2) 1 : 2
(3) 0.35 m (4) 0.40 m
(3) 4 : 1 (4) 8 : 1

47. A particle moving in a circle of radius R with

42. 10 divisions on the main scale of a Vernier calliper
uniform speed takes time T to complete one
coincide with 11 divisions on the Vernier scale. If
revolution. If this particle is projected with the
each division on the main scale is of 5 units, the
same speed at an angle  to the horizontal, the
least count of the instrument is :
maximum height attained by it is equal to 4R. The
1 10
(1) (2) angle of projection  is then given by :
2 11
1
50 5  2gT 2  2
(3) (4) (1) sin −1  2 
11 11
  R 
1
43. In series LCR circuit, the capacitance is changed
 2R  2
from C to 4C. To keep the resonance frequency (2) sin −1  2
unchanged, the new inductance should be :  2gT 
1 1
(1) reduced by L  2gT 2  2
4 (3) cos −1  2 
(2) increased by 2L   R 
3 1
(3) reduced by L
4  R  2
(4) cos −1  2
(4) increased to 4L  2gT 

6
48. Consider a block and trolley system as shown in SECTION-B
figure. If the coefficient of kinetic friction between 51. A regular polygon of 6 sides is formed by bending a
wire of length 4  meter. If an electric current of
the trolley and the surface is 0.04, the acceleration
4 3 A is flowing through the sides of the
of the system in ms–2 is :
polygon, the magnetic field at the centre of the
(Consider that the string is massless and polygon would be x × l0–7 T. The value of x is ____.
unstretchable and the pulley is also massless and
frictionless) : 52. A rectangular loop of sides 12 cm and 5 cm, with
its sides parallel to the x-axis and y-axis
20 kg
respectively moves with a velocity of 5 cm/s in the
fk
positive x axis direction, in a space containing a
variable magnetic field in the positive z direction.
The field has a gradient of 10–3T/cm along the
negative x direction and it is decreasing with time
6 kg at the rate of 10–3 T/s. If the resistance of the loop
is 6 m, the power dissipated by the loop as heat is
60 N
_______ × 10–9 W.
(1) 3 (2) 4
(3) 2 (4) 1.2 53. The distance between object and its 3 times
magnified virtual image as produced by a convex
lens is 20 cm. The focal length of the lens used is
49. The minimum energy required by a hydrogen atom
__________ cm.
in ground state to emit radiation in Balmer series is
nearly : 54. Two identical charged spheres are suspended by
(1) 1.5 eV strings of equal lengths. The strings make an angle 
with each other. When suspended in water the angle
(2) 13.6 eV
remains the same. If density of the material of the
(3) 1.9 eV sphere is 1.5 g/cc, the dielectric constant of water
(4) 12.1 eV will be ________ (Take density of water = 1 g/cc)

55. The radius of a nucleus of mass number 64 is

50. A monochromatic light of wavelength 6000Å is
4.8 fermi. Then the mass number of another nucleus
incident on the single slit of width 0.01 mm. If the 1000
having radius of 4 fermi is , where x is _____.
diffraction pattern is formed at the focus of the x
convex lens of focal length 20 cm, the linear width
of the central maximum is : 56. The identical spheres each of mass 2M are placed
at the corners of a right angled triangle with
(1) 60 mm mutually perpendicular sides equal to 4 m each.
(2) 24 mm Taking point of intersection of these two sides as
(3) 120 mm origin, the magnitude of position vector of the
4 2
(4) 12 mm centre of mass of the system is , where the
x
value of x is ___________

7
57. A tuning fork resonates with a sonometer wire of 59. The current in a conductor is expressed as
length 1 m stretched with a tension of 6 N. When I = 3t2 + 4t3, where I is in Ampere and t is in
the tension in the wire is changed to 54 N, the second. The amount of electric charge that flows
same tuning fork produces 12 beats per second through a section of the conductor during t = 1s to
with it. The frequency of the tuning fork is t = 2s is ____________ C.
_______ Hz.
60. A particle is moving in one dimension
58. A plane is in level flight at constant speed and each (along x axis) under the action of a variable force.
of its two wings has an area of 40 m2. If the speed It's initial position was 16 m right of origin. The
of the air is 180 km/h over the lower wing surface variation of its position (x) with time (t) is given as
and 252 km/h over the upper wing surface, the x = –3t3 + 18t2 + 16t, where x is in m and t is in s.
mass of the plane is ________kg. (Take air density The velocity of the particle when its acceleration
to be 1 kg m–3 and g = 10 ms–2) becomes zero is _________ m/s.

8
 FINAL JEE–MAIN EXAMINATION – JANUARY, 2024
(Held On Thursday 01st February, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

CHEMISTRY TEST PAPER WITH ANSWER

SECTION-A
61. If one strand of a DNA has the sequence 65. In case of isoelectronic species the size of F–, Ne
ATGCTTCA, sequence of the bases in and Na+ is affected by:
complementary strand is: (1) Principal quantum number (n)
(1) CATTAGCT (2) TACGAAGT (2) None of the factors because their size is the
(3) GTACTTAC (4) ATGCGACT same
(3) Electron-electron interaction in the outer
orbitals
62. Given below are two statements : one is labelled as (4) Nuclear charge (z)
Assertion (A) and the other is labelled as Reason
(R).
Assertion (A) : Haloalkanes react with KCN to 66. According to the wave-particle duality of matter by
form alkyl cyanides as a main product while with de-Broglie, which of the following graph plot
AgCN form isocyanide as the main product. presents most appropriate relationship between
Reason (R) : KCN and AgCN both are highly wavelength of electron () and momentum of
ionic compounds. electron (p)?
In the light of the above statement, choose the most
appropriate answer from the options given below:
(1) (A) is correct but (R) is not correct
 p
(2) Both (A) and (R) are correct but (R) is not the
correct explanation of (A) (1) (2)
(3) (A) is not correct but (R) is correct
(4) Both (A) and (R) are correct and (R) is the p 
correct explanation of (A)

 
63. In acidic medium, K2Cr2O7 shows oxidising action (3) (4)
as represented in the half reaction
Cr2 O27− + XH+ + Ye− → 2A + ZH2O 1/p p
X, Y, Z and A are respectively are:
(1) 8, 6, 4 and Cr2O3 (2) 14, 7, 6 and Cr3+
(3) 8, 4, 6 and Cr2O3 (4) 14, 6, 7 and Cr3+ 67. Given below are two statements:
Statement (I): A solution of [Ni(H2O)6]2+ is green
in colour.
64. Which of the following reactions are Statement (II): A solution of [Ni(CN)4]2– is
disproportionation reactions? colourless.
(A) Cu+ → Cu2+ + Cu In the light of the above statements, choose the
(B) 3MnO24− + 4H + → 2MnO−4 + MnO2 + 2H2 O most appropriate answer from the options given
(C) 2KMnO4 → K2MnO4 + MnO2 + O2 below:
(1) Both Statement I and Statement II are incorrect
(D) 2MnO−4 + 3Mn 2 + + 2H2 O → 5MnO2 + 4H + (2) Both Statement I and Statement II are correct
Choose the correct answer from the options given (3) Statement I is incorrect but Statement II is
below: correct
(1) (A), (B) (2) (B), (C), (D) (4) Statement I is correct but Statement II is
(3) (A), (B), (C) (4) (A), (D) incorrect

9
68. Given below are two statements: one is labelled as 70. Given below are two statements:
Assertion (A) and the other is labelled as Reason Statement (I) : Aminobenzene and aniline are
(R). same organic compounds.
Assertion (A) : PH3 has lower boiling point than Statement (II) : Aminobenzene and aniline are
different organic compounds.
NH3.
In the light of the above statements, choose the
Reason (R) : In liquid state NH3 molecules are
most appropriate answer from the options given
associated through vander waal’s forces, but PH3 below:
molecules are associated through hydrogen (1) Both Statement I and Statement II are correct
bonding. (2) Statement I is correct but Statement II is
In the light of the above statements, choose the incorrect
most appropriate answer from the options given (3) Statement I is incorrect but Statement II is
below: correct
(4) Both Statement I and Statement II are incorrect
(1) Both (A) and (R) are correct and (R) is not the
correct explanation of (A)
(2) (A) is not correct but (R) is correct 71. Which of the following complex is homoleptic?
(3) Both (A) and (R) are correct but (R) is the (1) [Ni(CN)4]2–
correct explanation of (A) (2) [Ni(NH3)2Cl2]
(4) (A) is correct but (R) is not correct (3) [Fe(NH3)4Cl2]+
(4) [Co(NH3)4Cl2]+

69. Identify A and B in the following sequence of

72. Which of the following compound will most easily
reaction
be attacked by an electrophile?
CH3
CH3
⎯⎯⎯
Cl2 /h
→ A ⎯⎯⎯
H2 O
→B
373K (1) (2)

COCl CHO Cl OH
(1) (A) = (B) = (3) (4)

CHCl2 CHO
(2) (A) = (B) = 73. Ionic reactions with organic compounds proceed
through:
(A) Homolytic bond cleavage
(B) Heterolytic bond cleavage
CH2 Cl CHO
(C) Free radical formation
(D) Primary free radical
(3) (A) = (B) =
(E) Secondary free radical
Choose the correct answer from the options given
CHCl2 COOH below:
(1) (A) only
(4) (A) = (B) = (2) (C) only
(3) (B) only
(4) (D) and (E) only

10
74. Arrange the bonds in order of increasing ionic 78. Match List – I with List –II.
character in the molecules. LiF, K2O, N2, SO2 and List – I (Reactions) List – II (Reagents)
(A) (I) CH3MgBr, H2O
CIF3. CH3(CH2)5–C–OC2H5→CH3(CH2)5CHO
(1) CIF3 < N2 < SO2 < K2O < LiF O
(B) (II) Zn(Hg) and conc.
(2) LiF < K2O < CIF3 < SO2 < N2 C6H5COC6H5→C6H5CH2C6H5
HCl
(3) N2 < SO2 < CIF3 < K2O < LiF (C) C6H5CHO→C6H5CH(OH)CH3 (III) NaBH4 , H+
(4) N2 < CIF3 < SO2 < K2O < LiF (D) CH3COCH2COOC2H5→CH3C(OH)CH2COOC2H5 (IV) DIBAL-H, H2O
H

75. We have three aqueous solutions of NaCl labelled

as ‘A’, ‘B’ and ‘C’ with concentration 0.1 M, Choose the correct answer from options given
0.01M & 0.001 M, respectively. The value of below:
Vant' Hoff factor (i) for these solutions will be in (1) A-(III), (B)-(IV), (C)-(I), (D)-(II)
the order. (2) A-(IV), (B)-(II), (C)-(I), (D)-(III)
(1) iA < iB < iC (3) A-(IV), (B)-(II), (C)-(III), (D)-(I)
(2) iA < iC < iB (4) A-(III), (B)-(IV), (C)-(II), (D)-(I)
(3) iA = iB = iC
(4) iA > iB > iC
79. Choose the correct option for free expansion of an
ideal gas under adiabatic condition from the
76. In Kjeldahl’s method for estimation of nitrogen, following :
CuSO4 acts as : (1) q = 0, T  0, w = 0
(1) Reducing agent (2) q = 0, T < 0, w  0
(2) Catalytic agent
(3) q  0, T = 0, w = 0
(3) Hydrolysis agent
(4) q = 0, T = 0, w = 0
(4) Oxidising agent

80. Given below are two statements:

77. Given below are two statements :
Statement (I) : The NH2 group in Aniline is ortho
Statement (I) : Potassium hydrogen phthalate is a
and para directing and a powerful activating group.
primary standard for standardisation of sodium
hydroxide solution. Statement (II) : Aniline does not undergo Friedel-
Statement (II) : In this titration phenolphthalein Craft’s reaction (alkylation and acylation).
can be used as indicator. In the light of the above statements, choose the
In the light of the above statements, choose the most appropriate answer from the options given
most appropriate answer from the options given below :
below: (1) Both Statement I and Statement II are correct
(1) Both Statement I and Statement II are correct (2) Both Statement I and Statement II are incorrect
(2) Statement I is correct but Statement II is (3) Statement I is incorrect but Statement II is
incorrect correct
(3) Statement I is incorrect but Statement II is (4) Statement I is correct but Statement II is
correct incorrect
(4) Both Statement I and Statement II are incorrect

11
 SECTION-B 86. Total number of deactivating groups in aromatic
81. Number of optical isomers possible for electrophilic substitution reaction among the
2 – chlorobutane ……… following is
O O

CH3,
82. The potential for the given half cell at 298K is OCH3, –N CH3, –N –C  N, –OCH3
(-)………… × 10-2 V. H H
2H+(aq) + 2e- → H2 (g)
[H+] = 1M, PH2 = 2 atm
(Given: 2.303 RT/F = 0.06 V, log2 = 0.3)
87. Lowest Oxidation number of an atom in a
compound A2B is -2. The number of an electron in
its valence shell is
83. The number of white coloured salts among the
following is …………….
(A) SrSO4 (B) Mg(NH4)PO4 (c) BaCrO4 88. Among the following oxide of p - block elements,
(D) Mn(OH)2 (E) PbSO4 (F) PbCrO4 number of oxides having amphoteric nature is
(G) AgBr (H) PbI2 (I) CaC2O4 Cl2O7, CO, PbO2, N2O, NO, Al2O3, SiO2, N2O5,
(J) [Fe(OH)2(CH3COO)] SnO2

14 89. Consider the following reaction:

C 1
84. The ratio of 12 in a piece of wood is part that 3PbCl2 + 2(NH4)3PO4 → Pb3(PO4)2 + 6NH4Cl
C 8 If 72 mmol of PbCl2 is mixed with 50 mmol of
of atmosphere. If half life of 14C is 5730 years, the (NH4)3PO4 , then amount of Pb3(PO4)2 formed is
age of wood sample is ….. years. …… mmol. (nearest integer)

85. The number of molecules/ion/s having trigonal 90. Ka for CH3COOH is 1.8 × 10– 5 and Kb for NH4OH
bipyramidal shape is …….. . is 1.8 × 10–5. The pH of ammonium acetate
PF5, BrF5, PCl5, [PtCl4]2–, BF3, Fe(CO)5 solution will be

12