BRB Emulsions Presentation

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Silicone Emulsion for

Technical Market

© 2021 BRB International B.V.


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What is an emulsion ?

• Mixture of two non-miscible substances stabilised by surface


active ingredients
• Particles (droplets) are stabilized and formed by surfactants
• O/W emulsions replace solvent based products (environmental
friendly)

© 2021 BRB International B.V.


Typical properties
• O/W or W/O emulsions:
• O/W emulsions (e.g. Sempure 60) can be diluted with water
• W/O emulsions cannot be diluted with water

• Viscosity:
• Depends on active content, surfactant type/concentration,
thickener
• Sharp increase for o/w emulsions with >60% oil
• Often pre-diluted with water before use

© 2021 BRB International B.V.


Surfactant types

Types:
• Non-ionic (e.g. Alcohol ethoxylates)
• Anionic (e.g. Sodium Laurylethersulphate)
• Cationic (e.g. Alkyl Ammoniumchloride)
• Amphoteric (both anionic & cationic)

• Critical for emulsions stability


• Optimization of surfactant HLB based on emulsified
substance (silicone oil, mineral oil, water (w/o emulsion))

© 2021 BRB International B.V.


Surfactant choice
Non-ionic Cationic
• Softener
• Grease remover • Sanitizer
• Resistant to water
hardness deactivation
Amphoteric
• Mild, non irritant
Anionic • Compatible with all other
• Cleaning & foaming properties surfactant types
• Textile dirt remover • Compatible with high
• Sensitive to water hardness
concentrations of
deactivation
electrolytes, acids & alkalis
• High foaming properties

© 2021 BRB International B.V.


Shelf life

Instability = Coalescence, followed by


• Flocculation
• Creaming
• Breaking

Stability influenced by:


• Oil density
• Particle size
• Emulsion viscosity
• Emulsification methodology and chemistry

© 2021 BRB International B.V.


Markets & Product Selector
Application Mould release Polish Lubrication

shoe, leather…
Furniture, floor,

conveyor belts,
Plastic / rubber

Food contact

(paint & vinyl

Yarn, thread
conditioner)
Aluminum /

(paintable)
foundry

Hoses,

etc…
Car
Product

Sempure 35 X X X X X

Sempure 60 X X X X X
Sempure 357 X
Sempure 607 X
Sempure 5332 X
Sempure HV 6500 X X X
Sempure 1997 X X

Sempure 3733 X

© 2021 BRB International B.V.


Markets & Product Selector
Application Water repellant

Web offset
Synthetic fibers,
fur, textile finish
wool, fire-proof
Mineral / glass

Glass ware
(anti-slip)
materials
Product

Sempure 35 X X X
Sempure 60 X X X X
Sempure 1814 X
Sempure HJS X
Sempure SW 4 X
Sempure 379 X
Sempure HV 6500 X
Waxil AST X

© 2021 BRB International B.V.


Base oil technology
• Medium viscosity silicone oil: Sempure 35, 60, 357, 607
• High viscosity silicone oil: Sempure HV 6500, 1997
• Amino silicone: Sempure 3733
• Alkyl aryl silicone: Sempure 5332
• H-siloxane: Sempure 379
• Silanol fluid: Sempure 1814
• Silicone wax: Waxil AST
• Specialties: Sempure HJS, SW4

© 2021 BRB International B.V.


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