KHEMO DEVI PUBLIC SCHOOL Safiabad Road, Narela, Delhi-110040 CLASS -XI QUESTION PAPER Time : 3 Hours General Instructions Read the following instructions carefully All questions are compulsory. Use of log tables and calculators is not allowed. Section (CHEMISTRY ) Max. Marks : 70 |. There are 33 questions in this question paper with internal choice. 2. SECTION A consists of 16 Multiple-Choice questions carrying 1 mark each. |. SECTION B consists of 6 Short Answer questions carrying 2 marks each. - SECTION C consists of 7 Short Answer questions carrying 3 marks each. . SECTION D consists of 2 Case-Based questions carrying 4 marks each. SECTION E consists of 3 Long Answer questions carrying 5 marks each. The following questions are multiple choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. ‘1, What will be the K,, for the reaction 2NOCI(g) = 2NO(g) +Clo(g) at 1000 K? Given, that Ke at 1000 K is3.75xx10-®, (11x10 (031110 (o)3ta<104 (2) 0031110" 2. Why do the deviations occur from idealised shape of H,0 and NH molecules? (@) Same hybridisation () Different hybridisation () Repulsive effect (a) None of the above 3. At 363K, pure water has [H,O"]=10 M. The value of K,y at this temperature will be (a0 0 (ow? @io™ 4, Two students performed the same experiment separately and each one of them recorded two Feadings of mass which are given below. Correct reading of mass is 3.0 g. ‘Students Readings Oo @ A 3.01 299 8 3.05 2.95 On the basis of given data, mark the correct option . Out of the following statements. (a) Results of both the students are neither accurate nor precise () Results of student A are both preeise and accurate (©) Results of student B ate neither pre (@) Results of student Bare both precise and accurate 5. The structure of IF, is (8) square pyramidal (b) (© octabedrat xe nor accurate igonal bipyramidal (@) pentagonal bipyramidal6, The structures Structures: Butan-2-01 CH) — Oe GHC _ Diethylether ‘CHy— CH,— O— CH,— CH, Matosypropane _ CHy— O— CHy— CHy— Cy Tert-butyl alcohol re aie CHy— G—cHy on Which of the above compounds form a pair of metamers? (@) Diethylether and methoxypropane (@) Butan-t-ol and butan-2-0l (9 Butan-2-ol and diethylether (@ Methoxypropane and tert-butyl alcohol 7. Ifthe concentration of ghucose (C,H,.0,) in blood is 09 g/L. What will be the molarity of glucose in blood? @5M — (SOM (@)0.005M_— (AOS 8. CH,,NH5,HzO and HF are the examples of (molecular hydrides (b) metallic hydrides (© ionic hydrides (@) Both (a) and (e) 9. The reversible expansion of an ideal gas under adiabatic and isothermal is shown in the figure. Punt) 2 Jsonr 18 ern | 3 2. Ve, Ta) a aba — (Pa Va Td v— Which of the following (s) is incorrect? (7, =7, (b) T; >T, (© Wootermat >Waautatie (@) AVisothermat > AVastatic 10. The name of the following compound is le ——CH2 OOH COOH COOH @) 2hydroxypropane-1,2,3-tricarboxylic acid () 3-carboxy-3-hydroxy-1,5-pentanedioic acid (©) cite acia (@) All of the above cH qe fa few compounds are given below. 11. Dipole moment is usually designated by a Greek letter‘y’ m=Qxr Here, Qand represents (2) Q=charge,r =distance of separation (©) Q=heat,r = radius of cations (©) Q=charge, @ Q=charge, radius of cations radius of anions 12. Match the Column I and Column I and pick out Correct match codes from the given choices. Column | Column tt (Compound) (Properties) A. Molecule having sp'd 1, SFy hybridisation of central atom with lone pair one B. Molecule haivng sp? 2. XeF, hybridisation of central atom with lone pair zero ©. Molecule having so'u? 3. Fy, hybridisation central atom with two lone pait Codes @AUB>@;C5(2) WMA+AB70);C 30) (AGB (1);C (2) @A>O):B>@;C>() Assertion-Reason In the following questions (Q.No. 13-16) a statement of Assertion followed by a statement of Reason is given. Choose the correct answer ouf of the following choices. (a) Both (A) and (R) are correct and (R) is the correct explanation of (A). (b) Both (A) and (R) are correct but (R) is not the correct explanation of (A). (©) (A) is correct and (R) is incorrect (@ ()is incorrect and (R) is correct. 13, Assertion (A) A reactant that is entirely consumed when a reaction goes to completion is known as limiting reagent. Reason (R) The amount of limiting reagent limits the amount of product formed. 14. Assertion (A) NH and BF, form an adduct readily. Reason (R) NHg and BF, form a coordinate bond.15. Asser the following structural formula, eY) Itis cyclic and has conjugated 8z-electron system but it is not an aromatic compound. mn (A) The compound cyclooctatetraene has Reason (R) Huckel rule does not hold good and ring is not planar. 46. Assertion (A) Butane and 2-methyl butane are homologues. Reason (R) Butane is a straight chain alkane, while ‘2-methylbutane is a branched chain alkane, Section-B This section contains 5 questions with internal choice in one question. The following questions are very short answer type and carry 2 marks each. 17. Give reason for the following. (i) Electron gain enthalpy of O” is positive, while that of S is negative and electron gain enthalpy S” is positive, while that of O~ is negative. (ii) Why the increasing order of reactivity among group 17 elements is F > Cl>Br>1? 18. But-I-yne gives its sodium salt with NaNH,, which on reaction with ethylbromide gives hex-3-yne. Hex-3-yne on reduction with H / Pd-BaSO, gives cis hex-3-ene which on hydrolysis using alk. KMn0, gives hexane-3, 4-diol. ‘Write the related chemical equations. 19. (i) The density of 3M solution of NaClis 1.25 g mL. Calculate molality of the solution. (ii) Whatis the concentration of sugar (CygH»20,.) in mol L” if its 20g are dissolved in enough water to make a final volume up to 2L? Or Dinitrogen and dihydrogen react with each other to produce ammonia according to the following equation Section- N2(g) + 3H2(g) — 2NHa(g) (j) Calculate the mass of ammonia produced if 2.00 « 10%g dinitrogen reacts with 1.00 « 10° g of dihydrogen. (i) Will any of the two reactants remain unreacted. If, yes which one and what would be its mass ? 20. (i) Astronauts observe that the signals from the distant stars are weak, if a photon detector receives a total of 315 x 10" J from the radiations of 600 nm. Find the number of photons received by the detector. (ii) What physical mean is attributed to the square of the absolute value of wave function, (y?)? 21. (i) Give the IUPAC names for the following ‘compounds. ~ i) What is the hybridisation of each carbon in CH,—C=CH,? This section contains 7 questions with no infernal choice in in any question. The following questions are short answet type and carry 3 marks each. 22. Answer the following. () The first ionisation enthalpy (4,#) values of the third period elements, Na, Mg and Si are respectively 496, 737 and 786 kJ mol”, Predict the 4H, value for Al. (ii) Predict the formula of a stable binary ‘compound that would be formed by the combination of clement with atomic number 71 and fluorine. (tii) Electron affinity is positive when O° changes into 0% Explain. 23. Explain extensive and intensive properties with examples. Show that mole fraction and molarity are intensive properties, “a out the number of wave made by a Bohr electron in one complete revolution in its 3rd orb95, () Outof cand m-bonds, which one is stronger and on why? {i) What type of hybridisation is involved in $F? {ai) Outof p-orbital and sp-hybrid orbital which has greater directional character and why? 26, () Identify the substance that get reduced in the following reaction. Fe0a(s) +3 CO(g) —> 2Fe (s)+3CO,(g) (i) The compound AgF, is unstable compound. However, if formed, the compound acts as a very strong oxidising agent. Why? (iii) Zn rod is immersed in CuSO, solution. What will you observe after an hour? Explain your observation in terms of redox reaction, 27. Two oxides of a metal contain 27.6% and 30.0% of oxygen respectively. If the formula of the first oxide is MO, find that of the second, 28. (i) Write the structural formula of (a) o-ethylanisole (©) p-nitroaniline Gi) Write the correct stability order of the following. (CHg)3CCH,; (CHs)5¢, CH,CH,CH, Section-D The following questions are case-based questions. Fach question has an internal choice and carries 4(1+1+2) marks each. Read the passage carefully and answer the questions that follow. 29. An oxidation-reduction (redox) reaction is a type of chemical reaction that involves a transfer of electrons between two species. An oxidation-reduction reaction is any chemical reaction in which the oxidation number of a molecule, atom or ion changes by gaining or losing anelectron. Redox reactions are common and vital, to some of the basic functions of life, including photosynthesis, respiration, combustion and corrosion or rusting. The oxidation state of an element corresponds to the number of electrons () that an atom loses, gains, or appears to use When joining with other atoms in compounds. ‘The oxidation state of an individual atom is 0. The total oxidation state of all atoms in : a neutral species is 0 and in an ion is equal to the ion charge. Group 1 metals have an oxidation state of +1 and ftoup 2 an oxidation state of + 2. The oxidation state of fluorine is -1in compounds. Hydrogen generally has an oxidation state of + 1in compounds, Oxygen generally has an oxidation state of-2 in compounds. In binary metal compounds, group 17 elements have an oxidation state of ~1, group 16 elements of - 2 and group 15 elements of -3. The sum of the oxidation states is qual to zero for neutral compounds and equal to the charge for polyatomic ion species. Redox reactions are comprised of tw» parts, Teduced half and an oxidised half, that always ccur together. Answer the following questions. (i) 1 mole of acidified K,Cr,0; on reaction with excess KI will liberate n moles of I, then calculate the value of n. In alkaline medium, ClO, oxidises H,0, to 02 and itself gets reduced to Cl. How many mole of H,0, are oxidised by 1 mole of ClO,? Why does the following reaction occur? Xe0§"(aq) + 2F-(aq) +6H"(aq) — Xe0;3(g)+ Fo(g)+ 3H20 () What conclusion about the compound Na,XeOg (of which XeO$> is a part) can be drawn from the reaction? Or Write the half-reactions for the following redox reactions. (i) AU(s) +3Ag*(aq) —> Al®*(aq) +3Ag(s) (ii) 2K(6) +Cla(g) — 2KCKs) 30. A total of four quantum numbers are used to describe completely the movement and trajectories of each electron within an atom. Each electron in an atom has a unique set of quantum numbers; according to the Pauli exclusion principle, no two electrons can share the same combination of four quantum numbers. Quantum numbers are important because they can be used to determine the electron configuration of an atom and the probable location of the atom’s electrons. antum In atoms, there are a total of. four quant numbers: the principal quantum number (n), the orbital angular momentum quantum number (), (ii)the magnetic quantum number (m) and the electron spin quantum number (m,). The principal quantum number (n), describes the energy of an electron and the most probable distance of the electron from the nucleus. In other words, it refers to the size of the orbital and the energy level an electron is placed in, ‘The size of the atom and its atomic rai increases. Because the atomic radius increases, the electrons are farther from the nucleus. Thus, it is easier for the atom to expel an electron because the nucleus does not have as strong a pull on it and the ionisation energy decreases. We can designate a principal quantum number (n) anda certain subshell by combining the value ofn and the name of the subshell (which can be found using (1). The s orbital, because the value of m, can only be 0, can only exist in one plane. The p-orbital, however, has three possible because the value of m, and so, it has three possible orientations of the orbitals, shown by p,,pyand p,-The pattern continues, with the d-orbital containing 5 possible orbital orientations and f has 7. Answer the following questions. (i) Which of the following orbitals are degenerate? BdyyA dy, 3d,2,3dyzAdyeA d,s (ji) The electronic configuration of valence shell of Cuis3d'°4s! and not 3d°4s*. How is this configuration explained? (iit) The unpaired electrons in Al and Si are present in3p-orbital. Which electron will experience more effective nuclear charge from the nucleus? or ‘An atom of an clement contains 29 electrons and 35 neutrons. Deduce (i) the number of protons. i) the electronic configuration of the element. Section-E The following questions are long answer type and carry 5 marks each. All questions have an internal choice. 31. An alkyl halide C3H;,Br(A) reacts with ethanolic KOH to give an alkene ‘B’, which reacts with By, to give a compound ‘C’, which on dehydrobromination gives an alkyne ‘D’. On treatment with sodium metal in liquid ammonia, one mole of ‘D’ gives one mole of the sodium salt of ‘D’ and half a mole of hydrogen gas. Complete hydrogenation of ‘D’ yields a straight chain alkane. Identify 4, B, Cand D. Give the reactions involved. Or () What happen when (a) bromoethane is heated with zinc and hydrochloric acid? (b) hydrogen is passed into 2-bromopropane in the presence of palladium? (ii) Account for the following. (a) Hydrocarbon molecules with an odd number of carbon atoms have lower melting points than those with an even number of carbon atoms. (b) The C—C bonds rather than C—H bonds break during cracking of alkanes? (0) lodination of benzene is carried out in the presence of nitric acid or iodic acid, 32. Attempt any five of the following. (® Reactions with AG°<0 always have an equilibrium constant greater than 1. Give reason, Many thermodynamically feasible reactions do not occur under ordinary conditions. Comment. Atlow temperature, enthalpy change dominates the value of AG and at high temperature, it is the entropy which dominates the value of AG in Gibbs Helmholtz equation. Why? (iv) It is preferable to determine the change in enthalpy rather than the change in internal energy. Explain, (v) Itis necessary to define the ‘standard state’ (vi) Two moles of an ideal gas initially at 27°C and one atmospheric pressure are compressed isothermally and reversibly till the final pressure of the gas is 10 atm, Calculate W for the process, (vii) The enthalpy of vaporisation of an organic compound at its boiling point (85.0°C) is