Scribd
Upload
1K views13 pages

GOC Short Notes

Uploaded by

samsung.galaxy.tab.345c
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
1K views13 pages

GOC Short Notes

Uploaded by

samsung.galaxy.tab.345c
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
You are on page 1/ 13
mad. -y- Viel cor NU itome ia OG Substrate —““°9°""_., tintermediate] —— Product + byproducts c,c-, Cc" See ae ote Cats tnt: Peete a CE Caer ae ey Lie OTC Coen tet es Cit) S nea PENS aac) ane ca bh CT ee ae eerie Lary Pee eee TT) DO Ae ae alain eg - CHs-, X-, RO-, H20, NHs PRC ONE S “7 aay ra ~ Electron displacement effects: ioe arn ROM rts ae 3) Hyperconjugation INDUCTIVE EFFECT eee ee Ce aCe Ce Cee Eee lll] etic eA Le) Bee tle) rere rad 555-555 5+ 555-555 ofter the 3rd C atom ol eo eal Ce ee estima Le} Ce et rl eae) ORES En ee) ern Ecol Eel (eel) oe el En Led Eo onto ey Cnt a eet Ramee cee Ee Eee Ee eo oe Applications of Inductive effect RCRA TORT ae hs ceed oe eee t ‘ io D t stability +1 & 1/-1 stability -1 & 1/+1 stability -1 & 1/+1 Cee ee ae rd 2) To compare acidic strength of aliphatic alcohols & carboxylic acids i u ee oe ea) TTI tert ee eco rr iy Ca maa) Lie Cal awe es MX Po Oe ea ee Pe ES yo eae Se IR oa siweey ONCHY PERCONJUGATION delocalisation of e- from filled BMO to adjacent empty orbital PTC ee La ak Ak CMa ene oe alkenes: o - 1* a t ri ri] e a - Hi : ka cl i 4 cy H a carbocation: o-p c 4 rT + Pp fi a al cf tf w Cary re ee) Bee oot hte cl or cl cl ar + 7 A i a a al cl cl cl cl cl er Applications of hyperconjugation ROR LI Tone Cn CLR Gr hs stability < no. of HCS = no. of a-H Ce aa eC ras 2) To compare heat of hydrogenation of alkenes eG eT ae Cee ood Cees Don ) ) . Br, a a a ‘: aa TON 5, 5, an aN F) 3 RESONANCE PCr Ce ee er e-O-CG—G. Po Ua ety resonance hybrid Dro POR ec ae Ue tt Rea RCI a ed UR ecard roth Oe Oe LT CSC A Rue ie eee ed eee OLE ete) ew eee) ee eee ee Re ene E eee Seen ee eee ee et Pe ee ee tes Pet et ee ee et) SoC eee CUT Ree to eto tt) 4) stability < /opp. charge seperation o io AA . pe OC ee RCE tic a aa ‘MESOMERIC EFFECT Ua | Ue ee ee eC a eee alts Sati te ele) Se siaee- Bae PR ee eer) Re tts eee etter) ETT Ph eR ol [too Rotel ee Le Lo} Cerny i Stren Draco DCR ea a oa oe ue Oey Oe eee én cHo ene taaae ens ea oe cee : J withdrawing pores : Ss Iya ee eae Caer DRO Orc ioecrur i Curericr cc uniee ari ei ett ° ce) Uy ao Ps a aa - = See = . O = © a en O = O f Lae eeu Ue ree rae eee iJ os (a ACIDIC STRENGTH Oe On eae curl is Sa cr cer cary csr) cr ToT) ors S > - < coe a ac me na nf or Cory - 3 7 ‘ Perie om con " Penn Seo CTC (0 Portail Basic strength of nitrogenous bases: a? " , PRET a ee ein RES MTA RT ' ' eer COC nL ae Ortho effect in aromatic amines: a a ce Ce eo ee c due to Steric inhibition in a AROMATICITY Huckle’s Rule for Aromaticity: 1) Aromatic - ring + planar + cont. conjugation + (4n+2)Te- 2) Anti aromatic - ring + planar + cont. conjugation + (4n)Te- OR Lee ee ee im @) bearded Boa eo ed [6]-annulene —_[8]-annulene Be aniits Peri Pecans anon, aromatic PO Ir eT lea ear V AROMATICITY folie tdi sa Re SCR UCR Cet iacuts ore} a + aro y ao aro eee) mere a) >) o Ta rae ee ee le lla) on OH, ie a q <2 ee ea) a) 2] i) SIMPLY CONCISE CARBOCATIONS Selita 1) BB> Aro>M>HC>1 rT a rd Pc iiag = a et +HC ees Syren i i ERT " " SO CIEE ay aes Sees foMeet eis] iis a 3 J (@) oes oO (SECs ORCI EOE 28 ee on Pl eur teeta seater) ils y D 2) Ring Expansion - reduces strain & increase stability awene) Q. Which of the following will not rearrange: S Y © means CARBANIONS Stability: eee ee Pea ator] ola ail H-G2cl H-c=el aa i i vars) " " UNCUT eT aa Saar) Q. Compare stabil Ee) Coon FREE RADICALS PSS TT ta Reale) Pcs ee Reo ca 1 av 3) hybridisation : sp? > sp? > sp

You might also like