A PROJECT ON

ECO FRIENDLY-RECYCLING OF WASTE PET BOTTLES Via

RECOVERY OF TEREPHTHALIC ACID (TPA) USING AMBERLITE IR-
120[H+] RESIN AS A REUSABLE CATALYST

Submitted
In the partial fulfillment of the requirements for
JIGNASA –STUDENT STUDY PROJECT
in
CHEMISTRY

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 CERTIFICATE

This is to certify that the Student Study Project “ECO FRIENDLY-RECYCLING OF WASTE PET
BOTTLES Via RECOVERY OF TEREPHTHALIC ACID (TPA) USING AMBERLITE IR-120[H+]
RESIN AS A REUSABLE CATALYST” that is being submitted by B.Sc STUDENTS in partial fulfillment
for the JIGNASA STUDENT STUDY PROJECT in CHEMISTRY is a record of bonafide work carried out by
them under my guidance and supervision for the Academic Year 2023-24.

The results embodied in this student study project have not been submitted to any other
University or Institute for the award of any degree or diploma.

Dr.VASAM SREENIVAS

Associate Professor of Chemistry

 CERTIFICATE

This is to certify that the student study project “ECO FRIENDLY-RECYCLING OF WASTE PET
BOTTLES Via R E C O V E R Y OF TEREPHTHALIC ACID (TPA) USING AMBERLITE IR-
120[H+] RESIN AS A REUSABLE CATALYST” that is being submitted by B.Sc STUDENTS in
partial fulfillment for the JIGNASA STUDENT STUDY PROJECT2024 in CHEMISTRY to is a
record of bonafide work carried out by them under the guidance and supervision of Dr.Vasam
Sreenivas, Associate Prof. of. Chemistry, GDC(A), Siddipet for the Academic Year 2023-24, by the
students S. Sandya, G. Srilaxmi, G. Anuja, A. Bharath, Sana kouser and Ishrath Jahan.

HEAD OF THE DEPARTMENT PRINCIPAL

 DECLARATION

We hereby declare that the contents presented in the student study project entitled
“ECO FRIENDLY-RECYCLING OF WASTE PET BOTTLES Via RECOVERY OF
TEREPHTHALIC ACID (TPA) USING AMBERLITE IR-120[H+] RESIN AS A REUSABLE
CATALYST” that is being submitted in partial fulfillment for the JIGNASA STUDENT
STUDY PROJECT in Chemistry is a record of original work investigated by us under the
supervision of Dr.Vasam Sreenivas, Department of Chemistry, Government Degree College
Siddipet (Autonomous), for the Academic Year 2023-24

Further this is to state that the results embodied in this dissertation have not submitted to any
other university or institution for the award of any degree or diploma.

1. S. SANDYA B.Sc.FZC III YEAR 6025-21-461-048

2. G. SRILAXMI B.Sc. FZC III YEAR 6025-21-461-015
3. G. ANUJA B.Sc.FZC III YEAR 6025-21-461-014
4. A. BHARATH B.Sc.MBZC III YEAR 6025-21-457-001
5. SANA KOUSER B.Sc. BZCIIYEAR 6025-22-445-129
6. ISHRATH JAHAN B.Sc.BTBC I YEAR 6025-23-572-014
 ACKNOWLEDGEMENTS

We are thankful to Commissioner sir Sri Burra Venkatesam , IAS for encouraging
students in research program at undergraduate level.

We indeed grateful to Prof.Ch.Prasad, Principal, Government Degree College Siddipet

(Autonomous), for his cooperation and valuable observations during course of our study project.

It has been our proud privilege to undertake and complete present study under the able
guidance, sympathetic and encouraging attitude, ever inspiring influence and scholarly supervision
of Dr. Vasam Sreenivas, Associate Professor of Chemistry, Head Department of Chemistry,
Government Degree College Siddipet (Autonomous). It gives us great pleasure in expressing our
indebtedness and deep sense of gratitude to her. Without her valuable guidance, it was not possible
to complete the present work.

We also thank our Jignasa co-ordinator Dr. P. Pallavi, Assistant Professor of Microbiology
and Thank full to Department faculty members sri K.Anjaneyulu Assistant Professorof Chemistry,
Dr.G.Ravi Kumar Assistant Professorof Chemistry, Dr.P.Sumalatha Assistant Professor of
Chemistry, Sri.M.Shyamsunder Assistant Professor of Chemistry, Sri Md.Saleem Pasha Assistant
Professorof Chemistry, Dr.V. Balakishan Assistant Professor of Chemistry and Dr.K. Ravi kumar
Lecture in chemisty.

We are thankful to other faculty members, staff of Government Degree College Siddipet
(Autonomous), for their cooperation during this period.

1. S. SANDYA B.Sc.FZC III YEAR - 6025-21-461-048

2. G.SRILAXMI B.Sc. FZC III YEAR- 6025-21-461-015
3. G. ANUJA B.Sc.FZC III YEAR- 6025-21-461-014
4. A. BHARATH B.Sc.MBZC IIIYEAR- 6025-21-457-001
5. SANA KOUSER B.Sc. BZC II YEAR- 6025-22-445-129
6. ISHRATH JAHAN B.Sc.BTBC I YEAR- 6025-23-572-014
 CONTENTS

Title Page No

Introduction 1

Statement of the problem 2

Hypothesis 3

Aims and Objectives of the study 4-5

Review of literature 5

Methodology 6

Results & Discussions 11

Findings 15

Conclusion and Suggestions 15

References & Publication 16

Photo Gallery 17
Government Degree College Siddipet (Autonomous)

Eco Friendly-Recycling of Waste PET Bottles Via Recovery

of Terephthalic Acid (TPA) Using Amberlite IR-120[H+]
Resin as a Reusable Catalyst

INTRODUCTION

Plastic waste has become a global environmental problem. To prevent plastic

pollution and protect the ecological environment and reduce the consumption of
nonrenewable resources recycling is important. Polyethylene terephthalate (PET) is
common polymer used in Production of plastic bottles, fibers and packaging food and
beverage materials due to its desirable properties like transparency, strength and
recyclability. As per industry data more than 14 lakhs tones of PET plastic water and
beverage bottle being used annually in India. Even we collected the data from
Siddipet Town Municipality that they are collecting 70-80 tones waste PET bottles
per annum.
Terephthalic acid (TPA) is a key monomer used in the synthesis of PET. Recycling
PET bottle and recovering TPA through chemical processes have become essential for
sustainable waste management and resource conservation. We have chosen the
efficient recycling method of waste PET bottles to recover Terephthalic acid (TPA)
using Amberlite IR -120[H+] a reusable catalyst and Lewis acid NiCl 2, as part our
study project. Our study project explores the eco -friendly aspects and benefits of
recycling process.

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 Jignasa SSP 2023-24

What is PET?
PET (Polyethylene terephthalate) is versatile polyester with diverse applications, and
its synthesis involves poly condensation of teripthalic acid (TPA) with ethylene glycol
(EG).

STATEMENT OF THE PROBLEM

The disposal of plastic waste has become a significant environmental problem that
requires effective solutions for its management and sustainable use. Despite the
increasing importance of recycling, there is still a need to explore advanced methods
for the recovery of plastics, especially for polyethylene terephthalate (PET).
For PET recycling mechanical and chemical methods are currently in the usage but
chemical recycling methods got advantage over mechanical recycling because
mechanical recycling involves high energy and pollution. There is also a loss of
quality in the recycled product. In chemical methods hydrolysis is the most facile
method for PET treatment that comprises its depolymerization to teripthalic acid
(TPA) and ethylene glycol (EG). These monomers are the basic raw material for the
re polymerization into PET.
Generally, the hydrolysis o f PET is promoted by a n acid and base catalysts such as
H2SO4, HNO3 and NaOH. Unfortunately large amounts of strong acids or alkali
waste water are produced in these reaction system. Recovery and reuse is difficult
resulting in waste of resources. So for hydrolysis of PET to TPA monomer we have
chosen reusable catalysts like Amberlite IR-120[H+] resin or eco-friendly Lewis’s acid
NiCl2. Hydrolysis treatment by depolymerization with Amberlite IR-120[H+] resin or
Lewis’s acid NiCl2 in polar solvents at moderate to high temperature is a promising way
to recover PET (Scheme-1).

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Government Degree College Siddipet (Autonomous)

Reaction times and temperatures on the weight changes in PET and the subsequent
recovery of the valuable monomer terephthalic acid (TPA). Furthermore, a
comparative analysis of the efficiency of Amberlite IR-120[H+] resin and
NiCl2catalyst in PET recovery is essential.

Scheme1:PET hydrolysis mechanism with catalyst.

HYPOTHESIS

We hypothesize that the recovery of polyethylene terephthalate (PET) by hydrolysis

treatment with Amberlite IR-120[H+] resin or NiCl2 will be affected by different
reaction times and temperatures (Scheme2). In particular, we hypothesize that higher
temperatures and longer reaction times will lead to increased recovery of the
monomer terephthalic acid (TPA) from PET. We predict a positive correlation
between these variables, suggesting that optimal conditions for PET recovery can be
achieved by careful manipulation of hydrolysis parameters.
Furthermore, we propose that hydrolysis with Amberlite IR-120[H+] resin will
outperform NiCl2 hydrolysis in terms of comparable TPA yield and catalyst recovery.
It is expected that the chemical properties of Amberlite IR-120[H+] resin will improve
the depolymerization of PET, leading to a more efficient recovery of the valuable
monomer. This hypothesis is based on the understanding of the reactivity of
Amberlite IR-120[H+] resin with PET compared to NiCl2.By testing these
hypotheses, we aim to gain valuable insights into the factors influencing PET recovery

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 Jignasa SSP 2023-24

during hydrolysis and contribute to the development of optimized methods for the
conversion of plastic waste into high-value end products. These findings have the
potential to Support sustainable practices in plastic waste management and facilitate
the transitionto a circular and environmentally friendly approach to plastic recycling.

Scheme2: Synthesis of terephthalic acid (TPA) from PET

AIMS

The present study aims at investigating the effects of different hydrolysis conditions
on PET in presence of Amberlite IR-120[H+] resin and Lewis acid NiCl2 catalyst with
a focus on recovery of TPA a valuble chemical used in various industrial applications.
The comparison between Amberlite IR-120[H+] resin and Lewis acid NiCl2 catalyst
will provide crucial insights into the effectiveness of different catalyzed hydrolysis
agents under boiling polar solvent conditions. The results of this research will
contribute to the development of sustainable processes for the recycling of PET
plastic waste, reducing the environmental impact associated with plastic disposal.

OBJECTIVES

• Investigate Hydrolysis as a Plastic Waste Recovery Method: Investigating the

potential of hydrolysis treatment as an effective approach to recovering plastic
waste, with a particular focus on polyethylene terephthalate (PET). Evaluate the
contribution to solid waste management and the possibility of giving new life to
discarded plastics.
• Explore Recovery of PET with Amberlite IR-120[H+] or NiCl2 catalyst:
Investigation of PET plastic recovery by hydrolysis treatment with two different
agents such as Amberlite IR-120[H+] resin, NiCl2. Evaluation of the efficiency and
effectiveness of each hydrolysis solution in the recovery of plastic monomers
through the depolymerization process.
• Evaluate Monomer Recovery (TPA) from PET:Evaluate the recovery of the

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Government Degree College Siddipet (Autonomous)

monomer from PET, in particular terephthalic acid (TPA). Investigate how

different hydrolysis conditions affect the yield of TPA and gain insight into the
optimal parameters to maximize monomer recovery.
• Examine the Influence of Reaction Times and Temperatures: Investigation of
the effects of different reaction times and temperatures on the recovery of TPA
from PET. Analyze the trends and correlations between these variables with the aim
of identifying the conditions that promote high monomer recovery.
• Compare Amberlite IR-120[H+] resin and NiCl2catalyst reaction
conditions:Conduct a comparative analysis between Amberlite IR-120[H+] resin
and NiCl2 as hydrolyzing agents. Evaluate their respective abilities to recover
TPA from PET to gain insight into the relative effectiveness of these systems in
upcycling plastic waste.
• Correlate PET Residue with TPA Yield:To establish a correlation between the
measured PET residue (weight difference) and the corresponding TPA yield. The
aim is to validate the relationship between the observed changes in PET mass and
the success of the depolymerization process.
• Provide Knowledge for recycling Plastic Waste: To summarize and disseminate
the knowledge gained from the study in order to gain valuable insights into the
recycling of plastic waste into high-quality end products. This objective aims to
support the development of sustainable practices in the plastic waste industry based
on empirical evidence.

REVIEW OF LITERATURE

Plastic waste has become a global environmental problem, which has led to extensive
research into new ways for its recovery and long-term management. This study looks
at the national and international literature to provide an overview of the current state
of research on plastic waste recovery, with a focus on polyethylene terephthalate
(PET) and hydrolysis treatment.
Geyer and colleagues (2017). Production, use, and disposal of all plastics ever
created. Science Progresses, this major international study provides an in-depth
examination of global plastics production, consumption and fate in the environment.

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 Jignasa SSP 2023-24

It emphasizes the crucial importance of appropriate systems for the disposal of plastic
waste. Achilias and Karayannidis (2004) state. Hydrolysis of poly (ethylene
terephthalate) in the molten state. Polymer, This global study examines the hydrolysis
of PET in the molten state and provides insights into the chemical mechanisms
involved. The work provides useful information on the depolymerization of PET,
which is an important part of plastic waste recycling. The occurrence of microplastics
in the marine environment. Marine pollution by A. L. Andrady (2011).
While not directly related to hydrolysis, this international study raises awareness of
the global problem of microplastics and highlights the importance of sustainable
plastic waste management practices. Jambeck and colleagues (2015). Plastic waste
from land ends up in the sea. Published in the journal Science, this nationwide study
examines the import of plastic waste into the ocean, highlighting the importance of
land-based sources. It emphasizes the importance of appropriate waste recycling
systems, particularly hydrolysis processes, to reduce marine pollution. According to
Salem et.al,(2010). A overview of the recycling and recovery routes for plastic solid
waste (PSW). Management of Waste, This nationwide assessment, which focuses on
solid plastic waste, examines alternative recycling and recovery strategies, including
hydrolysis. The work sheds light on the feasibility of hydrolysis as a method of PET
recovery. Plastic waste to liquid gasoline by hydrolysis: An overview. Das et al.
(2018), Materials Today: Proceedings.
This national assessment looks at the hydrolysis of waste polymers to produce liquid
fuel and offers insights into the wider applications of hydrolysis in plastic waste
management. Worldwide literature highlights the global scale of the plastic waste
dilemma, while national research offers insights into specific areas of plastic waste
recycling, such as hydrolysis. The cited publications contribute to the growing body
of knowledge aimed at developing sustainable practices for plastic waste
management. Amberlite IR-120[H+] resin is an efficient catalyst for chemical
transformations such as condensation reactions and has attracted considerable
attention due to its recyclability (Sharma et al., 2009). NiCl 2 is a Lewis acid catalyst
that can also be useful for the saponification reaction Khan et al. (2003).
MATERIAL AND METHODS

PET bottles dumped in garbage vicinity near Government Degree College

(Autonomous) Siddipet and Siddipet municipality were collected.

Primarily a meticulous cleaning process was implemented for the experiment. The

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Government Degree College Siddipet (Autonomous)

PET bottlesunderwent a thorough rinse with distilled water, followed by an air-drying

procedure. Subsequently, the PET bottles were precisely cut into small, identical
pieces, eachmeasuring 1cm by 1cm, using scissors (Figure 1). This cutting process
was executedwith precision, ensuring that the selected region for cutting remained
flat. This precautionary measure was taken to guarantee a uniform surface area for all
samples,there by promoting consistent conditions for the hydrolysis reaction.
To further eliminate any potential impurities, the cut PET bottle pieces underwent
an additional rinsing step, this time utilizing deionized water. Following this rinse, the
samples were allowed to dry at room temperature once more. This sequential cleaning
and drying process was meticulously carried out to uphold a standardized approach in
the preparation of the PET samples for subsequent hydrolysis experiments.
This methodical procedure, from the careful selection of clear PET bottles to the
precise cutting and thorough cleaning processes, ensures that the hydrolysis reactions
take place on PET samples with uniform characteristics. This consistency is vital for
the reliability and accuracy of the experimental results, enabling a meaningful
analysis of PET hydrolysis under controlled conditions.

Figure 1: PET Bottles

Figure 2: Collection of plastic pieces.

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 Jignasa SSP 2023-24

Collection of PET Bottles from Nearby Collection of PET Bottles from

Siddipet Sewage Center of Municipality
Siddipet

Collection of
Collection of PET
PET Bottles
Bottlesfrom
from College
College Ground
Ground and
and Basil
Basil foundation
fondation

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Government Degree College Siddipet (Autonomous)

Two different hydrolysis agents, Amberlite IR-120[H+] resin and NiCl2 were
employed in the hydrolysis process in separate reaction setups. For the general
procedure, 5 g of PET flakes, 50.00 mL methanol or EG was weighed in analytical
balance or measured using volumetric pipette and placed into a 250 mL round-
bottom distilling flask. An amount of 3 g of the catalyst to be optimized was also
added to the flask. The flask was then equipped with a Claisen head, a reflux
condenser, a thermometer, and a magnetic stirrer. The mixture was heated up to its
boiling point with constant agitation using an oil bath placed in a magnetic-stirring hot
plate. A reflux condenser was placed to avoid loss of volatile products and reagents in
the reaction as much as possible. The reaction time was then optimized.This
experimental setup was adapted from the methodology outlined by Hanaoka et al. in
2021.

The part was to determine the optimal depolymerization parameters that would allow
the production of the highest yield of TPA and EG (ethylene glycol). For the TPA, at
the end of each run, the heat source was removed, and the mixture obtained was
filtered to separate the unreacted PET residue with catalyst. The residue was then
washed with distilled water, dried for 105 °C for 4 h, cooled, and weighed. Dilute
hydrochloric acid (1 M) was added drop wise to the filtrate obtained with constant
stirring to form the white precipitate, TPA. Afterwards, the TPA was digested at
70°C for 30 min to increase particle size, cooled, and then filtered. The TPA solid
was washed using distilled water to remove water soluble impurities, filtered again,
dried at 105 °C, and then finally weighed, and stored in a clean container.The
following parameters optimized were the catalyst used and reaction time. Then, the
TPA obtained was characterized together with their corresponding standards using
Fouriertransform-infrared spectroscopy (FT-IR).

Chemical Equations
Depolymerization of PET:
PET →TPA+ Ethylene Glycol(EG)
This reaction breaks down the PET polymer into its monomer units, TPA, and Ethylene
Glycol, through hydrolysis.
Recovery of TPA using Amberlite IR-120[H+] Resin
TPA+AmberliteIR-120[H+]→TPA-Amberlite ComplexTPA+Amberlite
Complex+Base(e.g., NaOH)→TPA+ Regenerated Amberlite IR120TPA-Amberlite
Complex+Base (e.g., NaOH)→TPA+Regenerated Amberlite IR-120
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 Jignasa SSP 2023-24

In this process, Amberlite IR-120[H+] resin acts as a catalyst to facilitate the reaction
and separation of TPA from the reaction mixture. The resin forms a complex with TPA,
which can then be regenerated by treating the complex with a base, yielding TPA and
regenerated Amberlite IR-120 resin for reuse.

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Government Degree College Siddipet (Autonomous)

RESULTS AND DISCUSSION

Effect of Temperature in Weight Different and TPA Yield of PET Plastic

In the depolymerization of waste PET to produce TPA, two parameters were
optimized, namely the catalyst used (Amberlite IR-120[H+] resin, NiCl2.6H2O) and
the reaction time. We further investigated the parameters to be optimized (Table-1).

Characterization of TPA:

The TPA is well characterized by elemental IR, 1HNMR spectral analysis. Fig. 3
shows the schematic diagram for the isolation of TPA. Fig. 4 is showing the
correlated FT-IR of TPA generated from depolymerization with reference TPA. Fig. 5
is showing the correlated 1HNMR of TPA generated from depolymerization with
reference TPA. We further checked optimum heating studies with different catalyst
and we find the TPA yields were improved with reflux temperatures with 24hrs
reaction time (Table-1). We also recovered catalyst along with PET traces which can
be re-used up to four cycles; we see barely any difference in the isolated yields.
Similar reaction condition was applied using NiCl2.6H20 catalyst and in this case,
catalyst was not recovered. We also conducted similar experiment in EG as solvent at
its boiling temperatures and wefound improved yields with TPA synthesis.

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 Jignasa SSP 2023-24

Figure 3: Isolation of TPA

Figure 4:FT-IR spectra of (a) TPA product in black and (b) TPA standard in green.

Figure 5:1HNMR of terephthalic acid (TPA) in DMSO-d6

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Government Degree College Siddipet (Autonomous)

Entry Catalyst Solvent Temperature, Reaction Yield, %

o
C Time, hrs
1 Amberlite IR-120[H+] CH3OH 65 24 20
resin
2 Amberlite IR-120[H+] CH3OH 65 48 22
resin
3 Amberlite IR-120[H+] EG 180 24 72
resin
4 NiCl2.6H2O EG 180 24 74
5 NiCl2.6H2O EG 180 48 81

Table1: Parameters to be optimized for TPA recovery

Parameters to be optimized for TPA recovery

200
180
160
140
120
100
80
60
40
20
0
Amberlite IR- Amberlite IR- Amberlite IR- NiCl2.6H2O NiCl2.6H2O
120[H+] resin 120[H+] resin 120[H+] resin

Temperature, oC Reaction Time, hrs Yield, %

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 Jignasa SSP 2023-24

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Government Degree College Siddipet (Autonomous)

FINDINGS

In this experiment with longer reaction times and at high temperature around 180 C
nearly 80% monomer (TPA) is recovered. From our experiment it was found that
hydrolysis in presence of either Amberlite IR-120[H+] Resin or NiCl2 is more
effective and green method compare to acid.

Amberlite IR-120[H+] Resin is reusable catalyst and can be used upto four cycles.
But taking cost into consideration we preferred NiCl2 catalyst and considered that it
is more convenient for experiment than Amberlite IR-120[H+].

CONCLUSION
Recycling of PET depolymerisation by hydrolysis is the most promising technology
which results in production of key monomer Terpthalic acid (TPA).The process that
we demonstrated involving Amberlite IR-120[H+] resin and NiCl2 is a sustainable and
eco-friendly approach to plastic waste management. This process not only helps in
reducing environmental impact but also contributes to resource conservation, energy
efficiency. It lowers energy consumption compared to producing TPA from virgin
petrochemical sources.

SUGGESTIONS
• Plastics in the environment pollute our water, harm wildlife and have
largely unknown health impacts on us.
• As citizens of society, we have a responsibility to manage our waste for
sustainable life.

• In recent years, the world has witnessed a significant increase in plastic

pollution. As a response to this environmental challenges it is everyone’s
responsibility to focus on recycling and recovering valuable materials from
waste plastic

• We can do this following 5R’s of waste management: Reduce, Reuse,

Recycle, Recover and Residual management.
“We must find ways to reduce and eventually eliminate single use plastic products”

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 Jignasa SSP 2023-24

REFERENCES

1. Achilias, D. S., &Karayannidis, G. P. (2004). Hydrolysis of poly (ethylene

terephthalate) in the molten state. Polymer, 45(12), 4111-4116.

2. Al-Salem, S. M., Lettieri, P., &Baeyens, J. (2010). Recycling and recovery

routes of plastic solid waste (PSW): A review. Waste Management, 30(11),
1934-1950.

3. Cˇolnik M, Knez Z and Škerget M 2021 Sub- and supercritical water for
chemical recycling of polyethylene terephthalate waste Chemical Engineering
Science 233 Article 116389

4. Das, B., Sarkar, D., Deka, D., & Baruah, D. C. (2018). Waste plastics to liquid
fuel through hydrolysis: An insight review. Materials Today: Proceedings,
5(1), 2390-2395.

5. Geyer, R., Jambeck, J. R., & Law, K. L. (2017). Production, use, and fate of
all plastics ever made. Science Advances, 3(7), e1700782.

6. Hanaoka T, Arao Y, Kayaki Y and Kuwata S 2021 Analysis of nitric acid

decomposition of epoxy resin network structures for chemical recycling
Polymer Degradation and Stability 186 Article 109537

7. Jambeck, J. R., Geyer, R., Wilcox, C., Siegler, T. R., Perryman, M., Andrady,
A., ... & Law, K. L. (2015). Plastic waste inputs from land into the ocean.
Science, 347(6223), 768-771.

8. Khan, A. T., Mondal, E., Sahu, P. R., & Islam, S. (2003). Nickel (II) chloride as an
efficient and useful catalyst for chemoselectivethioacetalization of
aldehydes. Tetrahedron letters, 44(5), 919-922.

9. Yang W, Liu R, Li C, Song Y and Hu C 2021 Hydrolysis of waste

polyethylene terephthalate catalyzed by easily recyclable terephthalic acid
Waste Management 135 267–274

10. Sharma S D, Konwar D. Synth Commun, 2009, 39: 980.

PUBLICATION

Eco Friendly-Recycling Of Waste PET Bottles Via Recovery Of Terephthalic Acid (TPA)
Using Amberlite IR-120[H+ ] Resin As A Reusable Catalyst. Sandhya. S, Srilaxmi. G and
Anuja. G (B.Sc. FZC-III) Bharath. A (B.Sc. MbZC III), Sana Kouser (B.Sc. BZC-II). Ishrath
Jahan (B.Sc. BTBC-I) *Dr. Vasam Sreenivas, Head & Associate Professor Department of
Chemistry Govt. Degree College, Siddipet-International Journal of creative Research
thought(IJCRT) 2024 IJCRT | Volume 12, Issue 3 March 2024 | ISSN: 2320-2882.

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Government Degree College Siddipet (Autonomous)

PHOTOGALLERY

Visited Municipal Dumping Yard Siddipet

Performing Experiments in Lab

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 Jignasa SSP 2023-24

Analyzing Compounds in CRL Lab GDC Siddipet

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Government Degree College Siddipet (Autonomous)

Awareness on disposal of PET Bottles in Siddipet Town

Awareness on disposal of PET Bottles in Siddipet Town

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 Jignasa SSP 2023-24

Awareness on disposal of PET Bottles in Siddipet Town

Awareness on disposal of PET Bottles in Siddipet Town

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