INTRODUCTION TO ORGANIC CHEMISTRY XXX

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ORGANIC

CHEMISTRY
Representing Organic Compounds
Introduction

• Organic Chemistry is the scientific study of the structure, properties, and


reactions of organic compounds. Organic compounds are those which contain
carbon
• For conventional reasons metal carbonates, carbon dioxide and carbon
monoxide are not included in organic compounds

Definition of a Hydrocarbon
• A compound that contains only hydrogen and carbon atoms

Representing Organic Molecules


• Organic compounds can be represented in a number of ways:
o Empirical Formulae
o Molecular Formulae
o General Formulae
o Structural Formulae
o Condensed Structural Formulae

• The empirical formula shows the simplest possible ratio of the atoms in a
molecule
o For example: Hydrogen peroxide is H2O2 but the empirical formula is HO
• The molecular formula shows the actual number of atoms in a molecule
o For example:

• The general formula shows a ratio of atoms in a family of compounds in terms of


'n' where n is a varying whole number
o For example, the general formula of a molecule that belong to the alkane
family is CnH2n+2

• The displayed formula shows the spatial arrangement of all the atoms and bonds in a
molecule
• This is also known as the graphical formula.

o For example:

• In a structural formulae enough information is shown to make the structure clear,


but most of the actual covalent bonds are omitted
• Only important bonds are always shown, such as double and triple bonds
• Identical groups can be bracketed together
• Side groups are also shown using brackets
• Straight chain alkanes are shown as follows:
• Three important terms to know in this topic are homologous series, functional
group and isomerism

Homologous Series
• This is a series or family of organic compounds that have similar features and
chemical properties due to them having the same functional group
• All members of a homologous series have:
o The same general formula
o Same functional group
o Similar chemical properties
o Gradation in their physical properties
o The difference in the molecular formula between one member and the next is
CH2

Functional Group
• Functional group: A group of atoms bonded in a specific arrangement that
influences the properties of the homologous series
• Some examples are shown here

Structures and Names of Common Functional Groups


Isomerism
• Isomers are compounds that have the same molecular formula but
different displayed formulae
o Eg. propene and cyclopropane

Isomers of C3H6 show the same molecular formula but different structures.

Isomers can show similar physical and chemical properties or if they have different
functional groups, the properties can be different.

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