Cambridge International General Certificate of Secondary Education

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Cambridge International Examinations

Cambridge International General Certificate of Secondary Education


* 0 6 8 9 6 1 4 2 9 6 *

CO-ORDINATED SCIENCES 0654/51


Paper 5 Practical Test May/June 2018
2 hours
Candidates answer on the Question Paper.
Additional Materials: As listed in the Confidential Instructions.

READ THESE INSTRUCTIONS FIRST

Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.

Answer all questions.


Electronic calculators may be used.
You may lose marks if you do not show your working or if you do not use appropriate units.
Notes for Use in Qualitative Analysis for this paper are printed on page 12.

At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.

For Examiner’s Use

Total

This document consists of 12 printed pages.

DC (LK/JG) 150104/2
© UCLES 2018 [Turn over
2

1 You are going to investigate an enzyme-catalysed reaction.

Hydrogen peroxide is broken down by catalase, an enzyme found in living cells such as the cells
of many types of bean. Oxygen gas is released during the reaction.

You are provided with a measuring cylinder containing bean puree and a supply of hydrogen
peroxide solution of concentration 1.5%.

(a) (i) Read through the whole of (a) and then complete the headings in Table 1.1 by adding
the units. [2]

(ii) • Use the syringe to add 5 cm3 of hydrogen peroxide solution by carefully running it
down the inside of the measuring cylinder.

• Start the stopclock.

Record, in Table 1.1, the volume of the mixture in the measuring cylinder to the nearest
division every 30 seconds for 5 minutes. [3]

Table 1.1

time / .................................. volume of mixture / ..........................................

30

60

90

120

150

180

210

240

270

300

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(b) (i) On the grid provided, plot a graph of volume of mixture (vertical axis) against time.

Label the axes.

75

70

65

60

55

50

45

40

35

30

25

20

15

10

0
0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300

[2]

(ii) Draw the best-fit smooth curve. [1]

(c) (i) Use your graph to predict the volume of the mixture at 200 seconds.

.......................................................................................................................................[1]

(ii) Use your graph to state how the rate of reaction changes during the 5 minutes.

.......................................................................................................................................[1]

(d) State and explain a safety precaution you took when carrying out the procedure in (a)(ii).

...................................................................................................................................................

...............................................................................................................................................[1]
© UCLES 2018 0654/51/M/J/18 [Turn over
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(e) Plan an experiment, using the same method as in (a)(ii), to investigate the effect of changing
the temperature of the hydrogen peroxide solution on the volume of the mixture.

You should not carry out this experiment.

In your answer, you should include

• variables you need to keep constant,


• suggestions for values of the variable you are going to change,
• how you would present your results on a graph.

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

...................................................................................................................................................

...............................................................................................................................................[4]

© UCLES 2018 0654/51/M/J/18


5

Please turn over for Question 2.

© UCLES 2018 0654/51/M/J/18 [Turn over


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2 Notes for use in Qualitative Analysis for this question are printed on page 12.

You are going to identify three solutions, H, J and K. The three solutions are each one of the
halide solutions shown.

sodium bromide solution


sodium chloride solution
sodium iodide solution

(a) (i) Steps

• Place about 2 cm depth of solution H in a test-tube.


• Add a few drops of silver nitrate solution.
• Record your observations in Table 2.1.
• Then add ammonia solution until the test-tube is nearly full.
• Stir the mixture carefully.
• Record your observations in Table 2.1. Holding the question paper behind the test-
tube will help you determine any colour.

Repeat the steps for solution J.

Repeat the steps for solution K.

Table 2.1

observations
test solution H solution J solution K

add silver nitrate


solution

then add ammonia


solution
and stir

[6]

(ii) Use your observations in Table 2.1 to identify which solution, H, J or K, is sodium chloride
solution.

Explain how you reached your identification.

sodium chloride solution is solution ..................

explanation ........................................................................................................................

...........................................................................................................................................
[1]

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(iii) State and explain whether the addition of silver nitrate solution followed by ammonia
solution can be used to distinguish between the three halide solutions, H, J and K.

...........................................................................................................................................

...........................................................................................................................................

.......................................................................................................................................[1]

(iv) Nitric acid is usually added to the unknown solution before adding silver nitrate solution.

Explain why adding nitric acid first is not necessary in this test for this investigation.

...........................................................................................................................................

.......................................................................................................................................[1]

(b) (i) Steps

• Place about 2 cm depth of solution H in a test-tube.


• Add an equal volume of chlorine water.
• Record your observations in Table 2.2.
• Then add a few drops of starch solution.
• Record your observations in Table 2.2.

Repeat the steps for solution J.

Repeat the steps for solution K.

Table 2.2

observations
test solution H solution J solution K

add
chlorine
water

then add a
few drops
of starch solution

[3]

(ii) Identify the substance made in (b)(i) which causes the starch to change colour.

Your knowledge of the food test for starch may help you answer this question.

.......................................................................................................................................[1]

© UCLES 2018 0654/51/M/J/18 [Turn over


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(iii) State what type of reaction has taken place between solution J and chlorine water.

.......................................................................................................................................[1]

(c) Use your observations in Table 2.1 and Table 2.2 to identify solutions H, J and K.

H is ...........................................................................................................................................

J is ............................................................................................................................................

K is ...........................................................................................................................................
[1]

© UCLES 2018 0654/51/M/J/18


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3 You are going to measure the length l of a spring when different loads L are added to it, and plot a
graph.

A spring has been set up in a clamp for you, as shown in Fig. 3.1.

clamp

spring

bench

Fig. 3.1

(a) (i) Measure and record the length l 0 of the unstretched spring to the nearest millimetre.

l 0 = ....................................................... mm [1]

(ii) Mark on Fig. 3.1 the length l 0 you measured. [1]

(iii) Describe how you avoided a parallax (line-of-sight) error when measuring the length of
the spring.

...........................................................................................................................................

.......................................................................................................................................[1]

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(b) (i) Hang a load L of 1.0 N on the spring. Measure the new length l of the spring to the
nearest millimetre.

Record the length l in Table 3.1. [1]

(ii) Repeat the steps in (b)(i) using loads of 2.0 N, 3.0 N, 4.0 N and 5.0 N and complete
Table 3.1. [2]

Table 3.1

load L / N spring length l / mm

1.0

2.0

3.0

4.0

5.0

(c) (i) On the grid provided, plot a graph of L against l. Start both axes from the origin (0, 0).

L/N

l / mm
[2]
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(ii) Draw the best-fit straight line. [1]

(iii) Use your graph to determine the length l 0 of the unstretched spring.

l 0 = ....................................................... mm [1]

(iv) Compare your answer in (a)(i) with your answer in (c)(iii).

State whether the answers agree within the limits of experimental accuracy.

Give a reason for your statement.

...........................................................................................................................................

.......................................................................................................................................[1]

(d) (i) Calculate the gradient of your line.

Show all working and indicate on your graph the values you chose to enable the gradient
to be calculated.

gradient = ....................... N / mm [2]

(ii) The gradient of your line measures the force constant of the spring. This is a measure
of the elastic stiffness of the spring. The greater the force constant, the harder it is to
stretch the spring.

On your graph, draw a line to represent the behaviour of a spring with the same
unstretched length as your spring, but with a greater force constant. Label this line D.
[2]

© UCLES 2018 0654/51/M/J/18


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NOTES FOR USE IN QUALITATIVE ANALYSIS


Tests for anions

anion test test result


carbonate (CO32–) add dilute acid effervescence, carbon dioxide
produced
chloride (Cl –) acidify with dilute nitric acid, then white ppt.
[in solution] add aqueous silver nitrate
nitrate (NO3–) add aqueous sodium hydroxide, ammonia produced
[in solution] then aluminium foil; warm carefully
sulfate (SO42–) acidify with dilute nitric acid, then add white ppt.
[in solution] aqueous barium nitrate

Tests for aqueous cations

cation effect of aqueous sodium hydroxide effect of aqueous ammonia


ammonium (NH4+) ammonia produced on warming –
copper(II) (Cu2+) light blue ppt., insoluble in excess light blue ppt., soluble in excess,
giving a dark blue solution
iron(II) (Fe2+) green ppt., insoluble in excess green ppt., insoluble in excess
iron(III) (Fe3+) red-brown ppt., insoluble in excess red-brown ppt., insoluble in excess
zinc (Zn2+) white ppt., soluble in excess, giving white ppt., soluble in excess,
a colourless solution giving a colourless solution

Tests for gases

gas test and test results


ammonia (NH3) turns damp red litmus paper blue
carbon dioxide (CO2) turns limewater milky
chlorine (Cl 2) bleaches damp litmus paper
hydrogen (H2) ‘pops’ with a lighted splint
oxygen (O2) relights a glowing splint

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge International
Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at www.cie.org.uk after
the live examination series.

Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local
Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.

© UCLES 2018 0654/51/M/J/18

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