795 Gray English MSDS

SAFETY DATA SHEET
DOW CHEMICAL (MALAYSIA) SDN. BHD.
Product name: DOWSIL™ 795 Silicone Building Sealant Gray Issue Date: 20.05.2021
Print Date: 21.05.2021
DOW CHEMICAL (MALAYSIA) SDN. BHD. encourages and expects you to read and understand the
entire (M)SDS, as there is important information throughout the document. We expect you to follow
the precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.
1. IDENTIFICATION OF THE HAZARDOUS CHEMICAL AND OF THE SUPPLIER

Product name: DOWSIL™ 795 Silicone Building Sealant Gray
Recommended use of the chemical and restrictions on use

Identified uses: Adhesive, binding agents
COMPANY IDENTIFICATION
DOW CHEMICAL (MALAYSIA) SDN. BHD.
LEVEL 6,CP TOWER,JALAN 16/11,
PUSAT DAGANG SECTION 16,
46350 PETALING JAYA
SELANGOR DARUL EHSAN
MALAYSIA
Customer Information Number: 603-7965-5200

[email protected]
EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: 1-800-80-1255
Local Emergency Contact: 1800-80-1255
2. HAZARDS IDENTIFICATION
GHS Classification
This product is not hazardous per the Globally Harmonized System of Classification and Labelling
(GHS).
GHS label elements
Precautionary statements
Prevention
Use only outdoors or in a well-ventilated area.
Other hazards
No data available
® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 17

company of Dow
3. COMPOSITION AND INFORMATION OF THE INGREDIENTS OF THE HAZARDOUS

CHEMICAL
This product is a mixture.

Component CASRN Concentration
Diisopropoxydi(ethoxyacetoacetyl 27858-32-8 >= 0.5 - <= 1.1 %

)titanate
Methyltrimethoxysilane 1185-55-3 >= 0.14 - <= 0.3 %
N-(3-(Trimethoxysilyl) propyl)-1,2- 1760-24-3 >= 0.05 - <= 0.14 %

ethanediamine
4. FIRST AID MEASURES

Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section
8 for specific personal protective equipment.
Inhalation: Move person to fresh air and keep comfortable for breathing; consult a physician.
Skin contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation or rash
occurs. Wash clothing before reuse. Discard items which cannot be decontaminated, including leather
articles such as shoes, belts and watchbands.
Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Most important symptoms and effects, both acute and delayed:

Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed

Notes to physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient. Skin contact may aggravate preexisting dermatitis.
Page 2 of 17
5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media: Water spray. Alcohol-resistant foam. Carbon dioxide (CO2).
Dry chemical.
Unsuitable extinguishing media: None known..
Special hazards arising from the substance or mixture
Hazardous combustion products: Carbon monoxide, carbon dioxide and unburned

hydrocarbons (smoke).. Metal oxides. Carbon oxides. Silicon oxides.
Unusual Fire and Explosion Hazards: Exposure to combustion products may be a hazard to
health..
Advice for firefighters
Fire Fighting Procedures: Use water spray to cool unopened containers.. Evacuate area..
Fire residues and contaminated fire extinguishing water must be disposed of in accordance
with local regulations..
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Remove undamaged containers from fire area if it is safe to do so.
Special protective equipment for firefighters: Wear self-contained breathing apparatus for
firefighting if necessary.. Use personal protective equipment..
6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Follow safe handling
advice and personal protective equipment recommendations.
Environmental precautions: Discharge into the environment must be avoided. Prevent further
leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local
authorities should be advised if significant spillages cannot be contained.
Methods and materials for containment and cleaning up: Wipe up or scrape up and contain for
salvage or disposal. Local or national regulations may apply to releases and disposal of this material,
as well as those materials and items employed in the cleanup of releases. You will need to determine
which regulations are applicable. For large spills, provide dyking or other appropriate containment to
keep material from spreading. If dyked material can be pumped, store recovered material in
appropriate container.
See sections: 7, 8, 11, 12 and 13.
Page 3 of 17
7. HANDLING AND STORAGE

Precautions for safe handling: Take care to prevent spills, waste and minimize release to the
environment. Handle in accordance with good industrial hygiene and safety practice. CONTAINERS
MAY BE HAZARDOUS WHEN EMPTY. Since emptied containers retain product residue follow all
(M)SDS and label warnings even after container is emptied.
Use only with adequate ventilation. See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.
Conditions for safe storage: Keep in properly labelled containers. Store in accordance with the
particular national regulations.
Do not store with the following product types: Strong oxidizing agents.
Unsuitable materials for containers: None known.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.
Component Regulation Type of listing Value
Methyltrimethoxysilane Dow IHG TWA 7.5 ppm
Further information: Skin Sensitizer
N-(3-(Trimethoxysilyl) Dow IHG See Further information
propyl)-1,2-ethanediamine
Further information: Skin Sensitizer
Isopropanol ACGIH TWA 200 ppm
Further information: A4: Not classifiable as a human carcinogen
ACGIH STEL 400 ppm
Further information: A4: Not classifiable as a human carcinogen
MY PEL TWA 983 mg/m3 400 ppm
The following substance(s), which have Occupational Exposure Limit(s) (OEL), may be formed during
handling or processing:, Isopropanol
Biological occupational exposure limits

Components CAS-No. Control Biological Sampling Permissible Basis
parameters specimen time concentration
Isopropanol 67-63-0 Acetone Urine End of 40 mg/l ACGIH
shift at BEI
end of
workweek
Exposure controls
Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain
airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure
limit requirements or guidelines, general ventilation should be sufficient for most operations. Local
exhaust ventilation may be necessary for some operations.
Individual protection measures

Eye/face protection: Use safety glasses (with side shields).
Skin protection
Page 4 of 17
Hand protection: Use gloves chemically resistant to this material. Examples of

preferred glove barrier materials include: Butyl rubber. Neoprene. Nitrile/butadiene
rubber ("nitrile" or "NBR"). Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl alcohol
("PVA"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. Examples of acceptable glove
barrier materials include: Natural rubber ("latex"). NOTICE: The selection of a
specific glove for a particular application and duration of use in a workplace should
also take into account all relevant workplace factors such as, but not limited to: Other
chemicals which may be handled, physical requirements (cut/puncture protection,
dexterity, thermal protection), potential body reactions to glove materials, as well as
the instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material.
Selection of specific items such as face shield, boots, apron, or full body suit will
depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to
exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit
requirements or guidelines, wear respiratory protection when adverse effects, such as
respiratory irritation or discomfort have been experienced, or where indicated by your risk
assessment process. For most conditions, no respiratory protection should be needed;
however, if handling at elevated temperatures without sufficient ventilation, use an approved
air-purifying respirator.
The following should be effective types of air-purifying respirators: Organic vapor cartridge.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state paste
Color grey
Odor slight
Odor Threshold No data available
pH Not applicable
Melting point/range No data available
Freezing point No data available
Boiling point (760 mmHg) Not applicable
Flash point Seta closed cup 91 °C
Evaporation Rate (Butyl Acetate Not applicable
= 1)
Flammability (solid, gas) Not classified as a flammability hazard
Lower explosion limit No data available
Upper explosion limit No data available
Vapor Pressure Not applicable
Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) 1.52
Water solubility No data available
Partition coefficient: n- No data available
octanol/water
Auto-ignition temperature No data available
Page 5 of 17
Decomposition temperature No data available

Dynamic Viscosity Not applicable
Kinematic Viscosity Not applicable
Explosive properties Not explosive
Oxidizing properties The substance or mixture is not classified as oxidizing.
Molecular weight No data available
Particle size No data available
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY

Reactivity: Not classified as a reactivity hazard.
Chemical stability: Stable under normal conditions.
Possibility of hazardous reactions: Can react with strong oxidizing agents. Vapours may form
explosive mixture with air.
Conditions to avoid: None known.
Incompatible materials: Avoid contact with oxidizing materials.
Hazardous decomposition products:

Decomposition products can include and are not limited to: Formaldehyde. Benzene. Isopropanol.
11. TOXICOLOGICAL INFORMATION
Toxicological information appears in this section when such data is available.
Information on likely routes of exposure

Eye contact, Skin contact, Ingestion.
Acute toxicity (represents short term exposures with immediate effects - no chronic/delayed
effects known unless otherwise noted)
Acute oral toxicity

Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may
cause injury.
As product: Single dose oral LD50 has not been determined.
Based on information for component(s):

LD50, > 2,000 mg/kg Estimated.
Information for components:
Diisopropoxydi(ethoxyacetoacetyl)titanate
Page 6 of 17
LD50, Rat, male, 23,020 mg/kg OECD 401 or equivalent
Methyltrimethoxysilane
LD50, Rat, male and female, 11,685 mg/kg
This substance may hydrolyze to release Methanol. Methanol is highly toxic to

humans and may cause central nervous system effects, visual disturbances up to
blindness, metabolic acidosis, and degenerative damage to other organs including
liver, kidney, and heart.
N-(3-(Trimethoxysilyl) propyl)-1,2-ethanediamine
LD50, Rat, male and female, 2,295 mg/kg OPPTS 870.1100
This substance may hydrolyze to release Methanol. Methanol is highly toxic to

humans and may cause central nervous system effects, visual disturbances up to
blindness, metabolic acidosis, and degenerative damage to other organs including
liver, kidney, and heart.
Acute dermal toxicity

Prolonged skin contact is unlikely to result in absorption of harmful amounts.
As product: The dermal LD50 has not been determined.

LD50, > 2,000 mg/kg Estimated.
For similar material(s): LD50, Rabbit, 12,870 mg/kg
LD50, Rabbit, male and female, > 9,500 mg/kg OECD 402 or equivalent
This substance may hydrolyze to release Methanol. Effects of methanol are the same
as observed via oral and inhalation exposure and include central nervous system
(CNS) depression, visual impairment up to blindness, metabolic acidosis, with effects
on organ systems such as liver, kidneys and heart, even death.
LD50, Rabbit, > 2,000 mg/kg No deaths occurred at this concentration.
This substance may hydrolyze to release Methanol. Effects of methanol are the same
as observed via oral and inhalation exposure and include central nervous system
(CNS) depression, visual impairment up to blindness, metabolic acidosis, with effects
on organ systems such as liver, kidneys and heart, even death.
Acute inhalation toxicity

Brief exposure (minutes) is not likely to cause adverse effects. Vapor from heated material
may cause respiratory irritation. Excessive exposure may cause: Central nervous system
effects.
As product: The LC50 has not been determined.
Page 7 of 17
For similar material(s): LC50, Rat, male and female, 4 Hour, vapour, > 198.65 mg/l
No deaths occurred at this concentration.
LC50, Rat, male and female, 6 Hour, vapour, > 7605 ppm OECD Test Guideline 403
This substance may hydrolyze to release Methanol. Inhalation of methanol may

cause effects ranging from headache, narcosis and visual impairment to metabolic
acidosis, blindness, and even death.
LC50, Rat, 4 Hour, dust/mist, 1.49 - 2.44 mg/l OECD Test Guideline 403
This substance may hydrolyze to release Methanol. Inhalation of methanol may

cause effects ranging from headache, narcosis and visual impairment to metabolic
acidosis, blindness, and even death.
Skin corrosion/irritation
Brief contact is essentially nonirritating to skin.
May cause drying and flaking of the skin.
Brief contact is essentially nonirritating to skin.
Brief contact may cause slight skin irritation with local redness.
Brief contact may cause moderate skin irritation with local redness.
Serious eye damage/eye irritation

May cause slight temporary eye irritation.
May cause mild eye discomfort.
May cause moderate eye irritation.
May cause corneal injury.
May cause slight temporary eye irritation.
Corneal injury is unlikely.
May cause severe irritation with corneal injury which may result in permanent impairment of
vision, even blindness. Chemical burns may occur.
Page 8 of 17
Sensitization
For skin sensitization:
Contains component(s) which have caused allergic skin sensitization in guinea pigs.
For respiratory sensitization:

No relevant data found.
For similar material(s):
Did not demonstrate the potential for contact allergy in mice.

For skin sensitization:
Has caused allergic skin reactions when tested in guinea pigs.

Has caused allergic skin reactions when tested in guinea pigs.

Specific Target Organ Systemic Toxicity (Single Exposure)

Contains component(s) which are classified as specific target organ toxicant, single exposure,
category 3.
May cause drowsiness or dizziness.
Route of Exposure: Inhalation
Target Organs: Central nervous system
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Available data are inadequate to determine single exposure specific target organ toxicity.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
Based on physical properties, not likely to be an aspiration hazard.
Page 9 of 17
May be harmful if swallowed and enters airways.
Based on available information, aspiration hazard could not be determined.
Chronic toxicity (represents longer term exposures with repeated dose resulting in
chronic/delayed effects - no immediate effects known unless otherwise noted)
Specific Target Organ Systemic Toxicity (Repeated Exposure)

Based on available data for the component(s), repeated exposures are not anticipated to cause
significant adverse effects.
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
In animals, effects have been reported on the following organs:
Respiratory tract.
Carcinogenicity
Contains a component(s) that is/are not expected to be bioavailable due to the physical state of the
material under normal handling and processing conditions.
Teratogenicity
Contains component(s) which did not cause birth defects or any other fetal effects in lab animals.
For similar material(s): Did not cause birth defects or other effects in the fetus even at doses
which caused toxic effects in the mother.
Page 10 of 17
Did not cause birth defects or any other fetal effects in laboratory animals.
Did not cause birth defects in laboratory animals.
Reproductive toxicity
Contains component(s) which did not interfere with reproduction in animal studies. Contains
component(s) which did not interfere with fertility in animal studies.
In animal studies, did not interfere with reproduction.
In animal studies, did not interfere with reproduction.
Mutagenicity
In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity studies in
animals were negative for component(s) tested.
In vitro genetic toxicity studies were negative.
In vitro genetic toxicity studies were negative in some cases and positive in other cases.
Animal genetic toxicity studies were negative.
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
12. ECOLOGICAL INFORMATION
Ecotoxicological information appears in this section when such data is available.
Ecotoxicity
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Rasbora heteromorpha (Harlequin fish), static test, 96 Hour, 4,200 mg/l
Acute toxicity to aquatic invertebrates

LC50, Daphnia magna (Water flea), static test, 48 Hour, > 100 mg/l, OECD Test Guideline 202
or Equivalent
Page 11 of 17
Acute toxicity to algae/aquatic plants

ErC50, Pseudokirchneriella subcapitata (green algae), static test, 72 Hour, Growth rate
inhibition, > 100 mg/l, OECD Test Guideline 201 or Equivalent
NOEC, Pseudokirchneriella subcapitata (green algae), static test, 72 Hour, Growth rate
inhibition, 100 mg/l, OECD Test Guideline 201 or Equivalent
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, > 110 mg/l, OECD Test Guideline 203
or Equivalent

EC50, Daphnia magna (Water flea), flow-through test, 48 Hour, > 122 mg/l, OECD Test
Guideline 202

ErC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate inhibition, > 3.6
mg/l, OECD Test Guideline 201
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate inhibition, >= 3.6
mg/l, OECD Test Guideline 201
Toxicity to bacteria
EC10, activated sludge, 3 Hour, Respiration rates., > 100 mg/l, OECD Test Guideline 209
Chronic toxicity to aquatic invertebrates

NOEC, Daphnia magna (Water flea), 28 d, number of offspring, >= 10 mg/l
Material is toxic to aquatic organisms (LC50/EC50/IC50 between 1 and 10 mg/L in the most
sensitive species).
For the hydrolysis product(s)
LC50, zebra fish (Brachydanio rerio), 96 Hour, 597 mg/l

EC50, Daphnia magna (Water flea), 48 Hour, 81 mg/l

ErC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate inhibition, 8.8
mg/l
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate inhibition, 3.1
mg/l
Toxicity to bacteria
EC50, Pseudomonas putida, 16 Hour, Growth inhibition, 67 mg/l
Chronic toxicity to aquatic invertebrates

Page 12 of 17
NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, > 1 mg/l
Toxicity to Above Ground Organisms

Material is moderately toxic to birds on an acute basis (LD50 between 51 and 500 mg/kg).
Toxicity to soil-dwelling organisms

NOEC, Eisenia fetida (earthworms), 14 d, >= 1,000 mg/kg
Persistence and degradability
Biodegradability: For similar material(s): Material is readily biodegradable. Passes OECD
test(s) for ready biodegradability.
10-day Window: Pass
Biodegradation: 66 %
Exposure time: 28 d
Method: OECD Test Guideline 301D
Biodegradability: Based on stringent OECD test guidelines, this material cannot be
considered as readily biodegradable; however, these results do not necessarily mean that the
material is not biodegradable under environmental conditions.
Exposure time: 28 d
Method: Regulation (EC) No. 440/2008, Annex, C.4-A
Biodegradability: Based on stringent OECD test guidelines, this material cannot be
considered as readily biodegradable; however, these results do not necessarily mean that the
material is not biodegradable under environmental conditions.
10-day Window: Fail
Exposure time: 28 d
Method: OECD Test Guideline 301A or Equivalent
Theoretical Oxygen Demand: 2.39 mg/mg Estimated.
Chemical Oxygen Demand: 1.76 mg/mg Estimated.
Biological oxygen demand (BOD)
Incubation BOD
Time
5d 23 %
10 d 30 %
20 d 29 %
Stability in Water (1/2-life)

Hydrolysis, half-life, 0.025 Hour, pH 7
Photodegradation
Test Type: Half-life (indirect photolysis)
Page 13 of 17
Sensitization: OH radicals
Atmospheric half-life: 0.088 d
Method: Estimated.
Bioaccumulative potential
Bioaccumulation: For similar material(s): Bioconcentration potential is low (BCF < 100 or
Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 0.05
Bioconcentration factor (BCF): 3 Fish Estimated.
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): -0.82 Estimated.
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): < 3 estimated
Mobility in Soil
Partition coefficient (Koc): 1.53 Estimated.
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Partition coefficient (Koc): > 5000 Estimated.
Results of PBT and vPvB assessment
This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This
substance is not considered to be very persistent and very bioaccumulating (vPvB).
Other adverse effects
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.
Page 14 of 17
13. DISPOSAL INFORMATION

Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Incinerator or other thermal destruction device. For additional information, refer to:
Handling & Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section10
Regulatory Information, MSDS Section 15
Treatment and disposal methods of used packaging: Empty containers should be recycled or
otherwise disposed of by an approved waste management facility. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. Do not re-use
containers for any purpose.
14. TRANSPORTATION INFORMATION
Classification for ROAD and Rail transport:

Not regulated for transport
Classification for SEA transport (IMO-IMDG):

Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Classification for AIR transport (IATA/ICAO):

This information is not intended to convey all specific regulatory or operational

requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
Page 15 of 17
15. REGULATORY INFORMATION

Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous
Chemicals) Regulations 2013.
Occupational Safety and Health (Use and Standards of Exposure of Chemicals Hazardous to Health)
Regulations 2000.
16. OTHER INFORMATION
Revision
Identification Number: 1914642 / A154 / Issue Date: 20.05.2021 / Version: 5.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
ACGIH BEI ACGIH - Biological Exposure Indices (BEI)
Dow IHG Dow Industrial Hygiene Guideline
MY PEL Malaysia. Occupational Safety and Health (Use and Standards of Exposure of
Chemicals Hazardous to Health) Regulations 2000.
STEL Short-term exposure limit
TWA Time weighted average
Full text of other abbreviations

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land of
Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen,
Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL -
Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx -
Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New
Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG -
Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice;
IARC - International Agency for Research on Cancer; IATA - International Air Transport Association;
IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization;
IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law
(Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals
Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a
test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed
(Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No
Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program;
NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and
Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent,
Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical
Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation,
Page 16 of 17
Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Temperature;

SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Transportation of
Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very
Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System
DOW CHEMICAL (MALAYSIA) SDN. BHD. urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
MY
Page 17 of 17

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SAFETY DATA SHEET

DOW CHEMICAL (MALAYSIA) SDN. BHD.

1. IDENTIFICATION OF THE HAZARDOUS CHEMICAL AND OF THE SUPPLIER

Recommended use of the chemical and restrictions on use

Customer Information Number: 603-7965-5200

EMERGENCY TELEPHONE NUMBER

GHS label elements

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 17

3. COMPOSITION AND INFORMATION OF THE INGREDIENTS OF THE HAZARDOUS

This product is a mixture.

Diisopropoxydi(ethoxyacetoacetyl 27858-32-8 >= 0.5 - <= 1.1 %

Methyltrimethoxysilane 1185-55-3 >= 0.14 - <= 0.3 %

N-(3-(Trimethoxysilyl) propyl)-1,2- 1760-24-3 >= 0.05 - <= 0.14 %

4. FIRST AID MEASURES

Most important symptoms and effects, both acute and delayed:

Indication of any immediate medical attention and special treatment needed

Unsuitable extinguishing media: None known..

Special hazards arising from the substance or mixture

Hazardous combustion products: Carbon monoxide, carbon dioxide and unburned

Advice for firefighters

6. ACCIDENTAL RELEASE MEASURES

7. HANDLING AND STORAGE

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Biological occupational exposure limits

Individual protection measures

Hand protection: Use gloves chemically resistant to this material. Examples of

9. PHYSICAL AND CHEMICAL PROPERTIES

Decomposition temperature No data available

10. STABILITY AND REACTIVITY

Chemical stability: Stable under normal conditions.

Conditions to avoid: None known.

Incompatible materials: Avoid contact with oxidizing materials.

Hazardous decomposition products:

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

Information on likely routes of exposure

Acute oral toxicity

As product: Single dose oral LD50 has not been determined.

Based on information for component(s):

Information for components:

LD50, Rat, male, 23,020 mg/kg OECD 401 or equivalent

This substance may hydrolyze to release Methanol. Methanol is highly toxic to

This substance may hydrolyze to release Methanol. Methanol is highly toxic to

Acute dermal toxicity

As product: The dermal LD50 has not been determined.

Based on information for component(s):

Information for components:

Acute inhalation toxicity

As product: The LC50 has not been determined.

Information for components:

This substance may hydrolyze to release Methanol. Inhalation of methanol may

This substance may hydrolyze to release Methanol. Inhalation of methanol may

Information for components:

Serious eye damage/eye irritation

Information for components:

For respiratory sensitization:

Information for components:

For respiratory sensitization:

For respiratory sensitization:

For respiratory sensitization: