Wa0033.

5. Explain aromaticity of thiophene and furan.
6. Explain classification of alkaloids.

7. Explain the Hoffmann's exhaustive methylation.
8. Explain isoprene rule.
PART-B
5X 10=50 Marks
Answer ALL the questions.
Each carries TEN marks
9(a). Explain the preparation and properties of of Amines.
(or)
(b)Explain the preparation and synthetic applications of Diazonium salts
10(a) Explain the Preparation and any three properties of napthalene.
(or)
(b). Explain the Preparation and structure elucidation of anthracene
11.(a) Explain the synthesis and reactions of pyrrole
(or)
(b) Explain the synthesis and reactions of pyridine
12 (a) Explain the Structure elucidation of Hygrine
(or)
(b). Write the synthesis of Nicotine
13. (a) Explain Structure elucidation and synthesis of citral
(or)
(b)Explain Structure elucidation and synthesis of a-terpineol.
PHYSICAL CHEMISTRY I-PHASE EQUILIBRIA

AND CHEMICAL KINETICS (CC-8)
Hours per week: 4 Semester End Examination: 60 Marks
Credits: 4 Continuous Evaluation: 40 marks
Course outcomes:
After completion of the course students are able to learn about:
CO1.Phase diagrams for systems of solid-liquidequilibria involving eutectic, congruent and incongruent
melting points.
CO2.Methods of Experimental determination of rate laws.
CO3. Collision theory of reaction rates
CO4.Langmuir and Freundlich isotherms.
COS. The cleansing action of detergents.
CO6: Emulsions and their classification
CO7: Freezing mixtures and their industrial importance
CO8:Concept of nanocatalysis and applications in industry.
MODULE-I: Phase Equilibria-1
Concept of phases, components and degrees of freedom, derivation of Gibbs Phase Rule for
nonreactive and reactive systems; Clausius-Clapeyron equation and its applications to solid-liquid,
liquid-vapour and solid-vapour equilibria, phase diagram for one component systems, with
applications.
Phase diagrams for systems of solid-liquid equilibria involving eutectic, congruent and incongruent
melting points. Freezing mixtures
MODULE-II: Phase equilibria-2
Three component systems, water-chloroform-acetic acid system.
Binary solutions: Gibbs-Duhem-Margules cquation, its derivation and applications to fractional
distillation of binary miscible liquids (ideal and non ideal), partial miscibility of liquids, CST, steam
distillation, Nernst distribution law: its derivation and applications.
MODULE-III: Chemical Kinetics
Order and molecularity of a reaction, rate laws in terms of theadvancement ofa reaction, differential
and integrated form of rate expressions up to second order reactions, experimental methods of the
determination of rate laws.
Temperature dependence of reaction rates;Arhenius equation;activation energy.Collision theory of
reaction rates, qualitative treatment of the theory of absolute reaction rates. Activated complex theory
non mathematical treatrnent.
MODULE-IV:Catalysis:
Definition of catalyst,types of catalysts -Homogeneous and heterogeneous catalysis -acid-base
catalysis- Autocatalysis nanocatalysis - prototropic and protolytic mechanism and derivation of rate
law, Enzyme catalysis,Michaelis-Menten kinetics.
MODULE-V: Surface chemistry:
Physical adsorption, chemisorption, Factors influencing adsorption-adsorption isotherms -types
Langmuir and Freundlich isotherms. Surface active agents- classification- emusions-types-critical
micellar concentration (CMC) - factors affecting the CMC of surfactants- determination of cmc.
Solubilisation-factors influencing the solubilization. Explanation of cleansing action of detergents.
Reference Books:
1 Peter Atkins & Julio De Paula, Physical Chemistry 10h Ed., Oxford University Press (2014).
2. Mortimer, R. G. Physical Chemistry 3rd Ed., Elsevier: NOIDA, UP (2009).

3. Levine, I. N. PhysicalChemistry 6 Ed., Tata McGraw-Hill (2011).
8PHYSICAL CHEMISTRY III LAB (PPC)
Hours per week: 3 Credits: 2 Continuous Evaluation: 100 marks
I. Determination of critical solution temperature and composition of the phenol-water
system and to study the effect of impurities on it.
II. Phase equilibria: Construction of the phase diagram using cooling curves or ignition tube
method:
a. simple eutectic and
b. congruently melting systems.
III. Distribution of acetic/ benzoic acid between water and cyclohexane.
IV. Study the equilibrium of at least one of the following reactions by the distribution method:
() I2(aq) +I’ B(a-)
(i) Cu?*(ag) + nNH3 ’ Cu(NH)
V. Study the kinetics of the following reactions.
1. Integrated rate method:
Acid hydrolysis of methyl acetate with hydrochloric acid.
2. Compare the strengths of HCI and H2S04 by studying kinetics of hydrolysis of methyl
acetate.
VI. Adsorption
Verify the Freundlich and Langmuir isotherms for adsorption of acetic acid on activated
charcoal.
Reference Books:
1. Khosla, B. D., Garg, V. C. & Gulati, A. Senior Practical Physical Chemistry, R. Chand & Co.: New
Delhi (2011).
2. Garland, C. W.; Nibler, J. W. & Shoemaker, D. P. Experiments in Physical Chemistry 8h Ed.; McGraw-Hill:
New York (2003).
3. Halpen, A. M. &McBane, G. C. Experimental Physical Chemistry 3rd Ed.,: W.H. Freeman &Co.: New
York (2003).
BLUE PRINT FOR QUESTION PAPER SETTER

TIME: 3 Hrs Max.Marks:75
MODULE NO. /CHAPTER NO. SHORT ESSAY MARKS
S.No. ANSWER QUESTIONS ALLOETD

QUESTIONS
(10 Marks) TO THE
(5 Marks) MODULE
1 1 1. Phase equilibria-1 2 2 30
2 2 2. Phase equilibria-2 1 2 25
3 3 3. Chemical Kinetics 2 2 30
4 4. Catalysis 1 2 25
5 5 5. Surface Chemistry 2 2 30
Total no. of Questions 10
Total Marks including Choice 140
Note:
1.The question paper setters are requested to kindly adhere to the format given in the
above table.
2.The question paper setters are also requested to set the questions in the following way:
a. 70 %of Questions -Memory (knowledge) and Understanding based
b. 30%of Questions -Creativity, Application and Skill based
MODEL PAPER-1
B.Sc, DEGREE EXAMINATION
SEMESTER-IV.PAPER-VIII CHE(H)-CC-VIlIPHYSICAL CHEMISTRY III-PHASE EQUILIBRIA AND CHEMICAL
KINETICS
Time 3 hours Maximum Marks. 75
PART-A 5X5-25 Marks
Answer any FIVE of the following questions each carries FIVE marks
1 Explain phase diagram of one component system
2. Derive Clausius-Clapeyron equation.
3. Write Nernst distribution law and any two its applications 4 Derive second order rate reaction
S Explain the order and molecurity with examples.
6. Explain acid base catalysis
7.Writ short notes on emulsions.
8. Explain Freundlich isotherms
PART-B 5X 10=50Marks
Answer ALL the questions. Each carries TEN marks
9 (a)Define phase rule?Explain the terms in phase rule
(or)
(b) Explain Phase diagrams for one component systems
10 (a) Explain the water-chloroform-acetic acid system
(or)
(b). Explain fractional distillation of binary miscible liquids
11. (a) Explain the experimental methods of the determination of rate law
(or)
(b) Explain Collision theory of reaction rates
12 (a) Define catalyst? Explain types of catalysis with exarmples
(or)
(b)Derive Michaelis-Menton equation
13(a). Explain Langmuir adsorption isotherms
(or)
(b) Define criticalmicellar concentration ? Explain factors affecting the CMC of Surfactants

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5. Explain aromaticity of thiophene and furan.

6. Explain classification of alkaloids.

PHYSICAL CHEMISTRY I-PHASE EQUILIBRIA

2. Mortimer, R. G. Physical Chemistry 3rd Ed., Elsevier: NOIDA, UP (2009).

BLUE PRINT FOR QUESTION PAPER SETTER

MODULE NO. /CHAPTER NO. SHORT ESSAY MARKS

S.No. ANSWER QUESTIONS ALLOETD

Total no. of Questions 10

Total Marks including Choice 140

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