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    CHE 103 1.0 - Chemical Thermodynamics

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    Risinu Wijesinghe
    The document contains questions about thermodynamics for a university exam. It asks about the zeroth law of thermodynamics, path properties, isolated systems, the first law of thermodynamics, reversible and irreversible processes, heat exchange, entropy, reaction quotients vs equilibrium constants, and the four master equations in thermodynamics.

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    CHE 103 1.0 - Chemical Thermodynamics

    Uploaded by

    Risinu Wijesinghe
    25 views2 pages
    The document contains questions about thermodynamics for a university exam. It asks about the zeroth law of thermodynamics, path properties, isolated systems, the first law of thermodynamics, reversible and irreversible processes, heat exchange, entropy, reaction quotients vs equilibrium constants, and the four master equations in thermodynamics.

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    CHE 103 1.0 - Chemical Thermodynamics (1) (1)

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    The document contains questions about thermodynamics for a university exam. It asks about the zeroth law of thermodynamics, path properties, isolated systems, the first law of thermodynamics, reversible and irreversible processes, heat exchange, entropy, reaction quotients vs equilibrium constants, and the four master equations in thermodynamics.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    25 views2 pages

    CHE 103 1.0 - Chemical Thermodynamics

    Uploaded by

    Risinu Wijesinghe
    The document contains questions about thermodynamics for a university exam. It asks about the zeroth law of thermodynamics, path properties, isolated systems, the first law of thermodynamics, reversible and irreversible processes, heat exchange, entropy, reaction quotients vs equilibrium constants, and the four master equations in thermodynamics.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    65

    UNIVERSITY OF SRI JAYEWARDENEPURA

    B.Sc. (General) Degree First Year Second Semester Ending Examination


    October/December 2018

    CHE 103 1.0 Chemical Thermodynamics


    FST 165 1.0 Chemical Thermodynamics

    Time - One Hour


    Answer All Questions
    Gass constant (R) = 8.314 J K'1 mol1, 1 atm = 101325 Pa, C n.m = 5R/2, Cv.m= 3R/2

    (i)

    a) Write down the zeroth law of thermodynamics.


    b) Giving two examples, define the path properties in thermodynamics.
    c) Giving two examples, define an isolated system.
    (10 marks)
    (2)
    a) Write the mathematical expression for the first law of thermodynamics. Define
    all the factors.
    b) Derive an expression for the work done (w) by a system for a reversible,
    isothermal expansion from Vj to V2 of an ideal gas containing n number of
    moles.
    - c) An amount of 64.0 g of O2 (g) is present in a closed vessal at 25°C and 1 atm.
    :
    Calculate the work done (w), heat exchange (q) and internal energy change
    (ALO when the volume of the gas is doubled,
    I i) reversibly and isothermally
    !
    ii) irreversibly and isothermally
    i
    iii) isobarically

    Molar heat capacity of O2 = 29.3 J K 1 mol -1


    Molar mass of O2 = 16.0 g mol -1

    (20 marks)

    y
    3)
    a) Slate the Kelvin and Clausius statements.
    b) One mole of He gas is placed under 2 atm and 25°C. The gas expands reversibly
    and isothermally until the final pressure reaches to 1 ATM. Calculate the,
    i) amount of heat exchange between the surrounding and the system
    ii) entropy change
    a) Of the system
    b) Of theSurrounding
    c) In the Universe
    (30 marks)

    (4)
    a) What is the difference between reaction quotient (Q) and the equilibrium constant
    (K).
    b) Consider the ammonia synthesis reaction given below,
    -l
    N2(g) + 3H2 (g) ^2NH3(g), AG° = -33.3 kJ mol

    For the following mixture of reactants and products at 298 K. With


    i appropriate calculations, predict the direction in which the system will shift to
    reach equilibrium.

    PNH3 = 1.00 atm, PN2 = 1.47 atm, PH2 = 1.00 x 10‘2 atm

    Use the following equation for the calculation,

    AG = AG°+ RT InQ

    (20 marks)
    (5)
    a) Write down the four master equations in thermodynamics.
    i b) Using the master equation for U, (U is a function of S and V), derive the
    Maxwell relationship given below.

    +
    s V
    1
    (20 marks)

    2
    ■

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