Polymer
Polymer
• Introduction
• Classification of Polymers
• Kinetics of Polymerization
• Number-average Concept
• Weight-average Concept
“Poly” “mer”
many repeat unit
H H H H H H H H H H H H H H H H H H
C C C C C C C C C C C C C C C C C C
4
Classification of Polymers
Polymers are classified in a number of ways:
Structure of Starch
Structure of Cellulose
(ii) Polypeptides and Proteins
Amino acids are the building blocks for proteins. All amino acids contain
an amino or NH2 group and a carboxyl (acid) or COOH group. There are
20 different amino acids commonly found in proteins and often 300 or
more amino acids per protein molecule.
Bakelite Nylon
(2) Classification of Polymers Based on Structure
Applications
Food packaging, shampoo bottles, Milk, water, and juice containers, grocery
bags, toys, liquid detergent bottles, Soft drink based cups, flower pots, drain
pipes, signs, stadium seats, trash cans, re-cycling bins, traffic barrier cones, golf
bag liners etc.
Bakelite
(4) Classification of Polymers Based on Inter Particle
Forces:
(a) Elastomers
(b) Fibers
(c) Thermoplastics
(d) Thermosetting Polymers
(a) Elastomers:
• These are the polymers in which the polymer chains are held up
by weakest attractive forces. They are amorphous polymers
having high degree of elasticity.
. .
R R R +R
Free radicals
-
H2O2 + Fe2+ HO + HO· + Fe3+
Hydrogen peroxide
H2N(CH2)6NH2 + HOOC(CH2)4COOH →
H2N(CH2)6NHOC(CH2)4COOH
• HO-M-COOH + HO-M-COOH → HO-M-COO-M-COOH
• Chain transfer: vt = ?
• the net rate of change of radical concentration is calculated as
d[.M ]
2 fki [ I ] 2kt [.M ]2
dt
production
1/ 2
fk
[.M ] i [ I ]1 / 2
kt
• The rate of polymerization
1/ 2
fk i
vp = kp[.M][M] = kp[M] [I ]1 / 2
t
k
The above equation states that the rate of polymerization is
proportional to the square root of the concentration of the initiator.
1/ 2
Solution: (a) fk
[.M ] i [ I ]1 / 2
kt
1 / 2 1
(b) v k[ M ][ I ] where k k p ( fki kt ) 1/ 2
2
(1) OSMOMETRY
The osmometry technique is a very widely used
method to determine the molecular weight of polymers.
It is of two types :
(a) The above method is simple but takes several hours to few
days in diffusion of solvent through the semipermeable
membrane. It is a very slow process and the time taken to attain
equilibrium is extremely high.
• The solvent starts condensing on the solution droplet and the rise
in temperature is directly measured as the bridge imbalance
output voltage, ΔV, when a output attains steady state.