Namma Kalvi 11th Chemistry Model Question Paper em 218154

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Mr.R.Abdul Saleem, M.Sc., M.Phil., B.Ed., www.nammakalvi.

org

J.B.A.S.MEM.MATRIC.HR.SECY.BOYS SCHOOL,TEYNAMPET,CHENNAI-18

+1 CHEMISTRY ORGANIC CHEMISTRY (UNIT NO.10 TO 15 ) ONLY

GOVERNMENT MODEL QUESTION PAPER 2020

TIME: 3 hrs MARKS: 70

PART – I

I. ANSWER ALL THE QUESTIONS; 15 x 1 = 15


1. The number of stereoisomers of 1,2 – dihydroxycyclopentane is---------
(a) 1 (b) 2 (c) 3 (d) 4
2. An organic compound weighing 0.15g gave on carius estimation, 0.12 g of silver
bromide. The percentage of bromine in the compound will be close to------
(a) 46% (b) 34% (c) 3.4% (d) 4.6%.
3. Ortho and para – nitro phenol can be separated by---------
(a) Azeotropic distillation (b) destructive distillation (c) steam distillation (d) cannot
be separated.
4. Which one of the following is not electrophile?
(a) NH3 (b) AlCl3 (c) FeCl3 (d) R – X
5. Identify the one which does not come under the organic addition reactions:
(a) Hydration (b) Dehydration (c) Halogenation (d) Hydro halogenation
6. CH3CHO (𝑜𝑥𝑖𝑑𝑎𝑡𝑖𝑜𝑛) → CH3COOH, Identify the type of reaction?
(a) Addition reaction (b) Elimination reaction (c) Reduction reaction (d) Oxidation
reaction.
7. Molecular formula of benzene is ------
(a) C6H6 (b) C6H5 (c)C7H8 (d) CH4
8. Which of the following is less reactive than benzene towards electrophilic
substitution reactions?
(a) Nitrobenzene (b) Aniline (c) Bromobenzene (d) Chlorobenzene.
9. Which conformation of ethane has the lowest potential energy?
(a) Eclipsed (b) Staggered (c) Skew (d) All will have equal potential energy.
10. Which of the following reagent is not used to convert alcohol to haloalkane?
(a) H-X (b) PCl5 (c) CCl4 (d) SOCl2
11. Which one of the following is used as insecticide and as a soil sterilizing agent?
(a) Chloroform (b) Chloral (c) Chloropicrin (d) Tetrachloromethane
12. Which one of the following compounds does not undergo nucleophilic substitution
reactions?

+1 Chemistry Organic Chemistry Model Question Paper. www.nammakalvi.org


Mr.R.Abdul Saleem, M.Sc., M.Phil., B.Ed., www.nammakalvi.org

(a) Ethyl bromide (b) Vinyl chloride (c) Benzyl Chloride (d) Isopropyl chloride.
13. Photo Chemical smog formed in congested metropolitan cities mainly consists of
(a) Ozone, SO2, Hydrocarbons (b) Ozone, PAN,and NO2 (c) PAN, Smoke, and SO2
(d) Hydrocarbons, SO2 and CO2.
14. Release of oxides of nitrogen and hydrocarbons into the atmosphere by motor
vehicles is prevented by using--------
(a) Grit chamber (b) scrubbers (c) trickling filters (d) catalytic converters.
15. Biological oxygen demand value less than 5 ppm indicates a water sample to be---
(a) Highly polluted (b) poor in dissolved oxygen (c) rich in dissolved oxygen (d) low
COD.
II. ANSWER ANY SIX OF THE FOLLOWING QUESTIONS Q.No.24 IS
COMPULSORY 6 x 2 = 12

16.Name the following functional groups: (a) –CHO (b) –COOR (c) –CONH2 (d)-SH

17. What is sublimation?

18. Give examples for the following types of organic reactions: (a) 𝛽-elimination (b)
electrophilic substitution.

19. What are Free radicals? Give examples.

20. How does huckel rule help to decide the aromatic character of a compound?

21. Describe the conformers of n- butane.

22. What happens when chloroform reacts with oxygen in the presence of sunlight?

23. Write short note on ; (a) Rasching Process (b) Dow Process.

24.What is called Walden inversion?

III. ANSWER THE FOLLOWING QUESTIONS: Q. NO.33 IS COMPULSORY

6 x 3 = 18.

25.List out the harmful effects of Chemical water pollutants.

26.How does classical smog differ from photochemical smog.

27.Explain the mechanism of SN1 reaction by highlighting the stereochemistry behind


it.

+1 Chemistry Organic Chemistry Model Question Paper. www.nammakalvi.org


Mr.R.Abdul Saleem, M.Sc., M.Phil., B.Ed., www.nammakalvi.org

28. How will you prepare the following compounds from CH3MgI. (a) Higher ethers
(b) Acetaldehyde (c) Ethanol

29. Write the mechanism of Halogenation reaction and Sulphonation reaction.

30. (a) Convert Propyne → Propan – 2 –one? (b) Convert Acetylene →Methanoic
acid?

31.What is meant by Hyper conjugation? And mention the condtion for


hyperconjugation.

32.Write a note on Thin Layer Chromatography Technique.

33.(a)What are the conditions for optical isomerism? (b) Define Optical activity.

IV. ANSWER ALL THE QUESTIONS 5 x 5 = 25

34. (a) (i) Write the estimation of nitrogen by Dumas method. (b)What is meant by
enolisation?

(OR)

(b) (i) 0.33g of an organic compound containing phosphrous gave 0.397g of Mg2P2O7
by the analysis. Calculate the percentage of Phosphrous in the compound. (ii)
Define Chromatography.

35.(a) (i) Explain electromeric effect. (ii) Convert ethylene into ethyl bromide.

(OR)

(b)(i) Give the three ponts of difference between inductive effect and resonance
effect. (ii) Write a note on acidity of phenol.

36. (a) Discuss the conformation of ethane. (ii) What is BHC? Write its preparation.?

(OR)

(b)(i) Write the mechanism of E1 and E2 reaction with an example? (ii) Write short
note on Wurtz-fittig reaction?

37. (a) Neo-pentyl bromide undergoes nucleophilic substitution reactions very slowly
justify. (b) Write the structure of the following. (a) 1.4,dichlorobut-2-ene (b) 2-chloro-
3-methyl pentane.

+1 Chemistry Organic Chemistry Model Question Paper. www.nammakalvi.org


Mr.R.Abdul Saleem, M.Sc., M.Phil., B.Ed., www.nammakalvi.org

(OR)

(b)(i)Alkylchloride on treatment with aqueous KOH gives alcohols but the addition of
alcoholic KOH gives alkene rather than alcohol as major product.Why? (ii)Difference
between SN1 and SN2 reaction mechanism.

38. (a) (i)What is the role of Nitrogen oxides in the Ozone depletion? (ii) Define Acid
Rain.

(OR)

(b)(i)What are the various methods you suggests to protect our environment from
pollution. (ii) What is the importance of measuring BOD of water body?

PART – I Answer Key: 1. ( C ) 2. (b) 3.( c ) 4. (a) 5. (b) 6.(d) 7.(a) 8.(a) 9.(b) 10.(c)
11.(c) 12.(b) 13.(b) 14.(c) 15.(c).

Prepared by: Mr.R.Abdul Saleem., m.Sc., M.Phil., B.ed., P.G.T. Chemistry


Teacher, Chennai – 18.

+1 Chemistry Organic Chemistry Model Question Paper. www.nammakalvi.org

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