Test Bank for Chemistry The Central Science 13th Edition

by Brown LeMay Bursten Murphy Woodward Stoltzfus

ISBN 0321910419 9780321910417
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Chapter 7 Periodic Properties of the Elements

7.1 Multiple-Choice Questions

1) In which set of elements would all members be expected to have very similar
chemical properties?

1. A) O, S, Se
2. B) N, O, F
3. C) Na, Mg, K
4. D) S, Se, Si
5. E) Ne, Na, Mg

Answer: A
Diff: 1 Var: 1 Page Ref: Sec. 7.1

GO: G2

2) In which set of elements would all members be expected to have very similar
chemical properties?

1. A) P, Se, I
2. B) Cl, Br, Na
3. C) Si, As, Te
4. D) Ne, Na, Mg 5. E) Br, I, At

Answer: E

Diff: 1 Var: 1 Page Ref: Sec. 7.1

GO: G2

3) Electrons in the 1s subshell are much closer to the nucleus in Ar than in He

due to the larger in Ar. 1. A) nuclear charge
2. B) paramagnetism
3. C) diamagnetism
4. D) Hund’s rule
5. E) azimuthal quantum number

Answer: A

Diff: 1 Var: 1 Page Ref: Sec. 7.2

LO: 7.2

GO: G2
4) Screening of the nuclear charge by core electrons in atoms is .

1. A) less efficient than that by valence electrons

2. B) more efficient than that by valence electrons
3. C) essentially identical to that by valence electrons
4. D) responsible for a general decrease in atomic radius going down a group
5. E) both essentially identical to that by valence electrons and responsible for a
general decrease in atomic radius going down a group

Answer: B

Diff: 1 Var: 1 Page Ref: Sec. 7.2

LO: 7.2

GO: G2

5) The effective nuclear charge of an atom is primarily affected by .

1. A) inner electrons
2. B) outer electrons
3. C) nuclear charge

4. D) electron distribution
5. E) orbital radial probability

Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 7.2

LO: 7.2

GO: G2
6) The atomic radius of main-group elements generally increases down a group
because .

1. A) effective nuclear charge increases down a group

2. B) effective nuclear charge decreases down a group
3. C) effective nuclear charge zigzags down a group
4. D) the principal quantum number of the valence orbitals increases
5. E) both effective nuclear charge increases down a group and the principal
quantum number of the valence orbitals increases

Answer: D

Diff: 2 Var: 1 Page Ref: Sec. 7.3

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

7) Atomic radius generally increases as we move .

1. A) down a group and from right to left across a period

2. B) up a group and from left to right across a period
3. C) down a group and from left to right across a period
4. D) up a group and from right to left across a period
5. E) down a group; the period position has no effect

Answer: A
Diff: 1 Var: 1 Page Ref: Sec. 7.3

LO: 7.2, 7.3, 7.4, 7.5

GO: G2
8) Atomic radius generally decreases as we move .

1. A) down a group and from right to left across a period

2. B) up a group and from left to right across a period
3. C) down a group and from left to right across a period
4. D) up a group and from right to left across a period
5. E) down a group; the period position has no effect

Answer: B

Diff: 1 Var: 1 Page Ref: Sec. 7.3

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

9) Of the following, which gives the correct order for atomic radius for Mg, Na, P, Si
and Ar?

1. A) Mg > Na > P > Si > Ar

2. B) Ar > Si > P > Na > Mg
3. C) Si > P > Ar > Na > Mg
4. D) Na > Mg > Si > P > Ar
5. E) Ar > P > Si > Mg > Na

Answer: D

Diff: 1 Var: 1 Page Ref: Sec. 7.3

LO: 7.2, 7.3, 7.4, 7.5

GO: G2
10) Of the following, which gives the correct order for atomic radius for Ca, K, As, Ge
and Kr?

1. A) Ca > K > As > Ge > Kr

2. B) Kr > Ge > As > K > Ca
3. C) Ge > As > Kr > K > Ca
4. D) K > Ca > Ge > As > Kr
5. E) Kr > As > Ge > Ca > K
Answer: D

Diff: 1 Var: 1 Page Ref: Sec. 7.3

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

11) Of the compounds below, has the smallest ionic separation.

1. A) KF
2. B) K2S
3. C) RbCl
4. D) SrBr2
5. E) RbF

Answer: A

Diff: 1 Var: 1 Page Ref: Sec. 7.3

LO: 7.2, 7.3, 7.4, 7.5

GO: G2
12) Which of the following is an isoelectronic series?
1. A) B5-, Si4-, As3-, Te2- 2. B) F-, Cl-, Br-, I- 3. C) S, Cl, Ar, K
4. D) Si2-, P2-, S2-, Cl2-
5. E) O2-, F-, Ne, Na+

Answer: E

Diff: 1 Var: 1 Page Ref: Sec. 7.3

LO: 7.3

GO: G2
13) Which isoelectronic series is correctly arranged in order of increasing radius?

1. A) K+ < Ca2+ < Ar < Cl- 2. B) < Ar < K+ < Ca2+

3. C) Ca2+ < Ar < K+ < Cl- 4. D) Ca2+ < K+ < Ar < Cl-
5. E) Ca2+ < K+ < Cl- <Ar

Answer: D

Diff: 1 Var: 1 Page Ref: Sec. 7.3

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

14) Of the choices below, which gives the order for first ionization energies?

1. A) Cl > S > Al > Ar > Si

2. B) Ar > Cl > S > Si > Al
3. C) Al > Si > S > Cl > Ar
4. D) Cl > S > Al > Si > Ar
5. E) S > Si > Cl > Al > Ar
Answer: B

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

15) Of the choices below, which gives the order for first ionization energies?

1. A) Kr > Se > Br > Ga > Ge

2. B) Kr > Br > Se > Ge > Ga
3. C) Ga > Br > Ge > Kr > Se
4. D) Ga > Ge > Se > Br > Kr
5. E) Br > Se > Ga > Kr > Ge

Answer: B
Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

16) have the lowest first ionization energies of the groups listed.

1. A) Alkali metals
2. B) Transition elements
3. C) Halogens
4. D) Alkaline earth metals
5. E) Noble gases

Answer: A

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

17) Which of the following correctly represents the second ionization of aluminum?

1. A) Al+(g) + e- → Al (g)
2. B) Al (g) → (g) + e- 3. C) Al-(g) + e- → Al2- (g)
4. D) Al+ (g) + e- → Al2+ (g)
5. E) Al+(g) → Al2+ (g) + e-

Answer: E

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.4

GO: G2

18) Which of the following correctly represents the third ionization of aluminum?
1. A) Al2+(g) + e- → Al+ (g)
2. B) Al (g) → Al+ (g) + e- 3. C) Al2-(g) + e- → Al3- (g)

4. D) Al2+(g) + e- → Al3+ (g)

5. E) Al2+(g) → Al3+ (g) + e-

Answer: E

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.4

GO: G2
19) Which of the following correctly represents the second ionization of
phosphorus?

1. A) P+(g) + e- → P2+ (g)

2. B) P (g) → P+ (g) + e- 3. C) P-(g) + e- → P2- (g)
4. D) P+(g) → P2+ (g) + e-
5. E) P+(g) + e- → P (g)

Answer: D

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.4

GO: G2

20) Which equation correctly represents the first ionization of calcium?

1. A) Ca (g) → Ca+ (g) + e-

2. B) Ca (g) → Ca- (g) + e-
3. C) Ca (g) + e- → Ca- (g)
4. D) Ca-(g) → Ca (g) + e- 5. E) Ca+(g) + e- → Ca (g)

Answer: A

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.4 GO:

G2

21) Which of the following correctly represents the second ionization of calcium?
1. A) Ca (g) → Ca+ (g) + e- 2. B) Ca+ (g) → Ca2+ (g) + e- 3. C) Ca-(g) + e- → Ca2-
(g)

4. D) Ca+(g) + e- → Ca2+ (g)

5. E) Ca+(g) + e- → Ca (g)

Answer: B

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.4

GO: G2

22) Which of the following correctly represents the second ionization of copper?

1. A) Cu (g) → Cu+ (g) + e- 2. B) Cu+(g) → Cu2+ (g) + e-

3. C) Cu-(g) + e- → Cu2- (g)

4. D) Cu+(g) + e- → Cu2+ (g)

5. E) Cu+(g) + e- → Cu (g)

Answer: B

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.4

GO: G2

23) Which ion below has the largest radius?

1. A) Cl-

2. B) K+
3. C) Br-
4. D) F-
5. E) Na+

Answer: C

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.3

GO: G2

24) Of the following species, ___ has the largest radius.

1. A) Rb+
2. B) Sr2+
3. C) Br-
4. D) Kr
5. E) Ar

Answer: C

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.3 GO:

G2

Consider the following electron configurations to answer the questions that follow:

(i) 1s2 2s2 2p6 3s1

(ii) 1s2 2s2 2p6 3s2

(iii) 1s2 2s2 2p6 3s2 3p1

(iv) 1s2 2s2 2p6 3s2 3p4

(v) 1s2 2s2 2p6 3s2 3p5

25) The electron configuration belonging to the atom with the highest second
ionization energy is .

1. A) (i)
2. B) (ii)
3. C) (iii)
4. D) (iv)
5. E) (v)

Answer: A

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

26) The electron configuration that belongs to the atom with the lowest second
ionization energy is .

1. A) (i)
2. B) (ii)
3. C) (iii)
4. D) (iv)
5. E) (v)

Answer: B

Diff: 1 Var: 1 Page Ref: Sec. 7.4

LO: 7.2, 7.3, 7.4, 7.5

27) The electron configuration of the atom with the most negative electron affinity
is .

1. A) (i)
2. B) (ii)
3. C) (iii)
4. D) (iv)
5. E) (v)

Answer: E

Diff: 1 Var: 1 Page Ref: Sec. 7.5

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

28) The electron configuration of the atom that is expected to have a positive
electron affinity is _ .

1. A) (i)
2. B) (ii)
3. C) (iii)
4. D) (iv)
5. E) (v)

Answer: B

Diff: 1 Var: 1 Page Ref: Sec. 7.5

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

29) Of the following elements, has the most negative electron affinity.

1. A) S
2. B) Cl
3. C) Se
4. D) Br
5. E) I Answer:B

Diff: 1 Var: 1 Page Ref: Sec. 7.5

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

30) Of the following elements, has the most negative electron affinity.

1. A) P
2. B) Al
3. C) Si
4. D) Cl
5. E) B

Answer: D

Diff: 1 Var: 1 Page Ref: Sec. 7.5

LO: 7.2, 7.3, 7.4, 7.5

GO: G2

31) Of the following elements, has the most negative electron affinity.
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