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1.9 Rate Equations CheckSheets

This check sheet provides an overview of the key topics covered in the A-Level Chemistry syllabus for AQA related to physical chemistry and rate equations. It includes 3 main sections: 1) Covered it - topics that have been introduced, 2) Learnt it - topics that are understood, and 3) Exam ready - confident and prepared for the exam on that topic. Specific sub-topics are listed under each main topic, such as definitions of order of reaction and rate constant, use of rate equations, effect of temperature on rate constant, determination of rate equation from concentration-time graphs and providing information about reaction mechanisms.

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30 views1 page

1.9 Rate Equations CheckSheets

This check sheet provides an overview of the key topics covered in the A-Level Chemistry syllabus for AQA related to physical chemistry and rate equations. It includes 3 main sections: 1) Covered it - topics that have been introduced, 2) Learnt it - topics that are understood, and 3) Exam ready - confident and prepared for the exam on that topic. Specific sub-topics are listed under each main topic, such as definitions of order of reaction and rate constant, use of rate equations, effect of temperature on rate constant, determination of rate equation from concentration-time graphs and providing information about reaction mechanisms.

Uploaded by

tiahayes2801
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOC, PDF, TXT or read online on Scribd
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CHECK SHEETS A-Level Chemistry Syllabus (AQA) - September 2015

Instructions: Use this check sheet to tick off your progress and identify areas that need attention in order to successfully
prepare for your exam.
 Covered it: I have seen this content
 Learnt it: I understand this content and can apply my knowledge
 Exam ready: I am confident on this and ready to do the exam!

Module 1. Physical Chemistry

Exam ready
Covered it
Learnt it
Topic 1.9. Rate Equations

1.9.1. Rate Equations


a) The rate of a chemical reaction is related to the concentration of reactants by a rate
equation of the form: rate = k[A]m[B]n where m and n are the orders of reaction with
respect to reactants A and B and k is the rate constant
Recall b) The orders m and n are restricted to the values 0, 1 and 2
c) The rate constant k varies with temperature as shown by the equation
k = Ae-Ea/RT where A is a constant, known as the Arrhenius constant, Ea is the
activation energy and T is the temperature in K.
d) Define the terms order of reaction and rate constant
e) Perform calculations using the rate equation
f) Explain the qualitative effect of changes in temperature on the rate constant k
g) Perform calculations using the equation k = Ae-Ea/RT
Application
h) Understand that the equation k = Ae-Ea/RT can be rearranged into the form ln k = -Ea/RT +
ln A and know how to use this rearranged equation with experimental data to plot a
straight line graph with slope –Ea/R
*note: these equations and gas constant, R, will be given when required.
1.9.2. Determination of Rate Equation
a) The rate equation is an experimentally determined relationship
Recall b) The orders with respect to reactants can provide information about the mechanism of a
reaction
c) Use concentration-time graphs to deduce the rate of a reaction
d) Use initial concentration-time data to deduce the initial rate of a reaction
e) Use rate-concentration data or graphs to deduce the order (0, 1 or 2) with respect to a
reactant
Application
f) Derive the rate equation for a reaction from the orders with respect to each of the
reactants
g) Use the orders with respect to reactants to provide information about the rate
determining/limiting step of a reaction
h) Measuring the rate of reaction by:
Practical 7  An initial rate method
 A continuous monitoring method

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