POGIL Oxidation and Reduction-S-1

Oxidation and Reduction
What happens when electrons are transferred in a chemical reaction?
Why?
Silver tarnishes when it comes in contact with sulfur compounds in the air. Copper gets coated in
beautiful green patina as it ages. Metals rust or corrode in the presence of air and water. Minerals (ionic
compounds) found in ore can be decomposed with the use of electricity to produce pure metals and
nonmetals. All of these reactions are examples of oxidation and reduction, otherwise known as redox
reactions. In this activity you will explore what is happening at the atomic level in redox reactions.
Model 1 – Redox Reactions

Redox Reactions
A. Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s) B. 2I–(aq) + S2O82–(aq) → I2(s) + 2SO42–(aq)
C. 4Fe(s) + 3O2(g) → 2Fe2O3(s) D. 4H+(aq) + MnO4–(aq)+ 3Fe2+(aq) → 3Fe3+(aq)+ MnO2(aq)+ 2H2O(l)
Nonredox Reactions
E. HCl(g) + H2O(l) → H3O+(aq) + Cl–(aq) F. 2NaOH(aq) + H2SO4(aq) → Na2SO4(aq) + 2H2O(l)
G. Ba2+(aq) + 2OH–(aq) → Ba(OH)2(s) H. 2AgNO3(aq) + CaCl2(aq) → Ca(NO3)2(aq) + 2AgCl(s)
1. What two types of reactions are shown in Model 1?
2. Examine the redox and nonredox reactions in Model 1. Is/are there any feature(s) in the redox
reactions that would allow you to identify them as redox reactions? If yes, use specific examples
from Model 1 to support your answer.
Oxidation and Reduction 1

3. In the space under each reaction in Model 1, write the oxidation number for every atom. Divide
the work among your group members. An example is shown here:
4Fe(s) + 3O2(g) → 2Fe2O3(s)
0 0 +3 –2
0 +3 –2
–2
4. Identify any elements that changed oxidation number in the reactions in Model 1. Connect the
starting and ending oxidation numbers with a line. An example is shown here:
4Fe(s) + 3O2(g) → 2Fe2O3(s)
0 0 +3 –2
0 +3 –2
–2
5. Based on the oxidation number analysis you just performed for the reactions in Model 1, are
there any features of the redox reactions that would allow you to identify them as redox reac-
tions? If yes, use specific examples from Model 1 to support your answer.
6. Identify the following reactions as either redox or nonredox using oxidation numbers as evidence.
a. Pb(NO3)2(aq) + 2NaI(aq) → PbI2(s) + 2NaNO3(aq)
b. 2H2O → 2H2 + O2
c. CH4 + 2O2 → 2H2O + CO2
d. HCl + NaOH → H2O + NaCl
2 POGIL™ Activities for High School Chemistry

Read This!
The process of oxidation and reduction can be thought of as a transfer of electrons from one atom to
another. Thus, one atom gives up electrons and the other atom gains them. As a result of this process, the
oxidation numbers of both atoms change. All redox reactions can be divided up into two reactions—an
oxidation half-reaction and a reduction half-reaction. This allows for better understanding of the elec-
tron transfer process.
Model 2 – Half Reactions

A. Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s) B. 2I–(aq) + S2O82–(aq) → I2(s) + 2SO42–(aq)
ox: Zn → Zn2+ + 2e– ox: 2I– → I2 + 2e–
red: Cu2+ + 2e– → Cu red: S2O82– + 2e– → 2SO42–
C. 4Fe(s) + 3O2(g) → 2Fe2O3(s) D. 4H+(aq)+ MnO4–(aq)+ 3Fe2+(aq) → 3Fe3+(aq)+ MnO2(aq)+ 2H2O(l)

ox: Fe → Fe3+ + 3e– ox: Fe2+ → Fe3+ + e–
red: O2 + 4e– → 2O2– red: 4H+ + MnO4– + 3e– → MnO2 + 2H2O
7. What does the “e–“ symbol represent in the oxidation and reduction half-reactions shown in
Model 2?
8. Look at the oxidation half-reactions in Model 2.

a. Which of the following types of particles may undergo oxidation? (Circle all that apply.)
Neutral atoms/molecules Cations Anions
b. Are electrons lost or gained by an atom during the process of oxidation?
c. Does the oxidation number of an atom involved in the process of oxidation increase or
decrease?
9. Look at the examples of reduction in Model 2.

a. Which of the following types of particles undergo reduction? (Circle all that apply.)
Neutral atoms/molecules Cations Anions
b. Are electrons lost or gained by an atom during the process of reduction?
c. Does the oxidation number of an atom involved in the process of reduction increase or
decrease?

10. Consider the word “reduction” as it is used in the English language. In reduction half-reactions,
what is “reduced”? Use the examples in Model 1 to verify your answer.
Read This!
Oxidation occurs when atoms lose electrons. Reduction occurs when atoms gain electrons. These two
processes always occur together. In other words, you can’t just let electrons loose into space—they must
be grabbed by some other atom. Likewise, you can’t just grab electrons from space—they must be taken
from some other atom. An easy way to remember these processes is to remember the phrase “LEO the
lion goes GER.”
LEO = Loss of Electrons is Oxidation GER = Gain of Electrons is Reduction
11. Consider the incomplete half-reactions below.
a. Use oxidation numbers to identify the reactions below as oxidation or reduction.
b. Place the correct number of electrons on the appropriate side of the reaction to complete the
equation.
I2 → 2I– Cr2+ → Cr3+
Sr → Sr2+ ClO2– + H2O → ClO3– + 2H+
12. Consider Reaction A in Model 2. Show that the two half-reactions can be added together to
give the overall redox reaction. Hint: Consider how you would add two equations together in
algebra.

13. Show how the two half-reactions for Reaction B in Model 2 can be added together to give the
overall redox reaction.
14. Recall that the same number of electrons that are lost by atoms during oxidation must be gained
by atoms during reduction. Show how the half-reactions for Reactions C and D in Model 2 can
be added together to give the overall redox reactions shown.

Extension Questions
15. Are electrons conserved in redox reactions? Explain.
16. When iron is exposed to oxygen, it forms rust as described by the following equation. In this
reaction oxygen is acting as the oxidizing agent.
4Fe(s) + 3O2(g) → 2Fe2O3(s)
a. What element was oxidized in the reaction above?
b. Explain why oxygen is considered the oxidizing agent in this reaction? Hint: Consider the
purpose of an “insurance agent” or a “real estate agent.”
c. What is the reducing agent in the reaction above? Explain.

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Oxidation and Reduction

What happens when electrons are transferred in a chemical reaction?

Model 1 – Redox Reactions

C. 4Fe(s) + 3O2(g) → 2Fe2O3(s) D. 4H+(aq) + MnO4–(aq)+ 3Fe2+(aq) → 3Fe3+(aq)+ MnO2(aq)+ 2H2O(l)

G. Ba2+(aq) + 2OH–(aq) → Ba(OH)2(s) H. 2AgNO3(aq) + CaCl2(aq) → Ca(NO3)2(aq) + 2AgCl(s)

1. What two types of reactions are shown in Model 1?

Oxidation and Reduction 1

c. CH4 + 2O2 → 2H2O + CO2

d. HCl + NaOH → H2O + NaCl

2 POGIL™ Activities for High School Chemistry

Model 2 – Half Reactions

C. 4Fe(s) + 3O2(g) → 2Fe2O3(s) D. 4H+(aq)+ MnO4–(aq)+ 3Fe2+(aq) → 3Fe3+(aq)+ MnO2(aq)+ 2H2O(l)

8. Look at the oxidation half-reactions in Model 2.

9. Look at the examples of reduction in Model 2.

Oxidation and Reduction 3

Sr → Sr2+ ClO2– + H2O → ClO3– + 2H+

4 POGIL™ Activities for High School Chemistry

Oxidation and Reduction 5

c. What is the reducing agent in the reaction above? Explain.

6 POGIL™ Activities for High School Chemistry

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